The thermal decomposition of ammonium 3-nitro-1,2,4-triazol-5-onate monohydrate[NH4(NTO)·H2O] was studied by means of thermal analysis-MS coupling and the combination technique of in situ thermolysis cell with ...The thermal decomposition of ammonium 3-nitro-1,2,4-triazol-5-onate monohydrate[NH4(NTO)·H2O] was studied by means of thermal analysis-MS coupling and the combination technique of in situ thermolysis cell with rapid-scan Fourier transform infrared spectroscopy. The results show that there are two endothermic steps and one exothermic step in the decomposition process of NH4(NTO)·H2O. The detected gas products consist of NH3, H2O, N2, CO2, CO, and NO2.展开更多
The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measu...The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measured from 283.15 K to 313.15 K by gravimetric method under atmospheric pressure thought as 0.1 MPa.The modi fied Apelblat equation,the CNIBS/R-K equation,the Hybrid model and the NRTL model were used to correlate the solubility of metamizol monohydrate,respectively.The results show that the solubility of metamizol monohydrate in all the tested solvents increases with the rising temperature which means that it has temperature dependence.What's more,the effects of solvent components of the binary solvent mixtures on solubility were discussed,it illustrates that the increasing of the molar fraction of methanol gives the system a greater dissolving power.Furthermore,according to the NRTL model,the enthalpy,the Gibbs energy and the entropy of the mixing process were also obtained and discussed.展开更多
A general expression for the ralationship between induction period and supersaturation was developed based on polynuclear approach.Different mechanism of primary nucleation in solution can be illustrated by the expres...A general expression for the ralationship between induction period and supersaturation was developed based on polynuclear approach.Different mechanism of primary nucleation in solution can be illustrated by the expression.The results of induction period determined by laser scatering method shows that the crystallization of ciprofloxacin hydrochloride monohydrate in water/ethanol or aqueous solution is by the mechanism of primary nucleation followed by one-dimensional diffusion growth,and then one-dimensional continuous or “birth and spread” growth on crystal face. The growth mechanism on the crystal face is affected by temperature and solvent.展开更多
With the high-quality requirements for cephalexin monohydrate,developing a robust and practical crystallization process to produce cephalexin monohydrate with good crystal habit,appropriate aspect ratio and high bulk ...With the high-quality requirements for cephalexin monohydrate,developing a robust and practical crystallization process to produce cephalexin monohydrate with good crystal habit,appropriate aspect ratio and high bulk density as well as suitable flowability is urgently needed.This research has explored the influence of ultrasound on crystallization of cephalexin monohydrate in terms of nucleation mechanism and crystal habit control.The results of metastable zone width and induction time measurement showed the presence of ultrasound irradiation can narrow the metastable zone and shorten induction time.Cavitation phenomena generated by ultrasound were used to qualitatively explain the mechanism of ultrasound promoting nucleation of cephalexin monohydrate.Furthermore,on the basis of classical nucleation theory and induction time data,a series of nucleation-related parameters(such as crystalliquid interfacial tension,radius of the critical nucleus and etc.)were calculated and showed a decreasing trend under ultrasound irradiation.The diffusion coefficient of the studied system was also determined to increase by 72.73%under ultrasound.The changes in these parameters have quantitatively confirmed the mechanism of ultrasound influence on the nucleation process.In further,the calculated surface entropy factor has confirmed that the growth of cephalexin monohydrate follows continuous growth mechanism under the research conditions of this work.Through the exploration of crystallization conditions,it is found that suitable ultrasonic treatment,seeding,supersaturation control and removal of fine crystals are conducive to improving the quality of cephalexin monohydrate product.Optimizing the crystallization process coupled continuous ultrasound irradiation with fine-crystal dissolution policy has achieved the controllable production of monodisperse cephalexin monohydrate crystal with good performance.展开更多
