Si/Cu3Si@C composites encapsulated in CNTs network(SCC-CNTs) were synthesized via the combination of ball-milling and CVD methods. SCC-CNTs consist of conductive Cu3Si, amorphous carbon layer, cross-linked CNTs, and t...Si/Cu3Si@C composites encapsulated in CNTs network(SCC-CNTs) were synthesized via the combination of ball-milling and CVD methods. SCC-CNTs consist of conductive Cu3Si, amorphous carbon layer, cross-linked CNTs, and the etched pores, which can play the synergistic effects on the improvement of electronic conductivity and Li^+ diffusion. The volume expansion of Si anode is also suppressed during the electrochemical process. The SCC-CNTs composites demonstrate a remarkably improved electrochemical performance compared with pure Si, which can deliver a discharge capacity of 2 171 mAh·g^-1 at 0.4 A·g^-1 with ICE of 85.2%, and retain 1197 mAh· g^-1 after 150 cycles. This work provides a facile approach to massively produce the high-performance Si-based anode materials for next-generation LIBs.展开更多
Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displ...Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.展开更多
An unlubricated sliding friction test on C/Cu composite materials is described. The result of the test proves that adhesive wear is the domination. At a certain speed, when the load upon the test block is light, the w...An unlubricated sliding friction test on C/Cu composite materials is described. The result of the test proves that adhesive wear is the domination. At a certain speed, when the load upon the test block is light, the wear rate remains low level and the friction pair has a good antifriction performance. But when the load increases to a certain value, the wear transitions happen, the wear becomes severe.展开更多
Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of ele...Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of electrical current on tribological property of the materials was investigated by using a pin-on-disk friction and wear tester.The results show that the friction coefficient and wear rate of CNTs/Cu composite as well as those of pure Cu bulk increase with increasing the electrical current without exception,and the effect of electrical current is more obvious on tribological property of pure Cu bulk than on that of CNTs/Cu composite;the dominant wear mechanisms are arc erosion wear and plastic flow deformation,respectively;CNTs can improve tribological property of Cu matrix composites with electrical current.展开更多
基金Funded by the National Key R&D Program of China(No.2016YFB0100302)
文摘Si/Cu3Si@C composites encapsulated in CNTs network(SCC-CNTs) were synthesized via the combination of ball-milling and CVD methods. SCC-CNTs consist of conductive Cu3Si, amorphous carbon layer, cross-linked CNTs, and the etched pores, which can play the synergistic effects on the improvement of electronic conductivity and Li^+ diffusion. The volume expansion of Si anode is also suppressed during the electrochemical process. The SCC-CNTs composites demonstrate a remarkably improved electrochemical performance compared with pure Si, which can deliver a discharge capacity of 2 171 mAh·g^-1 at 0.4 A·g^-1 with ICE of 85.2%, and retain 1197 mAh· g^-1 after 150 cycles. This work provides a facile approach to massively produce the high-performance Si-based anode materials for next-generation LIBs.
文摘Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.
文摘An unlubricated sliding friction test on C/Cu composite materials is described. The result of the test proves that adhesive wear is the domination. At a certain speed, when the load upon the test block is light, the wear rate remains low level and the friction pair has a good antifriction performance. But when the load increases to a certain value, the wear transitions happen, the wear becomes severe.
基金Project(2007CB607603)supported by the National Basic Research Program of China
文摘Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of electrical current on tribological property of the materials was investigated by using a pin-on-disk friction and wear tester.The results show that the friction coefficient and wear rate of CNTs/Cu composite as well as those of pure Cu bulk increase with increasing the electrical current without exception,and the effect of electrical current is more obvious on tribological property of pure Cu bulk than on that of CNTs/Cu composite;the dominant wear mechanisms are arc erosion wear and plastic flow deformation,respectively;CNTs can improve tribological property of Cu matrix composites with electrical current.
