Unveiling the cellular microstructure-property relations in martensitic stainless steel via laser powder bed fusion

Laser powder bed fusion(LPBF)is a widely recognized additive manufacturing technology that can fabricate complex components rapidly through layer-by-layer formation.However,there is a paucity of research on the effect of laser scanning speed on the cellular microstructure and mechanical properties of martensitic stainless steel.This study systematically investigated the influence of laser scanning speed on the cellular microstructure and mechanical properties of a developed Fe11Cr8Ni5Co3Mo martensitic stainless steel produced by LPBF.The results show that increasing the laser scanning speed from 400 to 1000 mm/s does not lead to a noticeable change in the phase fraction,but it reduces the average size of the cellular microstructure from 0.60 to 0.35μm.The scanning speeds of 400 and 1000 mm/s both had adverse effects on performances of sample,resulting in inadequate fusion and keyhole defects respectively.The optimal scanning speed for fabricating samples was determined to be 800 mm/s,which obtained the highest room temperature tensile strength and elongation,with the ultimate tensile strength measured at(1088.3±2.0)MPa and the elongation of(16.76±0.10)%.Furthermore,the mechanism of the evolution of surface morphology,defects,and energy input were clarified,and the relationship between cellular microstructure size and mechanical properties was also established.

Simulation of the Behaviour Laws in the Thermal Affected Zones of the 13Cr-4Ni Martensitic Stainless Steel

During the welding, many phenomena occur. The materials deform under the action of residual stresses. This tendency is due to the high gradients of temperature during the process. These deformations are really difficult for many professionals operating in the area. In the goal to predict these variations, one has established the behaviour laws which will be applied to evaluate residual stresses and strains. This research is focused on the study of the Thermal Affected Zone (TAZ) during the welding of the 13Cr-4Ni martensitic stainless steel. The TAZ does not know any change of state (solid/liquid). It only knows the metallurgical phase change (austenite/martensite). There are three types of behaviour laws in this study: thermal, mechanical and metallurgical behaviour laws. The thermal behaviour law serves to evaluate the temperature field which induces the mechanical strains. The mechanical behaviour law serves to evaluate spherical stress (pressure) and deviatoric stress which compose the residual stress. It also helps to measure the total strain. The metallurgical behaviour law serves for the evaluation of the metallurgical phase proportions. To validate the modelling developed in this study, one has made the simulations to compare the results obtained with the analytical and experimental data.

Constitutive modeling of hot deformation behavior of X20Cr13 martensitic stainless steel with strain effect

Hot deformation behavior ofX20Cr13 martensitic stainless steel was investigated by conducting hot compression tests on Gleeble-1500D thermo-mechanical simulator at the temperature ranging from 1173 to 1423 K and the strain rate ranging from 0.001 to 10 s^-1. The material constants of a and n, activation energy Q and A were calculated as a function of strain by a fifth-order polynomial fit. Constitutive models incorporating deformation temperature, strain rate and strain were developed to model the hot deformation behavior of X20Cr13 martensitic stainless steel based on the Arrhenius equation. The predictable efficiency of the developed constitutive models of X20Cr13 martensitic stainless steel was analyzed by correlation coefficient and average absolute relative error which are 0.996 and 3.22%, respectively.

Investigation of modeling on single grit grinding for martensitic stainless steel

Single grit grinding is the simplified model to abstract the macro scale grinding.Finite element analysis is a strong tool to study the physical fields during a single grit grinding process,compared to experimental research.Based on the dynamic mechanical behavior of 2Cr12Ni4Mo3VNbN steel and the mathematical statistics of abrasive grit,modeling of the single grit grinding process was conducted by using commercial software AdvantEdge.The validation experiment was designed to validate the correctness of the FEA model by contrast with grinding force.The validation result shows that the FEA model can well describe the single grit grinding process.Then the grinding force and multi-physics fields were studied by experimental and simulation results.It was found that both the normal and tangential grinding forces were linearly related to the cutting speed and cutting depth.The maximum temperature is located in the subsurface of the workpiece in front of the grit,while the maximum stress and strain are located under the grit tip.The strain rate can reach as high as about 106 s–1 during the single grit grinding,which is larger than other traditional machining operations.

