基于DIC及CPG技术的热冷循环后花岗岩Ⅰ型断裂特性

深部储层岩石的热力学特性,尤其是循环热冷作用下损伤破坏特性,对于增强型地热系统井壁稳定性分析及地热开采效率评估具有重要意义。针对中心直裂纹半圆盘(NSCB)花岗岩试样,首先进行不同热冷循环处理(加热温度400℃,最高循环次数13次),然后开展3点弯Ⅰ型断裂韧度特性试验。基于裂纹扩展计(CPG)和数字图像相关(DIC)测试技术,研究了热冷循环作用下花岗岩Ⅰ型断裂韧度、断裂过程区(FPZ)、裂纹扩展速率及断裂轮廓特征的影响规律。试验结果表明:当热冷循环次数达到10次以上,花岗岩试样脆性明显减弱,而峰前软化特性和峰后延性增强;花岗岩的断裂过程区由裂缝尖端开始逐步孕育,断裂过程区长度随荷载增大呈先增大后减小的趋势,Ⅰ型断裂韧度、最大断裂过程区长度及裂纹平均扩展速度随热冷循环次数增大而指数减小,Ⅰ型断裂面随热冷循环次数增大越来越不平整。最后,基于X-ray衍射(XRD)和扫描电镜(SEM)等微观测试技术,研究了热冷循环作用对花岗岩矿物成分及微观结构的影响规律,结果表明花岗岩4种矿物成分的峰值衍射强度及矿物质量分数均随热冷循环次数增大而降低,而微裂纹大小及数量随热冷循环次数增大而增大。热冷循环作用下花岗岩的损伤劣化机理包含了多次高温热损伤、水冷冲击及水弱化等3方面的联合作用结果。

基于双反射镜的2D-DIC变形测量系统开发

二维数字图像相关(two-dimensional digital image correlation,2D-DIC)在测量过程中不可避免地会出现相机光轴与测量表面非垂直,由此产生的离面位移而将导致较大的测量误差,同时在视场受限的环境中难以通过单台相机完成大范围的变形测量。有鉴于此,该文开发了基于双反射镜的2D-DIC变形测量系统,使用双反射镜成像缓解离面运动对2D-DIC的影响,通过可移动相机实现小视场下的图像采集,提出基于频域移位的高精度图像拼接方法,并改进了融合函数,最终获得试样的高分辨率图像。单轴拉伸实验结果表明,轴向应变的平均相对误差相比传统2D-DIC方法降低12.82%,测量分辨率提高约34.92%,验证了测量系统的可行性和有效性。

基于有限元和DIC测试对FRP部分约束混凝土柱应变响应及数值模型研究

纤维增强聚合物(FRP)部分约束混凝土应用可以提高混凝土的承载力和经济价值。然而,FRP部分约束混凝土在垂直方向上不均匀应变响应还不够深入,应力-应变模型不够准确。本文通过应变片和数字图像相关(DIC)记录对FRP部分约束混凝土进行了轴向压缩试验,并利用ABAQUS有限元建立了包括0/1,1/4,1/3,1/2,2/3,3/4和1/1约束面积比的部分约束混凝土。试验结果表明:DIC和应变片结果分别反应了垂直和水平方向的应变规律,即试件在应变硬化或应变软化响应下均发生了明显的应变局部化;有限元结果能捕捉到试件表面约束力与x,y和z三轴的应变关系,得到了不同约束面积比的FRP部分约束混凝土柱的应力-应变关系,所提出的应力-应变模型能有较高的预测效果。

基于DIC古建筑青砖受冻融循环作用的损伤演化

以内蒙古隆盛庄古建筑青砖砌体为研究对象,通过数字图像相关(DIC)技术,研究古建筑青砖在冻融循环作用下的损伤破坏规律,采用双因子——损伤程度因子和损伤局部化因子来表征古建筑青砖的单轴压缩损伤过程,并根据双因子损伤演化曲线建立了不同冻融循环次数下的损伤演化模型.结果表明:古建筑青砖在单轴压缩下的破坏过程可分为初始损伤闭合阶段、线弹性损伤阶段、弹塑性损伤阶段和塑性损伤阶段4个阶段;随着冻融循环次数的增加,青砖表面应变集中程度增大,使其承载能力降低;冻融循环会缩短双因子曲线的线弹性阶段,同时利用双因子建立的损伤演化模型能有效反映冻融循环作用下古建筑青砖材料的损伤演化过程.

