采用DC Arc Plasma JetCVD方法沉积微/纳米复合自支撑金刚石膜

在30kW级直流电弧等离子体喷射化学气相沉积(DC Arc P lasm a Jet CVD)设备上,采用Ar-H2-CH4混合气体,通过调节甲烷浓度以及控制其他沉积参数,在Mo衬底上沉积出微/纳米复合自支撑金刚石膜。实验表明,当微米金刚石膜层沉积结束后,在随后的沉积中,随着甲烷浓度的增加,金刚石膜表面的晶粒大小是逐渐减小的。当甲烷浓度达到20%以上时,金刚石膜生长面晶粒呈现菜花状的小晶团,膜体侧面已经没有了粗大的柱状晶,而是呈现出光滑的断口,对该层进行拉曼谱分析显示,位于1145 cm-1附近有一定强度的散射峰出现。这说明所沉积的晶粒全部变为纳米级尺寸。

DC ARC发射光谱法测定纯金中18个杂质元素

用DCARC发射光谱法研究了纯金中杂质元素的定量分析方法,配制了一套适合贸易、科研、生产的光谱标样。本方法可以一次定量测定纯金中18个杂质元素,还进行了检出限和测量不确定度实验,结果表明方法的检出限较低,不确定度低,各杂质元素的相对标准偏差一般<10%,检测方法具有准确度高,检测速度快,效率高的特点。

Energy Balance in DC Arc Plasma Melting Furnace

In order to treat hazardous municipal solid waste incinerator＇s （MSWI） fly ash, a new DC arc plasma furnace was developed. Taking an arc of 100 V/1000 A DC as an example, the heat transfer characteristics of the DC arc plasma, ablation of electrodes, heat properties of the fly ash during melting, heat transfer characteristics of the flue gas, and heat loss of the furnace were analyzed based on the energy conservation law, so as to achieve the total heat information and energy balance during plasma processing, and to provide a theoretical basis for an optimized design of the structure and to improve energy efficiency.

Comparison of Reynolds average Navier-Stokes turbulence models in numerical simulations of the DC arc plasma torch

Five turbulence models of Reynolds average Navier-Stokes(RANS),including the standard k-ω model,the RNG k-e model taking into account the low Reynolds number effect,the realizable k-ω model,the SST k-ω model,and the Reynolds stress model(RSM),are employed in the numerical simulations of direct current(DC)arc plasma torches in the range of arc current from 80 A to 240 A and air gas flow rate from 10 m^3 h^-1 to 50 m^3 h^-1.The calculated voltage,electric field intensity,and the heat loss in the arc chamber are compared with the experiments.The results indicate that the arc voltage,the electric field,and the heat loss in the arc chamber calculated by using the standard k-ω model,the RNG k-ωmodel taking into account the low Reynolds number effect,and the realizable k-ω model are much larger than those in the experiments.The RSM predicts relatively close results to the experiments,but fails in the trend of heat loss varying with the gas flow rate.The calculated results of the SST k-ω model are in the best agreement with the experiments,which may be attributed to the reasonable predictions of the turbulence as well as its distribution.

Numerical simulation of the effects of protrusion on DC arc anode attachment

The attachment of the DC arc on the anode is usually affected by surface morphology such as protrusions due to ablation or melting deformation.A three-dimensional thermodynamic and chemical non-equilibrium model is used to numerically simulate the effect of artificially assumed surface protrusions on the arc anode attachment.The numerical simulation results show that the arc deflects toward the protrusions on the anode and attaches to them in a constricted mode,resulting in an increase in the temperature of the arc attachment region.The analysis shows that the presence of protrusion on the anode surface changes the electric field distribution,intensifies the degree of thermodynamic and chemical non-equilibrium in its vicinity,further influences the chemical kinetic process of the plasma around it,which is the main reason for the deflection of the arc toward the protrusions and the arc anode attachment in a constricted mode.In order to verify the numerical simulation results,verification experiments are also performed using similar size scale anode protrusion,and the results showed that the presence of protrusion can indeed cause the deflection of the arc and even cause the ablation of the protrusion.

Dynamic physical characteristics of DC arc on arcing horn for HVDC grounding electrode line

The dynamic physical characteristics of a DC arc on an arcing horn for a high voltage direct current(HVDC)grounding electrode line are significantly different from those of the switching device arc,secondary arc,AC fault arc and pantograph-catenary arc.In this work,an experimental platform for the DC arc on the arcing horn was built,and mechanisms of the arc column short circuit and arc root movement were studied.This work further analyzes the characteristics and mechanisms of the arc motion when wind speed and direction,magnetic field and the expansion angle of the electrode are varied.Arc root movement is more likely to occur at the upper electrode.There is a competitive relationship between arc expansion and the transferring effect.The effect of wind on the arc column is greater than the effect on the arc root.The magnetic field has a significant driving effect on both the arc column and the arc root.The research results provide a comprehensive experimental basis for forther probing the method of DC arc suppression,and the improvement of the arcing horn.