Ammonium 5-sulfosalicylic acid monohydrate (NH4·C7H5O6S·H2O, ASSA) was synthesized and optical grade crystal with dimensions of 45ram × 20mm × 18mm was obtained from aqueous solution by the cooli...Ammonium 5-sulfosalicylic acid monohydrate (NH4·C7H5O6S·H2O, ASSA) was synthesized and optical grade crystal with dimensions of 45ram × 20mm × 18mm was obtained from aqueous solution by the cooling solution method. The crystal structure was confirmed by X-ray single-crystal diffraction method and the empirical composition is C7HIINO7S with formula weight 253.23. The crystal belongs to monoclinic space group P21/c with a = 1 1.884(9), b = 7.306(5), c = 12.152(9) A, β = 104.851(13)°, V= 1019.8(13) A3, Z = 4, Dc = 1.649 g/cm3,μ = 0.340 mm-1, F(000) =528, the final R= 0.0307 and wR= 0.0866 for 7494 observed reflections (I〉 2σ(I)), Elemental analysis, 1R and 1H-NMR spectrum were used to characterize the compound. Thermal analysis showed that one coordination water molecule was contained and dehydration temperature of ASSA crystal was 106℃. Optical transmission and fluorescence spectrum revealed that the ASSA crystal exhibited a strong absorption in ultraviolet region with the sharp absorption edge located at 340 nm and a significant blue fluorescent emission band at 442 nm.展开更多
The heterogenized δ-RuCl<sub>2</sub>(Nazpy)<sub>2</sub> deposited on carbon toray (CT) was studied for the first time as electrochemical catalyst. Before, it was characterized by visible-ultra...The heterogenized δ-RuCl<sub>2</sub>(Nazpy)<sub>2</sub> deposited on carbon toray (CT) was studied for the first time as electrochemical catalyst. Before, it was characterized by visible-ultraviolet spectra and theoretically by TDDFT method at B3LYP/Lanl2DZ level. It displayed an MLCT t<sub>2g</sub>e<sub>g</sub> → π* transition where t<sub>2g</sub>e<sub>g</sub> due to the structure of Nazpy that considerably reduces energy between d AOs of Ru represents the HOMO of the complex and π* is identified as the LUMO. Electrochemistry study shows two redox ranges in both negative and positive sides of the potential. The positive side that corresponds to the couple Ru<sup>IV</sup>/Ru<sup>III</sup> of catalyst appears to be active for oxidation of D-glucose in carbonate buffer with a high turnover. Therefore, Keto-2-gluconic and gluconic acids were the two main products obtained with respectively 80% and 17.6% of selectivity. Moreover, a small amount of tartaric and glycol acids coming from the c-c bond cleavage due to non-protection of the anomeric carbon of D-glucose were also observed.展开更多
A new piperazinium 4-nitro phenolate monohydrate single crystal(PNP)was grown by employing the solution growth technique piperazine and 4-nitrophenol,were the source material used for the growth,acetonitrile is used a...A new piperazinium 4-nitro phenolate monohydrate single crystal(PNP)was grown by employing the solution growth technique piperazine and 4-nitrophenol,were the source material used for the growth,acetonitrile is used as solvent.The grown crystal was characterized by Single X-ray analysis and it shows that piperazinium 4-nitrophenol monohydrate crystallizes in the monoclinic space group P2 1/c,with cell parameters a=10.902 5(4),b=6.226 1(3),c=14.031 8(5),and z=4.The lattice parameters of the substances were also determined by using powder diffraction methods.The functional groups are identified by using FTIR spectral analysis.The absorbance of title compound were analyzed using UV-Vis spectra.The thermo analytical properties of the crystal were studied using TG,DTA.展开更多
In the sample compartment of a conventional spectrophotometer, mounting of a polarizer before sample and an analyzer behind sample allows the determination of the optical rotatory dispersion of optical active media by...In the sample compartment of a conventional spectrophotometer, mounting of a polarizer before sample and an analyzer behind sample allows the determination of the optical rotatory dispersion of optical active media by measurement of the transmission ratio of crossed and parallel arranged polarizer and analyzer. A formula for the determination of the angle of rotation is derived from the transmission ratio. The arrangement is applied to determine the molar optical rotation of D-glucose in water in the wavelength range from 220 nm to 820 nm.展开更多
The crystal structure of the title compound (C19H17F3N2O4, Mr = 394.35) was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with a = 28.383(6), b = 10.355(2), ...The crystal structure of the title compound (C19H17F3N2O4, Mr = 394.35) was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with a = 28.383(6), b = 10.355(2), c = 12.799(3) A, β = 111.74(3)°, V= 3493.8(12) A3, Z = 8, De = 1.499 g,/cm3, λ(MoKα) = 0.71073, F(000) = 1632,μ = 0.127 mm^-1, R = 0.0412 and wR = 0.1019. In the title compound, there exist three intermolecular hydrogen interactions (O(4)...O(1), 0(4)...0(3) and O(4)...N(1)) between water. The neighboring molecules are linked to each other generating a two-dimensional network structure via the three intermolecular hydrogen bonds and π-π interactions shaped by phen-phen with centroid distance of 4.049 A.展开更多
