The Gejiu (个旧) deposit is a superlarge tin-copper polymetallic ore-forming concentration area characterized by excellent metallogenic geological settings and advantageous ore-controlling factors. The deposit displ...The Gejiu (个旧) deposit is a superlarge tin-copper polymetallic ore-forming concentration area characterized by excellent metallogenic geological settings and advantageous ore-controlling factors. The deposit displays diverse mineralization properties due to different minerals and mineral deposit types. Based on the principal metallogenic factors, metallogenic mechanisms, mineralized components, and occurrence of mineral deposits or ore bodies, the Gejiu mineral district can be divided into 2 combinations of metallogenic series, 4 metallogenic series, 8 subseries, and 27 mineral deposit types. Spatial zonality is evident. The distribution regularity of the elements in both plane and section is Be-W, Sn (Cu, Mo, Bi, Be)-Sn, Pb, Ag-Pb, Zn around a granitic intrusion. The metallogenic epoch is mainly concentrated in the late Yanshanian. During this period, large-scale metallogenic processes related to movement caused by tectonics and magmatism occurred, and a series of magmatic hydrothermal deposits formed. The ore-forming processes can be divided into 4 stages: the silicate stage, the oxide stage, the sulphide stage, and the carbonate stage. Based on the orderliness and diversity (in terms of time, space, and genesis) of the mineralization, the authors have developed a comprehensive spectrum of ore deposits in the Gejiu area. This newly proposed diversity of mineralization and the spectrum developed in this work are useful not only for interpreting the genesis of the Gejiu deposit but also for improving mineral exploration in the area, and in particular, for finding large deposits.展开更多
The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic d...The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic deposit is always an interesting topic of research. We used the finite difference method to model the mineralizing process of the chalcopyrite in this region with considering the field geological features, mineralogy and geochemistry. In particular, the modern mineralization theory was used to quantitatively estimate the related chemical reactions associated with the chalcopyrite formation in the Kaerqueka polymetallic deposit. The numerical results indicate that the hydrothermal fluid flow is a key controlling factor of mineralization in this area and the temperature gradient is the driving force of pore-fluid flow. The metallogenic temperature of chalcopyrite in the Kaerqueka polymetallic deposit is between 250 and 350 ℃. The corresponding computational results have been verified by the field observations. It has been further demonstrated that the simulation results of coupled models in the field of emerging computational geosciences can enhance our understanding of the ore-forming processes in this area.展开更多
The Gejiu tin polymetallic deposits are located in the southeastern part of Yunnan Province in China. A detailed electronic microprobe study has been carried out to document geochemical compositions of tourmalines fro...The Gejiu tin polymetallic deposits are located in the southeastern part of Yunnan Province in China. A detailed electronic microprobe study has been carried out to document geochemical compositions of tourmalines from the deposits. The results indicate a systematic change of mineral geochemical compositions, which might be used as a mineral geochemical tracer for post-magmatic hydrothermal fluid, basin fluid and their mixture. The tourmalines from granite are schori with Fe/ (Fe+Mg) ratios of 0.912-1.00 and Na/(Na+Ca) ratios of 0.892-0.981. Tourmalines as an inclusion in quartz from the ore bodies are dravite with Fe/(Fe+Mg) ratios of 0.212-0.519 and Na/(Na+Ca) ratios of 0.786--0.997. Tourmalines from the country rocks are dravite with Fe/(Fe+Mg) ratios of 0.313--0.337 and Na/(Na+Ca) ratio of 0.599-0.723. Tourmalines from cassiterite-tourmaline veins that occur in crannies within the country rocks show distinct optical zoning with alternate occurrence of dravite and schorl, Fe/(Fe+Mg)=0.374-0.843, Na/(Na+Ca)=0.538-0.987. It suggests that schorl in granite and dravite in carbonatite are related to magmatic fluid and basin fluid respectively. When magmatic fluid rose up and entered into crannies of the country rocks, consisting mainly of carbonatite, basin fluid would be constantly added to the magmatic fluid. The two types of fluid were mixed in structural crannies of the sedimentary basin accompanied with periodic geochemical oscillations to form material records in chemical composition zonings of tourmalines.展开更多
