Chalcostibite(CuSbS2)is composed of earth-abundant elements and has a proper band gap(Eg=1.05 eV)as a thermoelectric(TE)material.Herein,we report the TE properties in the CuSbS2 based composites with a mole ratio of(1...Chalcostibite(CuSbS2)is composed of earth-abundant elements and has a proper band gap(Eg=1.05 eV)as a thermoelectric(TE)material.Herein,we report the TE properties in the CuSbS2 based composites with a mole ratio of(1–x)CuSbS2–x Cu1.8S(x=0,0.1,0.2,0.3),which were prepared by mechanical alloying(MA)combined with spark plasma sintering(SPS).X-ray diffraction(XRD)and back-scattered electron image(BSE)results indicate that a single phase of CuSbS2 is synthesized at x=0 and the samples consist of CuSbS2,Cu3SbS4,and Cu12Sb4S13 at 0.1≤x≤0.3.The correlation between the phase structure,microstructure,and TE transport properties of the bulk samples is established.The electrical conductivity increases from 0.14 to 50.66 S·cm–1 at 723 K and at0≤x≤0.03,while the Seebeck coefficient holds an appropriate value of 190.51μV·K–1.The highest ZT value of 0.17 is obtained at 723 K and at x=0.3 owing to the combination of a high PF183μW·m–1·K–2 and a lowκ0.8 W·m–1·K–1.展开更多
基金supported by National Key R&D Program of China (Grant No. 2018YFB0703600)the National Natural Science Foundation of China (Grant No. 11474176)
文摘Chalcostibite(CuSbS2)is composed of earth-abundant elements and has a proper band gap(Eg=1.05 eV)as a thermoelectric(TE)material.Herein,we report the TE properties in the CuSbS2 based composites with a mole ratio of(1–x)CuSbS2–x Cu1.8S(x=0,0.1,0.2,0.3),which were prepared by mechanical alloying(MA)combined with spark plasma sintering(SPS).X-ray diffraction(XRD)and back-scattered electron image(BSE)results indicate that a single phase of CuSbS2 is synthesized at x=0 and the samples consist of CuSbS2,Cu3SbS4,and Cu12Sb4S13 at 0.1≤x≤0.3.The correlation between the phase structure,microstructure,and TE transport properties of the bulk samples is established.The electrical conductivity increases from 0.14 to 50.66 S·cm–1 at 723 K and at0≤x≤0.03,while the Seebeck coefficient holds an appropriate value of 190.51μV·K–1.The highest ZT value of 0.17 is obtained at 723 K and at x=0.3 owing to the combination of a high PF183μW·m–1·K–2 and a lowκ0.8 W·m–1·K–1.
