One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis

One new polymer [Co（L）（H2O）2]n（1） was synthesized by 4-（ethoxycarbonyl）-5-methyl-1H-1,2,3-triazole-1-carboxylic acid（Emtc） under the in situ solvent thermal reaction（H2L = 1-（carboxymethyl）-5-methyl-1H-1,2,3-triazole-4-carboxylic acid）. The title complex performs a wave-like 2D framework and the ligand H2L demonstrates the coordination mode as μ4-η-2：η-1η-1：η-1. The crystal structure has been established by single-crystal X-ray diffraction, and characterized by FT-IR. Fluorescent property was investigated in this work. Hirshfeld surface analysis has also been carried out on 1, and obvious main intermolecular interactions are observed.

THE SECOND RECIPROCAL DERIVATIVE CHRONOPOTENTIOMETRY ANALYSIS

Theories of the second reciprocal derivative chronopotentiometry analysis were deduced and experimentally verificated.Results in this study show that chronopotentiometry is significantly developed in both sensitivity and resolution for signals treated by the second reciprocal derivative.

THE SECOND RECIPROCAL DERIVATIVE POTENTIOMETRIC STRIPPING ANALYSIS

A theory of the second reciprocal derivative potentiometric stripping analysis with a mercury thin-film electrode is reported.

SiZer for exploration of inhomogeneous structure in temporal distribution of earth-quakes

In this paper, the inhomogeneous structure of generalized seismic strain release time series (GSSRTS) of earth- quakes in East, West China and their subtectonic regions as Xinjiang, Qinghai-Xizang (Tibetan) Plateau, Northeast China, North China, South China and Taiwan have been analyzed by using the method of significant analysis on zero crossings of derivatives (SiZer). Results show that when index η for estimating GSSRTS is close to zero and bandwidth is large enough, GSSRTSs feature significant increasing in Xinjiang, Northeast China, South China and Taiwan tectonic regions and decreasing in Qinghai-Xizang (Tibetan Platean) and North China tectonic regions from January 1, 1970 to January 1, 2000. While with the dwindling of bandwidth GSSRTSs in all the above tec- tonic regions characterize clustering, that is to say, significant increasing and decreasing emerge alternatively. When η is large enough, GSSRTSs would have no significant statistical variation in most of above tectonic regions except Qinghai-Xizang (Tibetan Platean) and Taiwan where significant increasing or decreasing hold in several time intervals within limited bandwidths.

Self-contained eigenvector algorithm applied to the identification of aerodynamic derivatives of bridge model

On one hand, when the bridge stays in a windy environment, the aerodynamic power would reduce it to act as a non-classic system. Consequently, the transposition of the system’s right eigenmatrix will not equal its left eigenmatrix any longer. On the other hand, eigenmatrix plays an important role in model identification, which is the basis of the identification of aerodynamic derivatives. In this study, we follow Scanlan’s simple bridge model and utilize the information provided by the left and right eigenmatrixes to structure a self-contained eigenvector algorithm in the frequency domain. For the purpose of fitting more accurate transfer function, the study adopts the combined sine-wave stimulation method in the numerical simulation. And from the simulation results, we can conclude that the derivatives identified by the self-contained eigenvector algorithm are more dependable.

Platelet derived growth factor and basic fibroblast growth factor immunolocalized in proliferative retinal diseases

Objective To study the role of platelet derived growth factor (PDGF) and basic fibroblast growth factor (bFGF) in the development of proliferative vitreoretinopathy (PVR) Methods Immunohistochemical localization was performed on frozen sections of the epiretinal or subretinal membranes from 21 PVR patients using!monoclonal antibodies against PDGF and bFGF and the streptavidin peroxidase system Results PDGF was expressed in 15 of 21 specimens (71 4%), and bFGF was expressed in 14 specimens (66 7%) Different cell density was seen in different types of epiretinal membranes The cell density of vascular membranes induced by PDR and Eales disease was the highest (≥61 cells/field, ×1000); nonvascular membranes induced by PVR or traumatic PVR had moderate cell density (31-60 cells/field); and the macular membrane had the lowest cell density (≤30 cells/field) Conclusion The presents of PDGF and bFGF in PVR tissues suggest that PDGF and bFGF may play an important role in the development of PVR

Intranasal administration of tetrabromobisphenol A bis(2-hydroxyethyl ether) induces neurobehavioral changes in neonatal Sprague Dawley rats

Tetrabromobisphenol A（TBBPA） and its derivatives are now being highly concerned due to their emerging environmental occurrence and deleterious effects on non-target organisms.Considering the potential neurotoxicity of TBBPA derivatives which has been demonstrated in vitro, what could happen in vivo is worthy of being studied. Tetrabromobisphenol A bis（2-hydroxyethyl ether）（TBBPA-BHEE）, a representative TBBPA derivative, was selected for a21-day exposure experiment on neonatal Sprague Dawley（SD） rats through intranasal administration. The neurobehavioral, histopathological changes, and differentially expressed genes based on RNA microarray were investigated to evaluate the neurological effects of this chemical. The results indicated that TBBPA-BHEE exposure significantly compromised the motor co-ordination performance and the locomotor activities（p 〈 0.05）. The neurobehavioral phenotype could be attributed to the obvious histopathological changes in both cerebrum and cerebellum, such as neural cell swelling, microglial activation and proliferation. A total of 911 genes were up-regulated, whereas 433 genes were down-regulated. Gene set enrichment analysis showed multiple signaling pathways, including ubiquitin-mediated proteolysis and wingless-int（Wnt） signaling pathway etc. were involved due to TBBPA-BHEE exposure. The gene ontology enrichment analysis showed the basic cellular function and the neurological processes like synaptic transmission were influenced. The toxicological effects of TBBPA-BHEE observed in this study suggested the potential neuronal threaten from unintended exposure,which would be of great value in the biosafety evaluation of TBBPA derivatives.