We consider the decay parameter, invariant measures/vectors and quasi-stationary dis- tributions for 2-type Markov branching processes. Investigating such properties is crucial in realizing life period of branching mo...We consider the decay parameter, invariant measures/vectors and quasi-stationary dis- tributions for 2-type Markov branching processes. Investigating such properties is crucial in realizing life period of branching models. In this paper, some important properties of the generating functions for 2-type Markov branching q-matrix are firstly investigated in detail. The exact value of the decay parameter λC of such model is given for the communicating class C = Z+2 \ 0. It is shown that this λC can be directly obtained from the generating functions of the corresponding q-matrix. Moreover, the λC-invariant measures/vectors and quasi-distributions of such processes are deeply considered. A λC-invariant vector for the q-matrix (or for the process) on C is given and the generating functions of λC-invariant measures and quasi-stationary distributions for the process on C are presented.展开更多
Stochastic processes such as diffusion can be analyzed by means of a partial differential equation of the Fokker-Planck type (FPE), which yields a transition probability density, or by a stochastic differential equati...Stochastic processes such as diffusion can be analyzed by means of a partial differential equation of the Fokker-Planck type (FPE), which yields a transition probability density, or by a stochastic differential equation of the Langevin type (LE), which yields the time evolution of a statistical process variable. Provided the stochastic process is continuous and certain boundary conditions are met, the two approaches yield equivalent information. However, Brownian motion of radioactively decaying particles is not a continuous process because the Brownian trajectories abruptly terminate when the particle decays. Recent analysis of the Brownian motion of decaying particles by both approaches has led to different mean-square displacements. In this paper, we demonstrate the complete equivalence of the two approaches by 1) showing quantitatively and operationally how the probability densities and statistical moments predicted by the FPE and LE relate to one another, 2) verifying that both approaches lead to identical statistical moments at all orders, and 3) confirming that the analytical solution to the FPE accurately describes the Brownian trajectories obtained by Monte Carlo simulations based on the LE. The analysis in this paper addresses both the spatial distribution of the particles (i.e. the question of displacement as a function of diffusion time) and the temporal distribution (i.e. the question of first-passage time to fixed absorbing boundaries).展开更多
The exotic radioactive decay mode,in which a heavy cluster is emitted,is considered as a fission-like process.The potential barrier associated with an axially symmetric shape distortion is calculated in terms of the i...The exotic radioactive decay mode,in which a heavy cluster is emitted,is considered as a fission-like process.The potential barrier associated with an axially symmetric shape distortion is calculated in terms of the interplay between the surface and the coulomb energies.The experimental branch ratios of ^(14)C and ^(24)Ne emissions toα-decays have been reproduced within about one power of ten,and some new kinds of radioactivities may be expected.展开更多
An approximate method is presented for obtaining analytical solutions for the conditional first passage probability of systems under modulated white noise excitation. As the method is based on VanMarcke's approximati...An approximate method is presented for obtaining analytical solutions for the conditional first passage probability of systems under modulated white noise excitation. As the method is based on VanMarcke's approximation, with normalization of the response introduced, the expected decay rates can be evaluated from the second-moment statistics instead of the correlation functions or spectrum density functions of the response of considered structures. Explicit solutions to the second-moment statistics of the response are given. Accuracy, efficiency and usage of the proposed method are demonstrated by the first passage analysis of single-degree-of-freedom (SDOF) linear systems under two special types of modulated white noise excitations.展开更多
Kurtosis is regarded as a meaningful and promising observable in searching for the possible critical point predicted by QCD. In this paper, the effects of elliptic flow and resonance decay process on the Kurtosis have...Kurtosis is regarded as a meaningful and promising observable in searching for the possible critical point predicted by QCD. In this paper, the effects of elliptic flow and resonance decay process on the Kurtosis have been studied with Monte Carlo event generators in Au + Au collisions at sNN^(1/2) = 200 GeV. The results show that the Kurtosis is not sensitive to elliptic flow and resonance decay process.展开更多
