The title complex [Zn(-O2CCH=CHCO2)(C3H4N2)(H2O)]n was prepared by the reaction of zinc carbonate with maleic acid and imidazole in an aqueous-alcohol solution at 333 K, and its crystal structure has been solved by si...The title complex [Zn(-O2CCH=CHCO2)(C3H4N2)(H2O)]n was prepared by the reaction of zinc carbonate with maleic acid and imidazole in an aqueous-alcohol solution at 333 K, and its crystal structure has been solved by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group Pc with a = 5.3858(7), b = 22.685(3), c = 7.6782(1) ? = 92.261(2)o, V = 937.4(2) 3, Z = 1, C14H16N4O10Zn2, Mr = 531.05, Dc = 1.882 g/cm3, = 2.623 mm1, F(000) = 532, the final R = 0.0372 and wR = 0.0930 for 1926 observed reflections with I>2s(I). The central zinc atom is five-coordinated in a distorted square pyramidal environment to three oxygen atoms of two different maleate ligands, a nitrogen atom of the imi- dazole ligand and an oxygen atom of water. In the complex two carboxylate groups of the maleate ligands have two coordination modes. One acts as a bidentate chelate ligand and the other a monoatomic monodentate ligand to bridge two zinc centers. As a result, 1-D infinite polymeric chains are formed, which are linked together by pairs of OH…O hydrogen bonds between the coordination water OH groups and carboxylate oxygen atoms to construct a 2-D layered polymer, and the layer structure is stabilized by p-p stacking of the imidozel ligands.展开更多
临床医生可通过观察眼底视网膜血管及其分支对人体是否患有疾病进行早期诊断,但由于视网膜中的血管错综复杂,模型在分割时会出现对微细血管分割精确度不足的问题。为此,提出一种结合残差模块Res2-net以及高效通道注意力机制(efficient c...临床医生可通过观察眼底视网膜血管及其分支对人体是否患有疾病进行早期诊断,但由于视网膜中的血管错综复杂,模型在分割时会出现对微细血管分割精确度不足的问题。为此,提出一种结合残差模块Res2-net以及高效通道注意力机制(efficient channel attention,ECA)的D-Linknet模型。首先,利用Res2-net代替基础模型中的残差模块Res-net以提升每个网络层的感受野;其次,在Res2-net中添加一种结合压缩激励(squeeze and excitation,SE)和门通道(gated channel transformation,GCT)的注意力机制模块,改善处于复杂背景下的血管分割效果和效率;在网络的解码层加入ECA确保模型计算的性能,避免因降维导致的精度下降;最后,融合改进的模型输出图与掩膜图细化分割结果。在公开数据集DRIVE、STARE上进行分割实验,模型准确度(accuracy,AC)分别为97.11%、96.32%,灵敏度(sensitivity,SE)为84.55%、83.92%,曲线下方范围的面积(area under curve,AUC)为0.9873和0.9766,分割效果优于其他模型。实验证明了算法的可行性,为后续研究提供科学依据。展开更多
In response to the primary electric field originated by the fluid-core-dynamo, electric charges accumulate at the boundaries of a solid conducting D″ layer due to the poor circuitry conditions until the irrotational ...In response to the primary electric field originated by the fluid-core-dynamo, electric charges accumulate at the boundaries of a solid conducting D″ layer due to the poor circuitry conditions until the irrotational primary electric field is neutralized. The neutralization undoes the internal induction excited by the primary electric field and, as a result, eliminates the secondary toroidal magnetic field inside the D″. The primary magnetic field generated by the fluid-core-dynamo gives rise to a sustainable secondary poloidal magnetic field inside the conducting D″ layer. We introduce the general kinematic boundary conditions that are valid with different induction processes and parameter jumps across the core mantle boundary.We find by dimensional analysis that the strength of the secondary poloidal magnetic field is much weaker, by a factor of ~10-2, than the irrotational primary. These findings indicate that the D' is in effect an insulator for the geodynamo regardless of its material composition. Any mechanism for the coremantle magnetic coupling should take this fact into consideration.展开更多
