High-performance Cu/Graphene composite wire synergistically strengthened by nano Cr_(3)C_(2) phase was directly synthesized via hot press sintering followed by severe cold plastic deformation, using liquid paraffin an...High-performance Cu/Graphene composite wire synergistically strengthened by nano Cr_(3)C_(2) phase was directly synthesized via hot press sintering followed by severe cold plastic deformation, using liquid paraffin and CuCr alloy powder as the raw materials. Since graphene is in situ formed under the catalysis of copper powder during the sintering process, the problem that graphene is easy to agglomerate and difficult to disperse uniformly in the copper matrix has been solved. The nano Cr_(3)C_(2)-particles nailed at the interface favor to improve the interface bonding. The Cu/Graphene composite possesses high electrical conductivity, hardness, and plasticity. The composite wire exhibits high electrical conductivity of 96.93% IACS, great tensile strength of 488MPa, and excellent resistance to softening. Even after annealing at 400℃ for 1 h, the tensile strength can still reach 268 MPa with a conductivity of about 99.14% IACS.The wire's temperature coefficient of resistance(TCR) is largely reduced to 0.0035/℃ due to the complex structure,which leads the wire to present low resistivity at higher temperatures. Such Cu/Graphene composite wire with excellent comprehensive performance has a good application prospect in high-power density motors.展开更多
The preferred internal oxidation of aluminum in Cu Al alloy was used to obtain in situ Al 2O 3/Cu composites. The reinforcement particles were mainly γ Al 2O 3, some θ Al 2O 3 and a little α Al 2O 3. Thermodynamics...The preferred internal oxidation of aluminum in Cu Al alloy was used to obtain in situ Al 2O 3/Cu composites. The reinforcement particles were mainly γ Al 2O 3, some θ Al 2O 3 and a little α Al 2O 3. Thermodynamics analyses show that the chemical reactions are 3Cu 2O+2Al=6Cu+Al 2O 3 or 3CuO+2Al=3Cu+Al 2O 3. A related equilibrium diagram was drawn. The experiments and investigation show that the formation rate of Al 2O 3 was controlled by the diffusion of oxygen in matrix.展开更多
In this paper,diamond/CuCr and diamond/CuB composites were prepared using the pressure infiltration method.The physical property measurement system(PPMS)was adopted to evaluate the thermal conductivity of diamond/Cu a...In this paper,diamond/CuCr and diamond/CuB composites were prepared using the pressure infiltration method.The physical property measurement system(PPMS)was adopted to evaluate the thermal conductivity of diamond/Cu and MoCu composites within the range of100–350 K,and a scanning electron microscope(SEM)was utilized to analyze the microstructure and fracture appearance of the materials.The research indicates that the thermal conductivity of diamond/Cu composite within the range of100–350 K is 2.5–3.0 times that of the existing MoCu material,and the low-temperature thermal conductivity of diamond/Cu composite presents an exponential relationship with the temperature.If B element was added to a Cu matrix and a low-temperature binder was used for prefabricated elements,favorable interfacial adhesion,relatively high interfacial thermal conductivity,and favorable low-temperature heat conduction characteristics would be apparent.展开更多
For electronic packaging applications, Mo/Cu composites with volume fractions of 55%, 60% and 67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and thermal and electric conduction ...For electronic packaging applications, Mo/Cu composites with volume fractions of 55%, 60% and 67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and thermal and electric conduction properties of the Mo/Cu composites were investigated. The results show that Mo particles are homogeneous and uniform, and the Mo-Cu interfaces are clean and free from interfacial reaction products and amorphous layers; the densifications of the Mo/Cu composites are higher than 99%. The thermal conductivities of Mo/Cu composites range from 220 to 270W/(m·℃) and decrease with an increase in volume fraction of Mo content. The thermal conductivities agree well with the predicted values of theoretical models. The electric conductivities of Mo/Cu composites are in the range of 2228MS/m and decrease with the increase of Mo content. The achievement of higher thermal and electric conduction is attributed to the full densities and high purity Mo/Cu composites, which are attained through the cost-effective squeeze-casting technology processes.展开更多