The title compound 5-allyl-2,3-dihydro-9-(2-hydroxy-5-oxocyclopent-1-enyl)-cyclopenta[b]chromen-1(9H)-one monohydrate(C20H18O4.H2O,Mr = 340.36) was synthesized and crystallized.It crystallizes in the triclinic s...The title compound 5-allyl-2,3-dihydro-9-(2-hydroxy-5-oxocyclopent-1-enyl)-cyclopenta[b]chromen-1(9H)-one monohydrate(C20H18O4.H2O,Mr = 340.36) was synthesized and crystallized.It crystallizes in the triclinic system,space group P with a = 8.5840(17),b = 8.7027(17),c = 11.561(2),α = 89.69(3),β = 74.33(3),γ = 86.13(3)°,V = 829.6(3)(A°)^3,Z = 2,Dc = 1.363 g/cm^3,MoKa radiation(λ = 0.71073 ),F(000) = 360,μ = 0.098 mm^-1,the final R = 0.0430 and wR = 0.1008 for 2957 observed reflections with(I 〉 2σ(I)).X-ray analysis reveals that atoms C(1),C(2),C(3),C(4),C(5) and O(1) on the new pyran ring are coplanar,which is obviously different from the half-chair or boat conformations of other similar compounds.展开更多
The anomeric specificity of D-glucose metabolism in erythrocytes has been since 1985 the matter of extensive investigations reported in about ten publications. The present report aims at providing an integrated review...The anomeric specificity of D-glucose metabolism in erythrocytes has been since 1985 the matter of extensive investigations reported in about ten publications. The present report aims at providing an integrated review of the major findings on this issue.展开更多
We report results from the investigation of the nonlinear refractive index and nonlinear absorption coefficient of {(1Z)-[4-(Dimethylamino)phenyl]methylene} 4-nitrobenzocarboxy hydrazone mono-hydrate (DMPM4NBCHM) solu...We report results from the investigation of the nonlinear refractive index and nonlinear absorption coefficient of {(1Z)-[4-(Dimethylamino)phenyl]methylene} 4-nitrobenzocarboxy hydrazone mono-hydrate (DMPM4NBCHM) solution using Z-scan technique with a continuous wave (CW) Argon ion laser. The results show that this type of organic material has a large nonlinear absorption and nonlinear refractive index at 488 nm and 514 nm. The origin of the nonlinear effects was discussed. We demonstrate that the light induced nonlinear refractive index variation, leads to limiting effect. The results indicated that DMPM4NBCHM could be promising candidates for application on nonlinear photonic devices and optical limiters.展开更多
The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate in sulfuric acid solutions were measured at temperatures ranging from 278.15 to 338.15 K by using a dynamic method. The conc...The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate in sulfuric acid solutions were measured at temperatures ranging from 278.15 to 338.15 K by using a dynamic method. The concentration of sulfuric acid solution ranged from 0 to 80wt%,. The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate increased with temperature, and both of them were the lowest at 70wt %, of sulfuric acid solution(w^0_3 =0.70)while the highest in pure water. The solubility data were correlated by the modified Apelblat equation. Based on the solubility difference between 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate, a new technique in which sodium sulfate was used to replace sodium sulfite in the neutralization reaction was developed. The suitable mole ratio of H_2O to Na_2SO_4 in the neutralization reaction was 80∶1, and that of 2-naphthalenesulfonic acid monohydrate to Na_2SO_4 was 3.2∶1. The material balance under the suitable mole ratios was given and discussed.展开更多
Objective To analyze and identify the differentially expressed proteins in human renal tubular epithelial ceils ( HK-2) after injury caused by oxalic acid and calcium oxalate monohydrate ( COM ) crystal,and to explore...Objective To analyze and identify the differentially expressed proteins in human renal tubular epithelial ceils ( HK-2) after injury caused by oxalic acid and calcium oxalate monohydrate ( COM ) crystal,and to explore the potential role of renal tubular cell injury in kidney stone formation. Methods Normal HK-2 cells展开更多
1 INTRODUCTIONAfter Prausnitz et al.published the perturbed hard-sphere chain theory(PHCT),manymodified theories have been put forward,such as the perturbed soft-sphere chain theory(PSCT),the perturbed anisotropic cha...1 INTRODUCTIONAfter Prausnitz et al.published the perturbed hard-sphere chain theory(PHCT),manymodified theories have been put forward,such as the perturbed soft-sphere chain theory(PSCT),the perturbed anisotropic chain theory(PACT)and the associated perturbedanisotropic chain theory(APACT).These theories are all concerned with the parameter3c.But,Wertheim in his work proved that the free energy of hard-sphere chain couldbe calculated without 3c.Induced by the work done by Wertheim,Chapman展开更多
