In order to study the detonation velocity deficits of bending flexible detonating fuses,a physical model and a theoretical mathematical equation of detonation velocity deficits for bending flexible detonation fuses we...In order to study the detonation velocity deficits of bending flexible detonating fuses,a physical model and a theoretical mathematical equation of detonation velocity deficits for bending flexible detonation fuses were established based on the detonation wave's corner effects and delay time phenomenon by using non-dimensional analysis method.Besides,a semi-empirical formula of detonation velocity deficit for bending fuses in the same charge size was obtained through experiment and curve fitting.The result shows that an exponential relationship between the detonation velocity deficits and reciprocal of curvature radius.展开更多
The nitrogen content of tetrazolo triazines is 68.9%.In this paper,tetrazolotriazines was synthetized.The TG-DSC test indicated its decomposition process in detail.The non-isothermal kinetic parameters were speculated...The nitrogen content of tetrazolo triazines is 68.9%.In this paper,tetrazolotriazines was synthetized.The TG-DSC test indicated its decomposition process in detail.The non-isothermal kinetic parameters were speculated by Kissinger and Ozawa methods.It revealed the mechanism function of thermal decomposition.The impact and friction sensitivity were tested.The detonation pressure and velocity were calculated.It has a wide range of potential applications as a kind of energetic material.展开更多
In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obta...In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obtained from the steady state VOD measurement of emulsion explosives HEF100 and degree of blast fragmentation conducted on an open pit blast. The aim of this study was to compare the steady state VOD measured in the field and the published VOD of HEF100 under ideal laboratory conditions and ascertain its efficacy. In the trial, a resistance wire continuous VOD measurement system connected to a SpeedVOD was employed to measure and record the steady state VOD values from five different blast holes. Furthermore, a post fragmentation analysis was conducted using the existing fragmentation models and an image processing software. The steady state VOD values recorded from the field ranged between 4981 m/s to 5387 m/s consistent with the published VOD subjected to ideal laboratory conditions and the analyzed fragmentation size distribution indicates that 90% of the blasted muck pile was within the allowable and optimal 700 mm passing size.展开更多
In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by...In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by a detonation velocity measuring instrument under conditions of different ignition.The experimental results and theoretical analysis show that the maximum detonation propagation velocity depends on the explosive materials with the maximum velocity among all the explosive materials.Using detonating cord in a superposition charge can shorten detonation propagation time and improve the efficiency of explosive energy.The measurement method of detonation propagation velocity and experimental results are presented and investigated.展开更多
In this paper, detonation parameters of fuel cloud, such as propylene oxide (PO), isopropyl nitrate (IPN), hex- ane, 90# oil and decane were measured in a self-designed and constructed vertical shock tube. Results...In this paper, detonation parameters of fuel cloud, such as propylene oxide (PO), isopropyl nitrate (IPN), hex- ane, 90# oil and decane were measured in a self-designed and constructed vertical shock tube. Results show that the deto- nation pressure and velocity of PO increase to a peak value and then decrease smoothly with increasing equivalence ra- tio. Several nitrate sensitizers were added into PO to make fuel mixtures, and test results indicated that the additives can efficiently enhance detonation velocity and pressure of fuel cloud and one type of additive n-propyl nitrate (NPN) played the best in the improvement. The critical initiation energy that directly initiated detonation of all the test liquid fuel clouds showed a U-shape curve relationship with equiva- lence ratios. The optimum concentration lies on the rich-fuel side (;b 〉 1). The critical initiation energy is closely related to molecular structure and volatility of fuels. IPN and PO have similar critical values while that of alkanes are larger. Detonation cell sizes of PO were respectively investigated at 25;C, 35;C and 50;C with smoked foil technique. The cell width shows a U-shape curve relationship with equivalence ratios at all temperatures. The minimal cell width also lies on the rich-fuel side (;b 〉 1). The cell width of PO vapor is slightly larger than that of PO cloud. Therefore, the deto- nation reaction of PO at normal temperature is controlled by gas phase reaction.展开更多
The mechanical sensitivity, the critical thickness of detonation wave propagation and detonation velocity of desensitized PETN film were studied by experiments. The relationship between the mass of desensitizer paraff...The mechanical sensitivity, the critical thickness of detonation wave propagation and detonation velocity of desensitized PETN film were studied by experiments. The relationship between the mass of desensitizer paraffin wax and the friction sensitivity of desensitized PETN film was tested. According to the microstructure of film, the function of desensitizer was explained. It was proved that the explosive film could make explosive element micromation and kept its inherence properties by the result of testing the propagating critical dimension of the desensitized PETN film detonation wave. The explosive velocity of confined desensitized PETN film was tested by the multiplex optical fibre..展开更多