不同DIC评分系统对脓毒症患者凝血功能障碍早期诊断和预后预测的价值

目的基于脓毒症患者评价5种DIC评分系统,探讨不同DIC评分系统在诊断脓毒症患者中DIC发生和预后的价值,比较不同的DIC评分系统对脓毒症并发DIC的适用性。方法回顾性分析2019年12月1日至2021年12月31日于甘肃省人民医院住院部收治的脓毒症患者24h内的实验室指标和临床资料。分别使用5种DIC评分系统进行评分,比较5种DIC评分系统在不同严重程度的脓毒症患者中诊断率及出院转归的差异;绘制5种DIC评分系统的ROC曲线,评估各个评分系统在诊断脓毒症患者中DIC的准确性。结果脓毒症的病死率随着脓毒症严重程度加重逐渐升高(P<0.05);5种评分系统DIC与非DIC的出院转归比较,差异均有统计学意义(P<0.05);JAAM诊断的病例中包含了JMHW、CDSS和部分ISTH,非显性ISTH诊断的病例中包含了ISTH;ISTH、JAAM、JMHW、CDSS、非显性ISTH 5种评分系统诊断DIC病例中,未愈与死亡分别是非DIC病例的3.0、3.8、4.2、3.9、3.0倍。结论JAAM评分系统对于成人脓毒症患者的诊断率和敏感性较高;CDSS和JMHW评分系统对脓毒症患者预后判断的准确性较好。

A review of physicochemical properties of dissolved organic carbon and its impact over mountain glaciers

Investigating the characteristics and transformation of water-soluble carbonaceous matter in the cryosphere regions is important for understanding biogeochemical process in the earth system.Water-soluble carbonaceous matter is a heterogeneous mixture of organic compounds that is soluble in aquatic environments.Despite its importance,we still lack systematic understanding for dissolved organic carbon(DOC)in several aspects including exact chemical composition and physical interactions with microorganisms,glacier meltwater.This review presents the chemical composition and physical properties of glacier DOC deposited through anthropogenic emission,terrestrial,and biogenic sources.We present the molecular composition of DOC and its effect over snow albedo and associated radiative forcings.Results indicate that DOC in snow/ice is made up of aromatic protein-like species,fulvic acid-like materials,and humic acid-like materials.Light-absorbing impurities in surface snow and glacier ice cause considerable albedo reduction and the associated radiative forcing is definitely positive.Water-soluble carbonaceous matter dominated the carbon transport in the high-altitude glacial area.Owing to prevailing global warming and projected increase in carbon emission,the glacial DOC is expected to release,which will have strong underlying impacts on cryosphere ecosystem.The results of this work have profound implications for better understanding the carbon cycle in high altitude cryosphere regions.A new compilation of globally distributed work is required,including large-scale measurements of glacial DOC over high-altitude cryosphere regions,to overcome and address the scientific challenges to constrain climate impacts of light-absorbing impurities related processes in Earth system and climate models.

基于DIC技术的自密实混凝土界面裂缝扩展规律研究

采用自密实混凝土作为堆石混凝土坝的抗冲磨层并与坝体进行一体化浇筑成型是一种新构造,其中抗冲磨层与坝体的界面性能至关重要。通过制作600 mm×600 mm×600 mm自密实混凝土(SCC)试件(C40SCC、C25SCC)及C40、C25SCC分层浇注试件(C40-C25SCC),结合数字图像技术(DIC)开展劈裂抗拉试验,分析了自密实混凝土界面裂缝扩展规律。结果表明:SCC断面破坏形态表现为骨料劈裂和剥落2种破坏形式;C40SCC、C25SCC及C40-C25SCC劈裂抗拉强度分别为1.861、1.416和1.362 MPa;基于DIC技术获取了裂缝相关参数,其中C40-C25SCC裂缝最大开口宽度、扩展时间均为最大,分别为0.125 mm、10.667 ms,C25SCC裂缝最大扩展速度最快,为10.12 m/s。研究表明:骨料的存在及粒径大小改变了试件破坏形态,影响了裂缝开口宽度及扩展速度变化。