Introduction: We present the results of scientific and traditional knowledge, which were performed on students attending the School of Dental Surgery at the Faculty of Higher Studies Zaragoza UNAM and parents in the M...Introduction: We present the results of scientific and traditional knowledge, which were performed on students attending the School of Dental Surgery at the Faculty of Higher Studies Zaragoza UNAM and parents in the Milpa Alta policy delegation of the Federal District with the purpose to articulate such knowledge for planning oral health programs where the protection and promotion of oral health are prioritized. Method: This study was qualitative and quantitative, and 413 students of the career Dentist Faculty of Higher Studies Zaragoza UNAM and 2100 parents of twelve elementary school of the Milpa Alta delegation participated. Results: One of the results was that almost a third (28%) of the students go to the dentist only when they need to, however 40% of parents said they go to consultation only when they start to experience pain. Conclusion: It is important to articulate scientific knowledge with the traditional and famed in Odontology, for the operation alization of health programs attached to particular contexts where all stakeholders are involved to prevent oral problems.展开更多
Nuclear β-decay half-lives are predicted based on an empirical formula and the mass predictions from various nuclear models.It is found that the empirical formula can reproduce the nuclearβ-decay half-lives well,esp...Nuclear β-decay half-lives are predicted based on an empirical formula and the mass predictions from various nuclear models.It is found that the empirical formula can reproduce the nuclearβ-decay half-lives well,especially for short-lived nuclei with T_(1/2)<1s.The theoretical half-life uncertainties fromβ-decay energies and the parameters of the empirical formula are further investigated.It is found that the uncertainties of the half-lives are relatively large for heavy nuclei and nuclei near the neutron-drip line.For nuclei on the r-process path,the uncertainties for those with N=126 are about one order of magnitude,which are much larger than the uncertainties for those with N=50 and 82.However,theoretical uncertainties from the parameters of the empirical formula are relatively small for the nuclei on the r-process path,which indicates that the empirical formula is very suitable for predicting theβ-decay half-lives in r-process simulations.展开更多
Fungi play vital roles in the decomposition of deadwood due to their secretion of various enzymes that break down plant cell-wall complexes.The compositions of woodinhabiting fungal(WIF)communities change over the c...Fungi play vital roles in the decomposition of deadwood due to their secretion of various enzymes that break down plant cell-wall complexes.The compositions of woodinhabiting fungal(WIF)communities change over the course of the decomposition process as the remaining mass of wood decreases and both abiotic and biotic conditions of the wood significantly change.It is currently not resolved which substrate-related factors govern these changes in WIF communities and whether such changes influence the deadwood decomposition rate.Here we report a study on fungal richness and community structure in deadwood of Norway spruce and European beech in temperate forest ecosystems using 454 pyrosequencing.Our aims were to disentangle the factors that correspond to WIF community composition and to investigate the links between fungal richness,taxonomically-resolved fungal identity,and microbial-mediated ecosystem functions and processes by analyzing physico-chemical wood properties,lignin-modifying enzyme activities and wood decomposition rates.Unlike fungal richness,we found significant differences in community structure between deadwood of different tree species.The composition of WIF communities was related to the physico-chemical properties of the deadwood substrates.Decomposition rates and the activities of ligninmodifying enzymes were controlled by the succession of the fungal communities and competition scenarios rather than fungal OTU richness.Our results provide further insights into links between fungal community structure and microbialmediated ecosystem functions and processes.展开更多
The neutrino closure method can be used to obtain the decay kinematics with one missing final state particle(ν)in semileptonic decays.Its solution should give the square of the invariant mass of the lv system(q;)and ...The neutrino closure method can be used to obtain the decay kinematics with one missing final state particle(ν)in semileptonic decays.Its solution should give the square of the invariant mass of the lv system(q;)and momentum(P)of the decayed mother particle in semileptonic decay process.However,the resolution obtained by solving two-solution problems with existing algorithms is limited.We propose a new method based on deep learning to improve the resolution of the two key physical quantities when processing Large Hadron Collider beauty(LHCb)experimental data.Resolution of q;(P)can be improved evenly 1.7%(8.2%)by regression algorithm and 2.7%(9.6%)by classification algorithm compared to linear regression algorithm.The resolution improvements using the new method will benefit the studies on semileptonic decays in hardon collider experiments.Moreover,the new method can be applied to other decays with a missing particle in the final state.展开更多
