Concentrations of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) were measured from Nov. 1995 to Sep. 1997 in seawater of Jiaozhou Bay, other ecological factors such as water temperature, salinity, Chl a ...Concentrations of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) were measured from Nov. 1995 to Sep. 1997 in seawater of Jiaozhou Bay, other ecological factors such as water temperature, salinity, Chl a and zooplankton were also investigated. Distribution of DMS showed remarkable variation spatially and temporally, ranging from 0.3 to 52.3 nmol/L. Seasonally, DMS concentration was high in late spring and low in autumn and winter. There was similar but weaker seasonal variation of DMSP. Generally, DMS concentration inside the bay was higher than that outside the bay; highest concentration often occurred nearshore. In some summer and autumn cruises DMS surface water was significantly higher than that in bottom water. Analysis indicated that salinity and zooplankton had significant influence on total DMS level in seawater. The estimation of sea-air flux of DMS showed significant seasonal variation, was the highest in spring [2441 μgS/(m2·d)] and lowest in winter [272 (m2 · d) ], with an annual average of 924 μgS/(m2 ·d) .展开更多
The distributions of DMS and its precursor dimethylsulfoniopropionate, in both dissolved （DMSPd） and particulate fractions （DMSPp） were determined in the sea-surface microlayer and corresponding subsurface water o...The distributions of DMS and its precursor dimethylsulfoniopropionate, in both dissolved （DMSPd） and particulate fractions （DMSPp） were determined in the sea-surface microlayer and corresponding subsurface water of the Jiaozhou Bay, China and its adjacent area in May and August 2006. The concentrations of all these components showed a clear seasonal variation, with higher concen- trations occurring in summer. This can be mainly attributed to the higher phytoplankton biomass observed in summer. Simultaneously, the enrichment extents of DMSPd and DMSPp in the mi- crolayer also exhibited seasonal changes, with higher values in spring and lower ones in summer. Higher water temperature and stronger radiant intensity in summer can enhance their solubility and photochemical reaction in the microlayer water, reducing their enrichment factors （the ratio of concentration in the microlayer to that in the corresponding subsurface water）. A statistically significant relationship was found between the microlayer and subsurface water concentrations of DMS, DMSP and chlorophyll a, demonstrating that the biogenic materials in the microlayer come primarily from the underlying water. Moreover, our data show that the concentrations of DMSPp and DMS were significantly correlated with the levels of chlorophyll a, indicating that phytoplankton biomass might play an important role in controlling the distributions of biogenic sulfurs in the study area. The ratios of DMS/chlorophyll a and DMSPpchlorophyll a varied little from spring to summer, suggesting that there was no obvious change in the proportion of DMSP producers in the phytoplankton community. The mean sea-to-air flux of DMS from the study area was estimated to be 5.70 μmol/（m^2·d）, which highlights the effects of human impacts on DMS emission.展开更多
Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expec...Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.展开更多
This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O_2 fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and thatthe diffe...This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O_2 fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and thatthe difference of DO was great in upper and bottom waters in Apr. 1994; but that seawater mixingwas strong and the difference of DO was small in upper and bettom waters in Oct. 1994. The above con-dusions were specially obvious in continental shelf waters under 100m. The DO maximum in subsurfacelayer waters appeared only at several stations and in general the DO in the waters decreased with depth.The horizontal distributions of O_2 fluxes across the sea-air interface appeared in stripes in Leg 9404 whenmost regions covend were supersaturated with O_2. seawater to air flux wn large, and that on section No.1was 1.594 L/m^2·d. The horizontal distribution of O_2 fluxes across the sea-air interface appeared lumpy inLeg 9410, when most regions covered were unsaturated with O_2. O_2 was dissolved from air to seawater,and the fluxes were 0.819 L/m^2·d on section No. 1 in Leg 9310, 0.219 L/m^2·d in Leg 9410. The mainreasons for DO change in surface layer seawater were the mixture of upper and bottom layer water, and theexchange of O_2 across the sea-air interface. The variation of DO by biological activity was only 20% of totalchange of DO.展开更多
Net heat flux,sea surface temperature(SST),and sea surface wind in the northern Indian Ocean were investigated using the TropFlux,ERA5,and J-OFURO3 datasets and correlation analysis,power spectrum analysis,and singula...Net heat flux,sea surface temperature(SST),and sea surface wind in the northern Indian Ocean were investigated using the TropFlux,ERA5,and J-OFURO3 datasets and correlation analysis,power spectrum analysis,and singular value decomposition(SVD)methods,respectively.The relationships between net heat flux,SST,and sea surface winds were determined.The coupled modes of net heat flux and wind have been found to explain the SST variations in the Indian Ocean basin and the generation mechanism of the Indian Ocean Dipole(IOD).The correlation between net heat flux and wind is strongly negative.The SST lags the net heat flux and wind by approximately one month and has strong positive and negative correlations,respectively.The correlation between net heat flux and wind in the northern Indian Ocean is not only seasonal but also regionally dependent on seasonal variations.Using the SVD method,the important role of net heat flux in local sea-air interactions is discussed and identified as the initial perturbation that triggers the SST anomalies in the Southeast Indian Ocean,and the areas with key sea-air interactions and the generation mechanisms of the local sea-air interactions that form the IOD are determined.展开更多