The Baoshan Cu-Pb-Zn polymetallic deposit is lied in the central Nanling mineralization zone,and belongs to the junction area of the Chenzhou-Linwu fault zone and the Leiyang-Linwu fault zone.It is a significant part ...The Baoshan Cu-Pb-Zn polymetallic deposit is lied in the central Nanling mineralization zone,and belongs to the junction area of the Chenzhou-Linwu fault zone and the Leiyang-Linwu fault zone.It is a significant part of Nanling polymetallic deposit belt.The outcropping stratas consist of upper Devonian Shetianqiao,Xikuangshan Formation,Lower Carboniferous Menggong’ao,Shidengzi,Ceshui,and Zimenqiao Formation.Igneous rocks in the Baoshan ore area mainly comprise granodiorite porphyry.Furthermore,the radio isotopic age ranges from 123 Ma to 183 Ma,belonging to the early to middle Yanshanian.展开更多
The Lanping Mesozoic—Cenozoic sedimentary basin, situated in the Middle section of the “Sanjiang" (Nujiang—Lancangjiang—Jinshajiang) area in the east margin of the Tibet plateau, is well known for its large p...The Lanping Mesozoic—Cenozoic sedimentary basin, situated in the Middle section of the “Sanjiang" (Nujiang—Lancangjiang—Jinshajiang) area in the east margin of the Tibet plateau, is well known for its large production of base\|metal sulphide deposits. The worldwide famous super\|large Jinding Pb\|Zn deposit is located in the middle of the basin. The evolution history of the Lanping basin since Mesozoic can be divided into six stages, i.e., ①active continental marginal basin (T 1—T 2); ②back\|arc rift basin (T 3—J 1); ③intracontinental depressive basin (J 2—J 3); ④foreland basin (K); ⑤strike\|slipping and mutual thrusting (E 1—E 3); and ⑥strike\|slipping and pull\|apart basin (N 1\|present). Three main types of Ag\|Cu polymetal deposits are recognized in the basin. Deposits of sedimentary exhalation\|hydrothermal reworking origin (type Ⅰ) are hosted chiefly in limestones, dolomitic limestones, and siliceous rocks of the Upper Triassic Sanhedong Formation (T 3 s ) in Sanshan area. Deposits formed through normal chemical sedimentation in closed to semi\|closed environments (type Ⅱ; e.g., Jinman and Baiyangchang) during the depressive and foreland basin stages occur in various horizons of Jurassic and Cretaceous ages. Hydrothermal reworking on deposits of this type during the Himalayan period are locally pronounced, especially in the west margin of the basin near the Lancangjiang thrust fault. The third deposit type in the basin (type Ⅲ; e.g., Baiyangping and Fulongchang) is the Ag\|bearing tetrahedrite vein deposits occurring almost in all Mesozoic—Cenozoic strata, especially in the Cretaceous. Ore minerals formed during synsedimentary periods of types Ⅰ and Ⅱ are relatively simple and dominated by chalcopyrite and bornite, though sphalerite, galena, pyrite, tetrahedrite and pyrite are also present. In the deposits of type Ⅲ as well as in the ores formed during the hydrothermal reworking period in deposits of type Ⅰ and Ⅱ, ore minerals are extremely complicated and characterized by predominant Ag\|bearing tetrahedrite and other complex sulfosalts of Cu\|Ni\|Co\|Fe\|As\|S and Cu\|Bi\|S series. The associated gangue minerals are mainly quartz, siderite, Fe\|dolomite, barite, and celestite.展开更多
A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research & Development A...A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research & Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.展开更多
