期刊文献+
共找到4篇文章
< 1 >
每页显示 20 50 100
铜改性TiO_(2)/碳纤维膜光热协同催化H_(2)O_(2)脱除燃煤烟气中NO性能
1
作者 杨娟 冷冲冲 +2 位作者 张鸽 单启月 丰之翔 《煤炭学报》 EI CAS CSCD 北大核心 2024年第4期2099-2114,共16页
燃煤电厂排放的烟气中含有大量氮氧化物(NO_(x)),太阳能驱动的光催化技术为烟气脱硝提供了近零排放的新途径,但单一光催化脱硝效率有限,为实现燃煤烟气中高浓度NO的有效脱除,亟需开发基于光催化的协同氧化脱硝技术。采用水热法并结合氢... 燃煤电厂排放的烟气中含有大量氮氧化物(NO_(x)),太阳能驱动的光催化技术为烟气脱硝提供了近零排放的新途径,但单一光催化脱硝效率有限,为实现燃煤烟气中高浓度NO的有效脱除,亟需开发基于光催化的协同氧化脱硝技术。采用水热法并结合氢气还原处理制备了富含氧空位的TiO_(2)纳米片(Defective TiO_(2),D-TiO_(2))后,利用液相浸渍法将铜氧化物(CuO_(x))负载至D-TiO_(2)表面,制得复合样品CuO_(x)/D-TiO_(2)。利用透射电镜(TEM)、X-射线光电子能谱(XPS)、室温电子顺磁共振(EPR)及紫外-可见漫反射光谱等表征技术对复合催化剂的微观组成和能带结构进行测定分析,结果表明,负载的铜物种为混合价态CuO_(x),CuO_(x)改性未影响D-TiO_(2)的微观形貌,但可使D-TiO_(2)的导带电势负移,增强光生电子的还原能力。以CuO_(x)/D-TiO_(2)作为活化H_(2)O_(2)的催化剂,在模拟太阳光照射下考察CuO_(x)负载量对NO脱除率的影响,并以性能最佳的5%CuO_(x)/D-TiO_(2)为光催化剂,研究模拟烟气流速和NO初始体积分数对脱硝活性的影响。基于密度泛函理论的DFT计算结果表明,氧空位有利于NO吸附与活化,光电化学和EPR测试结果表明,复合CuO_(x)不仅增强了D-TiO_(2)的光生电荷分离效率,同时CuO_(x)作为H_(2)O_(2)分解产生·OH的活性位点,起到了助催化剂的关键作用。自由基猝灭实验结果表明,表面·OH是NO光氧化脱除的主要活性自由基,助催化剂CuO_(x)和氧空位的协同作用使NO脱除率由TiO_(2)的15.1%提升至5%CuO_(x)/D-TiO_(2)的63.8%。同时,将5%CuO_(x)/D-TiO_(2)固载至改性碳纤维(MCF)表面构筑了整体式催化剂CuO_(x)/D-TiO_(2)/MCF,MCF载体的光热效应可将吸收的近红外光转化为热,使CuO_(x)/D-TiO_(2)表面产生局部温升,有效加速光电子界面传输与H_(2)O_(2)分解反应动力学,进一步提升NO脱除率达95.2%。此外,NO光氧化脱除的主要产物是可用于生产氮肥的NO_(3)^(-),副产物NO_(2)的质量浓度仅为4.7 mg/m^(3),NO_(2)与残余NO质量浓度均远低于燃煤锅炉NO_(x)质量浓度不超过50 mg/m^(3)的超低排放标准,且该整体式催化剂可在连续操作的工况下净化烟气中高浓度NO。基于CuO_(x)/D-TiO_(2)/MCF的光热协同催化体系在实际工业烟气脱硝与氮资源化利用领域具有良好的应用前景。 展开更多
关键词 NO氧化脱除 光热协同催化 氧空位 cuo_(x) 整体式催化剂
下载PDF
Modulate the superficial structure of La_(2)Ce_(2)O_(7) catalyst with anchoring CuO_(x) species for the selective catalytic oxidation of NH_(3) 被引量:1
2
作者 Xiangchen Kong Zhenguo Li +6 位作者 Yuankai Shao Xiaoning Ren Kaixiang Li Hanming Wu Congjie Lv Cheng Lv Shengli Zhu 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第16期1-8,共8页
Air contamination caused by the ammonia slip phenomenon has gradually captured the researcher’s extensive attention.An effective strategy for controlling fugitive NH_(2)is critical to improving the air quality and li... Air contamination caused by the ammonia slip phenomenon has gradually captured the researcher’s extensive attention.An effective strategy for controlling fugitive NH_(2)is critical to improving the air quality and living environment.In the present work,CuO_(x)/La_(2)Ce_(2)O_(7)composite as a potential candidate catalyst is synthesized through the electrostatic adsorption method for the selective catalytic oxidation(SCO_(2))of NH_(2)to N.The 5%Cu Ox/La_(2)Ce_(2)O_(7)exhibits the best catalytic activity(T=243℃)and ammonia conversion efficiency.The improvement of performance is mainly attributed to the superficial connection of[Ce-O-Cu],which enhances the capturing ability of ammonia molecule and accelerates the dissociating efficiency of N–H bonding for Nevolution,simultaneously.This work provides a facile method to synthesis pyrochlore-like composite catalyst of NH_(2)-SCO_(2) for solving the problem of ammonia slip pollution in the future. 展开更多