In this article, a sensitivity test of air-sea surface flux model was carried out with the field observation data of Project “South China Sea Air-Sea Flux Measurement in 2000”. The results show that sensible heat fl...In this article, a sensitivity test of air-sea surface flux model was carried out with the field observation data of Project “South China Sea Air-Sea Flux Measurement in 2000”. The results show that sensible heat fluxes are sensitive to observation errors, increasing the error of model calculation; In contrast, the latent heat flux and momentum flux are not as sensitive to observation errors as the sensible heat, and their calculated results are reliable. The test result also verifies the rationality of the surface flux values calculated and the conclusions can be used to detect errors in observed data.展开更多
Reviews on the current studies on the sea to air flux of dimethyl sulfide (DMS) have been made at home and abroad, pointing out that the flux of DMS is influenced by many factors. There is great difference between the...Reviews on the current studies on the sea to air flux of dimethyl sulfide (DMS) have been made at home and abroad, pointing out that the flux of DMS is influenced by many factors. There is great difference between the results coming from different models. Besides, this paper focuses on the oxidation mechanisms of DMS by OH and NO3 radicals after it enters the atmosphere, the oxidation products’ contribution to acid rain and fog and the relationships among the DMS, CCN and climate system.展开更多
The distributions of dimethylsulfide （DMS） and its precursor dimethylsulfoniopropionate （DMSP） in surface water of the Yellow Sea and the Bohai Sea were studied during June 2011. The mean concentrations and ranges...The distributions of dimethylsulfide （DMS） and its precursor dimethylsulfoniopropionate （DMSP） in surface water of the Yellow Sea and the Bohai Sea were studied during June 2011. The mean concentrations and ranges of DMS, dissolved DMSP （DMSPd）, and particulate DMSP （DMSPp） in surface waters were 6.85 （1.60-12.36）, 7.25 （2.28-19.05） and 61.87 （6.28-224.01） nmol/L, respectively. There were strong correlations between DMSPp and chlorophyll a in the Bohai Sea and the North Yellow Sea, respectively, and concentrations of DMS and DMSP were high, with a relatively high proportion of dinoflagellates, in the region of the South Yellow Sea Cold Water Mass. Results show that phytoplankton biomass and species composition were important factors that controlled the distribution of DMS and DMSP. Complex environmental factors, including nutrients, transparency, and terrestrial runoff, might also influence the variability in DMS and DMSP. Biological production and consumption rates of DMS in the Bohai Sea were higher than those in the Yellow Sea. DMS production rates were closely correlated with DMSPd concentrations. DMS and DMSP exhibited obvious diel variations, with high concentrations occurring in the late afternoon （16：00-19：00） and low concentrations occurring during the night, implying that the intensity of solar radiation had a significant influence on these variations. Size distributions of chlorophyll a and DMSPp were also investigated and large nanoplankton （5-20 μm）, mainly diatoms, contributed significantly to chlorophyll a and DMSPp at most stations. The average sea-to-air flux of DMS in the study area was estimated to be 11.07 μmol/（m^2·d） during the summer.展开更多
The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) and improved DM-EMIs is shown, and possible applications to heat engines as one of the energy harvesting t...The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) and improved DM-EMIs is shown, and possible applications to heat engines as one of the energy harvesting technologies are also discussed. The idea is induced by integrating irreversible thermodynamical mechanism of a water drinking bird with that of a Stirling engine, resulting in thermoelectric energy generation different from conventional heat engines. The current thermoelectric energy conversion with DM-EMI can be applied to wide ranges of temperature differences. The mechanism of DM-EMI energy converter is examined in terms of axial flux magnetic lines and categorized as the axial flux generator. It is useful for practical applications to macroscopic heat engines such as wind, geothermal, thermal and nuclear power turbines and heat-dissipation lines, for supporting thermoelectric energy conversions. The technique of DM-EMI will contribute to environmental problems to maintain clean and susceptible energy as one of the energy harvesting technologies.展开更多
基金This study was supported by the NSFC project No.40232021,30170189 and 40176037
文摘Concentrations of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) were measured from Nov. 1995 to Sep. 1997 in seawater of Jiaozhou Bay, other ecological factors such as water temperature, salinity, Chl a and zooplankton were also investigated. Distribution of DMS showed remarkable variation spatially and temporally, ranging from 0.3 to 52.3 nmol/L. Seasonally, DMS concentration was high in late spring and low in autumn and winter. There was similar but weaker seasonal variation of DMSP. Generally, DMS concentration inside the bay was higher than that outside the bay; highest concentration often occurred nearshore. In some summer and autumn cruises DMS surface water was significantly higher than that in bottom water. Analysis indicated that salinity and zooplankton had significant influence on total DMS level in seawater. The estimation of sea-air flux of DMS showed significant seasonal variation, was the highest in spring [2441 μgS/(m2·d)] and lowest in winter [272 (m2 · d) ], with an annual average of 924 μgS/(m2 ·d) .
