Two cyano\|bridged complexes {\\-2\[Fe(CN)\-6\]}\-∞(L=NH\-2CH\-2CH\-2CH\-2OH(ampt)(1),NH\-2CH\-2CH(CH\-3)OH(amtt)(2)) and cyanobridged Ni\+Ⅱ\-6Fe\+Ⅱ cluster \[Fe(CN—Ni(tetren))\-6\](ClO\-4)\-8(tetren)(3) were synt...Two cyano\|bridged complexes {\\-2\[Fe(CN)\-6\]}\-∞(L=NH\-2CH\-2CH\-2CH\-2OH(ampt)(1),NH\-2CH\-2CH(CH\-3)OH(amtt)(2)) and cyanobridged Ni\+Ⅱ\-6Fe\+Ⅱ cluster \[Fe(CN—Ni(tetren))\-6\](ClO\-4)\-8(tetren)(3) were synthesized,and have been characterized by elemental analysis and IR spectrum.The experimental results show that the oxide state of Fe is changed from Fe\+Ⅲ to Fe\+Ⅱ after the synthesis reaction.The magnetization versus T and magnetic susceptibility of (2) were measured and showed that the interaction between Cu\+Ⅱ ions separated by diamagnetic low spin Fe\+Ⅱ is weak antiferromagnetic.展开更多
用溶胶-凝胶法制得Cu/Fe2O3-TiO2光催化材料。用XRD、Ram an、TPR、IR、TEM、UV-V is DRS测试技术和光催化反应等对固体材料的结构和性能进行了表征。结果表明,Fe2O3的质量分数为10%时,在TiO2表面以单分子层分散,Fe2O3的引入使TiO2吸光...用溶胶-凝胶法制得Cu/Fe2O3-TiO2光催化材料。用XRD、Ram an、TPR、IR、TEM、UV-V is DRS测试技术和光催化反应等对固体材料的结构和性能进行了表征。结果表明,Fe2O3的质量分数为10%时,在TiO2表面以单分子层分散,Fe2O3的引入使TiO2吸光限蓝移。Fe2O3含量超过单分子层分散时,有晶相Fe2O3生成,光吸收性能下降。Fe—O—Ti键的形成加强了半导体之间的相互作用,有利于光生载流子在半导体间的输送。少量Cu的引入,使复合材料的吸光域向可见光范围扩展。光催化反应性能与材料的光响应能力密切相关。在光催化CO2和CH3NH2直接合成NH2CH2COOH的反应中,负载质量分数为10%Fe2O3的光催化反应性能最优。在120℃、常压、空速200 h-1、CO2与CH3NH2摩尔比为1∶1和6.5×10-4W/cm2的紫外灯照射下,CH3NH2转化率为1.35%,NH2CH2COOH选择性达92.0%。展开更多
基金Project(2013JSJJ0001)supported by Teachers’Research Found,ChinaProject(2013AA032401)supported by the National High Technology Research and Development Program of ChinaProject supported by the Nonferrous Metal Oriented Advanced Structural Materials and Manufacturing Cooperative Innovation Center,China
文摘Two cyano\|bridged complexes {\\-2\[Fe(CN)\-6\]}\-∞(L=NH\-2CH\-2CH\-2CH\-2OH(ampt)(1),NH\-2CH\-2CH(CH\-3)OH(amtt)(2)) and cyanobridged Ni\+Ⅱ\-6Fe\+Ⅱ cluster \[Fe(CN—Ni(tetren))\-6\](ClO\-4)\-8(tetren)(3) were synthesized,and have been characterized by elemental analysis and IR spectrum.The experimental results show that the oxide state of Fe is changed from Fe\+Ⅲ to Fe\+Ⅱ after the synthesis reaction.The magnetization versus T and magnetic susceptibility of (2) were measured and showed that the interaction between Cu\+Ⅱ ions separated by diamagnetic low spin Fe\+Ⅱ is weak antiferromagnetic.
文摘用溶胶-凝胶法制得Cu/Fe2O3-TiO2光催化材料。用XRD、Ram an、TPR、IR、TEM、UV-V is DRS测试技术和光催化反应等对固体材料的结构和性能进行了表征。结果表明,Fe2O3的质量分数为10%时,在TiO2表面以单分子层分散,Fe2O3的引入使TiO2吸光限蓝移。Fe2O3含量超过单分子层分散时,有晶相Fe2O3生成,光吸收性能下降。Fe—O—Ti键的形成加强了半导体之间的相互作用,有利于光生载流子在半导体间的输送。少量Cu的引入,使复合材料的吸光域向可见光范围扩展。光催化反应性能与材料的光响应能力密切相关。在光催化CO2和CH3NH2直接合成NH2CH2COOH的反应中,负载质量分数为10%Fe2O3的光催化反应性能最优。在120℃、常压、空速200 h-1、CO2与CH3NH2摩尔比为1∶1和6.5×10-4W/cm2的紫外灯照射下,CH3NH2转化率为1.35%,NH2CH2COOH选择性达92.0%。