Diamond-copper composites were prepared by powder metallurgy,in which the diamond particles were pre-coated by magnetic sputtering with copper alloy containing a small amount of carbide forming elements(including B,Cr...Diamond-copper composites were prepared by powder metallurgy,in which the diamond particles were pre-coated by magnetic sputtering with copper alloy containing a small amount of carbide forming elements(including B,Cr,Ti,and Si).The influence of the carbide forming element additives on the microstructure and thermal conductivity of diamond composites was investigated.It is found that the composites fabricated with Cu-0.5B coated diamond particles has a relatively higher density and its thermal conductivity approaches 300 W/(m·K).Addition of 0.5%B improves the interfacial bonding and decreases thermal boundary resistance between diamond and Cu,while addition of 1%Cr makes the interfacial layer break away from diamond surface.The actual interfacial thermal conductivity of the composites with Cu-0.5B alloy coated on diamond is much higher than that of the Cu-1Cr layer,which suggests that the intrinsic thermal conductivity of the interfacial layer is an important factor for improving the thermal conductivity of the diamond composites.展开更多
For electronic packaging applications,Mo/Cu composites with volume fractions of 55%-67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and properties of the Mo/Cu composites were in...For electronic packaging applications,Mo/Cu composites with volume fractions of 55%-67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and properties of the Mo/Cu composites were investigated. The results show that Mo particles are homogeneous and uniformly,and the Mo-Cu interfaces are clean and free-from interfacial reaction products and amorphous layers,the densifications of the Mo/Cu composites are higher than 99%. The mean linear coefficients of thermal expansion(20-100 ℃) of Mo/Cu composites range from 7.9 to 9.3×10-6/℃ and decrease with increasing volume fraction of Mo. The experimental coefficients of thermal expansion agree well with predicted values based on Kerner's model. The thermal and electric conductivities of Mo/Cu composites are in range of 220-270 W/(m·℃) and 22-28 MS/m,respectively,and decrease with increasing volume fraction of Mo. The achievement of higher thermal and electric conduction is attributed to the full densities and high purity,which are obtained through the cost-effective squeeze-casting technology processes.展开更多
To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8+20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by las...To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8+20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by laser cladding, respectively. SEM (scanning electron microscopy), EDS (energy dispersive X-ray spectroscopy), XRD (X-ray diffraction) and TEM (transmission electron microscopy) techniques were employed to study the phases of the coatings. The results show that the coatings mainly consist of amorphous phase and different intermetallic compounds. The reason of formation of amorphous phase and the function of SiC particles were explained in details.展开更多
Using the Gleeble-1500 D simulator, the hot deformation behavior and dynamic recrystallization critical conditions of the 10%Ti C/Cu-Al2O3(volume fraction) composite were investigated by compression tests at the tempe...Using the Gleeble-1500 D simulator, the hot deformation behavior and dynamic recrystallization critical conditions of the 10%Ti C/Cu-Al2O3(volume fraction) composite were investigated by compression tests at the temperatures from 450 °C to 850 °C with the strain rates from 0.001 s-1 to 1 s-1. The results show that the softening mechanism of the dynamic recrystallization is a feature of high-temperature flow true stress-strain curves of the composite, and the peak stress increases with the decreasing deformation temperature or the increasing strain rate. The thermal deformation activation energy was calculated as 170.732 k J/mol and the constitutive equation was established. The inflection point in the lnθ-ε curve appears and the minimum value of-(lnθ)/ε-ε curve is presented when the critical state is attained for this composite. The critical strain increases with the increasing strain rate or the decreasing deformation temperature. There is linear relationship between critical strain and peak strain, i.e., εc=0.572εp. The predicting model of critical strain is described by the function of εc=1.062×10-2Z0.0826.展开更多