Diagnosis of gas phase near the substrate surface in diamond film deposition by high-power DC arc plasma jet CVD

Optical emission spectroscopy （OES） was used to study the gas phase composition near the substrate surface during diamond deposition by high-power DC arc plasma jet chemical vapor deposition （CVD）. C2 radical was determined as the main carbon radical in this plasma atmosphere. The deposition parameters, such as substrate temperature, anode-substrate distance, methane concentration, and gas flow rate, were inspected to find out the influence on the gas phase. A strong dependence of the concentrations and distribution of radicals on substrate temperature was confirmed by the design of experiments （DOE）. An explanation for this dependence could be that radicals near the substrate surface may have additional ionization or dissociation and also have recombination, or are consumed on the substrate surface where chemical reactions occur.

Preparation of Carbon Encapsulated Iron Nanoparticles with Very Thin Shells by DC Arc Discharge

Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution transmission electron microscope （HRTEM）, energy dispersive X-ray （EDX） spectroscope, X-ray diffraction （XRD）, and X-ray photoelectron spectroscope （XPS） characterizations on the product B show that the thickness of the carbon shells of CEINPs in the product B is in the range of ca. 0.5-5.3 nm, i. e., which can be as thin as only two layers of graphite. The average diameter of the CEINPs is about 24. 7 nm. The total content of Fe element in the product B is 77.0 wt%. The saturation magnetization （Ms） and coercivity （Hc） of the product B are 107.4 emu/g and 143 Oe. resnectivelv. The formation of the CEINPs in the oroduct B is discussed briefly.

STUDY ON THE EXCITATION BEHAVIOUR OF RARE EARTH ELEMENTS IN DC ARC BY AXIAL-INTRODUCTION OF AEROSOL

In order to eliminate influence of the carriers on the evaporation of rare earth elements in DC arc,a de- vice which introduces axially the sample aerosol has been designed to study the effects of controlled-atmos- phere,discharge current,electrode polarity and introduction direction of aerosol on the emission of rare earth elements in DC arc discharge.The influence of various matrices and carriers on the line density and excitation condition of rare earth elements have also been studied,then the related excitation mechnism is proposed.

Arc deflection model and arc direction control for DC arc furnace

Based on the analysis of three-dimensional power conductor for DC arcfurnace, the electric arc deflection model was set up and the control system of the arc directionwas configured. According to the bus bar distribution at the bottom electrodes cooled by water, thearc direction control principle and its configuration were described. The simulation results showthat the control system can restrain the electric arc deflection and control the arc direction.

Effects of deposition parameters on microstructure and thermal conductivity of diamond films deposited by DC arc plasma jet chemical vapor deposition

The uniform diamond films with 60 mm in diameter were deposited by improved DC arc plasma jet chemical vapor deposition technique. The structure of the film was characterized by scanning electronic microcopy(SEM) and laser Raman spectrometry. The thermal conductivity was measured by a photo thermal deflection technique. The effects of main deposition parameters on microstructure and thermal conductivity of the films were investigated. The results show that high thermal conductivity, 10.0 W/(K·cm), can be obtained at a CH4 concentration of 1.5% (volume fraction) and the substrate temperatures of 880-920 ℃ due to the high density and high purity of the film. A low pressure difference between nozzle and vacuum chamber is also beneficial to the high thermal conductivity.

OES study of the gas phase during diamond films deposition in high power DC arc plasma jet CVD system

This paper used optical emission spectroscopy （OES） to study the gas phase in high power DC arc plasma jet chemical vapour deposition （CVD） during diamond films growth processes. The results show that all the deposition parameters （methane concentration, substrate temperature, gas flow rate and ratio of H2/Ar） could strongly influence the gas phase. C2 is found to be the most sensitive radical to deposition parameters among the radicals in gas phase. Spatially resolved OES implies that a relative high concentration of atomic H exists near the substrate surface, which is beneficial for diamond film growth. The relatively high concentrations of C2 and CH are correlated with high deposition rate of diamond. In our high deposition rate system, C2 is presumed to be the main growth radical, and CH is also believed to contribute the diamond deposition.

Integrated purification of gadolinium and preparation of Gd2O_(3) nanoparticles by DC arc plasma

The rare-earth metal Gd plays an important role in the energy,information,and national defence fields due to its special optical,electrical,magnetic,and catalytic properties.In this study,Gd was purified by direct current(DC)arc plasma,and Gd2O_(3) nanoparticles were prepared via an integration method using purified Gd.The effects of arc current,melting time,gas pressure,and atmosphere on the purification of Gd by DC arc plasma were investigated.With an increase in the arc current and melting time,the rate of removal of impurities from Gd enhances.Moreover,Gd melting was conducted by H_(2)-Ar arc plasma,which improves the impurity removal rate by increasing the H_(2) content.High thermal conductivity and chemical activity of the activated H atoms generated by the dissociation of H_(2) are the main reasons for the significant improvement in the impurity removal rate.The mechanism of Gd purification was analysed based on the above-mentioned experimental results.The as-synthesised Gd2 O_(3) nanoparticles have a uniform spherical structure(average diameter of 32.7 nm),appropriate dispersibility,and high purity.This study provides a new strategy for the integrated purification of metals and preparation of metal/metal-based nanomaterials by DC arc plasma.