文摘The thermal decomposition of ammonium 3-nitro-1,2,4-triazol-5-onate monohydrate[NH4(NTO)·H2O] was studied by means of thermal analysis-MS coupling and the combination technique of in situ thermolysis cell with rapid-scan Fourier transform infrared spectroscopy. The results show that there are two endothermic steps and one exothermic step in the decomposition process of NH4(NTO)·H2O. The detected gas products consist of NH3, H2O, N2, CO2, CO, and NO2.
基金Supported by National Natural Science Foundation of China(21206109)China Ministry of Science and Major National Scientific Instrument Development Project(21527812)
文摘The thermodynamic properties of metamizol monohydrate in pure solvents(methanol,ethanol,n-propanol and isopropanol) and two binary mixed solvent systems including(methanol+ethanol) and(methanol+isopropanol) were measured from 283.15 K to 313.15 K by gravimetric method under atmospheric pressure thought as 0.1 MPa.The modi fied Apelblat equation,the CNIBS/R-K equation,the Hybrid model and the NRTL model were used to correlate the solubility of metamizol monohydrate,respectively.The results show that the solubility of metamizol monohydrate in all the tested solvents increases with the rising temperature which means that it has temperature dependence.What's more,the effects of solvent components of the binary solvent mixtures on solubility were discussed,it illustrates that the increasing of the molar fraction of methanol gives the system a greater dissolving power.Furthermore,according to the NRTL model,the enthalpy,the Gibbs energy and the entropy of the mixing process were also obtained and discussed.
文摘A general expression for the ralationship between induction period and supersaturation was developed based on polynuclear approach.Different mechanism of primary nucleation in solution can be illustrated by the expression.The results of induction period determined by laser scatering method shows that the crystallization of ciprofloxacin hydrochloride monohydrate in water/ethanol or aqueous solution is by the mechanism of primary nucleation followed by one-dimensional diffusion growth,and then one-dimensional continuous or “birth and spread” growth on crystal face. The growth mechanism on the crystal face is affected by temperature and solvent.
基金the financial support of National Natural Science Foundation of China(22078238)Special Project for the Transformation of Major Scientific and Technology Achievements of Hebei Province(19042822Z).
文摘With the high-quality requirements for cephalexin monohydrate,developing a robust and practical crystallization process to produce cephalexin monohydrate with good crystal habit,appropriate aspect ratio and high bulk density as well as suitable flowability is urgently needed.This research has explored the influence of ultrasound on crystallization of cephalexin monohydrate in terms of nucleation mechanism and crystal habit control.The results of metastable zone width and induction time measurement showed the presence of ultrasound irradiation can narrow the metastable zone and shorten induction time.Cavitation phenomena generated by ultrasound were used to qualitatively explain the mechanism of ultrasound promoting nucleation of cephalexin monohydrate.Furthermore,on the basis of classical nucleation theory and induction time data,a series of nucleation-related parameters(such as crystalliquid interfacial tension,radius of the critical nucleus and etc.)were calculated and showed a decreasing trend under ultrasound irradiation.The diffusion coefficient of the studied system was also determined to increase by 72.73%under ultrasound.The changes in these parameters have quantitatively confirmed the mechanism of ultrasound influence on the nucleation process.In further,the calculated surface entropy factor has confirmed that the growth of cephalexin monohydrate follows continuous growth mechanism under the research conditions of this work.Through the exploration of crystallization conditions,it is found that suitable ultrasonic treatment,seeding,supersaturation control and removal of fine crystals are conducive to improving the quality of cephalexin monohydrate product.Optimizing the crystallization process coupled continuous ultrasound irradiation with fine-crystal dissolution policy has achieved the controllable production of monodisperse cephalexin monohydrate crystal with good performance.