基于2D-DIC的轴体扭矩测量方法

针对传统二维数字图像相关法易受离面位移影响,难以用于测量扭矩这一现状,文中在现有二维数字图像相关法的基础上,提出基于曲面展开和位移量预测的轴体扭矩测量方法。采用曲面展开法将二维轴体图像与轴体物理结构进行结合,获取轴体三维曲面信息,有效补偿了轴体扭转位移计算结果,并利用位移量预测法减少了参考子区与变形子区相对位移的计算量。进行了曲面展开法补偿扭转位移前后的对比实验,传统数字图像相关法与位移量预测法的对比实验和不同直径轴体扭矩测量实验。实验结果表明:加入曲面展开法后,扭矩测量结果的绝对误差最高减小了0.21 N·m;位移量预测法相对传统方法计算结果相近,但计算速度最高提升了31.6%;不同直径轴体扭矩测量结果的相对误差在±4.35%以内,具有较好的稳定性和准确性。

基于DIC的切削应变观测实验平台开发与应用

切削过程是刀具与工件相互作用形成切屑的过程,会出现包括切削力、热、应力应变等物理现象。对于切削过程的观测,有利于学生对机械工程相关专业“机械制造技术基础”、“现代加工技术”等课程的深入理解,同时对切削加工技术的发展和进步具有重要意义。本文基于数字图像相关法建立了切削过程的应变观测实验平台,包括双目相机、恒定光源、外置触发器、表面清洁装置及数据分析软件等,通过相机连续拍摄被加工零件表面的随机散斑分布,计算分析出切削加工过程中的应变情况。该实验平台适用多种切削加工方式,弥补了传统方法不能实验观测切削应变的不足,具备适用性强、应用成本低、安全性高、直观易操作等特点,对于高校学生展开切削物理现象观测进而研究切削过程应力应变等信息提供了软硬件支持。

基于3D-SLDV和高速3D-DIC的离心轮模态分析

全场振型对于研究发动机结构动特性至关重要,介绍了基于3D-SLDV和高速3D-DIC两种全场振动测试方法的测试原理。以液体火箭发动机离心轮为例,分别采用两种技术获得了5 kHz内离心轮的固有频率和振型,对比分析了两种测试方法的优缺点,结果表明:3D-SLDV技术比3D-DIC技术具有更低的位移本底噪声,对高频振型辨识更有利,但该方法属于逐点扫描测试,测试时间长;3D-DIC技术全场数据同时采集,采集时间短,具有更精细的振型,但图像的数据量大,数据传输和分析时间长,同时这种基于位移的测试方法存在本底噪声限制。

Recent progress on nanomaterial-based electrochemical dissolved oxygen sensors

Dissolved oxygen(DO)usually refers to the amount of oxygen dissolved in water.In the environment,medicine,and fermentation industries,the DO level needs to be accurate and capable of online monitoring to guide the precise control of water quality,clinical treatment,and microbial metabolism.Compared with other analytical methods,the electrochemical strategy is superior in its fast response,low cost,high sensitivity,and portable device.However,an electrochemical DO sensor faces a trade-off between sensitivity and long-term stability,which strongly limits its practical applications.To solve this problem,various advanced nanomaterials have been proposed to promote detection performance owing to their excellent electrocatalysis,conductivity,and chemical stability.Therefore,in this review,we focus on the recent progress of advanced nanomaterial-based electrochemical DO sensors.Through the comparison of the working principles on the main analysis techniques toward DO,the advantages of the electrochemical method are discussed.Emphasis is placed on recently developed nanomaterials that exhibit special characteristics,including nanostructures and preparation routes,to benefit DO determination.Specifically,we also introduce some interesting research on the configuration design of the electrode and device,which is rarely introduced.Then,the different requirements of the electrochemical DO sensors in different application fields are included to provide brief guidance on the selection of appropriate nanomaterials.Finally,the main challenges are evaluated to propose future development prospects and detection strategies for nanomaterial-based electrochemical sensors.