South China is the most important polymetallic (tungsten, tin, bismuth, copper, silver, antimony, mercury, rare metals, heavy rare earth elements, gold and lead-zinc) province in China. This paper describes the basi...South China is the most important polymetallic (tungsten, tin, bismuth, copper, silver, antimony, mercury, rare metals, heavy rare earth elements, gold and lead-zinc) province in China. This paper describes the basic characteristics of Mesozoic large-scale mineralization in South China. The large-scale mineralization mainly took place in three intervals: 170-150 Ma, 140-126 Ma and 110-80 Ma. Among these the first stage is mainly marked by copper, lead-zinc and tungsten mineralization and the third stage is mainly characterized by tin, gold, silver and uranium mineralization. The stage of 140-126 Ma mainly characterized by tungsten and tin mineralization is a transitional interval from the first to the third stage. In fight of the current research results of the regional tectonic evolution it is proposed that the large-scale mineralization in the three stages is related to post-collision between the South China block and the North China block, transfer of the principal stress-field of tectonic regimes from N-S to E-W direction, and multiple back-arc lithospheric extensions caused by subduction of the Paleo-Pacific plate.展开更多
The Lanping sedimentary basin has experienced a five-stage evolution since the late Paleozoic: ocean-continent transformation (late Paleozoic to early mid-Triassic); intracontinental rift basin (late mid-Triassic ...The Lanping sedimentary basin has experienced a five-stage evolution since the late Paleozoic: ocean-continent transformation (late Paleozoic to early mid-Triassic); intracontinental rift basin (late mid-Triassic to early Jurassic); down-warped basin (middle to late Jurassic); foreland basin (Cretaceous); and strike-slip basin (Cenozoic). Three major genetic types of Ag-Cu polymetallic ore deposits, including the reworked hydrothermal sedimentary, sedimentary-hydrothermally reworked and hydrothermal vein types, are considered to be the products of basin fluid activity at specific sedimentary-tectonic evolutionary stages. Tectonic differences of the different evolutionary stages resulted in considerable discrepancy in the mechanisms of formation-transportation, migration direction and emplacement processes of the basin fluids, thus causing differences in mineralization styles as well as in genetic types of ore deposit.展开更多
The development of 3D geological models involves the integration of large amounts of geological data,as well as additional accessible proprietary lithological, structural,geochemical,geophysical,and borehole data.Luan...The development of 3D geological models involves the integration of large amounts of geological data,as well as additional accessible proprietary lithological, structural,geochemical,geophysical,and borehole data.Luanchuan,the case study area,southwestern Henan Province,is an important molybdenum-tungsten -lead-zinc polymetallic belt in China.展开更多
Aftabrou polymetallic prospect is located at the contact of Oligo-Miocene calcalkaline granodioritic to dioritic and Eocene andesitic to basaltic volcanic complex in middle section of Urumiyeh-Dokhtar volcanic arc in ...Aftabrou polymetallic prospect is located at the contact of Oligo-Miocene calcalkaline granodioritic to dioritic and Eocene andesitic to basaltic volcanic complex in middle section of Urumiyeh-Dokhtar volcanic arc in NW of Saveh city. Petrographic study indicated that the volcanic rocks are mostly: lava and tuff. Composition of lavas is mainly andesite and tuffs are mainly composed of dacite to rhyodacite. Major phenocrysts in these rocks are plagioclase, clinopyroxene, hornblende and opac minerals. Petrographic and geochemical studies indicated an I-type granitoid and, calcalkaline magmatism associated with continental margin of subduction zone. This study determined three mineralization subzones of 0.2% - 5.3% Cu, 0.02 - 1.31 ppm Au and 1.2% - 3.9% Zn. Fluid inclusion studies on quartzic veins associated with magmatism, demonstrated that homogenization temperatures of this mineralization fluid are between 170°C to 330°C, the salinity of the system is between 11.7 to 23.5 weight percent, density of this fluid is 0.8 - 1.1 g/cm3 and is occurred in depth of less than 1800 m of surface. Fluid inclusion studies suggested that formation of mineral deposit is simple cooling and mixing with atmospheric water and type of Aftabrou deposit is IOCG. In this base, it is assumed that this IOCG mineralization is occurred associate with magmatism that is formed as a result of Neo-Tethys oceanic subduction beneath the Central Iran zone which is replaced in the Orumieh-Dokhtar magmatic arc.展开更多