Hydrogen trapping in high strength 0Cr16Ni5Mo martensitic stainless steel

Hydrogen trapping behavior has been investigated by means of thermal desorption spectroscopy(TDS) for a high strength steel after it was tempered at the temperatures of 430 °C, 500 °C and 520 °C, respectively. The loss of ductility was characterized by slow strain rate test(SSRT) and microscopic observation. It shows that with hydrogen charging the fracture feature transfers from ductile to brittle, resulting in the loss of ductility. Undeformed microstructure immediately beneath the fracture surface in charged specimen corresponds to badly ductility compared to the obviously streamline plastic deformation in uncharged specimen. The activation energies for the peaks present in the TDS analysis are calculated for all tested steel and the activation energies for all temperature peaks are similar, corresponding to the similar types of hydrogen traps.

IMPROVEMENT OF MECHANICAL PROPERTIES OF MARTENSITIC STAINLESS STEEL BY PLASMA NITRIDING AT LOW TEMPERATURE

A series of experiments were carried out to study the influence of low temperature plasma nitriding on the mechanical properties of AISI 420 martensitic stainless steel. Plasma nitriding experiments were carried out for 15 h at 350℃ by means of DC- pulsed plasma in 25%N2＋ 75%H2 atmosphere. The microstructure, phase composition, and residual stresses profiles of the nitrided layers were determined by optical microscopy and X-ray diffraction. The microhardness profiles of the nitridied surfaces were also studied. The fatigue life, sliding wear, and erosion wear loss of the untreated specimens and plasma nitriding specimens were determined on the basis of a rotating bending fatigue tester, a ball-on-disc wear tester, and a solid particle erosion tester. The results show that the 350℃ nitrided surface is dominated by c-Fe3N and ON, which is supersaturated nitrogen solid solution. They have high hardness and chemical stabilities. So the low temperature plasma nitriding not only increases the surface hardness values but also improves the wear and erosion resistance. In addition, the fatigue limit of AISI 420 steel can also be improved by plasma nitriding at 350℃ because plasma nitriding produces residual compressive stress inside the modified layer.

Effect of Ni Contents on the Microstructure and Mechanical Properties of Martensitic Stainless Steel Guide Roll by Centrifugal Casting

A novel process based on centrifugal casting was developed to produce martensitic stainless steel for guideroll materials. Centrifugal casting provides a lower production cost and less of the thermal cracking defects which normally occur in the overlaid welding process. In this study, the effects of Ni on the microstructure and mechanical properties of martensitic stainless steel were investigated. The results show that the addition of Ni resulted in a decrease in the volume fraction of delta ferrite and an increase in the volume fraction of the retained austenite, respectively. Moreover, a tensile strength of 1600 MPa with an elongation of 4% were obtained after tempering at 500℃ for 2 h. These values were higher than those obtained by using the conventional overlaid process.

Influence of nitrogen-alloying on the tempering properties of the martensitic stainless steel 00Cr13Ni4Mo

The mechanical and corrosive properties of 00Cr13Ni4Mo （S13 -4N） were tested and compared with those of 00Cr13Ni6Mo （S13 -6）. The effects of nitrogen on the properties of the steels were analyzed. The results of the tensile and corrosion tests show the strength,the ductility,and the pitting corrosion resistance of S13 -4N are higher, lower and poorer than those of S13 -6 respectively, when tempered at a temperature below 550 ℃and vice versa when the tempering temperature is higher than 550℃. The results of the X-ray diffraction （XRD） and the electron backscattered diffraction （EBSD） analyses reveal that inversed austenite appears at 550℃ and the amount of it peaks at 600 ℃ with the best ductility. And the total amount of the inversed austenite in S13 -6 is more than that in S13 -4N in different forms. Nitrogen performs better in terms of stabilizing inversed austenite while nickel is more favorable for forming inversed austenite, the amount and stability of which affect the ductility remarkably. The reason for the embrittlement of S13 -4N at 450℃ can be the result of carbide and nitride precipitating at grain boundaries.

