Application and study in aluminum melt degassing technologies

The classification, characteristics and current situation of aluminum melt hydrogen-removal methods and technologies have been summarized. The latest studies and research results of aluminum melt degassing technology have been summed up. The tendency and prospect of aluminum degassing technology was discussed.

Effect of ultrasonic melt treatment on degassing of Mg-6Zn-1Ca alloy

The effect of ultrasonic power and treatment time on degassing of Mg-6Zn-1Ca alloy was studied in this paper. The degassing effect was characterized by measuring densities of ingots. The results show that proper ultrasonic treatment can remove hydrogen from the melt of the Mg-6Zn-1Ca alloy. The ultrasonic degassing effect is closely related to the ultrasonic power density and treatment time. The degassing efficiency increases with an increase in ultrasonic power density when the melt is treated at 690 °C for 120 s, reaching its highest value at 1.2 W·cm-3. When the power density is 1.2 W·cm-3, with an increase in ultrasonic treatment time, the degassing efficiency increases at first, reaches its peak value at 120 s, then decreases as the ultrasonic treatment is further prolonged. In this experiment, the optimum degassing effect with an efficiency of 67.5 % is obtained by ultrasonic treatment with the power density of 1.2 W·cm-3 for 120 s. The maximum density of ingot can be increased from 1.8069 g·cm-3 to 1.8146 g·cm-3(increased by 0.43%).

Degassing of primordial hydrogen and helium as the major energy source for internal terrestrial processes

Examples of the mightiest energy releases by great earthquakes and volcanic eruptions and hypotheses providing explanations for them are analyzed along with the results of some recently pub- lished researches and visualizations. The emerging conclusions are that the mechanism of the strong earthquake is a chemical explosion; that volcanic eruption is a special type of earthquake wherein the hypocenter rises to the earth-surface; and that there is an association between the seismic-volcanic processes and mantle ＂fluids＂ and the lack of energy for mantle plumes. A conceptual system of hypoth- eses is put forward to explain the conservation of energy during Earth＇s accretion, its quasi-stable release by primordial H- and He-degassing and of the crucial role of the energy of degassing-eomprising- reactions in endogenic processes. Specific mechanisms and chemical processes are proposed for the gas-liquid mantle plumes melting through the solid mantle using heat-energy released in reactions of their metamorphic and chemical transformation under gradual decrease of pressure and temperature; volcanic gases are put forward as energy carriers. 3He performance as a unique measuring transformer correlative to the internal heat flow was used for calculation of energy release by degassing; it equals to 5.12 × 1020 J/yr, an amount of energy five-fold greater than the entire energy loss involved in earthquake and volcanic activity. The hypotheses proposed are objectively testable.

Degassing effect of ultrasonic vibration in molten melt and semi-solid slurry of Al-Si alloys

In the process of semi-solid slurry preparation with direct ultrasonic vibration (UV) by dipping the horn into the melt, one of the questions is whether the gas content in the melt would be increased or not by the cavitation effect of ultrasonic vibration. By application of quantitative gas content measurement technique, this paper investigated the effect of the ultrasonic vibration on the gas content of both the melt and the semi-solid slurry of Al-Si alloys, and the variations of the gas contents in two kinds of aluminum alloys, i.e., A356 alloy and Al-20Si-2Cu-1Ni-0.6RE alloy (Al-20Si for short). The results show that ultrasonic vibration has an obvious degassing effect on the molten melt, especially on the semi-solid slurry of Al-Si alloy which is below the liquidus temperature by less than 20 ℃. The ultrasonic degassing efficiency of the A356 alloy decreases with the reduction of the initial gas content in the melt, and it is nearly unchanged for the Al-20Si alloy. The gas content of both alloys decreases when the ultrasonic vibration time is increased. The best vibration time for Al-20Si alloy at the liquid temperature of 710 ℃ and semi-solid temperature of 680 ℃ is 60 s and 90 s, respectively; and the degassing efficiency is 48% and 35%, respectively. The mechanism of ultrasonic degassing effect is discussed.

