This paper reports a new approach to estimate kinetic parameters for the thermal decomposition of the solid state from TG-DTG or DSC curve.Reduced equations are derived for the first tlme.The validity of these equatio...This paper reports a new approach to estimate kinetic parameters for the thermal decomposition of the solid state from TG-DTG or DSC curve.Reduced equations are derived for the first tlme.The validity of these equations was demonstrated employing data obtained from the dehydration process of calcium oxalate monohydrate.展开更多
The curing proces of chemical reactombetween flexible unsaturated polymer resin and diphenyl-methane bismaleimides which have been chain-prolonged by diaminodiphenylmethane is presented. also the kinetics parameter...The curing proces of chemical reactombetween flexible unsaturated polymer resin and diphenyl-methane bismaleimides which have been chain-prolonged by diaminodiphenylmethane is presented. also the kinetics parameters and curing technology are investigated.展开更多
The influences of pre-ageing temperature and natural ageing time on subsequent artificial age hardening behavior and precipitation sequence of new type Al-1.01Mg-0.O8Si-l.78Cu alloy were investigated by hardness test,...The influences of pre-ageing temperature and natural ageing time on subsequent artificial age hardening behavior and precipitation sequence of new type Al-1.01Mg-0.O8Si-l.78Cu alloy were investigated by hardness test, differential scanning calorimetry （DSC） test and transmission electronic microscopy （TEM） observations. When pre-ageing temperature is 20℃ （natural ageing）, the peak hardness of subsequent artificial aged alloy is lower than that of T6 treated alloy （negative effect）, while a positive effect appears when pre-ageing temperature is above 80℃. The size of needlelike /3-precipitate in subsequent artificial aged alloy is much coarser when pre-ageing temperature is 20℃, which causes a decrease in peak-hardness. The positive effect occurs again when natural ageing time is longer than 3 weeks. There are seven exothermic peaks in DSC curve of as-quenched alloy, while the number and height of exothermic peak decrease with increasing pre-ageing temperature and natural ageing time.展开更多
文摘This paper reports a new approach to estimate kinetic parameters for the thermal decomposition of the solid state from TG-DTG or DSC curve.Reduced equations are derived for the first tlme.The validity of these equations was demonstrated employing data obtained from the dehydration process of calcium oxalate monohydrate.
文摘The curing proces of chemical reactombetween flexible unsaturated polymer resin and diphenyl-methane bismaleimides which have been chain-prolonged by diaminodiphenylmethane is presented. also the kinetics parameters and curing technology are investigated.
基金supported by the National Key Technology R&D Program of China under grant No.2007BAE38B01
文摘The influences of pre-ageing temperature and natural ageing time on subsequent artificial age hardening behavior and precipitation sequence of new type Al-1.01Mg-0.O8Si-l.78Cu alloy were investigated by hardness test, differential scanning calorimetry （DSC） test and transmission electronic microscopy （TEM） observations. When pre-ageing temperature is 20℃ （natural ageing）, the peak hardness of subsequent artificial aged alloy is lower than that of T6 treated alloy （negative effect）, while a positive effect appears when pre-ageing temperature is above 80℃. The size of needlelike /3-precipitate in subsequent artificial aged alloy is much coarser when pre-ageing temperature is 20℃, which causes a decrease in peak-hardness. The positive effect occurs again when natural ageing time is longer than 3 weeks. There are seven exothermic peaks in DSC curve of as-quenched alloy, while the number and height of exothermic peak decrease with increasing pre-ageing temperature and natural ageing time.