基金carried out under the sponsorship and financial support from the Key Laboratory of Optoelectronic Materials Chemistry and Physics,Chinese Academy of Sciences
文摘Ammonium 5-sulfosalicylic acid monohydrate (NH4·C7H5O6S·H2O, ASSA) was synthesized and optical grade crystal with dimensions of 45ram × 20mm × 18mm was obtained from aqueous solution by the cooling solution method. The crystal structure was confirmed by X-ray single-crystal diffraction method and the empirical composition is C7HIINO7S with formula weight 253.23. The crystal belongs to monoclinic space group P21/c with a = 1 1.884(9), b = 7.306(5), c = 12.152(9) A, β = 104.851(13)°, V= 1019.8(13) A3, Z = 4, Dc = 1.649 g/cm3,μ = 0.340 mm-1, F(000) =528, the final R= 0.0307 and wR= 0.0866 for 7494 observed reflections (I〉 2σ(I)), Elemental analysis, 1R and 1H-NMR spectrum were used to characterize the compound. Thermal analysis showed that one coordination water molecule was contained and dehydration temperature of ASSA crystal was 106℃. Optical transmission and fluorescence spectrum revealed that the ASSA crystal exhibited a strong absorption in ultraviolet region with the sharp absorption edge located at 340 nm and a significant blue fluorescent emission band at 442 nm.
文摘The heterogenized δ-RuCl<sub>2</sub>(Nazpy)<sub>2</sub> deposited on carbon toray (CT) was studied for the first time as electrochemical catalyst. Before, it was characterized by visible-ultraviolet spectra and theoretically by TDDFT method at B3LYP/Lanl2DZ level. It displayed an MLCT t<sub>2g</sub>e<sub>g</sub> → π* transition where t<sub>2g</sub>e<sub>g</sub> due to the structure of Nazpy that considerably reduces energy between d AOs of Ru represents the HOMO of the complex and π* is identified as the LUMO. Electrochemistry study shows two redox ranges in both negative and positive sides of the potential. The positive side that corresponds to the couple Ru<sup>IV</sup>/Ru<sup>III</sup> of catalyst appears to be active for oxidation of D-glucose in carbonate buffer with a high turnover. Therefore, Keto-2-gluconic and gluconic acids were the two main products obtained with respectively 80% and 17.6% of selectivity. Moreover, a small amount of tartaric and glycol acids coming from the c-c bond cleavage due to non-protection of the anomeric carbon of D-glucose were also observed.
文摘A new piperazinium 4-nitro phenolate monohydrate single crystal(PNP)was grown by employing the solution growth technique piperazine and 4-nitrophenol,were the source material used for the growth,acetonitrile is used as solvent.The grown crystal was characterized by Single X-ray analysis and it shows that piperazinium 4-nitrophenol monohydrate crystallizes in the monoclinic space group P2 1/c,with cell parameters a=10.902 5(4),b=6.226 1(3),c=14.031 8(5),and z=4.The lattice parameters of the substances were also determined by using powder diffraction methods.The functional groups are identified by using FTIR spectral analysis.The absorbance of title compound were analyzed using UV-Vis spectra.The thermo analytical properties of the crystal were studied using TG,DTA.
文摘In the sample compartment of a conventional spectrophotometer, mounting of a polarizer before sample and an analyzer behind sample allows the determination of the optical rotatory dispersion of optical active media by measurement of the transmission ratio of crossed and parallel arranged polarizer and analyzer. A formula for the determination of the angle of rotation is derived from the transmission ratio. The arrangement is applied to determine the molar optical rotation of D-glucose in water in the wavelength range from 220 nm to 820 nm.
