DOV216303 was synthesized via six procedures starting from 3,4-dichlorophenylacetic acid in an overall yield of 14%.The structure of the target compound was confirmed by 1H-NMR and MS.This improved method could avoid ...DOV216303 was synthesized via six procedures starting from 3,4-dichlorophenylacetic acid in an overall yield of 14%.The structure of the target compound was confirmed by 1H-NMR and MS.This improved method could avoid the usage of the expensive reagents,reduce the cost and increase the total yield.展开更多
The deflection of the vertical(DOV)is the key information in the study of ocean gravity field.However,in most areas,the precision of the prime component of DoV is significantly lower than that of the meridian componen...The deflection of the vertical(DOV)is the key information in the study of ocean gravity field.However,in most areas,the precision of the prime component of DoV is significantly lower than that of the meridian component.To obtain higher accuracy and resolution of ocean gravity information,researchers have proposed a novel altimeter called the wide-swath altimeter.This altimeter allows for the simultaneous acquisition of high-precision and high-resolution two-dimensional measurements of sea surface height(SSH).In this paper,the Surface Water and Ocean Topography(SWOT)mission with a wide-swath altimeter on board is selected for research.One cycle of swoT sea surface height data is simulated to inverse the DOV in the Arabian Sea(45°E—80°E,0°-30°N),and the inversion results are compared with those of conventional altimeter data.The results demonstrate that the difference between the meridian and prime components derived from the inversion of swoT wide-swath data is minimal,significantly outperforming the inversion results of conventional nadir altimeter data.The advantage of swoT wide-swath altimeter lies in its ability to use the multi-directional geoid slope at any sea surface measurement point to invert the components in the meridian and prime directions.To investigate the impact of this advantage on inversion precision,this paper employs a method to calculate the gradient of the geoid in multiple directions to invert DoV components.The improvement effect of calculating the gradient of the geoid in multiple directions on the precision of DoV component is analyzed.It is found that the accuracy of DoV inversion has significantly improved with the increase of geodetic gradient calculation direction.In addition,the effects of various errors and grid spacing in SwoT wide sea surface height data on the precision of Dov inversion are also analyzed.展开更多
推导了传统全球卫星导航定位系统(GNSS)测定垂线偏差(Deflection of the Vertical, DOV)形式误差的表达式;提出一种可用以解算并置站DOV的小网参数转换法.利用乌鲁木齐南山多技术并置站控制网观测信息,开展了算法验证,并对该站内多个地...推导了传统全球卫星导航定位系统(GNSS)测定垂线偏差(Deflection of the Vertical, DOV)形式误差的表达式;提出一种可用以解算并置站DOV的小网参数转换法.利用乌鲁木齐南山多技术并置站控制网观测信息,开展了算法验证,并对该站内多个地点DOV开展了实测.结果表明,高精度的小网DOV仅由点位观测精度最高、覆盖面积最广的3个站点决定.个别精度较差的点会为DOV的测定值带来较大的不确定性;采用小网转换法所解算的DOV与实测值间的一致性分别为-2.3″±4.3″(子午分量)和0.2″±4.6″(卯酉分量);小网转换求取DOV的方法在精度上与经典的GNSS水准方法相当,但步骤更加简便.鉴于多技术并置站会不定期地开展本地测量,可利用该方法实现多技术并置站DOV的零成本长期监测.展开更多
文摘DOV216303 was synthesized via six procedures starting from 3,4-dichlorophenylacetic acid in an overall yield of 14%.The structure of the target compound was confirmed by 1H-NMR and MS.This improved method could avoid the usage of the expensive reagents,reduce the cost and increase the total yield.
基金support from the National Natural Science Foundation of China(No.42274006,42192535,42242015).
文摘The deflection of the vertical(DOV)is the key information in the study of ocean gravity field.However,in most areas,the precision of the prime component of DoV is significantly lower than that of the meridian component.To obtain higher accuracy and resolution of ocean gravity information,researchers have proposed a novel altimeter called the wide-swath altimeter.This altimeter allows for the simultaneous acquisition of high-precision and high-resolution two-dimensional measurements of sea surface height(SSH).In this paper,the Surface Water and Ocean Topography(SWOT)mission with a wide-swath altimeter on board is selected for research.One cycle of swoT sea surface height data is simulated to inverse the DOV in the Arabian Sea(45°E—80°E,0°-30°N),and the inversion results are compared with those of conventional altimeter data.The results demonstrate that the difference between the meridian and prime components derived from the inversion of swoT wide-swath data is minimal,significantly outperforming the inversion results of conventional nadir altimeter data.The advantage of swoT wide-swath altimeter lies in its ability to use the multi-directional geoid slope at any sea surface measurement point to invert the components in the meridian and prime directions.To investigate the impact of this advantage on inversion precision,this paper employs a method to calculate the gradient of the geoid in multiple directions to invert DoV components.The improvement effect of calculating the gradient of the geoid in multiple directions on the precision of DoV component is analyzed.It is found that the accuracy of DoV inversion has significantly improved with the increase of geodetic gradient calculation direction.In addition,the effects of various errors and grid spacing in SwoT wide sea surface height data on the precision of Dov inversion are also analyzed.
文摘推导了传统全球卫星导航定位系统(GNSS)测定垂线偏差(Deflection of the Vertical, DOV)形式误差的表达式;提出一种可用以解算并置站DOV的小网参数转换法.利用乌鲁木齐南山多技术并置站控制网观测信息,开展了算法验证,并对该站内多个地点DOV开展了实测.结果表明,高精度的小网DOV仅由点位观测精度最高、覆盖面积最广的3个站点决定.个别精度较差的点会为DOV的测定值带来较大的不确定性;采用小网转换法所解算的DOV与实测值间的一致性分别为-2.3″±4.3″(子午分量)和0.2″±4.6″(卯酉分量);小网转换求取DOV的方法在精度上与经典的GNSS水准方法相当,但步骤更加简便.鉴于多技术并置站会不定期地开展本地测量,可利用该方法实现多技术并置站DOV的零成本长期监测.