GPS signals play a very important role in the modern industry, science, tourism, military and domestic operations. However, GPS signals are not free from some mistakes caused by disturbances appearing in D and E layer...GPS signals play a very important role in the modern industry, science, tourism, military and domestic operations. However, GPS signals are not free from some mistakes caused by disturbances appearing in D and E layers of the atmosphere. A quantum approach is proposed to the theory of propagation of a satellite GPS signal through the D and E layers of the atmosphere, which reduces to the problem of scattering of photons moving in the electromagnetic field of a signal in Rydberg complexes formed in a two-temperature non-equilibrium plasma. The processes of creation of additional photons as a result of stimulated emission and resonance scattering of photons are considered. It is shown that the first process leads to a direct increase in the power of the received signal, and the second to a shift in the signal carrier frequency and the time delay of its propagation. This occurs because of the scattering of the Rydberg electron by the ion core and the neutral medium molecule in the intermediate autoionization states of the composite system populated by the strong non-adiabatic coupling of electron and nuclear motions.展开更多
Applying a novel method of arc-glow plasma depositing, a 2μm-thick coating with 12 sub-layers of TiN and CrN was deposited alternately on the surface of magnesium alloy AZ91D to improve its wear resistance. The wear ...Applying a novel method of arc-glow plasma depositing, a 2μm-thick coating with 12 sub-layers of TiN and CrN was deposited alternately on the surface of magnesium alloy AZ91D to improve its wear resistance. The wear behavior was investigated by test of ball on disc sliding. The composition and microstructure of the coating were also analyzed by means of X-ray diffraction (XRD) and glow discharge spectrum (GDS), and the morphology of TiN-CrN film was surveyed through scanning electronic microscopy (SEM) and atom force microscopy (AFM).The adhesion strength between film and matrix was evaluated by ways of stick-peeling test. The surface micro-hardness of the coating is above HK0.011 433, and the specific wear ratio of specimens coated with TiN-CrN films tested decreases greatly compared to that of the bare metal.展开更多
This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layer...This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layered earth model. When these 6 coefficients are considered together with those of the magnetic field of a horizontally layered earth model,the analytic and approximate wave impedance equations can be derived for the MT response of a horizontally layered earth model with near-surface 2-D and 3-D inhomogeneities. These approximate wave impedance equations are used with inverted MT data for 2-D and 3-D forward modelling. Although these 6 coefficients cannot be determined before inversion,initial estimates can be used. The 6 coefficients and the asistivity and thickness of each layer of a horizontally layered earth can be obtained by using published inversion methods. The 6 coefficients give important informaion (depths and resistivities) on the near-surface inhomogenelties.The authors inverted 2-D and 3-D theoretical models for Fast Approximate Inversion of Magnetotelluric (FAIMT) data for a horizontally layered earth with near-surface inhomogeneities compares favorably with traditional invrsion methods, especially for inverting regional or basin structures. This method simplifies computation and gives a reasonable 1 -D geological model with fewer nonuniquenas problems.展开更多
An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical react...An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical reaction equations was developed, validated, and used for studying the ozone concentrations, distribution and peak of the layer, ozone depletion and total ozone abundance in the stratosphere. The calculated ozone concentrations and profile at both the Equator and a 60˚N location were found to follow closely with the measured data. The calculated average ozone concentration was within 1% of the measured average, and the deviation of ozone profiles was within 14%. The monthly evolution of stratospheric ozone concentrations and distribution above the Equator was studied with results discussed in details. The influences of slow air movement in both altitudinal and radial directions on ozone concentrations and profile in the stratosphere were explored and discussed. Parametric studies of the influences of