Effect of electroslag remelting on carbides in 8Cr13MoV martensitic stainless steel

The effect of electroslag remelting（ESR） on carbides in 8Cr13MoV martensitic stainless steel was experimentally studied. Phases precipitated from liquid steel during solidification were calculated using the Thermo-Calc software. The carbon segregation was analyzed by original position analysis（OPA）, and the carbides were analyzed by optical microscopy（OM）, scanning electron microscopy（SEM）, energy-dispersive X-ray spectroscopy（EDS） and X-ray diffraction（XRD）. The results indicated that more uniform carbon distribution and less segregation were obtained in the case of samples subjected to the ESR process. After ESR, the amount of netty carbides decreased significantly, and the chromium and vanadium contents in the grain-boundary carbides was reduced. The total area and average size of carbides were obviously smaller after the ESR process. In the sample subjected to ESR, the morphology of carbides changed from lamellar and angular to globular or lump, whereas the types of carbides did not change; both M23C6 and M7C3 were present before and after the ESR process.

Effects of chloride ion concentration and pH values on the corrosion behavio of Cr12Ni3Co12Mo4W ultra-high-strength martensitic stainless steel

The effects of Cl ion concentration and pH values on the corrosion behavior of Cr12Ni3Co12Mo4W ultra-high-strength martensitic stainless steel（UHSMSS） were investigated by a series of electrochemical tests combined with observations by stereology microscopy and scanning electron microscopy. A critical Cl- ion concentration was found to exist（approximately 0.1wt%）, above which pitting occurred. The pitting potential decreased with increasing Cl- ion concentration. A UHSMSS specimen tempered at 600°C exhibited a better pitting corrosion resistance than the one tempered at 400°C. The corrosion current density and passive current density of the UHSMSS tempered at 600°C decreased with increasing pH values of the corrosion solution. The pits developed a shallower dish geometry with increasing polarization potential. A lacy cover on the pits of the UHSMSS tempered at 400°C accelerated pitting, whereas corrosion products deposited in the pits of the UHSMSS tempered at 600°C hindered pitting.

Controlled Laser Transformation Hardening of Martensitic Stainless Steel by Pulsed Nd:YAG Laser

Laser transformation hardening （LTH） was applied to the surface of the AISI 420 martensitic stainless steel by a pulsed Nd：YAG laser to obtain optimum hardness. The influences of process parameters （laser pulse energy, duration time, and travel speed） on the depth and hardness of laser treated area were investigated. Image analysis of SEM microstructure of AISI 420 showed that plate-like carbide have almost fully and （30-40）% of globular carbide particles dissolved into the matrix after laser transformation hardening by pulsed laser and the microstructure was refined to obtain controlled tempered martensite microstructure with 450 VHN hardness.

Fuzzy Modeling of Prediction M_s Temperature for Martensitic Stainless Steel

A method of fuzzy modeling based on fuzzy clustering and Kalman filtering was proposed for predicting M s temperature from chemical composition for martensitic stainless steel. The membership degree of each sample was calculated by the fuzzy clustering algorithm. Kalman filtering was used to identify the consequent parameters. Only Grade 95 steel are available for training and validation, and the fuzzy model is valid for the following element concentration ranges (wt%): 0.01<C<0.7; 0<Si<1.0; 0.10<Mn<1.25; 11.5<Cr< 17.5; 0<Ni<2.5; 0<Mo<1.0. Compared with that of several empirical models reported, the accuracy of the fuzzy model was almost 5 times higher than that of the best empirical model. Furthermore, the compositional dependences of Ms were successfully determined and compared with those of the empirical formulae. It was found that the specific element dependences were a function of the overall composition, something could not easily be found using conventional statistics.

