The development of surface modification technology for temperature sensitive fibers has been a huge challenge.In this work,a novel technique based on cold plasma treatment was developed for the preparation of anti-bac...The development of surface modification technology for temperature sensitive fibers has been a huge challenge.In this work,a novel technique based on cold plasma treatment was developed for the preparation of anti-bacterial polypropylene(PP)fibers.The results showed that plasma treatment introduced a rough surface and polar groups,which acted as the anchor point and initiators for diallyldimethyl ammonium chloride(DADMAC)graft-polymerization.The fabricated PP membranes presented a high bacterial sterilization rate,as well as excellent adhesion force and washing durability.After ultrasonic treatment for 30 min,the physical coating sample had lost anti-bacterial effect,while the plasma grafted sample still showed a sterilization rate of 91.67%.This work provided a clean and novel DADMAC grafting method and it is also applicable for anti-bacterial material fabrication.展开更多
Although inorganic phosphate is an essential plant nutrient, elevated levels in surface waters lead to adverse effects in the environment. These effects are attributed to runoff from rain or irrigation events that may...Although inorganic phosphate is an essential plant nutrient, elevated levels in surface waters lead to adverse effects in the environment. These effects are attributed to runoff from rain or irrigation events that may cause the sorbed phosphate to be transported from the application sites and to move into neighboring watersheds. Increased phosphate concentration in watersheds may lead to a variety of environmental problems including increased algal blooms, bacterial contamination, and in some cases eutrophication. To overcome these effects, polymer flocculants have been shown to reduce the phosphate concentration in water by removing suspended solids and thereby removing the phosphate sorbed to the solids. The purpose of this study is to determine the amount, if any, of phosphate removed by several commercial polymers. The polymers chosen include the polyacrylamides Magnifloc 494C, Magnifloc 985N and Poly (diallyldimethyl ammonium chloride) (Poly (DADMAC)). Using these polymers, it is discovered that the positive charge density of the polymers affects the amount of phosphate removed from solution with Poly (DADMAC) (having 100% positive charge density) removing 40% of the phosphate from a solution containing 10 ppm phosphate.展开更多
基金supported by National Natural Science Foundation of China(Nos.51877205 and 52011530191)Fundamental Research Funds for the Central Universities(No.buctrc201906)Beijing Nova Program(No.2022015)。
文摘The development of surface modification technology for temperature sensitive fibers has been a huge challenge.In this work,a novel technique based on cold plasma treatment was developed for the preparation of anti-bacterial polypropylene(PP)fibers.The results showed that plasma treatment introduced a rough surface and polar groups,which acted as the anchor point and initiators for diallyldimethyl ammonium chloride(DADMAC)graft-polymerization.The fabricated PP membranes presented a high bacterial sterilization rate,as well as excellent adhesion force and washing durability.After ultrasonic treatment for 30 min,the physical coating sample had lost anti-bacterial effect,while the plasma grafted sample still showed a sterilization rate of 91.67%.This work provided a clean and novel DADMAC grafting method and it is also applicable for anti-bacterial material fabrication.
文摘Although inorganic phosphate is an essential plant nutrient, elevated levels in surface waters lead to adverse effects in the environment. These effects are attributed to runoff from rain or irrigation events that may cause the sorbed phosphate to be transported from the application sites and to move into neighboring watersheds. Increased phosphate concentration in watersheds may lead to a variety of environmental problems including increased algal blooms, bacterial contamination, and in some cases eutrophication. To overcome these effects, polymer flocculants have been shown to reduce the phosphate concentration in water by removing suspended solids and thereby removing the phosphate sorbed to the solids. The purpose of this study is to determine the amount, if any, of phosphate removed by several commercial polymers. The polymers chosen include the polyacrylamides Magnifloc 494C, Magnifloc 985N and Poly (diallyldimethyl ammonium chloride) (Poly (DADMAC)). Using these polymers, it is discovered that the positive charge density of the polymers affects the amount of phosphate removed from solution with Poly (DADMAC) (having 100% positive charge density) removing 40% of the phosphate from a solution containing 10 ppm phosphate.