The title compound（C25H16Cl2N3O3S）,as a thiopyran derivative,has been synthe-sized by the cyclization of an organic intermediate obtained from Baylis-Hillman adducts with a β-aroylthioamide using copper（I） salt a...The title compound（C25H16Cl2N3O3S）,as a thiopyran derivative,has been synthe-sized by the cyclization of an organic intermediate obtained from Baylis-Hillman adducts with a β-aroylthioamide using copper（I） salt as the catalyst.The crystal belongs to the monoclinic system,space group P21/c with a = 13.668（3）,b = 8.4803（17） c = 21.999（4） ,β = 113.57（3）°,V = 2337.2（10） 3,Z = 4,Mr = 510.38,Dc = 1.451 g/cm3,μ = 0.401 mm-1,F（000） = 1048,the final R = 0.0487 and wR = 0.1079 for 3678 observed reflections with I〉 2σ（I）.展开更多
We investigate the electron injection effect of inserting a thin aluminum（Al） layer into cesium carbonate（Cs2CO3）injection layer. Two groups of organic light-emitting devices（OLEDs） are fabricated. For the first...We investigate the electron injection effect of inserting a thin aluminum（Al） layer into cesium carbonate（Cs2CO3）injection layer. Two groups of organic light-emitting devices（OLEDs） are fabricated. For the first group of devices based on Alq3, we insert a thin Al layer of different thickness into Cs2CO3 injection layer, and the device＇s maximum current efficiency of 6.5 cd/A is obtained when the thickness of the thin Al layer is 0.4 nm. However, when the thickness of Al layer is 0.8 nm, the capacity of electron injection is the strongest. To validate the universality of this approach, then we fabricate another group of devices based on another blue emitting material. The maximum current efficiency of the device without and with a thin Al layer is 4.51 cd/A and 4.84 cd/A, respectively. Inserting a thin Al layer of an appropriate thickness into Cs2CO3 layer can result in the reduction of electron injection barrier, enhancement of the electron injection, and improvement of the performance of OLEDs. This can be attributed to the mechanism that thermally evaporated Cs2CO3 decomposes into cesium oxides, the thin Al layer reacts with cesium oxides to form Al–O–Cs complex, and the amount of the Al–O–Cs complex can be controlled by adjusting the thickness of the thin Al layer.展开更多
The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed ...The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed by slow evaporation. The crystal structure was established on the basis of the single crystal X ray diffraction data. Cs 2[Mg(CO 3) 2(H 2O) 4] crystallized in the orthorhombic space group Pbca (No. 61) with a =0.658 4(1) nm, b =1.257 9(1) nm, c =1.301 3(1) nm, \{ V =1.077 8 nm 3, Z =4, D x=2.971 g·cm -3 , μ =69.20 cm -1 , F (000)=888, T =298 K, final R =0.029 and R w=0.024 for 1 037 observed reflections. The crystal consists of Cs + cations and the complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions with each Mg atom coordinated by the six oxygens of two carbonate groups and four water molecules [ d (Mg_O)=0.203 6(4), 0.207 4(4), 0.213 4(4) nm]. The complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions are arranged in a strongly compressed bcc pattern. A 3D network was formed through the intermolecular hydrogen bonds. The Cs + cations are located in cavities, each being surrounded by nine oxygens of five complex anions with d (Cs_O)=0.306 1-0.348 8 nm. The CO 2- 3 group reveals a lowering of D 3h symmetry due to site and coordination effects, but not any observable deviation from co planarity [ d (C_O)=0.127 2(6), 0.127 5(7) , 0.130 5(6) nm and O_C_O=119.6(5)°, 120.1(5)°, 120.4(5)°].展开更多
The phase diagrams of the CH3CH2OH-Cs2CO3-H2O system were determined at 10, 30 and 50 ℃, respectively. It was found that the effect of the temperature on the phase equilibrium was insignificant within the investigate...The phase diagrams of the CH3CH2OH-Cs2CO3-H2O system were determined at 10, 30 and 50 ℃, respectively. It was found that the effect of the temperature on the phase equilibrium was insignificant within the investigated range. The binodal curves were given using a five-parameter equation and the tie lines were fitted using the Oth-mer-Tobias and Bancroft correlations. Correlation coefficients (R) for all equations exceeded 0.99. Samples of the solid phase at 30 ℃ were analyzed by TGA showing that it consisted of Cs2CO3·3.5H2O. The refractive index of the systems was also determined.展开更多
Phase behavior and extraction ability of aqueous two-phase systems（ATPs） consisting of ionic liquids（ILs）, Cs2CO3 and water were investigated in this paper. Four kinds of ionic liquids, namely, 1-amyl-3-methylimid...Phase behavior and extraction ability of aqueous two-phase systems（ATPs） consisting of ionic liquids（ILs）, Cs2CO3 and water were investigated in this paper. Four kinds of ionic liquids, namely, 1-amyl-3-methylimidazolium bromide（[Csmim]Br）, 1-hexyl-3-methylimidazolium bromide（[C6nim]Br）, 1-heptyl-3-methylimidazolium bromide （[C7mim]Br） and 1-octyl-3-methylimidazolium bromide（[C8mim]Br）, were examined to discuss the influence of alkyl groups. Binodal curves and tie-lines at 288.15, 298.15 and 308.15 K were obtained. The partitioning behavior for L-tryptophan in such ATPs was further investigated. The effect of temperature, pH, Cs2CO3 concentration and the structure of ionic liquids on the partitioning were discussed in detail.展开更多
基金supported by the National Natural Science Foundation of China (No. 20872074 and 21072110)the Natural Science Foundation of Shandong Province (No. Z2008B03 and ZR2010BM007)the Doctoral Foundation of Qingdao University of Science and Technology
文摘The title compound（C25H16Cl2N3O3S）,as a thiopyran derivative,has been synthe-sized by the cyclization of an organic intermediate obtained from Baylis-Hillman adducts with a β-aroylthioamide using copper（I） salt as the catalyst.The crystal belongs to the monoclinic system,space group P21/c with a = 13.668（3）,b = 8.4803（17） c = 21.999（4） ,β = 113.57（3）°,V = 2337.2（10） 3,Z = 4,Mr = 510.38,Dc = 1.451 g/cm3,μ = 0.401 mm-1,F（000） = 1048,the final R = 0.0487 and wR = 0.1079 for 3678 observed reflections with I〉 2σ（I）.