关键词 La_(2)Ce_(2)O_(7)catalyst Selective catalytic oxidation cuo_(x)species Ammonia slip
原文传递
Synergically regulated silver species and surface oxygen on manganese oxide for promoted activity of formaldehyde oxidation
3
作者 Shuo Hu Jianghao Zhang +3 位作者 Xueyan Chen Xiaoxiao Qin Jinshui Yao Changbin Zhang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第4期709-718,共10页
Formaldehyde(HCHO)is a common indoor pollutant that is detrimental to human health.Its efficient removal has become an urgent demand to reduce the public health risk.In this work,Ag-MnO_(x)-based catalysts were prepar... Formaldehyde(HCHO)is a common indoor pollutant that is detrimental to human health.Its efficient removal has become an urgent demand to reduce the public health risk.In this work,Ag-MnO_(x)-based catalysts were prepared and activated under different atmosphere(i.e.,air,hydrogen(H_(2))and carbon monoxide(CO))for efficient oxidation of HCHO.The catalyst activated with CO(Ag/Mn-CO)displayed the highest activity among the tested samples with 90% conversion at 100℃ under a gas space velocity of 75,000 mL/(g_(cat)·hr).Complementary characterizations demonstrate that CO reduction treatment resulted in synergically regulated content of surface oxygen on support to adsorb/activate HCHO and size of Ag particle to dissociate oxygen to oxidize the adsorbed HCHO.In contrast,other catalysts lack for either abundant surface oxygen species or metallic silver with the appropriate particle size,so that the integrate activity is limited by one specific reaction step.This study contributes to elucidating the mechanisms regulating the oxidation activity of Ag-based catalysts. 展开更多
关键词 HCHO oxidation Ag-MnO_(x)-based catalyst Activation condition Synergic regulation Surface oxygen Oxidized Ag
原文传递
低温等离子体催化水煤气变换反应:催化剂载体的影响 被引量:1
4
作者 李志 杜学森 +3 位作者 汪宇 沈小强 李为 陶亚琴 《工程热物理学报》 EI CAS CSCD 北大核心 2022年第8期2202-2211,共10页
水煤气变换反应是工业上用于提纯H_(2)以及去除CO的重要化学反应。为克服水煤气变换反应低温下动力学的限制,本文建立一种低温等离子体协同铜基催化剂催化水煤气变换反应体系,使得反应能在120℃时进行。通过研究不同载体(Al_(2)O_(3)、C... 水煤气变换反应是工业上用于提纯H_(2)以及去除CO的重要化学反应。为克服水煤气变换反应低温下动力学的限制,本文建立一种低温等离子体协同铜基催化剂催化水煤气变换反应体系,使得反应能在120℃时进行。通过研究不同载体(Al_(2)O_(3)、CeO_(2)、TiO_(2)、SiO_(2)、SAPO-34)负载铜催化剂对等离子体催化的影响后发现,当CuO_(x)/CeO_(2)催化剂同等离子体耦合时,表现出最佳的催化活性,CO转化率57%,氢气产率42%。研究表明,更好的催化性能归因于CuO_(x)/CeO_(2)催化剂表面的氧空位以及数量众多的Cu活性位点,有利于吸附反应物,促使反应的进行。但是载体的比表面积、颗粒尺寸、酸性位点数量,介电常数并不是影响本文实验条件下低温等离子体催化WGS反应的主要因素。 展开更多
关键词 介质阻挡放电 低温等离子体 低温水煤气变换反应 cuo_(x)基催化剂
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部