Effect of strain-induced martensitic phase transformation on the formability of nitrogen-alloyed metastable austenitic stainless steels

Strain-induced martensitic phase transformation and its influence on the forrnability of newly developed nitrogen-alloyed metastable austenitic stainless steels were systematically investigated. Yield strength for the as- received steels bearing low nickel content was around 300 MPa and their elongation ratios varied from 55.2% to 61.7%. Erichsen numbers of these samples differed from 13.82 to 14.57 mm. Although its Cu content was lower than that of other samples, steel D2 exhibited better plasticity and formability, which was attributed to ~/--,c~＇ martensitic phase transformation. EBSD, XRD, and magnetism tests showed that increases in deformation ratio gradually increased the α＇ martensite phase of a sample ,thereby contributing to its strain and inducing the optimal transformation-induced plasticity effect. An Meeo/5o temperature of around 20 ℃, which is close to the deformation temperature,provided the austenite with adequate stability and gradually transformed it into martensite, thereby endowing lean ASS with better formability.

Processing maps and hot working mechanisms of supercritical martensitic stainless steel

The hot working mechanism of 2Cr11 MolVNbN steel was investigated by means of compression tests at temperatures of900-1150 ℃ and strain rates of 0.005-5 s^(-1).At strains of 0.2,0.3,0.5 and 0.7,the relationship among strain rate sensitivity,power dissipation efficiency and instability parameter under different conditions were studied.Power dissipation maps and instability maps at different strains were established.The optimal and the instable deformation regimes were established by the processing maps based on the dynamic material model.The processing maps were developed for the typical strains of 0.2,0.3,0.5 and 0.7,predicting the instability regions occurring at high strain rate more than 0.05 s^(-1),which should be avoided during hot deformation.The optimized processing parameters for hot working of 2CrllMolVNbN supercritical stainless steel were temperatures of 1080-1120 ℃ and strain rates of 0.005-0.01 s^(-1).

Effect of heat treatment on the behavior ofδ-ferrite in B410D martensitic stainless steel

The morphology and the evolution of δ-ferrite existing in B410D slabs, hot-rolled plates, annealed plates and quenched plates were studied through metallographic observation. Results show that δ-ferrite forms during the solidification process and that it easily grows and increases in quantity during high temperature annealing. Band-shaped δ-ferrite in hotrolled plates is difficult to be eliminated by conventional heat treatment and hard to recrystallize.

Study on microstructure and mechanical properties of martensitic stainless steel 6Cr15MoV

Martensitic stainless steel containing 12%-18%Cr have high hardness due to high carbon content. These steels are common utilized in quenching and tempering processes for knife and cutlery steel.The properties obtained in these materials are significantly influenced by matrix composition after heat treatment,especially as Cr and C content.Comprehensive considered the hardness and corrosion resistance,a new type martensitic stainless steel 6Cr15MoV has been developed.This study emphatic researches the effect of heat treatment processes on microstructure and mechanical properties of 6Cr15MoV martensitic stainless steel.Thermo-Calc software has been carried out to thermodynamic calculation;optical microscope(OM),scanning electronic microscope(SEM) and transmission electron microscope(TEM) have been carried out to microstructure observation;hardness and impact toughness test have been carried out to evaluate the mechanical properties.Results show that the equilibrium carbide in 6Cr15MoV steel is M_(23),C_6 carbide,and finely distributed of M_(23)C_6 carbides can be observed on annealed microstructure of 6Cr15MoV stainless steel.6Cr15MoV martensitic stainless steel has a wider quenching temperature range,the hardness value of steel 6Cr15MoV can reach to 60.8 -61.6 HRC when quenched at 1060 - 1100℃.Finely distributed carbides will exist in quenched microstructure,and effectively inhabit the growth of austenite grain.With the increasing of quenching temperature,the volume fraction of undissolved carbides will decrease.The excellent comprehensive mechanical properties can be obtained by quenched at 1060-1100℃with tempered at 100-150℃,and it is mainly due to the high carbon martensite and fine grain size.At these temperature ranges,the hardness will retain about 59.2-61.6 HRC and the Charpy U-notch impact toughness will retain about 17.3-20 J.The morphology of impact fracture surface of tested steel is small dimples with a small amount of cleavage planes.The area of cleavage planes increases with the increasing of tempering temperature.