文摘The crystal structure of the title compound (C19H17F3N2O4, Mr = 394.35) was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with a = 28.383(6), b = 10.355(2), c = 12.799(3) A, β = 111.74(3)°, V= 3493.8(12) A3, Z = 8, De = 1.499 g,/cm3, λ(MoKα) = 0.71073, F(000) = 1632,μ = 0.127 mm^-1, R = 0.0412 and wR = 0.1019. In the title compound, there exist three intermolecular hydrogen interactions (O(4)...O(1), 0(4)...0(3) and O(4)...N(1)) between water. The neighboring molecules are linked to each other generating a two-dimensional network structure via the three intermolecular hydrogen bonds and π-π interactions shaped by phen-phen with centroid distance of 4.049 A.
基金Industrialization Project (JHB2011-57) of the Education Committee of Jiangsu ProvinceIndustrialization Project of Huaian City (HAG2010075)
文摘The title compound 5-allyl-2,3-dihydro-9-(2-hydroxy-5-oxocyclopent-1-enyl)-cyclopenta[b]chromen-1(9H)-one monohydrate(C20H18O4.H2O,Mr = 340.36) was synthesized and crystallized.It crystallizes in the triclinic system,space group P with a = 8.5840(17),b = 8.7027(17),c = 11.561(2),α = 89.69(3),β = 74.33(3),γ = 86.13(3)°,V = 829.6(3)(A°)^3,Z = 2,Dc = 1.363 g/cm^3,MoKa radiation(λ = 0.71073 ),F(000) = 360,μ = 0.098 mm^-1,the final R = 0.0430 and wR = 0.1008 for 2957 observed reflections with(I 〉 2σ(I)).X-ray analysis reveals that atoms C(1),C(2),C(3),C(4),C(5) and O(1) on the new pyran ring are coplanar,which is obviously different from the half-chair or boat conformations of other similar compounds.
文摘The anomeric specificity of D-glucose metabolism in erythrocytes has been since 1985 the matter of extensive investigations reported in about ten publications. The present report aims at providing an integrated review of the major findings on this issue.
文摘We report results from the investigation of the nonlinear refractive index and nonlinear absorption coefficient of {(1Z)-[4-(Dimethylamino)phenyl]methylene} 4-nitrobenzocarboxy hydrazone mono-hydrate (DMPM4NBCHM) solution using Z-scan technique with a continuous wave (CW) Argon ion laser. The results show that this type of organic material has a large nonlinear absorption and nonlinear refractive index at 488 nm and 514 nm. The origin of the nonlinear effects was discussed. We demonstrate that the light induced nonlinear refractive index variation, leads to limiting effect. The results indicated that DMPM4NBCHM could be promising candidates for application on nonlinear photonic devices and optical limiters.
文摘The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate in sulfuric acid solutions were measured at temperatures ranging from 278.15 to 338.15 K by using a dynamic method. The concentration of sulfuric acid solution ranged from 0 to 80wt%,. The solubilities of 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate increased with temperature, and both of them were the lowest at 70wt %, of sulfuric acid solution(w^0_3 =0.70)while the highest in pure water. The solubility data were correlated by the modified Apelblat equation. Based on the solubility difference between 2-naphthalenesulfonic acid monohydrate and sodium 2-naphthalenesulfonate, a new technique in which sodium sulfate was used to replace sodium sulfite in the neutralization reaction was developed. The suitable mole ratio of H_2O to Na_2SO_4 in the neutralization reaction was 80∶1, and that of 2-naphthalenesulfonic acid monohydrate to Na_2SO_4 was 3.2∶1. The material balance under the suitable mole ratios was given and discussed.
文摘Objective To analyze and identify the differentially expressed proteins in human renal tubular epithelial ceils ( HK-2) after injury caused by oxalic acid and calcium oxalate monohydrate ( COM ) crystal,and to explore the potential role of renal tubular cell injury in kidney stone formation. Methods Normal HK-2 cells
基金Supported by the National Nature Science Foundation of China.
文摘1 INTRODUCTIONAfter Prausnitz et al.published the perturbed hard-sphere chain theory(PHCT),manymodified theories have been put forward,such as the perturbed soft-sphere chain theory(PSCT),the perturbed anisotropic chain theory(PACT)and the associated perturbedanisotropic chain theory(APACT).These theories are all concerned with the parameter3c.But,Wertheim in his work proved that the free energy of hard-sphere chain couldbe calculated without 3c.Induced by the work done by Wertheim,Chapman