The behavior of the charge initiation of the coated-type projectile penetrating target is researched by means of numerical simulation. The influences on charge initiation of the projectile shape, shell thickness, char...The behavior of the charge initiation of the coated-type projectile penetrating target is researched by means of numerical simulation. The influences on charge initiation of the projectile shape, shell thickness, charge diameter, and projectile velocity are analyzed. Results show that projectile shape takes an obvious impact on critical detonation velocity, that for the projectile with the same quality, it is more vulnerable for the cylindrical projectile with the one length-diameter ratio to occurring shock initiation than the spherical projectile, the charge diameter is an important factor that affecting critical detonation velocity, which significantly decreases as the charge diameter increases.展开更多
In the paper, we aim to show N-(2,4,6-trinitrophenyl)-1H-1,2,4-triazol-3-amine (HM-I) as explosive material that satisfies requirements of sensitivity and hydrolytically stability. The influence of nitro group substit...In the paper, we aim to show N-(2,4,6-trinitrophenyl)-1H-1,2,4-triazol-3-amine (HM-I) as explosive material that satisfies requirements of sensitivity and hydrolytically stability. The influence of nitro group substitutions on the thermal and chemical stability as well as the explosive performance of HM-I is also investigated. We found that nitro group substitution to the triazole ring of HM-I can significantly improve the properties of this new material. Only -NH2 substitution position (but not their number) in the core molecule is appropriate to increase the stability and improve explosive performances of HM-I.展开更多
A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small sphe...A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small spherical explosive charge generated in rock, is used to further study the triggering time of strain gauges installed in radial direction at same distances but different positions surrounding a cylindrical explosive charge in rock. The duration of the first compression phase and peak value of strain wave, and furthermore, their differences are analyzed and some explanations are given. Besides that, the gauge orientation in which the maximum peak value occurs is also discussed. At last, the effect of velocity of detonation(V.O.D.) of a cylindrical explosive charge on the strain waves generated in the surrounding rock is taken as key research and the pattern of peak amplitude of a strain wave varies with the V.O.D. is likely to have been found.展开更多
The pulse detonation rocket engine (PDRE) requires periodic supply of oxidizer, fuel and purge gas. A rotary-valve assembly is fabricated to control the periodic supply in this research. Oxygen and liquid aviation k...The pulse detonation rocket engine (PDRE) requires periodic supply of oxidizer, fuel and purge gas. A rotary-valve assembly is fabricated to control the periodic supply in this research. Oxygen and liquid aviation kerosene are used as oxidizer and fuel respectively. An ordinary automobile spark plug, with ignition energy as low as 50 mJ, is used to initiate combustion. Steady operation of the PDRE is achieved with operating frequency ranging from 1 Hz to 10 Hz. Experimentally measured pressure is lower than theoretical value by 13% at 1 Hz and 37% at 10 Hz, and there also exists a velocity deficit at different operating frequencies. Both of these two phenomena are believed mainly due to droplet size which depends on atomization and vaporiza-tion of liquid fuel.展开更多
基金Supported by the Foundation of State Key Laboratory of Explosion Science and Technology(YBKT10-04)
文摘In order to study the detonation velocity deficits of bending flexible detonating fuses,a physical model and a theoretical mathematical equation of detonation velocity deficits for bending flexible detonation fuses were established based on the detonation wave's corner effects and delay time phenomenon by using non-dimensional analysis method.Besides,a semi-empirical formula of detonation velocity deficit for bending fuses in the same charge size was obtained through experiment and curve fitting.The result shows that an exponential relationship between the detonation velocity deficits and reciprocal of curvature radius.
基金Supported by the State Key Laboratory of Explosion Science and Technology(Beijing Institute of Technology)(YBKT16-09,QNKT16-03)
文摘The nitrogen content of tetrazolo triazines is 68.9%.In this paper,tetrazolotriazines was synthetized.The TG-DSC test indicated its decomposition process in detail.The non-isothermal kinetic parameters were speculated by Kissinger and Ozawa methods.It revealed the mechanism function of thermal decomposition.The impact and friction sensitivity were tested.The detonation pressure and velocity were calculated.It has a wide range of potential applications as a kind of energetic material.
文摘In holes, the measurement of the velocity of detonation(VOD) helps in comparing and evaluating relative performance of explosives. In this paper a blast performance assessment was conducted based on the results obtained from the steady state VOD measurement of emulsion explosives HEF100 and degree of blast fragmentation conducted on an open pit blast. The aim of this study was to compare the steady state VOD measured in the field and the published VOD of HEF100 under ideal laboratory conditions and ascertain its efficacy. In the trial, a resistance wire continuous VOD measurement system connected to a SpeedVOD was employed to measure and record the steady state VOD values from five different blast holes. Furthermore, a post fragmentation analysis was conducted using the existing fragmentation models and an image processing software. The steady state VOD values recorded from the field ranged between 4981 m/s to 5387 m/s consistent with the published VOD subjected to ideal laboratory conditions and the analyzed fragmentation size distribution indicates that 90% of the blasted muck pile was within the allowable and optimal 700 mm passing size.
文摘In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by a detonation velocity measuring instrument under conditions of different ignition.The experimental results and theoretical analysis show that the maximum detonation propagation velocity depends on the explosive materials with the maximum velocity among all the explosive materials.Using detonating cord in a superposition charge can shorten detonation propagation time and improve the efficiency of explosive energy.The measurement method of detonation propagation velocity and experimental results are presented and investigated.