This paper studied the microstructure evolution of a deformation-processed Cu-7Cr in situ composite prepared by thermo-mechanical processing. The longitudinal and transverse sectional microstructures were analyzed usi...This paper studied the microstructure evolution of a deformation-processed Cu-7Cr in situ composite prepared by thermo-mechanical processing. The longitudinal and transverse sectional microstructures were analyzed using an optical microscope and a scanning electronic microscope. In the longitudinal section, the initially randomly distributed Cr dendrites in the as-cast Cu-7Cr alloy were transformed into the fibres aligned parallel to the drawing axis;the Cr dendrites experienced breaking, flattening and rotating, lapping and merging, and homogenizing and refinement during thermo-mechanical processing. In the transverse section, the initially randomly distributed Cr dendrites in the as-cast Cu-7Cr alloy were changed into the curvy ribbon like fibres;the Cr dendrites underwent breaking, flattening and rotating, folding and twisting, and irregularizing and refinement during thermo-mechanical processing.展开更多
An adequate hardness of MoS2/Cu composites has not been achieved if these materials are applied under the extreme wear conditions. Therefore, Me-reinforced MoS2/Cu composites were prepared by powder metallurgy (P/M)...An adequate hardness of MoS2/Cu composites has not been achieved if these materials are applied under the extreme wear conditions. Therefore, Me-reinforced MoS2/Cu composites were prepared by powder metallurgy (P/M) methods. The electrical sliding wear properties in the absence or presence of Mereinforced MoS2/Cu composites were tested by HST-100 high speed electric-tribometer. The hardness, electrical conductivity, density, and microstmcture of MoS2/Cu composites were observed. Me-reinforcement MoS2/Cu composites are of good electrical conductivity, while the hardness of Mo-reinforcedment MoS2/Cu composites is about 33.3% higher than that of MoS2/Cu composites. With the addition of Me, composites show better wear properties under high speed and large electric current due to the improvement of hardness. The effects of current intensity and sliding velocity on the wear properties of the tested materials are complicated, and the wear mechanisms of MoS2/Cu composites are mainly abrasive wear and adhesive wear with arc erosion.展开更多
基金supported by the National Key Research and Development Program of China under Grant2021YFB2500600the Youth Innovation Promotion Association CAS under Grant2022138+2 种基金the National Natural Science Foundation of China under Grant51901221the Institute of Electrical EngineeringCAS under GrantE155710201 and E155710301。
文摘High-performance Cu/Graphene composite wire synergistically strengthened by nano Cr_(3)C_(2) phase was directly synthesized via hot press sintering followed by severe cold plastic deformation, using liquid paraffin and CuCr alloy powder as the raw materials. Since graphene is in situ formed under the catalysis of copper powder during the sintering process, the problem that graphene is easy to agglomerate and difficult to disperse uniformly in the copper matrix has been solved. The nano Cr_(3)C_(2)-particles nailed at the interface favor to improve the interface bonding. The Cu/Graphene composite possesses high electrical conductivity, hardness, and plasticity. The composite wire exhibits high electrical conductivity of 96.93% IACS, great tensile strength of 488MPa, and excellent resistance to softening. Even after annealing at 400℃ for 1 h, the tensile strength can still reach 268 MPa with a conductivity of about 99.14% IACS.The wire's temperature coefficient of resistance(TCR) is largely reduced to 0.0035/℃ due to the complex structure,which leads the wire to present low resistivity at higher temperatures. Such Cu/Graphene composite wire with excellent comprehensive performance has a good application prospect in high-power density motors.
文摘The preferred internal oxidation of aluminum in Cu Al alloy was used to obtain in situ Al 2O 3/Cu composites. The reinforcement particles were mainly γ Al 2O 3, some θ Al 2O 3 and a little α Al 2O 3. Thermodynamics analyses show that the chemical reactions are 3Cu 2O+2Al=6Cu+Al 2O 3 or 3CuO+2Al=3Cu+Al 2O 3. A related equilibrium diagram was drawn. The experiments and investigation show that the formation rate of Al 2O 3 was controlled by the diffusion of oxygen in matrix.
