(-)-curdione,the antipode of the antitumor principle of Chinese herb Curcuma aromtica Salisb.was synthesized from(-)-carvone via oxy-Cope rearrangement.This result also confirmed the absolute configuration of natural(...(-)-curdione,the antipode of the antitumor principle of Chinese herb Curcuma aromtica Salisb.was synthesized from(-)-carvone via oxy-Cope rearrangement.This result also confirmed the absolute configuration of natural(+)-curdione.展开更多
基金the National Outstanding Youth Foundation by NNSF of China(39925040)Trans-Century Training Program Foundation for the Talents by the Ministry of Education for financial support
文摘(-)-curdione,the antipode of the antitumor principle of Chinese herb Curcuma aromtica Salisb.was synthesized from(-)-carvone via oxy-Cope rearrangement.This result also confirmed the absolute configuration of natural(+)-curdione.