The crystal and molecular structure of [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH has been determined by X ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with Mr=771.26 (C45H41CuO4P2), a=0.9...The crystal and molecular structure of [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH has been determined by X ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with Mr=771.26 (C45H41CuO4P2), a=0.96413(19)nm, b=1.5780(3)nm, c=2.5426(5)nm, β=100.27(3)°, V=3.8065(13)nm3, The title compound consists of discrete copper? bis(triphenylphosphine) salicylate molecules and ethanol solvate. Each Cu is coordinated to two phosphorus atoms of triphenylphosphine ligands and one of carboxylate oxygens in a trigonal planar geometry. In the solid, the intramolecular hydrogen bond and extensive intermolecular interaction connecting (PPh3)2Cu(O2CPhOH) molecules and ethanol solvate form hydrogen bonds network which stabilize the crystal structure. CCDC: 208730.展开更多
文摘The crystal and molecular structure of [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH has been determined by X ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with Mr=771.26 (C45H41CuO4P2), a=0.96413(19)nm, b=1.5780(3)nm, c=2.5426(5)nm, β=100.27(3)°, V=3.8065(13)nm3, The title compound consists of discrete copper? bis(triphenylphosphine) salicylate molecules and ethanol solvate. Each Cu is coordinated to two phosphorus atoms of triphenylphosphine ligands and one of carboxylate oxygens in a trigonal planar geometry. In the solid, the intramolecular hydrogen bond and extensive intermolecular interaction connecting (PPh3)2Cu(O2CPhOH) molecules and ethanol solvate form hydrogen bonds network which stabilize the crystal structure. CCDC: 208730.