Diagnosis of Electron,Vibrational and Rotational Temperatures in an Ar/N2 Shock Plasma Jet Produced by a Low Pressure DC Cascade Arc Discharge

In this paper, a low pressure Ar/N2 shock plasma jet with clearly multicycle al- ternating zones produced by a DC cascade arc discharge has been investigated by an emission spectral method combined with Abel inversion analysis. Plasma emission intensity, electron, vi- brational and rotational temperatures of the shock plasma have been measured in the expansion and compression zones. The results indicate that the ranges of the measured electron temperature, vibrational temperature and rotational temperature are 1.1 eV to 1.6 eV, 0.2 eV to 0.7 eV and 0.19 eV to 0.22 eV, respectively, and it is found for the first time that the vibrational and rota- tional temperatures increase while the electron temperature decreases in the compression zones. The electron temperature departs from the vibrational and the rotational temperatures due to non-equilibrium plasma effects. Electrons and heavy particles could not completely exchange energy via collisions in the shock plasma jet under the low pressure of 620 Pa or so.

Fluid Flow Modeling of Arc Plasma and Bath Circulation in DC Electric Arc Furnace

A mathematical model describing the flow field, heat transfer and the electromagnetic phenomenon in a DC electric arc furnace has been developed. First the governing equations in the arc plasma region are solved and the calculated results of heat transfer, current density and shear stresses on the anode surface are used as boundary conditions in a model of molten bath. Then a two-dimensional time-dependent model is used to describe the flow field and electromagnetic phenomenon in the molten bath. Moreover, the effect of bottom electrode diameter on the circulation of molten bath is studied.

Study on the Detection Methods of DC Series Arc Fault

It is difficult to detect and extinguish direct current(DC)arc in power electronics systems,and the arc could easily lead to a fire and cause great damage to surrounding equipment.A DC arc generation simulation unit is established,in which DC series arcs are generated by dragging the moving electrode away from the fixed one with the help of the stepper motor.In addition,a ferrite rod antenna is used to receive the electromagnetic radiation signals induced by the arcs.Based on experiments using the unit,the general characteristics of DC arc,including the pulse characteristics of arc current and source output in corresponding time window,and the frequency-domain characteristics of arc current,are studied.With discussion on three detection methods,it is concluded that the variation of current and voltage of arc,the spectrum of the arc current during the discontinuous intervals and the radiating electromagnetic signal are all features that can be adopted for detecting DC series arc.Therefore,a synthetic judgment method is suggested for further study.

3D Numerical Analysis of the Arc Plasma Behavior in a Submerged DC Electric Arc Furnace for the Production of Fused MgO

A three dimensional steady-state magnetohydrodynamic model is developed for the arc plasma in a DC submerged electric arc furnace for the production of fused MgO. The arc is generated in a small semi-enclosed space formed by the graphite electrode, the molten bath and unmelted raw materials. The model is first used to solve a similar problem in a steel making furnace, and the calculated results are found to be in good agreement with the published measurements. The behavior of arcs with different arc lengths is also studied in the furnace for MgO production. From the distribution of the arc pressure on the bath surface it is shown that the arc plasma impingement is large enough to cause a crater-like depression on the surface of the MgO bath. The circulation of the high temperature air under the electrode may enhance the arc efficiency, especially for a shorter arc.

Synthesis of High Quality Diamond Film by DC Arc Discharge Plasma Chemical Vapor Deposition

Diamond film is one of the special function materials in high technological area.There is an intense competition in the preparing methods and applications of dia-mond film. The successful synthesis of diamond film opens vast vistas for theapplication of diamond’s unique properties such as high thermal conductivity, highelectrical resistance, good optical transmission, extreme hardness and so on. So far,

Mathematical model on heat transfer of water-cooling steel-stick bottom electrode of DC electric arc furnace

For predicting and controlling the melted depth of bottomelectrode during the process of steelmaking, the water-cooling steel-stick electrode is taken as an example, to analyze the process ofheat transfer, then 3D mathematical model by control capacity methodis built. At the same time, the measurement on the melted depth ofbottom electrode is conducted which verified the correctness of thebuilt mathematical model. On the base of verification, all kinds ofkey parameters are calculated through the application and a series ofresults are simulated. Finally, the optimum parameters are found andthe service life of bottom electrode is prolonged.

Prodigy DC Arc直流电弧光谱仪在铌中铪元素分析中的应用

将纯铌及纯铌制品样品完全转化成氧化物,按一定比例与载体混合,直流电弧阳极激发,中阶梯光栅和棱镜色散系统进行分光。选择光谱特征谱线由L-PAD检测器进行信号接收,由计算机进行信号转换和数据处理。用直流电弧原子发射光谱法测定铌中铪元素。方法线性范围为10—200μg/g,方法简单,精密度和准确度较好。