A large specific surface area perovskite-type mixed oxide PbTiO3 supported cupric oxide was synthesized as a catalyst for NO decomposition and characterized by techniques such as XPS, XRD, H2-TPR before and after NO d...A large specific surface area perovskite-type mixed oxide PbTiO3 supported cupric oxide was synthesized as a catalyst for NO decomposition and characterized by techniques such as XPS, XRD, H2-TPR before and after NO decomposition reactions. The catalytic properties were tested with a fix-bed micro-reactor. The results showed that the PbTiO3 was inactive for the reactions, but 1wt % Cu/PbTiO3 catalyst gave fairly good activities for NO decomposition at temperature as low as 473 K. Copper species were found well-dispersed but weakly interacted with the support before NO decomposition, and the NO decomposition caused significant change in the environment of the copper species, which became Cu(Ⅰ)and most probably incorporated into surface crystal lattice of the nano-sized PbTiO3. In NO reaction, a large amount of oxygen atoms from the decomposition of NO penetrated into the nano-sized PbTiO3 support and caused small expansion of crystal lattice. The transport of oxygen between the copper species and the catalyst support may be helpful to speed up the kinetic regeneration of active metal sites from oxygen occupancy and resulted in good catalytic performance.展开更多
在加氢脱硫催化剂中，关于石墨负载的MoS2、Co—Mo—S、Ni—Mo—S和Nj—W—S纳米团簇，高角环形暗场扫描透射电子显微技术（high-angle annular dark field-scanning transmission electron microscope，HAADF-STEM）可以精确的观察到...在加氢脱硫催化剂中，关于石墨负载的MoS2、Co—Mo—S、Ni—Mo—S和Nj—W—S纳米团簇，高角环形暗场扫描透射电子显微技术（high-angle annular dark field-scanning transmission electron microscope，HAADF-STEM）可以精确的观察到纳米团簇的表面形态。展开更多
文摘目的 单原子纳米酶(single-atom nanozyme,SAN)因其高原子利用率及丰富的类酶活性被广泛研究。但是目前大多数SAN活性位点负载量较低,限制了其进一步应用和发展。本研究旨在制备一种高原子负载量的SAN,并对其类酶活性进行系统研究,希望为高负载SAN的制备提供思路,并为SAN在更广泛领域的应用提供理论支持。方法 本研究通过原位锚定策略将金属盐前驱体锚定在氨基化石墨烯量子点框架中,在惰性气体保护下进行高温热解稳定Cu原子和载体之间的化学键,制备出负载量高达7.66%(质量百分比)的高负载Cu单原子纳米酶(high-loading Cu SAN)。此外,以3,3’,5,5’-四甲基联苯胺(TMB)和氮蓝四唑(NBT)为显色剂,评估了high-loading Cu SAN的类过氧化物酶(POD)、类氧化物酶(OXD)及类超氧化物歧化酶(SOD)活性,并与传统金属有机框架锚定法制备的低负载Cu单原子纳米酶(low-loading Cu SAN)作比较。以过氧化氢(H_(2)O_(2))为催化底物,对比研究了高/低负载Cu SAN的类过氧化氢酶(CAT)活性。结果 研究表明,本文制备的高负载Cu SAN的类POD和SOD活性分别是低负载Cu SAN的3.4倍和8.88倍,且表现出类酶催化选择性。结论 本研究为高负载SAN的制备和活性研究提供了思路,为SAN在检测传感、疾病治疗以及环境保护等方面的应用奠定了基础。
文摘A large specific surface area perovskite-type mixed oxide PbTiO3 supported cupric oxide was synthesized as a catalyst for NO decomposition and characterized by techniques such as XPS, XRD, H2-TPR before and after NO decomposition reactions. The catalytic properties were tested with a fix-bed micro-reactor. The results showed that the PbTiO3 was inactive for the reactions, but 1wt % Cu/PbTiO3 catalyst gave fairly good activities for NO decomposition at temperature as low as 473 K. Copper species were found well-dispersed but weakly interacted with the support before NO decomposition, and the NO decomposition caused significant change in the environment of the copper species, which became Cu(Ⅰ)and most probably incorporated into surface crystal lattice of the nano-sized PbTiO3. In NO reaction, a large amount of oxygen atoms from the decomposition of NO penetrated into the nano-sized PbTiO3 support and caused small expansion of crystal lattice. The transport of oxygen between the copper species and the catalyst support may be helpful to speed up the kinetic regeneration of active metal sites from oxygen occupancy and resulted in good catalytic performance.
文摘在加氢脱硫催化剂中，关于石墨负载的MoS2、Co—Mo—S、Ni—Mo—S和Nj—W—S纳米团簇，高角环形暗场扫描透射电子显微技术（high-angle annular dark field-scanning transmission electron microscope，HAADF-STEM）可以精确的观察到纳米团簇的表面形态。