Decomposition of Transformer Oil Under Ultrasonic Irradiation During Degassing Process

In the degassing process of transformer oil with ultrasonic waves, decomposition of the oil was observed. Light hydrocarbons, including methane, ethane, ethylene, acetylene, propane etc, were found to be released continuously from the oil into headspace within a closed vial placed in an ultrasonic field. The gases came from decomposition of hydrocarbon molecules under cavitation effect.

Influences of different degassing processes on refining effect and properties of 4004 Al alloy

In order to improve the plasticity of 4004 Al alloy and subsequently the productivity of 4004 Al foil, the research studied in detail the influence of the rotary impeller degassing process on the refining effect of 4004 Al alloy, in which the impacts of four major parameters: gas flow, rotational speed, refining time, and stewing time, on degassing rate of 4004 Al alloy was systematically studied by using an orthogonal experiment methodology. Results show that the rotational speed has the greatest impact on the degassing of 4004 Al alloy, followed by gas flow and refining time; stewing time has the least impact. The optimum purification parameters obtained by current orthogonal analysis were: rotor speed of 500 r·min-1, inert gas flow of 0.4 mL·h-1, refining time of 15 min, and stewing time of 6 min. Degassing rate using the optimum parameters reaches 68%. In addition, the comparison experiments among C2Cl6 refining, rotary impeller degassing, and combined treatment of C2Cl6 refining and rotary impeller degassing for 4004 Al alloy were performed. The experimental data indicated that the combined treatment of C2Cl6 refining and rotary impeller degassing has the best degassing effect. Degassing rate of C2Cl6 refining, rotary impeller degassing and combined refining treatment is 39%, 69.1% and 76.9%, respectively. The mechanical properties of the specimen refined by rotary impeller degassing were higher than those by C2Cl6 refining, but lower than those by combined refining treatment.

Observation of Catastrophic Degassing from Mantle-Crust in Yinggehai Basin, South China Sea

To lower the CO 2 risk for hydrocarbon exploration in the west continental shelf of Yinggehai basin, South China Sea, we do attempt not only to know the CO 2 origins, but also to make an understanding of the degassing processes from the mantle and crust. Based on the stable carbon isotope ratios of CO 2 alone, the organic and inorganic CO 2 can be successively distinguished, but the formation conditions and mixing processes for inorganic CO 2 are still not clear. The relationships between lg[R(= 3He/ 4He)/R a(=1.386×10 -6)] and CO 2 content (%), CO 2/ 3He and δ 13C CO 2 have been employed, respectively, to obtain that the CO 2 gases in the reservoirs can be classified into three categories: (1) organic CO 2 with very low contents but contaminated by mantle-derived helium; (2) inorganic CO 2 gases with lower to higher contents being mixtures of crustal CO 2 with mantle-derived CO 2, the mantle- contributed percentage being in the range of 0 %-27 %, and (3) mainly crust-derived inorganic CO 2 gases being characterized by high contents (more than 50 %) and indicating the crustal addition by metamorphism of rich-in carbon rocks in basement. Nevertheless, some CO 2/ 3He ratios of organic CO 2 fall into the range 10 8-10 10, which made us inquire whether the CO 2/ 3He=(1-10)×10 9 can be the unique signature of magmatic CO 2 or not. All the observation of plutonic activities, fluid inclusion measurements in gas reservoirs, pre-stack depth/time seismic sections and the satellite infrared remote photography taken from Yinggehai basin, South China Sea, during Chichi earthquake in Taiwan on September 21, 1999, supports that the degassing processes are in a discontinuous mode, which may be triggered by igneous intrusion or extrusion, or earthquakes. In the central diapir zone of the basin, at least 3 to 4 orders of discharge of across-formational thermal fluid flows through fractures can be determined in different scales. The mantle degassing process may have a strong effect on overpressured system forming and outgassing in crust. However, it is very difficult to estimate the transferring rates for a special fractured zone at a specific time interval.