Layered Li-rich Mn-based oxides are promising cathode materials for Li-ion batteries due to their high capacity and high operation voltage.However,their commercial applications are hindered by irreversible capacity lo...Layered Li-rich Mn-based oxides are promising cathode materials for Li-ion batteries due to their high capacity and high operation voltage.However,their commercial applications are hindered by irreversible capacity loss in the first charge-discharge process,voltage decay during cycling,inefficient cyclability and rate capability.Many attempts have been performed to solve such issues,including the mechanism study and strategies to improve the electrochemical performance.This article provides a brief review and future perspective on the main challenges of the high-capacity Li-rich Mn-based cathodes for Li-ion batteries.展开更多
The spectroscopic properties of a series of Dy^(3+)single-doped and Dy^(3+)/Nd^(3+),Dy^(3+)/Tb^(3+),and Dy^(3+)/Tm^(3+)co-doped YAlO_(3)(yttrium aluminum perovskite,YAP)phosphors were investigated and compared through...The spectroscopic properties of a series of Dy^(3+)single-doped and Dy^(3+)/Nd^(3+),Dy^(3+)/Tb^(3+),and Dy^(3+)/Tm^(3+)co-doped YAlO_(3)(yttrium aluminum perovskite,YAP)phosphors were investigated and compared through the measurements of optical absorption,emission spectra,and fluorescence decay curves.For the Dy^(3+)ion single-doped samples,the intensity of each absorption band increases with an increment in Dy^(3+)ion doping concentration,and the identified strong absorption peak at 447 nm indicates that Dy^(3+):YAP phosphors are suitable to be pumped by a blue laser diode(LD).For all co-doped samples,absorption peaks of Dy^(3+)ion along with some of the absorption bands of Nd^(3+),Tb^(3+),and Tm^(3+)ions are observed.Under 351 and 447 nm excitation,a prominent emission peak at 572 nm was obtained in all the samples,corresponding to Dy^(3+):^(4)F_(9/2)→^(6)H_(13/2)transition.Here,2 at%Dy^(3+):YAP phosphor exhibits the highest yellow emission intensity under 447 nm pumping.Among the three kinds of Dy^(3+)co-doped phosphors,Dy^(3+)/Tb^(3+):YAP phosphor possesses the dominant yellow emission.The fluorescence decay curves show exponential behaviour and are fitted well.The Commission International de L’Eclairage(CIE)chromaticity coordinates were calculated following the respective emission spectra,and it is found that all the coordinates locate in the yellow region.The energy transfer(ET)processes were investigated and the concentration quenching mechanism was discussed.The obtained results suggest that Dy^(3+)-activated YAP phosphors are good candidates for yellow LED applications.展开更多
The investigation of electronic excited states in single-molecule junctions not only provides platforms to reveal the photophysical and photochemical processes at the molecular level,but also brings opportunities for ...The investigation of electronic excited states in single-molecule junctions not only provides platforms to reveal the photophysical and photochemical processes at the molecular level,but also brings opportunities for the development of single-molecule optoelectronic devices.Understanding the interaction mechanisms between molecules and nanocavities is essential to obtain ondemand properties in devices by artificial design,since molecules in junctions exhibit unique behaviors of excited states benefited from the structures of metallic nanocavities.Here,we review the excitation mechanisms involved in the interplay between molecules and plasmonic nanocavities,and reveal the influence of nanostructures on excited-state properties by demonstrating the differences in excited state decay processes.Furthermore,vibronic transitions of molecules between nanoelectrodes are also discussed,offering a new single-molecule characterization method.Finally,we provide the potential applications and challenges in single-molecule optoelectronic devices and the possible directions in exploring the underlying mechanisms of photophysical and photochemical processes.展开更多
Approaches for the cultivation-independent analysis of microbial communities are summarized as meta’omics,which predominantly includes metagenomic,-transcriptomic,-proteomic and-metabolomic studies.These have shown t...Approaches for the cultivation-independent analysis of microbial communities are summarized as meta’omics,which predominantly includes metagenomic,-transcriptomic,-proteomic and-metabolomic studies.These have shown that endophytic,root-associated and soil fungal communities are strongly shaped by associated plant species.The impact of plant identity on the composition of its litterssociated fungal community remains to be disentangled from the impact of litter chemistry.The composition of the plant community also shapes the fungal community.Most strikingly,adjacent plant species may share mycorrhizal symbionts even if the plants usually have different types of mycorrhizal fungi associated with them(ectomycorrhizal,ericoid and arbuscular mycorrhizal fungi).Environmental parameters weakly explain fungal community composition