基金The National Natural Science Foundation of China under contract Nos 40476034, 40525017 and 40490265 the Science and Technology Key Project of Shandong Province, China under contract No 2006GG2205024the Taishan Mountain Scholar Construction Engineering Special Fund of Shandong Province, China
文摘The distributions of DMS and its precursor dimethylsulfoniopropionate, in both dissolved （DMSPd） and particulate fractions （DMSPp） were determined in the sea-surface microlayer and corresponding subsurface water of the Jiaozhou Bay, China and its adjacent area in May and August 2006. The concentrations of all these components showed a clear seasonal variation, with higher concen- trations occurring in summer. This can be mainly attributed to the higher phytoplankton biomass observed in summer. Simultaneously, the enrichment extents of DMSPd and DMSPp in the mi- crolayer also exhibited seasonal changes, with higher values in spring and lower ones in summer. Higher water temperature and stronger radiant intensity in summer can enhance their solubility and photochemical reaction in the microlayer water, reducing their enrichment factors （the ratio of concentration in the microlayer to that in the corresponding subsurface water）. A statistically significant relationship was found between the microlayer and subsurface water concentrations of DMS, DMSP and chlorophyll a, demonstrating that the biogenic materials in the microlayer come primarily from the underlying water. Moreover, our data show that the concentrations of DMSPp and DMS were significantly correlated with the levels of chlorophyll a, indicating that phytoplankton biomass might play an important role in controlling the distributions of biogenic sulfurs in the study area. The ratios of DMS/chlorophyll a and DMSPpchlorophyll a varied little from spring to summer, suggesting that there was no obvious change in the proportion of DMSP producers in the phytoplankton community. The mean sea-to-air flux of DMS from the study area was estimated to be 5.70 μmol/（m^2·d）, which highlights the effects of human impacts on DMS emission.
文摘Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.
文摘This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O_2 fluxes acrossthe sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and thatthe difference of DO was great in upper and bottom waters in Apr. 1994; but that seawater mixingwas strong and the difference of DO was small in upper and bettom waters in Oct. 1994. The above con-dusions were specially obvious in continental shelf waters under 100m. The DO maximum in subsurfacelayer waters appeared only at several stations and in general the DO in the waters decreased with depth.The horizontal distributions of O_2 fluxes across the sea-air interface appeared in stripes in Leg 9404 whenmost regions covend were supersaturated with O_2. seawater to air flux wn large, and that on section No.1was 1.594 L/m^2·d. The horizontal distribution of O_2 fluxes across the sea-air interface appeared lumpy inLeg 9410, when most regions covered were unsaturated with O_2. O_2 was dissolved from air to seawater,and the fluxes were 0.819 L/m^2·d on section No. 1 in Leg 9310, 0.219 L/m^2·d in Leg 9410. The mainreasons for DO change in surface layer seawater were the mixture of upper and bottom layer water, and theexchange of O_2 across the sea-air interface. The variation of DO by biological activity was only 20% of totalchange of DO.
