M. Stoll's total synthetic route for dl-muscone was improved. 2.15.Hexadecanedione was synthesized by PTC method and converted into dehydromuscones through intramolecular aldol reaction by the mixture of zinc chlo...M. Stoll's total synthetic route for dl-muscone was improved. 2.15.Hexadecanedione was synthesized by PTC method and converted into dehydromuscones through intramolecular aldol reaction by the mixture of zinc chloride and the Grinard reagent of isoamyl bromide used as condensing agent. Catalytic hydrogenation of dehydromuscones gave dl-muscone.展开更多
文摘M. Stoll's total synthetic route for dl-muscone was improved. 2.15.Hexadecanedione was synthesized by PTC method and converted into dehydromuscones through intramolecular aldol reaction by the mixture of zinc chloride and the Grinard reagent of isoamyl bromide used as condensing agent. Catalytic hydrogenation of dehydromuscones gave dl-muscone.