Thermo-Electrochemical Processes of the Earth’s Degassing Creating Geomagnetic Field and Changing Its Value and Direction (Thermodynamic Approach)

The currently accepted theory of self-exciting dynamo generating magnetic field of the Earth and its shortage of energy is critically reviewed. Based on thermodynamic approach, a new hypothesis of the Earth’s magnetic field, created by thermo-electrochemical processes of the Earth’s degassing, gravitational differentiation and their energy, is proposed. The ion-exchange, extraction and solidification are sources of the ionic currents on solid core and lower mantle boundaries. These currents are carried by thermo-chemical flows, which create the primary exciting magnetic field. This field is amplified mostly by thermoelectricity generated by heat flow thus improving the heat and matter transport from the Earth’s core and lower mantle to surface. Migration of the solidification zones and inner core precession are the main causes of changes of the main magnetic field intensity and reversals of its polarity.

Effect of ultrasonic field treatment on degassing of 2024 alloy

The 2024 aluminum alloy was prepared with different ultrasonic processes.Effects of ultrasonic treatment parameters including ultrasonic power,treatment time,treatment temperature,and frequency resonance,as well as C_(2)Cl_(6) degasser on degassing of the 2024 aluminum alloy were investigated.Results indicate that increasing ultrasonic power at the same ultrasonic treatment time can improve the degassing effect.The optimum degassing efficiency can be obtained under the resonant ultrasound condition.With the combination of 1%C_(2)Cl_(6) addition and 150 W ultrasonic treatment for 40 s,the hydrogen content of the alloy is decreased by 52.9%.At the same time,the tensile strength and elongation are increased by 28.3%and 92.3%,respectively,and the yield strength is slightly increased by 6.7%.The degassing mechanism is also discussed.

A new high shear degassing technology and mechanism for 7032 alloy

Degassing is very important for aluminum alloys especially for 7xxx series alloys.In the present study,a high shear technology was used to degas 7032 aluminum alloy in order to study its degassing efficiency.The experimental results showed that the high shear technology can significantly degas 7032 aluminum alloy.By applying intensive melt shearing and an Ar injection of 60 seconds,the density index,D_i,was reduced from13.25%to 0.28%and the hydrogen concentration was significantly reduced from 0.31 to 0.10 mL/100 g Al.Compared with the conventional rotary degassing,high shear technology showed a much higher degassing efficiency,achieving a lower concentration of hydrogen in a shorter time.The water simulation experiment was used to study the mechanism of the high degassing efficiency.The small bubble size and the uniform distribution of Ar bubbles with the application of high shear technology are believed to be the main cause for the high degassing efficiency.

CO2 degassing and melting of metasomatized mantle lithosphere during rifting-Numerical study

:Reactivation of metasomatized mantle lithosphere may occur during continental extension,which is an important component of plate tectonics.The lower most part of the metasomatized domains in the subcontinental mantle lithosphere can be locally enriched in CO2.Therefore,partial melting of these metasomatized domains may play a crucial role in the global carbon cycle.However,little is known about this process and up until now few numerical constraints are available.Here we address this knowledge gap and use a 2-D high resolution petrological-thermomechanical model to assess lithospheric rifting.CO2 degassing and melting.We test 4 lithospheric thicknesses:90,110,130 and 200 km with a 10 km thick metasomatized layer at the base using CO2 of 2 wt.%in the bulk composition.The carbonate enriched layer is stable below^3 GPa(>110 km)for a temperature of 1300℃;therefore,we only observe degassing patterns for lithospheric models that are 130 km and 200 km thick.The metasomatized layer for the 130 km thick lithosphere mostly comprises carbonatite melting,whereas in the 200 km thick scenario propagation of melt development from kimberlites to carbonatites occurs as the metasomatic mantle is exhumed during extension.The numerical models fit well into natural rifting zones of the European Cenozoic Rift System for young(shallow)and of the North Atlantic Rift for old(thick)lithosphere.