The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic ...The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic composition is a calc-alkaline pluton, intrusion of which is responsible for the formation of the Sn-Pb-Zn polymetallic deposit through providing thermodynamic condition and ore-forming material. The long-active basement rifts initially formed in the Jinning period and the domal structure with induced secondary order faults formed by emplacement of the pluton, such as ring-detachment fault, top-detachment fault and joint fissure, act as the passage-way for magma and ore-forming fluid and impounding structure for ore deposit. The magma to form the pluton with DI>90 is intensively differentiated. The variation of the ore-forming fluid in composition with falling in temperature caused by action of magmatic hydrothermal convection system combined with groundwater convection system attributes to mineralization of various types in the orefield. The mineralization process can be divided into six stages, i.e., greisenization, skarnization of early stage, fluorite-stanniferous silication stage, skarnization of advanced stage, quartz and cassiterite-sulfuration stage and carbonation stage. The mineral assemblages formed in different mineralization stages are different owing to temperature changing and may be overlapped in space. Malayaite is recognized from the mineral assemblage formed in the fluorite-stanniferous silication stage. The ores in the Pengshan Sn-Pb-Zn polymetallic deposit are spatially zoned with variation from As-Sn mineral assemblage of high temperature in the inner zone through Sn-Pb and Pb-Zn-Ag mineral assemblage of middle temperature in the middle zone to fluorite mineral assemblage of low temperature in the outer zone. The exchanging of Sn, Mg and Fe between biotite and hydrothermal fluid resulted from variation of physicochemical condition during evolution processes of the hydrothermal fluid and its role in mineralization are also discussed in this paper.展开更多
A polymetallic zone dominated by U-W mineralization was found in NortheastGuangxi. Distributed along the east contact zone of a complex granite mass, it extends forabout 100 km in length, with more than fifty deposits...A polymetallic zone dominated by U-W mineralization was found in NortheastGuangxi. Distributed along the east contact zone of a complex granite mass, it extends forabout 100 km in length, with more than fifty deposits and prospects embraced. The depositsshow a wide range of genetic types, related to the granite, from magmatic (including peg-matite and skarn deposits) through hydrothermal mineralizations (hypo-, meso- and epither-mal) all the way to tin placers, constituting a very intact metallogenetic series of granites. Theepithermal U-W deposits are considered as a new type for their unique geological and geochemi-cal characters, such as the paragenesis of U and W and the large time gap (>40 Ma) betweenore and granite.展开更多
文摘The Gejiu (个旧) deposit is a superlarge tin-copper polymetallic ore-forming concentration area characterized by excellent metallogenic geological settings and advantageous ore-controlling factors. The deposit displays diverse mineralization properties due to different minerals and mineral deposit types. Based on the principal metallogenic factors, metallogenic mechanisms, mineralized components, and occurrence of mineral deposits or ore bodies, the Gejiu mineral district can be divided into 2 combinations of metallogenic series, 4 metallogenic series, 8 subseries, and 27 mineral deposit types. Spatial zonality is evident. The distribution regularity of the elements in both plane and section is Be-W, Sn (Cu, Mo, Bi, Be)-Sn, Pb, Ag-Pb, Zn around a granitic intrusion. The metallogenic epoch is mainly concentrated in the late Yanshanian. During this period, large-scale metallogenic processes related to movement caused by tectonics and magmatism occurred, and a series of magmatic hydrothermal deposits formed. The ore-forming processes can be divided into 4 stages: the silicate stage, the oxide stage, the sulphide stage, and the carbonate stage. Based on the orderliness and diversity (in terms of time, space, and genesis) of the mineralization, the authors have developed a comprehensive spectrum of ore deposits in the Gejiu area. This newly proposed diversity of mineralization and the spectrum developed in this work are useful not only for interpreting the genesis of the Gejiu deposit but also for improving mineral exploration in the area, and in particular, for finding large deposits.