globally,and their effect is inconsistent at local and regional scales.Decrease in similarity among communities with increasing distance(i.e.distance decay)has been reported from local to global scales.This pattern is only exceptionally caused by spatial dispersal limitation of fungal propagules,but mostly due to the inability of the fungi to establish at the particular locality(i.e.environmental filtering or competitive exclusion).Fungal communities usually undergo pronounced seasonal changes and also differ between consecutive years.This indicates that development of the communities is usually not solely cyclic.Meta’omic studies challenge the classical view of plant litter decomposition.They show that mycorrhizal and(previously)endophytic fungi may be involved in plant litter decomposition and only partly support the idea of a succession from an Ascomycota to a Basidiomycota-dominated community.Furthermore,vertical separation of saprotrophic and mycorrhizal species in soil and sequential degradation from easily accessible to‘recalcitrant’plant compounds,such as lignin,can probably not be generalized.The current models of litter decomposition may therefore have to be eventually refined for certain ecosystems and environmental conditions.To gain deeper insights into fungal ecology,a meta’omic study design is outlined which focuses on environmental processes,because fungal communities are usually taxonomically diverse,but functionally redundant.This approach would initially identify dynamics of chemical shifts in the host and/or substrate by metametabolomics.Detected shifts would be subsequently linked to microbial activity by correlation with metatranscriptomic and/or metaproteomic data.A holistic trait-based approach might finally identify factors shaping taxonomic composition in communities against the dynamics of the environmental process(es)they are involved in.展开更多
To overcome the problem of pulse pile-up at high count rates, a digital deconvolution algorithm is used to remove the exponential current tails of NaI(Tl) detectors, so as to obtain a current unit impulse. Then a na...To overcome the problem of pulse pile-up at high count rates, a digital deconvolution algorithm is used to remove the exponential current tails of NaI(Tl) detectors, so as to obtain a current unit impulse. Then a narrow pulse can be obtained through pulse shaping. The pulse deconvolution technique can thoroughly eliminate the influences of ballistic deficit and improve traditional pulse shaping systems in both pulse throughput and energy resolution. To demonstrate this method, the energy spectrum of a ^137Cs radioactive source was measured. When the shaping time constant is 1.5 μs, traditional pulse shaping systems yielded a 6.99% energy resolution and 68 kcps count rate, while the new pulse deconvolution technique, used to improve traditional pulse shaping systems, yielded a 6.37% energy resolution and 102 kcps count rate.展开更多
Purpose Develop a novel charge-detecting tile for future large-scale liquid xenon TPC for searching for neutrinoless doublebeta decay.Methods Use advanced microelectronic technologies to fabricate small metal pads on ...Purpose Develop a novel charge-detecting tile for future large-scale liquid xenon TPC for searching for neutrinoless doublebeta decay.Methods Use advanced microelectronic technologies to fabricate small metal pads on a fused-silica wafer.The pads are chained into orthogonal strips,and the strips are isolated at the cross sections.The size of the pads defines the pitch between parallel strips and can be flexibly tuned according to any optimized dimension from future Monte Carlo studies.Such tile also has good potential to suppress the radioactivity and control electronics noise.Furthermore,its modular design allows to easily cover a large size.Results The design and performance have been demonstrated by a prototype tile,particularly by comprehensive tests in liquid xenon.Conclusions A new design of charge detection tile and the fabrication technologies have been developed,which would be useful for future noble liquid detectors.展开更多
基金supported by National Natural Science Foundation of China (Grant No. 10771216)Project sponsored by Scientific Research Foundation for Returned Overseas Chinese Scholars, State Education Ministry(Grant No. [2007]1108)
文摘We consider the decay parameter, invariant measures/vectors and quasi-stationary dis- tributions for 2-type Markov branching processes. Investigating such properties is crucial in realizing life period of branching models. In this paper, some important properties of the generating functions for 2-type Markov branching q-matrix are firstly investigated in detail. The exact value of the decay parameter λC of such model is given for the communicating class C = Z+2 \ 0. It is shown that this λC can be directly obtained from the generating functions of the corresponding q-matrix. Moreover, the λC-invariant measures/vectors and quasi-distributions of such processes are deeply considered. A λC-invariant vector for the q-matrix (or for the process) on C is given and the generating functions of λC-invariant measures and quasi-stationary distributions for the process on C are presented.