基金supported by the National Natural Science Foundation of China (No. 50971020)
文摘In this paper,diamond/CuCr and diamond/CuB composites were prepared using the pressure infiltration method.The physical property measurement system(PPMS)was adopted to evaluate the thermal conductivity of diamond/Cu and MoCu composites within the range of100–350 K,and a scanning electron microscope(SEM)was utilized to analyze the microstructure and fracture appearance of the materials.The research indicates that the thermal conductivity of diamond/Cu composite within the range of100–350 K is 2.5–3.0 times that of the existing MoCu material,and the low-temperature thermal conductivity of diamond/Cu composite presents an exponential relationship with the temperature.If B element was added to a Cu matrix and a low-temperature binder was used for prefabricated elements,favorable interfacial adhesion,relatively high interfacial thermal conductivity,and favorable low-temperature heat conduction characteristics would be apparent.
文摘For electronic packaging applications, Mo/Cu composites with volume fractions of 55%, 60% and 67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and thermal and electric conduction properties of the Mo/Cu composites were investigated. The results show that Mo particles are homogeneous and uniform, and the Mo-Cu interfaces are clean and free from interfacial reaction products and amorphous layers; the densifications of the Mo/Cu composites are higher than 99%. The thermal conductivities of Mo/Cu composites range from 220 to 270W/(m·℃) and decrease with an increase in volume fraction of Mo content. The thermal conductivities agree well with the predicted values of theoretical models. The electric conductivities of Mo/Cu composites are in the range of 2228MS/m and decrease with the increase of Mo content. The achievement of higher thermal and electric conduction is attributed to the full densities and high purity Mo/Cu composites, which are attained through the cost-effective squeeze-casting technology processes.
基金Project(82129)supported by the Innovative Foundation of Science and Technology of General Research Institute of Nonferrous Metals,China
文摘Diamond-copper composites were prepared by powder metallurgy,in which the diamond particles were pre-coated by magnetic sputtering with copper alloy containing a small amount of carbide forming elements(including B,Cr,Ti,and Si).The influence of the carbide forming element additives on the microstructure and thermal conductivity of diamond composites was investigated.It is found that the composites fabricated with Cu-0.5B coated diamond particles has a relatively higher density and its thermal conductivity approaches 300 W/(m·K).Addition of 0.5%B improves the interfacial bonding and decreases thermal boundary resistance between diamond and Cu,while addition of 1%Cr makes the interfacial layer break away from diamond surface.The actual interfacial thermal conductivity of the composites with Cu-0.5B alloy coated on diamond is much higher than that of the Cu-1Cr layer,which suggests that the intrinsic thermal conductivity of the interfacial layer is an important factor for improving the thermal conductivity of the diamond composites.
基金Project(2003AA305110) supported by the National Hi-tech Research and Development Program of ChinaProject(2003AA5CG041) supported by the Key-Tech Research and Development Program of Harbin Province, China
文摘For electronic packaging applications,Mo/Cu composites with volume fractions of 55%-67% Mo were fabricated by the patented squeeze-casting technology. The microstructures and properties of the Mo/Cu composites were investigated. The results show that Mo particles are homogeneous and uniformly,and the Mo-Cu interfaces are clean and free-from interfacial reaction products and amorphous layers,the densifications of the Mo/Cu composites are higher than 99%. The mean linear coefficients of thermal expansion(20-100 ℃) of Mo/Cu composites range from 7.9 to 9.3×10-6/℃ and decrease with increasing volume fraction of Mo. The experimental coefficients of thermal expansion agree well with predicted values based on Kerner's model. The thermal and electric conductivities of Mo/Cu composites are in range of 220-270 W/(m·℃) and 22-28 MS/m,respectively,and decrease with increasing volume fraction of Mo. The achievement of higher thermal and electric conduction is attributed to the full densities and high purity,which are obtained through the cost-effective squeeze-casting technology processes.