Overview of the expert consensus on the digital therapeutics in addictiverelated disorders

Background Addictive disorders have gained worldwide attention.The Chinese Association of Drug Abuse Prevention and Treatment,along with the consensus panel on digital therapeutics(DTx)for addictive disorders,has published an expert consensus on DTx for addictive disorders.1 This consensus discusses and summarises the current research and application status of DTx for addictive disorders.It identifies its clinical value,application directions,research and development principles,and future prospects.As the consensus is published in Chinese,it may not be easily accessible to an international audience.To address this,we present here an overview of the expert consensus on DTx for addictive disorders in China.The recommendations from the consensus are summarised in table 1.

A numerical model study on the spatial and temporal variabilities of dissolved oxygen in Qinzhou Bay of the northern Beibu Gulf

Oxygen facilitates the breakdown of the organic material to provide energy for life.The concentration of dissolved oxygen(DO) in the water must exceed a certain threshold to support the normal metabolism of marine organisms.Located in the northern B eibu Gulf,Qinzhou B ay receives abundant freshwater and nutrients from several rivers which significantly influence the level of the dissolved oxygen.However,the spatial-temporal variations of DO as well as the associated driving mechanisms have been rarely studied through field observations.In this study,a three-dimension al coupled physical-biogeochemical model is used to investigate the spatial and seasonal variations of the DO and the associated driving mechanisms in Qinzhou B ay.The validation against observations indicates that the model can capture the seasonal and inter-annual variability of the DO concentration with the range of 5-10 mg/L.Sensitivity experiments show that the river discharges,winds and tides play crucial roles in the seasonal variability of the DO by changing the vertical mixing and stratification of the water column and the circulation pattern.In winter,the tide and wind forces have strong effects on the DO distribution by enhancing the vertical mixing,especially near the bay mouth.In summer,the river discharges play a dominant role in the DO distribution by inhibiting the vertical water exchange and delivering more nutrients to the Bay,which increases the DO depletion and results in lower DO on the bottom of the estuary salt wedge.These findings can contribute to the preservation and management of the coastal environment in the northern Beibu Gulf.

Molecular investigation into the transformation of recalcitrant dissolved organic sulfur in refinery sour water during stripping process

Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD)and organic sulfur contents.Even after the recovery of H_(2)S from the sour water by the stripping process,the effluent still contains a high concentration of dissolved organic sulfur(DOS),which can have a huge bad influence.While chemical composition of dissolved organic matter(DOM)in refinery wastewater has been extensively studied,the investigation of recalcitrant DOS from sour waters remains unclear.In the present study,chemical composition of sour water DOMs(especially DOS)was investigated using fluorescence spectroscopy(excitation-emission matrix,EEM)and mass spectrometry,including gas chromatography-mass spectrometry(GC-MS)and high-resolution Orbitrap MS.The GC-MS and EEM results showed that volatile and low-aromaticity compounds were effectively removed during the stripping process,while compounds with high hydrophilicity and humification degree were found to be more recalcitrant.The Orbitrap MS results showed that weak-polar oxygenated sulfur compounds were easier to be removed than oxygenated compounds.However,the effluent still contained significant amounts of sulfur-containing compounds with multiple sulfur atoms,particularly in the form of highly unsaturated and aromatic compounds.The Orbitrap MS/MS results of CHOS-containing compounds from the effluent indicate that the sulfur atoms may exist as sulfonates,disulfide bonds,thioethers.Understanding the composition and structure of sour water DOS is crucial for the development of effective treatment processes that can target polysulfide compounds and minimize their impact on the environment.

