The effects of potassium ferricyanide,sodium n-dodecyl sulfate,sodium hydroxide and temperature on the molecular weight and the yield of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) synthesized in an aqueous medium wer...The effects of potassium ferricyanide,sodium n-dodecyl sulfate,sodium hydroxide and temperature on the molecular weight and the yield of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) synthesized in an aqueous medium were studied.It was found that oxygen in air had little influence on the oxidative polymerization of 2,6-dimethylphenol(DMP) in the aqueous medium,and potassium ferricyanide was only an oxidant during the oxidative polymerization of DMP.Sodium n-dodecyl sulfate could stabilize polymer particles an...展开更多
The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational...The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational platform).The properties of the liquid film and the wall shear stress(WSS)are compared with those obtained for a potassium bromide solution.Different working conditions are considered.It is noted that the ionic liquid demonstrates a better absorption capability,with a coefficient of performance(COP)of 0.55.It is proved that the[EMIM][DMP]+H_(2)O ionic liquid working substance is superior to the potassium bromide solution in terms of heat and mass transfer.展开更多
基金supported by the National Natural Science Foundation of China(No.20674075)Natural ScienceFoundation of Zhejiang Province(No.Y404299)Young Talents Project of Zhejiang Province(No.2008R40G2010065).
文摘The effects of potassium ferricyanide,sodium n-dodecyl sulfate,sodium hydroxide and temperature on the molecular weight and the yield of poly(2,6-dimethyl-1,4-phenylene oxide)(PPO) synthesized in an aqueous medium were studied.It was found that oxygen in air had little influence on the oxidative polymerization of 2,6-dimethylphenol(DMP) in the aqueous medium,and potassium ferricyanide was only an oxidant during the oxidative polymerization of DMP.Sodium n-dodecyl sulfate could stabilize polymer particles an...
文摘The falling film of an ionic liquid([EMIM][DMP]+H_(2)O)and its effect on a refrigeration system are numerically simulated in the framework of a Volume of Fluid(VOF)method(as available in the ANSYS Fluent computational platform).The properties of the liquid film and the wall shear stress(WSS)are compared with those obtained for a potassium bromide solution.Different working conditions are considered.It is noted that the ionic liquid demonstrates a better absorption capability,with a coefficient of performance(COP)of 0.55.It is proved that the[EMIM][DMP]+H_(2)O ionic liquid working substance is superior to the potassium bromide solution in terms of heat and mass transfer.