gas diffusivities of ozone D<sub>O3</sub> and active atomic oxygen D<sub>O</sub> on ozone concentrations and distributions were also studied and delineated. Having both influences through physical diffusion and chemical reactions, the diffusivity (and diffusion) of atomic oxygen D<sub>O</sub> was found to be more sensitive and important than that of ozone D<sub>O3</sub> on ozone concentrations and distribution. The 2-D ozone model present in this paper for stratospheric ozone and its layer and depletion is shown to be robust, convenient, efficient, and executable for analyzing the complex ozone phenomena in the stratosphere. .展开更多
本研究做为电磁感应国际合作研究项目—EMSLAB计划的一部分,主要目的在于确定东太平洋年轻的海洋板块——Juan de Fuca板块及其周围地区岩石圈和软流圈的电性结构。 在对海底观测的大地电磁资料定性和定量分析的基础上,进行了二维数学...本研究做为电磁感应国际合作研究项目—EMSLAB计划的一部分,主要目的在于确定东太平洋年轻的海洋板块——Juan de Fuca板块及其周围地区岩石圈和软流圈的电性结构。 在对海底观测的大地电磁资料定性和定量分析的基础上,进行了二维数学模拟。在二维模型中,海洋地形和已知的表层构造被确定。通过改变模型的重要参数,评价响应函数和观测资料之间偏差的增加,检验模型的可靠性。结果表明,Juan de Fuca板块深部存在两个导电层,一个在40km,另一个在200km左右。这里岩石圈比其它较老板块的岩石圈薄。展开更多
基金Supported by the National Natural Science Foundation of China (No. 29872037) and the Natural Science Foundation of Fujian province (No. C0120002)
文摘The title complex [Zn(-O2CCH=CHCO2)(C3H4N2)(H2O)]n was prepared by the reaction of zinc carbonate with maleic acid and imidazole in an aqueous-alcohol solution at 333 K, and its crystal structure has been solved by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group Pc with a = 5.3858(7), b = 22.685(3), c = 7.6782(1) ? = 92.261(2)o, V = 937.4(2) 3, Z = 1, C14H16N4O10Zn2, Mr = 531.05, Dc = 1.882 g/cm3, = 2.623 mm1, F(000) = 532, the final R = 0.0372 and wR = 0.0930 for 1926 observed reflections with I>2s(I). The central zinc atom is five-coordinated in a distorted square pyramidal environment to three oxygen atoms of two different maleate ligands, a nitrogen atom of the imi- dazole ligand and an oxygen atom of water. In the complex two carboxylate groups of the maleate ligands have two coordination modes. One acts as a bidentate chelate ligand and the other a monoatomic monodentate ligand to bridge two zinc centers. As a result, 1-D infinite polymeric chains are formed, which are linked together by pairs of OH…O hydrogen bonds between the coordination water OH groups and carboxylate oxygen atoms to construct a 2-D layered polymer, and the layer structure is stabilized by p-p stacking of the imidozel ligands.
文摘临床医生可通过观察眼底视网膜血管及其分支对人体是否患有疾病进行早期诊断,但由于视网膜中的血管错综复杂,模型在分割时会出现对微细血管分割精确度不足的问题。为此,提出一种结合残差模块Res2-net以及高效通道注意力机制(efficient channel attention,ECA)的D-Linknet模型。首先,利用Res2-net代替基础模型中的残差模块Res-net以提升每个网络层的感受野;其次,在Res2-net中添加一种结合压缩激励(squeeze and excitation,SE)和门通道(gated channel transformation,GCT)的注意力机制模块,改善处于复杂背景下的血管分割效果和效率;在网络的解码层加入ECA确保模型计算的性能,避免因降维导致的精度下降;最后,融合改进的模型输出图与掩膜图细化分割结果。在公开数据集DRIVE、STARE上进行分割实验,模型准确度(accuracy,AC)分别为97.11%、96.32%,灵敏度(sensitivity,SE)为84.55%、83.92%,曲线下方范围的面积(area under curve,AUC)为0.9873和0.9766,分割效果优于其他模型。实验证明了算法的可行性,为后续研究提供科学依据。
文摘In response to the primary electric field originated by the fluid-core-dynamo, electric charges accumulate at the boundaries of a solid conducting D″ layer due to the poor circuitry conditions until the irrotational primary electric field is neutralized. The neutralization undoes the internal induction excited by the primary electric field and, as a result, eliminates the secondary toroidal magnetic field inside the D″. The primary magnetic field generated by the fluid-core-dynamo gives rise to a sustainable secondary poloidal magnetic field inside the conducting D″ layer. We introduce the general kinematic boundary conditions that are valid with different induction processes and parameter jumps across the core mantle boundary.We find by dimensional analysis that the strength of the secondary poloidal magnetic field is much weaker, by a factor of ~10-2, than the irrotational primary. These findings indicate that the D' is in effect an insulator for the geodynamo regardless of its material composition. Any mechanism for the coremantle magnetic coupling should take this fact into consideration.
