With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wi...With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wide applications in flexible LIBs. However, due to the prone-to-restacking feature of graphene layers, a long cycle life at high current densities is rather difficult to be achieved. Herein, a unique threedimensional(3D) hierarchically porous NiO micro-flowers/graphene paper(fNiO/GP) electrode is successfully fabricated. The resulting fNiO/GP electrode shows superior long-term cycling stability at high rates(e.g., storage capacity of 359 mAh/g after 600 cycles at a high current density of 1 A/g). The facile 3D porous structure combines both the advantages of the graphene that is highly conductive and flexible to ensure rapid electrons/ions transfer and buffer the volume expansion of NiO during charge/discharge,and of the micro-sized NiO flowers that induces hierarchical between-layer pores ranging from nanomicro meters to promote the penetration of the electrolyte and prevent the re-stacking of graphene layers. Such structural design will inspire future manufacture of a wide range of active materials/graphene composite electrodes for high performance flexible LIBs.展开更多
A numerical model was established to calculate the cycle feed rate through studying the case of a cold pilger mill with the 304 stainless steel pipe. Firstly, the precise constitutive equation of 304 stainless steel w...A numerical model was established to calculate the cycle feed rate through studying the case of a cold pilger mill with the 304 stainless steel pipe. Firstly, the precise constitutive equation of 304 stainless steel was obtained through nonlinearly fitting the true stress-strain data from unidirectional tensile test. Then, the numerical method to calculate the equivalent deformation was determined according to the plastic deformation feature of the steel tube during cold rolling and the incremental theory. Finally, the cycle feed rate of cold roiled 304 stainless steel pipe was extracted when formulating springback through utilizing above results comprehensively and unloading law. Stress state, metal flow, finished pipe size and distribution of residual stress were obtained by finite element method to calculate the whole rolling process when the cycle feed rate was 10 mm, and the optimized model was verified through finished pipe size.展开更多
基金financially supported by the National Key R&D Program of China (No.2017YFE0111500)the National Natural Science Foundation of China (No.51673123 and 51222305)Sichuan Province Science and Technology Project (No.2016JQ0049)。
文摘With the rapid emergence of wearable devices, flexible lithium-ion batteries(LIBs) are much more needed than ever. Free-standing graphene-based composite paper electrodes with various active materials have appealed wide applications in flexible LIBs. However, due to the prone-to-restacking feature of graphene layers, a long cycle life at high current densities is rather difficult to be achieved. Herein, a unique threedimensional(3D) hierarchically porous NiO micro-flowers/graphene paper(fNiO/GP) electrode is successfully fabricated. The resulting fNiO/GP electrode shows superior long-term cycling stability at high rates(e.g., storage capacity of 359 mAh/g after 600 cycles at a high current density of 1 A/g). The facile 3D porous structure combines both the advantages of the graphene that is highly conductive and flexible to ensure rapid electrons/ions transfer and buffer the volume expansion of NiO during charge/discharge,and of the micro-sized NiO flowers that induces hierarchical between-layer pores ranging from nanomicro meters to promote the penetration of the electrolyte and prevent the re-stacking of graphene layers. Such structural design will inspire future manufacture of a wide range of active materials/graphene composite electrodes for high performance flexible LIBs.
基金The authors are grateful for the financial assis- tance from the National Science Foundation of China （U1710113）, the China Postdoctoral Science Foundation （2017M622903）, the Fund for Shanxi Key Subjects Construction, Excellent innovation projects of graduate students in Shanxi （2017SY077）, Heavy Machinery Engineering Research Center of Ministry of Education （20172004）.
文摘A numerical model was established to calculate the cycle feed rate through studying the case of a cold pilger mill with the 304 stainless steel pipe. Firstly, the precise constitutive equation of 304 stainless steel was obtained through nonlinearly fitting the true stress-strain data from unidirectional tensile test. Then, the numerical method to calculate the equivalent deformation was determined according to the plastic deformation feature of the steel tube during cold rolling and the incremental theory. Finally, the cycle feed rate of cold roiled 304 stainless steel pipe was extracted when formulating springback through utilizing above results comprehensively and unloading law. Stress state, metal flow, finished pipe size and distribution of residual stress were obtained by finite element method to calculate the whole rolling process when the cycle feed rate was 10 mm, and the optimized model was verified through finished pipe size.