文摘Stochastic processes such as diffusion can be analyzed by means of a partial differential equation of the Fokker-Planck type (FPE), which yields a transition probability density, or by a stochastic differential equation of the Langevin type (LE), which yields the time evolution of a statistical process variable. Provided the stochastic process is continuous and certain boundary conditions are met, the two approaches yield equivalent information. However, Brownian motion of radioactively decaying particles is not a continuous process because the Brownian trajectories abruptly terminate when the particle decays. Recent analysis of the Brownian motion of decaying particles by both approaches has led to different mean-square displacements. In this paper, we demonstrate the complete equivalence of the two approaches by 1) showing quantitatively and operationally how the probability densities and statistical moments predicted by the FPE and LE relate to one another, 2) verifying that both approaches lead to identical statistical moments at all orders, and 3) confirming that the analytical solution to the FPE accurately describes the Brownian trajectories obtained by Monte Carlo simulations based on the LE. The analysis in this paper addresses both the spatial distribution of the particles (i.e. the question of displacement as a function of diffusion time) and the temporal distribution (i.e. the question of first-passage time to fixed absorbing boundaries).
文摘The exotic radioactive decay mode,in which a heavy cluster is emitted,is considered as a fission-like process.The potential barrier associated with an axially symmetric shape distortion is calculated in terms of the interplay between the surface and the coulomb energies.The experimental branch ratios of ^(14)C and ^(24)Ne emissions toα-decays have been reproduced within about one power of ten,and some new kinds of radioactivities may be expected.
基金supported by the National Natural Science Foundation of China (No. 50478017)
文摘An approximate method is presented for obtaining analytical solutions for the conditional first passage probability of systems under modulated white noise excitation. As the method is based on VanMarcke's approximation, with normalization of the response introduced, the expected decay rates can be evaluated from the second-moment statistics instead of the correlation functions or spectrum density functions of the response of considered structures. Explicit solutions to the second-moment statistics of the response are given. Accuracy, efficiency and usage of the proposed method are demonstrated by the first passage analysis of single-degree-of-freedom (SDOF) linear systems under two special types of modulated white noise excitations.
基金Supported by National Natural Science Foundation of China (10775058, 11075060)MOST of China (2008CB817707)
文摘Kurtosis is regarded as a meaningful and promising observable in searching for the possible critical point predicted by QCD. In this paper, the effects of elliptic flow and resonance decay process on the Kurtosis have been studied with Monte Carlo event generators in Au + Au collisions at sNN^(1/2) = 200 GeV. The results show that the Kurtosis is not sensitive to elliptic flow and resonance decay process.
文摘Introduction: We present the results of scientific and traditional knowledge, which were performed on students attending the School of Dental Surgery at the Faculty of Higher Studies Zaragoza UNAM and parents in the Milpa Alta policy delegation of the Federal District with the purpose to articulate such knowledge for planning oral health programs where the protection and promotion of oral health are prioritized. Method: This study was qualitative and quantitative, and 413 students of the career Dentist Faculty of Higher Studies Zaragoza UNAM and 2100 parents of twelve elementary school of the Milpa Alta delegation participated. Results: One of the results was that almost a third (28%) of the students go to the dentist only when they need to, however 40% of parents said they go to consultation only when they start to experience pain. Conclusion: It is important to articulate scientific knowledge with the traditional and famed in Odontology, for the operation alization of health programs attached to particular contexts where all stakeholders are involved to prevent oral problems.