基金Project(2017YFC0601503)supported by the National Key R&D Program of ChinaProjects(41872249,41472302,41772348)supported by the National Natural Science Foundation of China
文摘The Kaerqueka polymetallic deposit, Qinghai, China, is one of the typical skarn-type polymetallic ore deposits in the Qimantage metallogenic belt. The dynamic mechanism on the formation of the Kaerqueka polymetallic deposit is always an interesting topic of research. We used the finite difference method to model the mineralizing process of the chalcopyrite in this region with considering the field geological features, mineralogy and geochemistry. In particular, the modern mineralization theory was used to quantitatively estimate the related chemical reactions associated with the chalcopyrite formation in the Kaerqueka polymetallic deposit. The numerical results indicate that the hydrothermal fluid flow is a key controlling factor of mineralization in this area and the temperature gradient is the driving force of pore-fluid flow. The metallogenic temperature of chalcopyrite in the Kaerqueka polymetallic deposit is between 250 and 350 ℃. The corresponding computational results have been verified by the field observations. It has been further demonstrated that the simulation results of coupled models in the field of emerging computational geosciences can enhance our understanding of the ore-forming processes in this area.
基金supported by "Technology of Comprehensive Prospecting and Exploitability for Elements in Crisis Mines" (Grant No. 2008EG115074)a special fund managed by the Ministry of Science and Technology for technical R&D of scientific research institutions, and the Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences
文摘The Gejiu tin polymetallic deposits are located in the southeastern part of Yunnan Province in China. A detailed electronic microprobe study has been carried out to document geochemical compositions of tourmalines from the deposits. The results indicate a systematic change of mineral geochemical compositions, which might be used as a mineral geochemical tracer for post-magmatic hydrothermal fluid, basin fluid and their mixture. The tourmalines from granite are schori with Fe/ (Fe+Mg) ratios of 0.912-1.00 and Na/(Na+Ca) ratios of 0.892-0.981. Tourmalines as an inclusion in quartz from the ore bodies are dravite with Fe/(Fe+Mg) ratios of 0.212-0.519 and Na/(Na+Ca) ratios of 0.786--0.997. Tourmalines from the country rocks are dravite with Fe/(Fe+Mg) ratios of 0.313--0.337 and Na/(Na+Ca) ratio of 0.599-0.723. Tourmalines from cassiterite-tourmaline veins that occur in crannies within the country rocks show distinct optical zoning with alternate occurrence of dravite and schorl, Fe/(Fe+Mg)=0.374-0.843, Na/(Na+Ca)=0.538-0.987. It suggests that schorl in granite and dravite in carbonatite are related to magmatic fluid and basin fluid respectively. When magmatic fluid rose up and entered into crannies of the country rocks, consisting mainly of carbonatite, basin fluid would be constantly added to the magmatic fluid. The two types of fluid were mixed in structural crannies of the sedimentary basin accompanied with periodic geochemical oscillations to form material records in chemical composition zonings of tourmalines.
基金Supported by the Program of Superseding Resources Prospecting in Crisis Mines in China(20089927)
文摘The Baoshan Cu-Pb-Zn polymetallic deposit is lied in the central Nanling mineralization zone,and belongs to the junction area of the Chenzhou-Linwu fault zone and the Leiyang-Linwu fault zone.It is a significant part of Nanling polymetallic deposit belt.The outcropping stratas consist of upper Devonian Shetianqiao,Xikuangshan Formation,Lower Carboniferous Menggong’ao,Shidengzi,Ceshui,and Zimenqiao Formation.Igneous rocks in the Baoshan ore area mainly comprise granodiorite porphyry.Furthermore,the radio isotopic age ranges from 123 Ma to 183 Ma,belonging to the early to middle Yanshanian.