Inter-annual variations of dissolved oxygen and hypoxia off the northern Changjiang River(Yangtze River) Estuary in summer from 1997 to 2014

Hypoxia off the Changjiang River Estuary has been the subject of much attention,yet systematic observations have been lacking,resulting in a lack of knowledge regarding its long-term change and drivers.By revisiting the repeated surveys of dissolved oxygen(DO) and other relevant hydrographic parameters along the section from the Changjiang River Estuary to the Jeju-do in the summer from 1997 to 2014,rather different trends were revealed for the dual low-DO cores.The nearshore low-DO core,located close to the river mouth and relatively stable,shows that hypoxia has become more severe with the lowest DO descen ding at a rate of -0.07 mg/(L·a) and the thickness of low-DO zone rising at a rate of 0.43 m/a.The offshore core,centered around 40-m isobath but moving back and forth between 123.5°-125°E,shows large fluctuations in the minimum DO concentration,with the thickness of low-DO zone falling at a rate of -1.55 m/a.The probable factors affecting the minimum DO concentration in the two regions also vary.In the nearshore region,the decreasing minimum DO is driven by the increase in both stratification and primary productivity,with the enhanced extension of the Changjiang River Diluted Water(CDW) strengthening stratification.In the offshore region,the fluctuating trend of the minimum DO concentration indicates that both DO loss and DO supplement are distinct.The DO loss is primarily attributed to bottom apparent oxygen utilization caused by the organic matter decay and is also relevant to the advection of low-DO water from the nearshore region.The DO supplement is primarily due to weakened stratification.Our analysis also shows that the minimum DO concentration in the nearshore region was extremely low in 1998,2003,2007 and 2010,related to El Ni?o signal in these summers.

Straw mulching alters the composition and loss of dissolved organic matter in farmland surface runoff by inhibiting the fragmentation of soil small macroaggregates

Straw mulching is a widespread practice for reducing the soil carbon loss caused by erosion.However,the effects of straw mulching on dissolved organic matter(DOM)runoff loss from black soil are not well studied.How straw mulching affects the composition and loss of runoff DOM by changing soil aggregates remains largely unclear.Here,a straw mulching treatment was compared to a no mulching treatment(as a control)on sloping farmland with black soil erosion in Northeast China.We divided the soil into large macroaggregates(>2 mm),small macroaggregates(0.25-2 mm),and microaggregates(<0.25 mm).After five rain events,the effects of straw mulching on the concentration(characterized by dissolved organic carbon(DoC)and composition(analyzed by fluorescence spectroscopy)of runoff and soil aggregate DOM were studied.The results showed that straw mulching reduced the runoff amount by 54.7%.Therefore,although straw mulching increased the average DOc concentration in runoff,it reduced the total runoff DOM loss by 48.3%.The composition of runoff DOM is similar to that of soil,as both contain humic-like acid and protein-like components.With straw mulching treatment,the protein-like components in small macroaggregates accumulated and the protein-like components in runoff declined with rain events.Fluorescence spectroscopy technology may help in understanding the hydrological paths of rain events by capturing the dynamic changes of runoff and soil DOM characteristics.A variation partitioning analysis(VPA)indicated that the DOM concentration and composition of microaggregates explained 68.2%of the change in runoff DOM from no mulching plots,while the change in runoff DOM from straw mulching plots was dominated by small macroaggregates at a rate of 55.1%.Taken together,our results demonstrated that straw mulching reduces the fragmentation of small macroaggregates and the loss of microaggregates,thus effecting DOM compositions in soil and reducing the DOM loss in runoff.These results provide a theoretical basis for reducing carbon loss in sloping farmland.

The impact of typhoons on the biogeochemistry of dissolved organic matter in eutrophic bays in northwestern South China Sea

Highly productive estuaries facilitate intense decomposition of dissolved organic matter(DOM) as a carbon source.However,the specific impacts of typhoons on DOM decomposition in eutrophic bays remain unclear.To address this issue,we investigated the spectral characteristics of DOM before and after Typhoon Ewiniar in Zhanjiang B ay,a eutrophic semi-enclosed bay in the northwestern South China Sea.The results revealed that intense microbial decomposition of DOM occurred during the pre-typhoon period because high nutrient inputs facilitated the mobilization of DOM in the bay.However,the intrusion of external seawater induced by the typhoon diluted the nutrient levels in Zhanjiang B ay,reducing the impact of microbial decomposition on DOM during the post-typhoon perio d.Nevertheless,the net addition of DOM occurred in Zhanjiang Bay during the post-typhoon period,possibly because of the decomposition of particulate organic matter(POM) and desorption of particulate matter.In addition,an increase in apparent oxygen utilization,a decrease in DO saturation and the reduced level of Chl a indicated that organic matter(OM) decomposition was enhanced and OM decomposition shifted to POM decomposition in Zhanjiang Bay after the typhoon.Overall,our study highlighted the shift in the intense OM decomposition from DOM to POM decomposition before and after typhoons in eutrophic bays,providing new insights into the response of typhoons to biogeo chemistry.

