A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe（VI）, was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The syn...A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe（VI）, was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The synergistic action of various factors on the absorption of SO2 and NOx was investigated. The results show that a strong synergistic effect exists between Fe（VI） dose and reaction temperature for the desulfurization. It was observed that in the denitration process, the synergy of Fe（VI） dose and Ca/（S ＋ N） had the most significant impact on the removal of NO, followed by the synergy of Fe（VI） and reaction temperature, and then the synergy of reaction temperature and flue gas humidity. A scanning electron microscope（SEM） and an accessory X-ray energy spectrometer（EDS）were used to observe the surface characteristics of the raw and spent absorbent as well as fly ash. A reaction mechanism was proposed based on chemical analysis of sulfur and nitrogen species concentrations in the spent absorbent. The Gibbs free energy, equilibrium constants and partial pressures of the SO2–NOx binary system were determined by thermodynamics.展开更多
Waste calcium carbide slags(CS),which are widely applied to desulfurisation,are not typically used in denitration.Herein,to well achieve waste control by waste,a facile and highefficiency denitration strategy is devel...Waste calcium carbide slags(CS),which are widely applied to desulfurisation,are not typically used in denitration.Herein,to well achieve waste control by waste,a facile and highefficiency denitration strategy is developed using KOH to modify the calcium carbide slags(KCS).Various KCS samples were investigated using a series of physical and chemical characterisations.The performance test results showed that the KOH concentration and reaction temperature are the main factors affecting the denitration efficiency of KCS,and CS modified with 1.5 mol/L KOH(KCS-1.5)can achieve 100% denitration efficiency at 300℃.Such excellent removal efficiency is due to the catalytic oxidation of the oxygen-containing functional groups derived from the KCS.Further studies showed that KOH treatment significantly increased the concentration of oxygen vacancies,nitro compounds,and basic sites of CS.This study provides a novel strategy for the resource utilisation of waste CS in the future.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 51308212, 10974053)the National Key Technology R&D Program (No. 2011BAI02B03)+1 种基金the Fundamental Research Funds for the Central Universities (No. 13ZD18)the State Scholarship Fund (No. 201206735009)
文摘A novel ferruginous active absorbent, prepared by fly ash, industrial lime and the additive Fe（VI）, was introduced for synchronous abatement of binary mixtures of SO2–NOx from simulated coal-fired flue gas. The synergistic action of various factors on the absorption of SO2 and NOx was investigated. The results show that a strong synergistic effect exists between Fe（VI） dose and reaction temperature for the desulfurization. It was observed that in the denitration process, the synergy of Fe（VI） dose and Ca/（S ＋ N） had the most significant impact on the removal of NO, followed by the synergy of Fe（VI） and reaction temperature, and then the synergy of reaction temperature and flue gas humidity. A scanning electron microscope（SEM） and an accessory X-ray energy spectrometer（EDS）were used to observe the surface characteristics of the raw and spent absorbent as well as fly ash. A reaction mechanism was proposed based on chemical analysis of sulfur and nitrogen species concentrations in the spent absorbent. The Gibbs free energy, equilibrium constants and partial pressures of the SO2–NOx binary system were determined by thermodynamics.
基金supported by the National Natural Science Foundation of China(No.51968075)the Scientific Research Fund project of Yunnan Education Department(Nos.2022J0441 and 2022J0442)。
文摘Waste calcium carbide slags(CS),which are widely applied to desulfurisation,are not typically used in denitration.Herein,to well achieve waste control by waste,a facile and highefficiency denitration strategy is developed using KOH to modify the calcium carbide slags(KCS).Various KCS samples were investigated using a series of physical and chemical characterisations.The performance test results showed that the KOH concentration and reaction temperature are the main factors affecting the denitration efficiency of KCS,and CS modified with 1.5 mol/L KOH(KCS-1.5)can achieve 100% denitration efficiency at 300℃.Such excellent removal efficiency is due to the catalytic oxidation of the oxygen-containing functional groups derived from the KCS.Further studies showed that KOH treatment significantly increased the concentration of oxygen vacancies,nitro compounds,and basic sites of CS.This study provides a novel strategy for the resource utilisation of waste CS in the future.