基金supported by the National Natural Science Foundation of China(Grant No.60906022)the Natural Science Foundation of Tianjin,China(Grant No.10JCYBJC01100)+2 种基金the Scientific Developing Foundation of Tianjin Education Commission,China(Grant No.2011ZD02)the Key Science and Technology Support Program of Tianjin,China(Grant No.14ZCZDGX00006)the National High Technology Research and Development Program of China(Grant No.2013AA014201)
文摘We investigate the electron injection effect of inserting a thin aluminum（Al） layer into cesium carbonate（Cs2CO3）injection layer. Two groups of organic light-emitting devices（OLEDs） are fabricated. For the first group of devices based on Alq3, we insert a thin Al layer of different thickness into Cs2CO3 injection layer, and the device＇s maximum current efficiency of 6.5 cd/A is obtained when the thickness of the thin Al layer is 0.4 nm. However, when the thickness of Al layer is 0.8 nm, the capacity of electron injection is the strongest. To validate the universality of this approach, then we fabricate another group of devices based on another blue emitting material. The maximum current efficiency of the device without and with a thin Al layer is 4.51 cd/A and 4.84 cd/A, respectively. Inserting a thin Al layer of an appropriate thickness into Cs2CO3 layer can result in the reduction of electron injection barrier, enhancement of the electron injection, and improvement of the performance of OLEDs. This can be attributed to the mechanism that thermally evaporated Cs2CO3 decomposes into cesium oxides, the thin Al layer reacts with cesium oxides to form Al–O–Cs complex, and the amount of the Al–O–Cs complex can be controlled by adjusting the thickness of the thin Al layer.
基金supported by the National Natural Science Foundation of China(60906022,60676051)Natural Science Foundation of Tianjin, China(10JCYBJC01100)+1 种基金Scientific Developing Foundation of Tianjin Education Commission,China(2011ZD02)Jiangsu Natural Science Development Foundation for University,China(09KJB140006)~~
文摘The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed by slow evaporation. The crystal structure was established on the basis of the single crystal X ray diffraction data. Cs 2[Mg(CO 3) 2(H 2O) 4] crystallized in the orthorhombic space group Pbca (No. 61) with a =0.658 4(1) nm, b =1.257 9(1) nm, c =1.301 3(1) nm, \{ V =1.077 8 nm 3, Z =4, D x=2.971 g·cm -3 , μ =69.20 cm -1 , F (000)=888, T =298 K, final R =0.029 and R w=0.024 for 1 037 observed reflections. The crystal consists of Cs + cations and the complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions with each Mg atom coordinated by the six oxygens of two carbonate groups and four water molecules [ d (Mg_O)=0.203 6(4), 0.207 4(4), 0.213 4(4) nm]. The complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions are arranged in a strongly compressed bcc pattern. A 3D network was formed through the intermolecular hydrogen bonds. The Cs + cations are located in cavities, each being surrounded by nine oxygens of five complex anions with d (Cs_O)=0.306 1-0.348 8 nm. The CO 2- 3 group reveals a lowering of D 3h symmetry due to site and coordination effects, but not any observable deviation from co planarity [ d (C_O)=0.127 2(6), 0.127 5(7) , 0.130 5(6) nm and O_C_O=119.6(5)°, 120.1(5)°, 120.4(5)°].
基金the National Natural Science Foundation of China (No. 20171032).
文摘The phase diagrams of the CH3CH2OH-Cs2CO3-H2O system were determined at 10, 30 and 50 ℃, respectively. It was found that the effect of the temperature on the phase equilibrium was insignificant within the investigated range. The binodal curves were given using a five-parameter equation and the tie lines were fitted using the Oth-mer-Tobias and Bancroft correlations. Correlation coefficients (R) for all equations exceeded 0.99. Samples of the solid phase at 30 ℃ were analyzed by TGA showing that it consisted of Cs2CO3·3.5H2O. The refractive index of the systems was also determined.
基金Supported by the National Natural Science Foundation of China（No.21571120） and the Fundamental Research Funds for the Central Universities, China（No.GK201701003）.
文摘Phase behavior and extraction ability of aqueous two-phase systems（ATPs） consisting of ionic liquids（ILs）, Cs2CO3 and water were investigated in this paper. Four kinds of ionic liquids, namely, 1-amyl-3-methylimidazolium bromide（[Csmim]Br）, 1-hexyl-3-methylimidazolium bromide（[C6nim]Br）, 1-heptyl-3-methylimidazolium bromide （[C7mim]Br） and 1-octyl-3-methylimidazolium bromide（[C8mim]Br）, were examined to discuss the influence of alkyl groups. Binodal curves and tie-lines at 288.15, 298.15 and 308.15 K were obtained. The partitioning behavior for L-tryptophan in such ATPs was further investigated. The effect of temperature, pH, Cs2CO3 concentration and the structure of ionic liquids on the partitioning were discussed in detail.