文摘The Lanping Mesozoic—Cenozoic sedimentary basin, situated in the Middle section of the “Sanjiang" (Nujiang—Lancangjiang—Jinshajiang) area in the east margin of the Tibet plateau, is well known for its large production of base\|metal sulphide deposits. The worldwide famous super\|large Jinding Pb\|Zn deposit is located in the middle of the basin. The evolution history of the Lanping basin since Mesozoic can be divided into six stages, i.e., ①active continental marginal basin (T 1—T 2); ②back\|arc rift basin (T 3—J 1); ③intracontinental depressive basin (J 2—J 3); ④foreland basin (K); ⑤strike\|slipping and mutual thrusting (E 1—E 3); and ⑥strike\|slipping and pull\|apart basin (N 1\|present). Three main types of Ag\|Cu polymetal deposits are recognized in the basin. Deposits of sedimentary exhalation\|hydrothermal reworking origin (type Ⅰ) are hosted chiefly in limestones, dolomitic limestones, and siliceous rocks of the Upper Triassic Sanhedong Formation (T 3 s ) in Sanshan area. Deposits formed through normal chemical sedimentation in closed to semi\|closed environments (type Ⅱ; e.g., Jinman and Baiyangchang) during the depressive and foreland basin stages occur in various horizons of Jurassic and Cretaceous ages. Hydrothermal reworking on deposits of this type during the Himalayan period are locally pronounced, especially in the west margin of the basin near the Lancangjiang thrust fault. The third deposit type in the basin (type Ⅲ; e.g., Baiyangping and Fulongchang) is the Ag\|bearing tetrahedrite vein deposits occurring almost in all Mesozoic—Cenozoic strata, especially in the Cretaceous. Ore minerals formed during synsedimentary periods of types Ⅰ and Ⅱ are relatively simple and dominated by chalcopyrite and bornite, though sphalerite, galena, pyrite, tetrahedrite and pyrite are also present. In the deposits of type Ⅲ as well as in the ores formed during the hydrothermal reworking period in deposits of type Ⅰ and Ⅱ, ore minerals are extremely complicated and characterized by predominant Ag\|bearing tetrahedrite and other complex sulfosalts of Cu\|Ni\|Co\|Fe\|As\|S and Cu\|Bi\|S series. The associated gangue minerals are mainly quartz, siderite, Fe\|dolomite, barite, and celestite.
基金The National Basic Research Program(973 Program)of China under contract No.2013CB429702the National Oceanic Major Project of 12th Five Year under contract No.DY125-11-R-05
文摘A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research & Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.
文摘South China is the most important polymetallic (tungsten, tin, bismuth, copper, silver, antimony, mercury, rare metals, heavy rare earth elements, gold and lead-zinc) province in China. This paper describes the basic characteristics of Mesozoic large-scale mineralization in South China. The large-scale mineralization mainly took place in three intervals: 170-150 Ma, 140-126 Ma and 110-80 Ma. Among these the first stage is mainly marked by copper, lead-zinc and tungsten mineralization and the third stage is mainly characterized by tin, gold, silver and uranium mineralization. The stage of 140-126 Ma mainly characterized by tungsten and tin mineralization is a transitional interval from the first to the third stage. In fight of the current research results of the regional tectonic evolution it is proposed that the large-scale mineralization in the three stages is related to post-collision between the South China block and the North China block, transfer of the principal stress-field of tectonic regimes from N-S to E-W direction, and multiple back-arc lithospheric extensions caused by subduction of the Paleo-Pacific plate.
基金supported by the National Natural Science Foundation of China under the grants 40573031 and 40772060the 973 National Basic Research Priorities Program(2006CB701402)+1 种基金the 111 Project(No.B07011)of the Ministry of Educationthe State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences under grant no.GPMR0531
文摘The Lanping sedimentary basin has experienced a five-stage evolution since the late Paleozoic: ocean-continent transformation (late Paleozoic to early mid-Triassic); intracontinental rift basin (late mid-Triassic to early Jurassic); down-warped basin (middle to late Jurassic); foreland basin (Cretaceous); and strike-slip basin (Cenozoic). Three major genetic types of Ag-Cu polymetallic ore deposits, including the reworked hydrothermal sedimentary, sedimentary-hydrothermally reworked and hydrothermal vein types, are considered to be the products of basin fluid activity at specific sedimentary-tectonic evolutionary stages. Tectonic differences of the different evolutionary stages resulted in considerable discrepancy in the mechanisms of formation-transportation, migration direction and emplacement processes of the basin fluids, thus causing differences in mineralization styles as well as in genetic types of ore deposit.
文摘The development of 3D geological models involves the integration of large amounts of geological data,as well as additional accessible proprietary lithological, structural,geochemical,geophysical,and borehole data.Luanchuan,the case study area,southwestern Henan Province,is an important molybdenum-tungsten -lead-zinc polymetallic belt in China.