基金Partly supported by the National Natural Science Foundation of China under(11805004,11875070)the Key Research Foundation of Education Ministry of Anhui Province(KJ2020A0485)the Open fund for Discipline Construction,Institute of Physical Science and Information Technology,Anhui University.
文摘Nuclear β-decay half-lives are predicted based on an empirical formula and the mass predictions from various nuclear models.It is found that the empirical formula can reproduce the nuclearβ-decay half-lives well,especially for short-lived nuclei with T_(1/2)<1s.The theoretical half-life uncertainties fromβ-decay energies and the parameters of the empirical formula are further investigated.It is found that the uncertainties of the half-lives are relatively large for heavy nuclei and nuclei near the neutron-drip line.For nuclei on the r-process path,the uncertainties for those with N=126 are about one order of magnitude,which are much larger than the uncertainties for those with N=50 and 82.However,theoretical uncertainties from the parameters of the empirical formula are relatively small for the nuclei on the r-process path,which indicates that the empirical formula is very suitable for predicting theβ-decay half-lives in r-process simulations.
基金the DFG Priority Program 1374 on BInfrastructure-BiodiversityExploratories(KR 3587/1-1,KR 3587/3-2,BA 2821/9-2,BU 941/17-1,HO 1961/5-1,HO 1961/5-2)。
文摘Fungi play vital roles in the decomposition of deadwood due to their secretion of various enzymes that break down plant cell-wall complexes.The compositions of woodinhabiting fungal(WIF)communities change over the course of the decomposition process as the remaining mass of wood decreases and both abiotic and biotic conditions of the wood significantly change.It is currently not resolved which substrate-related factors govern these changes in WIF communities and whether such changes influence the deadwood decomposition rate.Here we report a study on fungal richness and community structure in deadwood of Norway spruce and European beech in temperate forest ecosystems using 454 pyrosequencing.Our aims were to disentangle the factors that correspond to WIF community composition and to investigate the links between fungal richness,taxonomically-resolved fungal identity,and microbial-mediated ecosystem functions and processes by analyzing physico-chemical wood properties,lignin-modifying enzyme activities and wood decomposition rates.Unlike fungal richness,we found significant differences in community structure between deadwood of different tree species.The composition of WIF communities was related to the physico-chemical properties of the deadwood substrates.Decomposition rates and the activities of ligninmodifying enzymes were controlled by the succession of the fungal communities and competition scenarios rather than fungal OTU richness.Our results provide further insights into links between fungal community structure and microbialmediated ecosystem functions and processes.
基金the National Natural Science Foundation of China(11735010,U1932108,U2032102,12061131006)。
文摘The neutrino closure method can be used to obtain the decay kinematics with one missing final state particle(ν)in semileptonic decays.Its solution should give the square of the invariant mass of the lv system(q;)and momentum(P)of the decayed mother particle in semileptonic decay process.However,the resolution obtained by solving two-solution problems with existing algorithms is limited.We propose a new method based on deep learning to improve the resolution of the two key physical quantities when processing Large Hadron Collider beauty(LHCb)experimental data.Resolution of q;(P)can be improved evenly 1.7%(8.2%)by regression algorithm and 2.7%(9.6%)by classification algorithm compared to linear regression algorithm.The resolution improvements using the new method will benefit the studies on semileptonic decays in hardon collider experiments.Moreover,the new method can be applied to other decays with a missing particle in the final state.