基金supported by the Open Fund of the State Key Laboratory of Advanced Welding Production Technology in Harbin Institute of Technology,Chinathe Open Fund of the State Key Laboratory of Materials Processing and Die&Mould Technology in Huazhong University of Science and Technology,China
文摘To improve the sliding wear resistance of AZ91D magnesium alloy, Cu-based amorphous composite coatings made of CuaTTi34Zr11Nis and Cu47Ti34Zr11Ni8+20 wt pct SiC powders were fabricated on AZ91D magnesium alloy by laser cladding, respectively. SEM (scanning electron microscopy), EDS (energy dispersive X-ray spectroscopy), XRD (X-ray diffraction) and TEM (transmission electron microscopy) techniques were employed to study the phases of the coatings. The results show that the coatings mainly consist of amorphous phase and different intermetallic compounds. The reason of formation of amorphous phase and the function of SiC particles were explained in details.
基金Project(51101052) supported by the National Natural Science Foundation of China
文摘Using the Gleeble-1500 D simulator, the hot deformation behavior and dynamic recrystallization critical conditions of the 10%Ti C/Cu-Al2O3(volume fraction) composite were investigated by compression tests at the temperatures from 450 °C to 850 °C with the strain rates from 0.001 s-1 to 1 s-1. The results show that the softening mechanism of the dynamic recrystallization is a feature of high-temperature flow true stress-strain curves of the composite, and the peak stress increases with the decreasing deformation temperature or the increasing strain rate. The thermal deformation activation energy was calculated as 170.732 k J/mol and the constitutive equation was established. The inflection point in the lnθ-ε curve appears and the minimum value of-(lnθ)/ε-ε curve is presented when the critical state is attained for this composite. The critical strain increases with the increasing strain rate or the decreasing deformation temperature. There is linear relationship between critical strain and peak strain, i.e., εc=0.572εp. The predicting model of critical strain is described by the function of εc=1.062×10-2Z0.0826.
文摘This paper studied the microstructure evolution of a deformation-processed Cu-7Cr in situ composite prepared by thermo-mechanical processing. The longitudinal and transverse sectional microstructures were analyzed using an optical microscope and a scanning electronic microscope. In the longitudinal section, the initially randomly distributed Cr dendrites in the as-cast Cu-7Cr alloy were transformed into the fibres aligned parallel to the drawing axis;the Cr dendrites experienced breaking, flattening and rotating, lapping and merging, and homogenizing and refinement during thermo-mechanical processing. In the transverse section, the initially randomly distributed Cr dendrites in the as-cast Cu-7Cr alloy were changed into the curvy ribbon like fibres;the Cr dendrites underwent breaking, flattening and rotating, folding and twisting, and irregularizing and refinement during thermo-mechanical processing.
基金The paper was financially supported by the National Natural Science Foundation of China (No. 50741003), Anhui Provincial Natural Science Foundation (No, 070414181) and key project of Science and Technology of Ministry of Education of China (No. 107066).
基金Funded by the National Natural Science Foundation of China(No:51371077)Non-ferrous Metal Generic Technology of Henan Collaborative Innovation Center
文摘An adequate hardness of MoS2/Cu composites has not been achieved if these materials are applied under the extreme wear conditions. Therefore, Me-reinforced MoS2/Cu composites were prepared by powder metallurgy (P/M) methods. The electrical sliding wear properties in the absence or presence of Mereinforced MoS2/Cu composites were tested by HST-100 high speed electric-tribometer. The hardness, electrical conductivity, density, and microstmcture of MoS2/Cu composites were observed. Me-reinforcement MoS2/Cu composites are of good electrical conductivity, while the hardness of Mo-reinforcedment MoS2/Cu composites is about 33.3% higher than that of MoS2/Cu composites. With the addition of Me, composites show better wear properties under high speed and large electric current due to the improvement of hardness. The effects of current intensity and sliding velocity on the wear properties of the tested materials are complicated, and the wear mechanisms of MoS2/Cu composites are mainly abrasive wear and adhesive wear with arc erosion.