THEORETICAL ANALYSIS FOR THE MOTION AND TEMPERATURE OF MELT DROPLETS IN SPRAY DEGASSING PROCESS

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process couM be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets wouM solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results,

Calculation of the CO2 Degassing during Contact Metamorphism and Its Geological Significance:The Model and Example from the Shuanshan Area of the South Tan-Lu Fault Belt

The paper studies CO2 degassing and controlling factors under the condition of contact metamorphism in the Shuangshan area, southern Tan-Lu fault belt and the method of calculating the amount of CO2 degassing. The results show that the amount of CO2 degassing is controlled by the characteristics of the country rocks, including the thermal conductivity, penetrability, porosity and connectivity. Compositions, size and depth of intrusive rock also have an important influence on CO2 degassing, i.e., they generated numerous cracks in the country rocks, and thus allowed the easy flow and accumulation of fluids. The amount of CO2 flux in contact metamorphism is calculated quantitatively based on the metamorphic reaction and time-integrated fluid flux. The value （0.729- 2.446×10^4 mol/cm^2） of CO2 flux suggests that CO2 was provided mainly by the contact metamorphic reaction. The generation and releasing of CO2 are positively correlated with the degree of metamorphism, and XCO2 in fluids gradually increases from dolomite zone to calcite zone, but in the zone of grossular, fluid flux is the largest and XCO2 sharply decreases due to involvement of magmatic water. This study presents evidence that a large amount of industrial-scale CO2 can be produced during contact metamorphism. On the basis of theoretical and practical studies, a cone model has been proposed to response CO2 degassing for the contact metamorphism, and it can be used to explore CO2 accumulations beyond the oil-gas basins. This model can also be applied to the study of inorganic genesis of CO2 accumulations.

Application of improved vacuum degassing technique to refinement of heat resistant steel P91

An effective vacuum melting technique based on the improved vacuum degassing technique was used to produce thick-walled seamless pipes of 9Cr-1Mo-V-Nb-N martensitic heat resistant steels in order to reduce the contents of harmful impurity such as oxygen, phosphorus. Then the pipe was heat treated by using optimized process technique. Both static and dynamic mechanical properties at room temperature and 566℃ were measured respectively and evaluated by means of comprehensive analysis of standard deviation and statistic test. The results show that the comprehensive mechanical properties of this pipe are much better than those of pipes untreated with the improved vacuum degassing technique and heat-treated by using original heat-treatment process and almost the same as those of imported P91 thick-walled seamless steel pipe.

Relationship between Helium Degassing of Cattle-Manure-Compost Adsorbents and Copper Ions Removal

This work was aimed to investigate the effect of helium degassing of cattle-manure-compost (CMC) based activated carbons on the adsorptive removal of copper ions from aqueous solution. Degassing temperatures were 500℃, 800℃ and 1000℃. Activated carbons were characterized according to surface chemistry and pore structures. Adsorption of copper ions was carried out using the conventional bottle-point technique to which the equilibrium data were correlated to Langmuir and Freundlich models. Results indicated that the uptake of copper ions could be well characterized by Langmuir model. It was found that the adsorption of copper ions decreased with significant decrease in surface area as a result of helium degassing at higher temperature. The increase of electron density on graphene layers offered higher affinity towards copper ions at lower equilibrium concentration. It was inferred that copper ions favorably adsorbed on mesopores at lower equilibrium concentration and switched to micropores at higher equilibrium concentration.

Warming of Antarctica as a Degassing Consequence

The warming of Antarctica observed in recent years is one of the consequences of deep degassing associated with the northward drift of the Earth’s core. Ascending streams of hydrogen and other gases move along the tectonic faults of the lithosphere. When they get into an oxidizing environment, there is an increase in the amount of water in the ocean and air, which is accompanied by a decrease in oxygen concentrations and the release of huge amounts of energy. The provisions of the proposed theory were tested using the method of mental critical experiment. The reality of atmospheric effects of subsurface degassing is confirmed by the facts of synchronous destruction of ozone in the stratosphere and an increase in the temperature of the surface air layer. These events usually coincide with releases of ozone-depleting and heat-generating hydrogen from the subsurface.