基金This work was supported by NSFC(21621091)National Key Research and Development of China(2016YFB0100202)+4 种基金Natural Science Foundation of Fujian Province(2015J01063)the support of National Materials Genome Project(2016YFB0700600)National Key R&D Program of China(2016YFB0700600)the Guangdong Innovation Team Project(No.2013N080)Shenzhen Science and Technology Research(Nos.JCYJ20151015162256516,JCYJ20150729111733470 and JCYJ20160226105838578)。
文摘Layered Li-rich Mn-based oxides are promising cathode materials for Li-ion batteries due to their high capacity and high operation voltage.However,their commercial applications are hindered by irreversible capacity loss in the first charge-discharge process,voltage decay during cycling,inefficient cyclability and rate capability.Many attempts have been performed to solve such issues,including the mechanism study and strategies to improve the electrochemical performance.This article provides a brief review and future perspective on the main challenges of the high-capacity Li-rich Mn-based cathodes for Li-ion batteries.
基金Projects supported by the National Natural Science Foundation of China(51872286,51832007,51472240,61675204)Science and Technology Plan Leading Project of Fujian Province(2018H0046)+3 种基金State Key Laboratory of Rare Earth Resource Utilization(RERU2018004,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences)the National Key Research and Development Program of China(2016YFB0701002)the fund of the State Key Laboratory of Solidification Processing(SKLSP201908,Northwestern Polytechnical University)Natural Science Foundation of Jiangxi Province(20181BAB211009)。
文摘The spectroscopic properties of a series of Dy^(3+)single-doped and Dy^(3+)/Nd^(3+),Dy^(3+)/Tb^(3+),and Dy^(3+)/Tm^(3+)co-doped YAlO_(3)(yttrium aluminum perovskite,YAP)phosphors were investigated and compared through the measurements of optical absorption,emission spectra,and fluorescence decay curves.For the Dy^(3+)ion single-doped samples,the intensity of each absorption band increases with an increment in Dy^(3+)ion doping concentration,and the identified strong absorption peak at 447 nm indicates that Dy^(3+):YAP phosphors are suitable to be pumped by a blue laser diode(LD).For all co-doped samples,absorption peaks of Dy^(3+)ion along with some of the absorption bands of Nd^(3+),Tb^(3+),and Tm^(3+)ions are observed.Under 351 and 447 nm excitation,a prominent emission peak at 572 nm was obtained in all the samples,corresponding to Dy^(3+):^(4)F_(9/2)→^(6)H_(13/2)transition.Here,2 at%Dy^(3+):YAP phosphor exhibits the highest yellow emission intensity under 447 nm pumping.Among the three kinds of Dy^(3+)co-doped phosphors,Dy^(3+)/Tb^(3+):YAP phosphor possesses the dominant yellow emission.The fluorescence decay curves show exponential behaviour and are fitted well.The Commission International de L’Eclairage(CIE)chromaticity coordinates were calculated following the respective emission spectra,and it is found that all the coordinates locate in the yellow region.The energy transfer(ET)processes were investigated and the concentration quenching mechanism was discussed.The obtained results suggest that Dy^(3+)-activated YAP phosphors are good candidates for yellow LED applications.
基金supported by the National Natural ScienceFoundation of China (Nos. 22173075, 21933012 and 31871877)the National Key R&D Program of China (No. 2017YFA0204902)+1 种基金the Fundamental Research Funds for the Central Universities(Nos. 20720200068 and 20720190002)the Beijing NationalLaboratory for Molecular Sciences (No. BNLMS202005).
文摘The investigation of electronic excited states in single-molecule junctions not only provides platforms to reveal the photophysical and photochemical processes at the molecular level,but also brings opportunities for the development of single-molecule optoelectronic devices.Understanding the interaction mechanisms between molecules and nanocavities is essential to obtain ondemand properties in devices by artificial design,since molecules in junctions exhibit unique behaviors of excited states benefited from the structures of metallic nanocavities.Here,we review the excitation mechanisms involved in the interplay between molecules and plasmonic nanocavities,and reveal the influence of nanostructures on excited-state properties by demonstrating the differences in excited state decay processes.Furthermore,vibronic transitions of molecules between nanoelectrodes are also discussed,offering a new single-molecule characterization method.Finally,we provide the potential applications and challenges in single-molecule optoelectronic devices and the possible directions in exploring the underlying mechanisms of photophysical and photochemical processes.
基金funded by the Deutsche Forschungsgemeinschaft(DFG,project PE 1673/4-1).