文摘In this paper, detonation parameters of fuel cloud, such as propylene oxide (PO), isopropyl nitrate (IPN), hex- ane, 90# oil and decane were measured in a self-designed and constructed vertical shock tube. Results show that the deto- nation pressure and velocity of PO increase to a peak value and then decrease smoothly with increasing equivalence ra- tio. Several nitrate sensitizers were added into PO to make fuel mixtures, and test results indicated that the additives can efficiently enhance detonation velocity and pressure of fuel cloud and one type of additive n-propyl nitrate (NPN) played the best in the improvement. The critical initiation energy that directly initiated detonation of all the test liquid fuel clouds showed a U-shape curve relationship with equiva- lence ratios. The optimum concentration lies on the rich-fuel side (;b 〉 1). The critical initiation energy is closely related to molecular structure and volatility of fuels. IPN and PO have similar critical values while that of alkanes are larger. Detonation cell sizes of PO were respectively investigated at 25;C, 35;C and 50;C with smoked foil technique. The cell width shows a U-shape curve relationship with equivalence ratios at all temperatures. The minimal cell width also lies on the rich-fuel side (;b 〉 1). The cell width of PO vapor is slightly larger than that of PO cloud. Therefore, the deto- nation reaction of PO at normal temperature is controlled by gas phase reaction.
文摘The mechanical sensitivity, the critical thickness of detonation wave propagation and detonation velocity of desensitized PETN film were studied by experiments. The relationship between the mass of desensitizer paraffin wax and the friction sensitivity of desensitized PETN film was tested. According to the microstructure of film, the function of desensitizer was explained. It was proved that the explosive film could make explosive element micromation and kept its inherence properties by the result of testing the propagating critical dimension of the desensitized PETN film detonation wave. The explosive velocity of confined desensitized PETN film was tested by the multiplex optical fibre..
基金Supported by the 11th Five-Year Defense Pre-research Fund(7130810)
文摘The behavior of the charge initiation of the coated-type projectile penetrating target is researched by means of numerical simulation. The influences on charge initiation of the projectile shape, shell thickness, charge diameter, and projectile velocity are analyzed. Results show that projectile shape takes an obvious impact on critical detonation velocity, that for the projectile with the same quality, it is more vulnerable for the cylindrical projectile with the one length-diameter ratio to occurring shock initiation than the spherical projectile, the charge diameter is an important factor that affecting critical detonation velocity, which significantly decreases as the charge diameter increases.
基金the LMA scientific project“A theoretical and experimental investigations of new potentially explosive materials using quantum mechanical methods(NSPROG-I4)”.
文摘In the paper, we aim to show N-(2,4,6-trinitrophenyl)-1H-1,2,4-triazol-3-amine (HM-I) as explosive material that satisfies requirements of sensitivity and hydrolytically stability. The influence of nitro group substitutions on the thermal and chemical stability as well as the explosive performance of HM-I is also investigated. We found that nitro group substitution to the triazole ring of HM-I can significantly improve the properties of this new material. Only -NH2 substitution position (but not their number) in the core molecule is appropriate to increase the stability and improve explosive performances of HM-I.
基金Projects(51304239,51374243)supported by the National Natural Science Foundation of China
文摘A superposing principle, by suitably adding the strain waves from a number of concentrated explosive charges to approximate the waves generated by a cylindrical charge based on the strain wave of a point or small spherical explosive charge generated in rock, is used to further study the triggering time of strain gauges installed in radial direction at same distances but different positions surrounding a cylindrical explosive charge in rock. The duration of the first compression phase and peak value of strain wave, and furthermore, their differences are analyzed and some explanations are given. Besides that, the gauge orientation in which the maximum peak value occurs is also discussed. At last, the effect of velocity of detonation(V.O.D.) of a cylindrical explosive charge on the strain waves generated in the surrounding rock is taken as key research and the pattern of peak amplitude of a strain wave varies with the V.O.D. is likely to have been found.
基金National Natural Science Foundation of China (50976094)Doctoral Program Foundation of Education Ministry of China (20096102110022)+1 种基金Doctorate Foundation of Northwestern Polytechnical University (CX201112)Graduate Innovation Lab Center of Northwestern Polytechnical University (10006,10013)
文摘The pulse detonation rocket engine (PDRE) requires periodic supply of oxidizer, fuel and purge gas. A rotary-valve assembly is fabricated to control the periodic supply in this research. Oxygen and liquid aviation kerosene are used as oxidizer and fuel respectively. An ordinary automobile spark plug, with ignition energy as low as 50 mJ, is used to initiate combustion. Steady operation of the PDRE is achieved with operating frequency ranging from 1 Hz to 10 Hz. Experimentally measured pressure is lower than theoretical value by 13% at 1 Hz and 37% at 10 Hz, and there also exists a velocity deficit at different operating frequencies. Both of these two phenomena are believed mainly due to droplet size which depends on atomization and vaporiza-tion of liquid fuel.