文摘GPS signals play a very important role in the modern industry, science, tourism, military and domestic operations. However, GPS signals are not free from some mistakes caused by disturbances appearing in D and E layers of the atmosphere. A quantum approach is proposed to the theory of propagation of a satellite GPS signal through the D and E layers of the atmosphere, which reduces to the problem of scattering of photons moving in the electromagnetic field of a signal in Rydberg complexes formed in a two-temperature non-equilibrium plasma. The processes of creation of additional photons as a result of stimulated emission and resonance scattering of photons are considered. It is shown that the first process leads to a direct increase in the power of the received signal, and the second to a shift in the signal carrier frequency and the time delay of its propagation. This occurs because of the scattering of the Rydberg electron by the ion core and the neutral medium molecule in the intermediate autoionization states of the composite system populated by the strong non-adiabatic coupling of electron and nuclear motions.
基金Project(20041065) supported by the Natural Science Foundation of Shanxi Province, China
文摘Applying a novel method of arc-glow plasma depositing, a 2μm-thick coating with 12 sub-layers of TiN and CrN was deposited alternately on the surface of magnesium alloy AZ91D to improve its wear resistance. The wear behavior was investigated by test of ball on disc sliding. The composition and microstructure of the coating were also analyzed by means of X-ray diffraction (XRD) and glow discharge spectrum (GDS), and the morphology of TiN-CrN film was surveyed through scanning electronic microscopy (SEM) and atom force microscopy (AFM).The adhesion strength between film and matrix was evaluated by ways of stick-peeling test. The surface micro-hardness of the coating is above HK0.011 433, and the specific wear ratio of specimens coated with TiN-CrN films tested decreases greatly compared to that of the bare metal.
文摘This paper discusses use of approximations and the Integral Mean Value Theorem to show that 6 coefficients approximately describe the distortions of near surface inhomogeneities on the MT field of a horizontally layered earth model. When these 6 coefficients are considered together with those of the magnetic field of a horizontally layered earth model,the analytic and approximate wave impedance equations can be derived for the MT response of a horizontally layered earth model with near-surface 2-D and 3-D inhomogeneities. These approximate wave impedance equations are used with inverted MT data for 2-D and 3-D forward modelling. Although these 6 coefficients cannot be determined before inversion,initial estimates can be used. The 6 coefficients and the asistivity and thickness of each layer of a horizontally layered earth can be obtained by using published inversion methods. The 6 coefficients give important informaion (depths and resistivities) on the near-surface inhomogenelties.The authors inverted 2-D and 3-D theoretical models for Fast Approximate Inversion of Magnetotelluric (FAIMT) data for a horizontally layered earth with near-surface inhomogeneities compares favorably with traditional invrsion methods, especially for inverting regional or basin structures. This method simplifies computation and gives a reasonable 1 -D geological model with fewer nonuniquenas problems.
文摘An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical reaction equations was developed, validated, and used for studying the ozone concentrations, distribution and peak of the layer, ozone depletion and total ozone abundance in the stratosphere. The calculated ozone concentrations and profile at both the Equator and a 60˚N location were found to follow closely with the measured data. The calculated average ozone concentration was within 1% of the measured average, and the deviation of ozone profiles was within 14%. The monthly evolution of stratospheric ozone concentrations and distribution above the Equator was studied with results discussed in details. The influences of slow air movement in both altitudinal and radial directions on ozone concentrations and profile in the stratosphere were explored and discussed. Parametric studies of the influences of gas diffusivities of ozone D<sub>O3</sub> and active atomic oxygen D<sub>O</sub> on ozone concentrations and distributions were also studied and delineated. Having both influences through physical diffusion and chemical reactions, the diffusivity (and diffusion) of atomic oxygen D<sub>O</sub> was found to be more sensitive and important than that of ozone D<sub>O3</sub> on ozone concentrations and distribution. The 2-D ozone model present in this paper for stratospheric ozone and its layer and depletion is shown to be robust, convenient, efficient, and executable for analyzing the complex ozone phenomena in the stratosphere. .
文摘本研究做为电磁感应国际合作研究项目—EMSLAB计划的一部分,主要目的在于确定东太平洋年轻的海洋板块——Juan de Fuca板块及其周围地区岩石圈和软流圈的电性结构。 在对海底观测的大地电磁资料定性和定量分析的基础上,进行了二维数学模拟。在二维模型中,海洋地形和已知的表层构造被确定。通过改变模型的重要参数,评价响应函数和观测资料之间偏差的增加,检验模型的可靠性。结果表明,Juan de Fuca板块深部存在两个导电层,一个在40km,另一个在200km左右。这里岩石圈比其它较老板块的岩石圈薄。