Advanced manufacturing technologies of large martensitic stainless steel castings with ultra low carbon and high cleanliness

The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfeid the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (R p0.2/R m ) ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.

Martensite transformation induced by deformation and its phase electrochemical behavior for stainless steels AISI 304 and 316L

The martensite transformation induced by tensile elongation and its effect onthe behavior of phase electrochemistry of AISI 304 and 316L in 3.5% NaCl solution were studied. Theresults show that the content of α′-martensite in stainless steel 304 increases with the truestrain. As α′-martensite content increased, free corrosion potential and pitting potential ofstainless steel 304 in 3.5% NaCl solution appeared the change trend of a minimum. It was also foundthat pitting nucleated preferentially at the phase interfaces between martensite and austenite.There existed apparent difference between electrochemical properties of austenite and of martensitefor stainless steel 304 and 316L in 3.5% NaCl solution.

Deformation at Room and Low Temperatures and Martensite Transformation in Resistance Spot Welding Duplexγ&α(δ) Materials of 301L Stainless Steel

Transformation induced plasticity （TRIP） and twinning induced plasticity （TWlP） effects had been widely studied in single austenite steel. But in duplex γ ＆ α（δ） phase, such as welding materials of stainless steel, they had been less studied. Tensile shear loading experiment of resistance spot welding specimens prepared with 2 mm 301L sheets, was carried out at 15℃ and -50℃. Optical microscopy and scanning electron microscopy （SEM） as well as X-ray diffraction （XRD） were used to investigate the microstructure of weld nugget, and specimens fracture surface. The results showed that the initial weld nugget was composed of 8.4% α（δ） ferrite and 91.6% austenite. Tensile shear load bearing capacity of spot welding specimen at -50℃ was 24.8 kN, 17.7% higher than that at 15℃. About 78.5 vol. pct. martensite transformation was induced by plastic deformation at -50℃, while about 67.9 vol. pct transformation induced at 15℃. The plasticity of spot welding joint decreased with the decline of experimental temperature.

A short review of antibacterial Cu-bearing stainless steel:antibacterial mechanisms,corrosion resistance,and novel preparation techniques

Cu-bearing stainless steel is widely used in the fields of food,medical and household sanitary equipment because of its surface finish and corrosion resistance.However,the growth of bacteria on stainless steel leads to the formation of biofilms,which causes corrosion.Therefore,the antibacterial property of stainless steel is a worthy research topic.Reviews of breakthroughs in the field of corrosion resistance and antimicrobial properties are still lacking.Herein,due to the scarcity of publications on the antibacterial mechanisms and processing methods of antibacterial Cu-bearing stainless steel,we review the current state of relevant research and progress.The toxicity of Cu,corrosion resistance mechanism of stainless steel,and antibacterial mechanism and preparation method of antibacterial stainless steel are reported.In addition,alloying,surface modification and other methods are found to have limitations in balancing the toxicity and antibacterial properties of copper and the relationship between the antibacterial properties and corrosion resistance of Cu-bearing stainless steel.A new preparation method of antibacterial stainless steel associated with selective laser melting(SLM)is proposed.SLM is becoming a powerful additive manufacturing technology that can be used to manufacture customized and complex metals.The research status of SLM applied in antibacterial stainless steel preparation is described.Finally,the future research direction of Cu-bearing antibacterial stainless steel is discussed.