文摘Approaches for the cultivation-independent analysis of microbial communities are summarized as meta’omics,which predominantly includes metagenomic,-transcriptomic,-proteomic and-metabolomic studies.These have shown that endophytic,root-associated and soil fungal communities are strongly shaped by associated plant species.The impact of plant identity on the composition of its litterssociated fungal community remains to be disentangled from the impact of litter chemistry.The composition of the plant community also shapes the fungal community.Most strikingly,adjacent plant species may share mycorrhizal symbionts even if the plants usually have different types of mycorrhizal fungi associated with them(ectomycorrhizal,ericoid and arbuscular mycorrhizal fungi).Environmental parameters weakly explain fungal community composition globally,and their effect is inconsistent at local and regional scales.Decrease in similarity among communities with increasing distance(i.e.distance decay)has been reported from local to global scales.This pattern is only exceptionally caused by spatial dispersal limitation of fungal propagules,but mostly due to the inability of the fungi to establish at the particular locality(i.e.environmental filtering or competitive exclusion).Fungal communities usually undergo pronounced seasonal changes and also differ between consecutive years.This indicates that development of the communities is usually not solely cyclic.Meta’omic studies challenge the classical view of plant litter decomposition.They show that mycorrhizal and(previously)endophytic fungi may be involved in plant litter decomposition and only partly support the idea of a succession from an Ascomycota to a Basidiomycota-dominated community.Furthermore,vertical separation of saprotrophic and mycorrhizal species in soil and sequential degradation from easily accessible to‘recalcitrant’plant compounds,such as lignin,can probably not be generalized.The current models of litter decomposition may therefore have to be eventually refined for certain ecosystems and environmental conditions.To gain deeper insights into fungal ecology,a meta’omic study design is outlined which focuses on environmental processes,because fungal communities are usually taxonomically diverse,but functionally redundant.This approach would initially identify dynamics of chemical shifts in the host and/or substrate by metametabolomics.Detected shifts would be subsequently linked to microbial activity by correlation with metatranscriptomic and/or metaproteomic data.A holistic trait-based approach might finally identify factors shaping taxonomic composition in communities against the dynamics of the environmental process(es)they are involved in.
基金Supported by National Natural Science Foundation of China(41474159)Sichuan Youth Science&Technology Foundation(2015JQ0035)Key Laboratory of Applied Nuclear Techniques in Geosciences Sichuan(gnzds2014006)
文摘To overcome the problem of pulse pile-up at high count rates, a digital deconvolution algorithm is used to remove the exponential current tails of NaI(Tl) detectors, so as to obtain a current unit impulse. Then a narrow pulse can be obtained through pulse shaping. The pulse deconvolution technique can thoroughly eliminate the influences of ballistic deficit and improve traditional pulse shaping systems in both pulse throughput and energy resolution. To demonstrate this method, the energy spectrum of a ^137Cs radioactive source was measured. When the shaping time constant is 1.5 μs, traditional pulse shaping systems yielded a 6.99% energy resolution and 68 kcps count rate, while the new pulse deconvolution technique, used to improve traditional pulse shaping systems, yielded a 6.37% energy resolution and 102 kcps count rate.
基金Program of International S&T Cooperation of MoST(2015DFG02000)CAS-IHEP Fund for PRC-US Collaboration inHEP,CAS Center for Excellence in Particle Physics(CCEPP).
文摘Purpose Develop a novel charge-detecting tile for future large-scale liquid xenon TPC for searching for neutrinoless doublebeta decay.Methods Use advanced microelectronic technologies to fabricate small metal pads on a fused-silica wafer.The pads are chained into orthogonal strips,and the strips are isolated at the cross sections.The size of the pads defines the pitch between parallel strips and can be flexibly tuned according to any optimized dimension from future Monte Carlo studies.Such tile also has good potential to suppress the radioactivity and control electronics noise.Furthermore,its modular design allows to easily cover a large size.Results The design and performance have been demonstrated by a prototype tile,particularly by comprehensive tests in liquid xenon.Conclusions A new design of charge detection tile and the fabrication technologies have been developed,which would be useful for future noble liquid detectors.