The Permian-Triassic Transitional Zone: Jordan, Arabian Plate;Linked to Siberian Large Igneous Province and Neo-Tethys Breakup Degassing via Climate Forcing, Atmospheric Hazard and Metal Toxicity

End-Permian Gondwana siliciclastics (50 - 70 m) of the Um Irna F exposed along the NE Dead Sea, exhibit carbonate-free fining upward cycles (FUC) deposited during acid flash flood events under tropical climate. Several ferruginous paleosol intercalations cover periods of drying upward formation (DUP) under semiarid/arid climates. Thin grey pelite beds interbedded between paleosol and overlying FUC, are interpreted as tephra deposits sourced in Siberian LIP- and Neo-Tethys (NT)-Degassing. The Wadi Bassat en Nimra-section exhibits the P-T transitional zone where flash flood deposits meet supra-/intertidal sediments of the southward-directed transgressive NT. Decreasing flash-flooding continued through the Lower Scythian (Ma’in F.) during transgression, reworking, and resedimentation. Two euryhaline foraminifera-bearing limestone beds are discussed as indicators for the end of mass extinction (recovery phase: ca. 250.8 - 250.4 Ma) possibly correlating with the Maximum Flooding Surface MFS Tr 10 (ca. 250.5 Ma) on the Arabian Shelf (Khuff cycles B;A). Comparable data from the Germanic Basin as FUC/DUP-cycles, tephrasuspicious “Grey Beds” with high concentrations of As, Co, Pb, Zn, and Cu as well as the U-Pb Age data of the Siberian LIP meet the PTB-Zone between the MFSs Intervals P 40 (ca. 254 Ma)/Tr 10 (ca 250.5 Ma) on the Arabian Shelf. MFS (Tr 10, 20, 30) and SBs resp. on the Arabian Plate, as well as Scythian Substage boundaries correlate with ∂13 C-excursions recorded at Musandam, UAE. Thereby, the ratio of greenhouse gases (+climate forcing)/aerosols und tephra (-climate forcing) takes a significant influence on the ∂13C-Variation.

钢液VD真空处理脱氮数学模型

根据钢液VD真空处理过程氮溶解热力学和脱氮动力学理论,建立了高碳钢VD真空处理过程脱氮的数学模型。采用该模型结合VD处理过程的工艺条件,可实现钢液VD真空处理过程脱氮预测。

Decarburization rate of RH refining for ultra low carbon steel

The decarburization behaviors of ultra low carbon steel in a 210-t RH vacuum degasser were investigated under practical operat- ing conditions. According to the apparent decarburization rate constant （Kc） calculated by the carbon content in the samples taken from the hot melt in a ladle at an interval of 1-2 min, it is observed that the total decarburization reaction period in RH can be divided into the quick decarburization period and the stagnant decarburization period, which is quite different from the traditional one with three stages. In this study, the average apparent decarburization rate constant during the quick decarburization period is 0.306 min^-1, and that of the stagnant period is 0.072 min^-1. Increasing the initial carbon content and enhancing the exhausting capacity can increase the apparent decarburization rate constant in the quick decarburization period. The decarburization reaction comes into the stagnant decarburization period when the carbon content in molten steel is less than 14× 10^-6 after 10 min of decarburization.

Carbon and oxygen behavior in the RH degasser with carbon powder addition

For ultra-low-carbon(ULC)steel production,the higher oxygen content before Ruhrstahl-Heraeus(RH)decarburization(de-C)treatment could shorten the de-C time in the RH degasser.However,this would lead to oxidation rates being exceeded by molten steel production,affecting ULC steel surface quality.In this work,a carbon powder addition(CPA)process was proposed to reduce the dissolved oxygen content at the end of RH de-C through addition of carbon powder to molten steel in the vacuum vessel.Carbon and oxygen behavior during the CPA and conventional process was then studied.The results demonstrated that the de-C rate with CPA was lower compared to the conventional process,but the carbon content at the end of de-C presented no difference.The de-C reaction for CPA process took place in the four reaction sites:(1)within the bulk steel where the spontaneous CO bubbles form;(2)splashing area on the liquid steel surface;(3)Ar bubble surface;(4)molten steel surface.The CPA process could significantly reduce the dissolved oxygen content at the end of de-C,the sum content of FeO and MnO in the slag,the aluminum consumption,and the defect rate of rolled products.This was beneficial in improving ULC steel cleanliness.