基金supported by Institut de Recherche pour le Développement(IRD,France)(ESSO-INCOIS-Indian National Centre for Ocean Information Services)funded by the Specialized in Global Change and Sea-Air Interactions and Special Projects-Study on the Mechanism of the Influence of Ocean Mixing on Leapfrog and the Tianjin Key Laboratory of Marine Meteorology 2020 Open Fund Project(No.2020TKLOMZD01)Large-Scale Wave Glider Platform Development
文摘Net heat flux,sea surface temperature(SST),and sea surface wind in the northern Indian Ocean were investigated using the TropFlux,ERA5,and J-OFURO3 datasets and correlation analysis,power spectrum analysis,and singular value decomposition(SVD)methods,respectively.The relationships between net heat flux,SST,and sea surface winds were determined.The coupled modes of net heat flux and wind have been found to explain the SST variations in the Indian Ocean basin and the generation mechanism of the Indian Ocean Dipole(IOD).The correlation between net heat flux and wind is strongly negative.The SST lags the net heat flux and wind by approximately one month and has strong positive and negative correlations,respectively.The correlation between net heat flux and wind in the northern Indian Ocean is not only seasonal but also regionally dependent on seasonal variations.Using the SVD method,the important role of net heat flux in local sea-air interactions is discussed and identified as the initial perturbation that triggers the SST anomalies in the Southeast Indian Ocean,and the areas with key sea-air interactions and the generation mechanisms of the local sea-air interactions that form the IOD are determined.
基金Key project in the Natural Science Foundation of China (40136010) Natural Science Foundation of China (40075003)
文摘In this article, a sensitivity test of air-sea surface flux model was carried out with the field observation data of Project “South China Sea Air-Sea Flux Measurement in 2000”. The results show that sensible heat fluxes are sensitive to observation errors, increasing the error of model calculation; In contrast, the latent heat flux and momentum flux are not as sensitive to observation errors as the sensible heat, and their calculated results are reliable. The test result also verifies the rationality of the surface flux values calculated and the conclusions can be used to detect errors in observed data.
文摘Reviews on the current studies on the sea to air flux of dimethyl sulfide (DMS) have been made at home and abroad, pointing out that the flux of DMS is influenced by many factors. There is great difference between the results coming from different models. Besides, this paper focuses on the oxidation mechanisms of DMS by OH and NO3 radicals after it enters the atmosphere, the oxidation products’ contribution to acid rain and fog and the relationships among the DMS, CCN and climate system.
基金Supported by the National Natural Science Foundation of China(Nos.41320104008,41030858,41306069)the National Natural Science Foundation for Creative Research Groups(No.41221004)+3 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20110132120010)the Cheung Kong Scholars Program of Chinathe Taishan Scholar Program of Shandong Provincethe Fundamental Research Funds for the Central Universities
文摘The distributions of dimethylsulfide （DMS） and its precursor dimethylsulfoniopropionate （DMSP） in surface water of the Yellow Sea and the Bohai Sea were studied during June 2011. The mean concentrations and ranges of DMS, dissolved DMSP （DMSPd）, and particulate DMSP （DMSPp） in surface waters were 6.85 （1.60-12.36）, 7.25 （2.28-19.05） and 61.87 （6.28-224.01） nmol/L, respectively. There were strong correlations between DMSPp and chlorophyll a in the Bohai Sea and the North Yellow Sea, respectively, and concentrations of DMS and DMSP were high, with a relatively high proportion of dinoflagellates, in the region of the South Yellow Sea Cold Water Mass. Results show that phytoplankton biomass and species composition were important factors that controlled the distribution of DMS and DMSP. Complex environmental factors, including nutrients, transparency, and terrestrial runoff, might also influence the variability in DMS and DMSP. Biological production and consumption rates of DMS in the Bohai Sea were higher than those in the Yellow Sea. DMS production rates were closely correlated with DMSPd concentrations. DMS and DMSP exhibited obvious diel variations, with high concentrations occurring in the late afternoon （16：00-19：00） and low concentrations occurring during the night, implying that the intensity of solar radiation had a significant influence on these variations. Size distributions of chlorophyll a and DMSPp were also investigated and large nanoplankton （5-20 μm）, mainly diatoms, contributed significantly to chlorophyll a and DMSPp at most stations. The average sea-to-air flux of DMS in the study area was estimated to be 11.07 μmol/（m^2·d） during the summer.
文摘The thermoelectric energy conversion technique by employing the Disk-Magnet Electromagnetic Induction (DM-EMI) and improved DM-EMIs is shown, and possible applications to heat engines as one of the energy harvesting technologies are also discussed. The idea is induced by integrating irreversible thermodynamical mechanism of a water drinking bird with that of a Stirling engine, resulting in thermoelectric energy generation different from conventional heat engines. The current thermoelectric energy conversion with DM-EMI can be applied to wide ranges of temperature differences. The mechanism of DM-EMI energy converter is examined in terms of axial flux magnetic lines and categorized as the axial flux generator. It is useful for practical applications to macroscopic heat engines such as wind, geothermal, thermal and nuclear power turbines and heat-dissipation lines, for supporting thermoelectric energy conversions. The technique of DM-EMI will contribute to environmental problems to maintain clean and susceptible energy as one of the energy harvesting technologies.
