The hydrothermal reaction of isonicotinic acid (4-C5H4N-COOH), Cu(ClO4)(2). 6H(2)O and water at 170 degreesC gave the title compound, [Cu(OH)(2)(H2O)(2)(4-C5H4N-COOH)(2)] (1), which was analyzed by single-crystal X-ra...The hydrothermal reaction of isonicotinic acid (4-C5H4N-COOH), Cu(ClO4)(2). 6H(2)O and water at 170 degreesC gave the title compound, [Cu(OH)(2)(H2O)(2)(4-C5H4N-COOH)(2)] (1), which was analyzed by single-crystal X-ray diffraction, The complex crystallizes in triclinic space group PY with unit cell parameters: a = 6.337(2), b = 6.894(3), c = 9.178(3). alpha = 99.40(3), beta = 105.26(3), gamma 108.17(5)degrees, V = 354.1(2)Angstrom (3), Z = 1, C12H16CuN2O8, M-r = 379.81, D-c = 1.791 Mg/m(3), F(000) 197, mu (MoK alpha) = 1.589 mm(-1). The final R and wR are 0.068 and 0.170 for 1249 observed reflections with I greater than or equal to2 sigma (I). The central copper ion is in a distorted octahedron geometry completed by two nitrogen atoms from carboxylic ligand, two oxygen atoms from hydroxyl groups and two oxygen atoms from coordinated water molecules. The intermolecular hydrogen bonding leads to the formation of a three-dimensional supramolecular structure.展开更多
Nano-CuO was prepared by heating nano-Cu2(OH)2CO3 precursors in different calcination temperatures. The precursor was synthesized from water-alcohol mixed solution of Cu(Ac)2 using mixed solution of NaOH and Na2CO3 as...Nano-CuO was prepared by heating nano-Cu2(OH)2CO3 precursors in different calcination temperatures. The precursor was synthesized from water-alcohol mixed solution of Cu(Ac)2 using mixed solution of NaOH and Na2CO3 as precipitants. XRD, FT-IR, TEM, TG-DTA and surface area measurement techniques were used to investigate the properties of the CuO powder. The results show that the spherical, well dispersed nano-CuO powder with the average size of 15 nm and higher catalytic activity for H2O2 decomposition was obtained at 300 ℃. With the increasing of calcination temperature, crystal of CuO grows up, agglomeration of the powder becomes heavier and catalytic activity decreases. FT-IR patterns revealed that the vibration fine structure of Cu-O bond in nano-CuO powder disappears and main absorption is red-shifted with the average size of nano-CuO reducing.展开更多
文摘The hydrothermal reaction of isonicotinic acid (4-C5H4N-COOH), Cu(ClO4)(2). 6H(2)O and water at 170 degreesC gave the title compound, [Cu(OH)(2)(H2O)(2)(4-C5H4N-COOH)(2)] (1), which was analyzed by single-crystal X-ray diffraction, The complex crystallizes in triclinic space group PY with unit cell parameters: a = 6.337(2), b = 6.894(3), c = 9.178(3). alpha = 99.40(3), beta = 105.26(3), gamma 108.17(5)degrees, V = 354.1(2)Angstrom (3), Z = 1, C12H16CuN2O8, M-r = 379.81, D-c = 1.791 Mg/m(3), F(000) 197, mu (MoK alpha) = 1.589 mm(-1). The final R and wR are 0.068 and 0.170 for 1249 observed reflections with I greater than or equal to2 sigma (I). The central copper ion is in a distorted octahedron geometry completed by two nitrogen atoms from carboxylic ligand, two oxygen atoms from hydroxyl groups and two oxygen atoms from coordinated water molecules. The intermolecular hydrogen bonding leads to the formation of a three-dimensional supramolecular structure.
文摘Nano-CuO was prepared by heating nano-Cu2(OH)2CO3 precursors in different calcination temperatures. The precursor was synthesized from water-alcohol mixed solution of Cu(Ac)2 using mixed solution of NaOH and Na2CO3 as precipitants. XRD, FT-IR, TEM, TG-DTA and surface area measurement techniques were used to investigate the properties of the CuO powder. The results show that the spherical, well dispersed nano-CuO powder with the average size of 15 nm and higher catalytic activity for H2O2 decomposition was obtained at 300 ℃. With the increasing of calcination temperature, crystal of CuO grows up, agglomeration of the powder becomes heavier and catalytic activity decreases. FT-IR patterns revealed that the vibration fine structure of Cu-O bond in nano-CuO powder disappears and main absorption is red-shifted with the average size of nano-CuO reducing.