文摘Aftabrou polymetallic prospect is located at the contact of Oligo-Miocene calcalkaline granodioritic to dioritic and Eocene andesitic to basaltic volcanic complex in middle section of Urumiyeh-Dokhtar volcanic arc in NW of Saveh city. Petrographic study indicated that the volcanic rocks are mostly: lava and tuff. Composition of lavas is mainly andesite and tuffs are mainly composed of dacite to rhyodacite. Major phenocrysts in these rocks are plagioclase, clinopyroxene, hornblende and opac minerals. Petrographic and geochemical studies indicated an I-type granitoid and, calcalkaline magmatism associated with continental margin of subduction zone. This study determined three mineralization subzones of 0.2% - 5.3% Cu, 0.02 - 1.31 ppm Au and 1.2% - 3.9% Zn. Fluid inclusion studies on quartzic veins associated with magmatism, demonstrated that homogenization temperatures of this mineralization fluid are between 170°C to 330°C, the salinity of the system is between 11.7 to 23.5 weight percent, density of this fluid is 0.8 - 1.1 g/cm3 and is occurred in depth of less than 1800 m of surface. Fluid inclusion studies suggested that formation of mineral deposit is simple cooling and mixing with atmospheric water and type of Aftabrou deposit is IOCG. In this base, it is assumed that this IOCG mineralization is occurred associate with magmatism that is formed as a result of Neo-Tethys oceanic subduction beneath the Central Iran zone which is replaced in the Orumieh-Dokhtar magmatic arc.
文摘The Pengshan Sn-Pb-Zn polymetallic orefield is located in the Jiujiang-Ruichang region, which is a segment of the middle-lower Yangtze River metallogenic belt. The Pengshan late Yanshanian buried pluton with granitic composition is a calc-alkaline pluton, intrusion of which is responsible for the formation of the Sn-Pb-Zn polymetallic deposit through providing thermodynamic condition and ore-forming material. The long-active basement rifts initially formed in the Jinning period and the domal structure with induced secondary order faults formed by emplacement of the pluton, such as ring-detachment fault, top-detachment fault and joint fissure, act as the passage-way for magma and ore-forming fluid and impounding structure for ore deposit. The magma to form the pluton with DI>90 is intensively differentiated. The variation of the ore-forming fluid in composition with falling in temperature caused by action of magmatic hydrothermal convection system combined with groundwater convection system attributes to mineralization of various types in the orefield. The mineralization process can be divided into six stages, i.e., greisenization, skarnization of early stage, fluorite-stanniferous silication stage, skarnization of advanced stage, quartz and cassiterite-sulfuration stage and carbonation stage. The mineral assemblages formed in different mineralization stages are different owing to temperature changing and may be overlapped in space. Malayaite is recognized from the mineral assemblage formed in the fluorite-stanniferous silication stage. The ores in the Pengshan Sn-Pb-Zn polymetallic deposit are spatially zoned with variation from As-Sn mineral assemblage of high temperature in the inner zone through Sn-Pb and Pb-Zn-Ag mineral assemblage of middle temperature in the middle zone to fluorite mineral assemblage of low temperature in the outer zone. The exchanging of Sn, Mg and Fe between biotite and hydrothermal fluid resulted from variation of physicochemical condition during evolution processes of the hydrothermal fluid and its role in mineralization are also discussed in this paper.
文摘A polymetallic zone dominated by U-W mineralization was found in NortheastGuangxi. Distributed along the east contact zone of a complex granite mass, it extends forabout 100 km in length, with more than fifty deposits and prospects embraced. The depositsshow a wide range of genetic types, related to the granite, from magmatic (including peg-matite and skarn deposits) through hydrothermal mineralizations (hypo-, meso- and epither-mal) all the way to tin placers, constituting a very intact metallogenetic series of granites. Theepithermal U-W deposits are considered as a new type for their unique geological and geochemi-cal characters, such as the paragenesis of U and W and the large time gap (>40 Ma) betweenore and granite.