Difluoromethane is typically produced vialiquid-phase fluorination as performed in a batch reactor.However,this process suffers from some problems,e.g.,severe corrosion of the reactor,high safety risk,and the regenera...Difluoromethane is typically produced vialiquid-phase fluorination as performed in a batch reactor.However,this process suffers from some problems,e.g.,severe corrosion of the reactor,high safety risk,and the regeneration of the catalyst.In this paper,a flow process as performed in the tubular reactor was designed.The optimum conditions for continuous synthesis of difluoromethane were obtained as follows:the reaction temperature was 100℃,the molar ratio of dichloromethane to hydrogen fluoride was 1.6:1 and the reaction time was 300 s.The operation of the cyclic process was stable for 24 h with the conversion per pass of hydrogen fluoride up to 16.2%.The unreacted raw materials were easily reused.The deactivation of the common catalyst,antimony pentachloride,was investigated by catalyst concentration curve and XPS analysis.The approach proposed in this work is proven to be safe,efficient and low amount of catalyst.展开更多
The research work on thermophysical properties of difluoromethane (HFC-32) is summarized. Experimental data of critical parameters, vapor pressure, PVT, speed of sound, ideal-gas heat capacity, surface tension, viscos...The research work on thermophysical properties of difluoromethane (HFC-32) is summarized. Experimental data of critical parameters, vapor pressure, PVT, speed of sound, ideal-gas heat capacity, surface tension, viscosity, thermal conductivity are given and corresponding correlations are developed. The cross equation of state, the correlations of saturated liquid density and second virial coefficient for HFC-32 are also developed.展开更多
We investigate thermophysical properties of environmental -friendly refrigerants of trifluo-roiodomethane and difluoromethane in detail. The progress of measurement techniques for thermophysical properties of fluids i...We investigate thermophysical properties of environmental -friendly refrigerants of trifluo-roiodomethane and difluoromethane in detail. The progress of measurement techniques for thermophysical properties of fluids is also described.展开更多
基金financial support from the National Natural Science Foundation of China(21878265,21606104)the National Key Research and Development Program of China(2016YFB0301800)。
文摘Difluoromethane is typically produced vialiquid-phase fluorination as performed in a batch reactor.However,this process suffers from some problems,e.g.,severe corrosion of the reactor,high safety risk,and the regeneration of the catalyst.In this paper,a flow process as performed in the tubular reactor was designed.The optimum conditions for continuous synthesis of difluoromethane were obtained as follows:the reaction temperature was 100℃,the molar ratio of dichloromethane to hydrogen fluoride was 1.6:1 and the reaction time was 300 s.The operation of the cyclic process was stable for 24 h with the conversion per pass of hydrogen fluoride up to 16.2%.The unreacted raw materials were easily reused.The deactivation of the common catalyst,antimony pentachloride,was investigated by catalyst concentration curve and XPS analysis.The approach proposed in this work is proven to be safe,efficient and low amount of catalyst.
文摘The research work on thermophysical properties of difluoromethane (HFC-32) is summarized. Experimental data of critical parameters, vapor pressure, PVT, speed of sound, ideal-gas heat capacity, surface tension, viscosity, thermal conductivity are given and corresponding correlations are developed. The cross equation of state, the correlations of saturated liquid density and second virial coefficient for HFC-32 are also developed.
文摘We investigate thermophysical properties of environmental -friendly refrigerants of trifluo-roiodomethane and difluoromethane in detail. The progress of measurement techniques for thermophysical properties of fluids is also described.