Impact of transparent exopolymer particles on the dynamics of dissolved organic carbon in the Amundsen Sea,Antarctica

The Southern Ocean is an important carbon sink pool and plays a critical role in the global carbon cycling.The Amundsen Sea was reported to be highly productive in inshore area in the Southern Ocean.In order to investigate the influence of transparent exopolymer particles(TEP)on the behavior of dissolved organic carbon(DOC)in this region,a comprehensive study was conducted,encompassing both open water areas and highly productive polynyas.It was found that microbial heterotrophic metabolism is the primary process responsible for the production of humic-like fluorescent components in the open ocean.The relationship between apparent oxygen utilization and the two humic-like components can be accurately described by a power-law function,with a conversion rate consistent with that observed globally.The presence of TEP was found to have little impact on this process.Additionally,the study revealed the accumulation of DOC at the sea surface in the Amundsen Sea Polynya,suggesting that TEP may play a critical role in this phenomenon.These findings contribute to a deeper understanding of the dynamics and surface accumulation of DOC in the Amundsen Sea Polynya,and provide valuable insights into the carbon cycle in this region.

Exploration of the Existence Forms and Patterns of Dissolved Oxygen Molecules in Water

The structure of liquid water is primarily composed of three-dimensional networks of water clusters formed by hydrogen bonds,and dis-solved oxygen is one of the most important indicators for assessing water qual-ity.In this work,distilled water with different concentration of dissolved oxygen were prepared,and a clear negative correlation between the size of water clus-ters and dissolved oxygen concentration was observed.Besides,a phenomenon of rapid absorption and release of oxygen at the water interfaces was unveiled,suggesting that oxygen molecules predominantly exist at the interfaces of water clusters.Oxygen molecules can move rapidly through the interfaces among water clusters,allowing dissolved oxygen to quickly reach a saturation level at certain partial pressure of oxygen and temperature.Further exploration into the mechanism by molecular dynamics simulations of oxygen and water clusters found that oxygen molecules can only exist stably at the interfaces among water clusters.A semi-empirical formula relating the average number of water molecules in a cluster(n)to ^(17)O NMR half-peak width(W)was summarized:n=0.1 W+0.85.These findings provide a foundation for exploring the structure and properties of water.

Impacts of Water-Sediment Regulation Scheme on Chromophoric Dissolved Organic Matter in the Lower Yellow River

As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been carried out annually in the Yellow River since 2002,is a typical human activity affecting river water quality.Chromophoric dissolved organic matter(CDOM)in river is susceptible to changes in ecological and environmental conditions as well as human activities.Here,we report variations in dissolved organic carbon concentrations,compositions and sources of CDOM in time series samples in the lower Yellow River during WSRS.In addition,a parallel factor fluorescence analysis(PARAFAC)method is applied to identify different fluorescent components in water samples during WRSR,showing four major components including tryptophan-like component(C1),microbial humic-like component(C2),terrestrial humic-like component(C3)and tyrosine-like component(C4).In general,C1 increased after water regulation,while C2 and C3 increased after sediment regulation,indicating that the water and sediment released by the dam have different effects on CDOM compositions.Under the impacts of the dam,source of CDOM in the lower Yellow River is mainly autochthonous related to microbial activities,and is regulated by the terrestrial input during WSRS period.Sediment resuspension inhibits microbial activities and reduces the production of autochthonous CDOM.Overall,human activities especially WSRS,as exemplified here,significantly alter the quality and quantity of CDOM in the lower Yellow River,affecting CDOM dynamics and biogeochemical processes in the estuarine environment.