Geochemical Anomaly at the Devonian/Carboniferous Boundary, Huangmao, Gnangxi, China

The abundances of nearly 40 elements, Ir included, have been measured using radio-chemical and instrumental neutron activation analysis (RNAA and INAA) across a Devonian/Carboniferous (D/C) boundary section at Huangmao, Guangxi, China. The Ir anomaly has been found in the D/C boundary bed. Its peak value is 156 ppt, richer by a factor of 12 than that in the underlying strata. Besides, as with Ir, other siderophile and chalcophile elements such as Au. Ni. Co. As and Sb are also enriched. The cause for the abundance anomalies of Ir and other elemets is discussed. Neither volcanic eruption nor extraterrestrial impact can explain it satisfactorily. The real mechanism for the anomalies awaits further study.

Reservoir characteristics and formation model of Upper Carboniferous bauxite series in eastern Ordos Basin,NW China

Through core observation,thin section identification,X-ray diffraction analysis,scanning electron microscopy,and low-temperature nitrogen adsorption and isothermal adsorption experiments,the lithology and pore characteristics of the Upper Carboniferous bauxite series in eastern Ordos Basin were analyzed to reveal the formation and evolution process of the bauxite reservoirs.A petrological nomenclature and classification scheme for bauxitic rocks based on three units(aluminum hydroxides,iron minerals and clay minerals)is proposed.It is found that bauxitic mudstone is in the form of dense massive and clastic structures,while the(clayey)bauxite is of dense massive,pisolite,oolite,porous soil and clastic structures.Both bauxitic mudstone and bauxite reservoirs develop dissolution pores,intercrystalline pores,and microfractures as the dominant gas storage space,with the porosity less than 10% and mesopores in dominance.The bauxite series in the North China Craton can be divided into five sections,i.e.,ferrilite(Shanxi-style iron ore,section A),bauxitic mudstone(section B),bauxite(section C),bauxite mudstone(debris-containing,section D)and dark mudstone-coal section(section E).The burrow/funnel filling,lenticular,layered/massive bauxite deposits occur separately in the karst platforms,gentle slopes and low-lying areas.The karst platforms and gentle slopes are conducive to surface water leaching,with strong karstification,well-developed pores,large reservoir thickness and good physical properties,but poor strata continuity.The low-lying areas have poor physical properties but relatively continuous and stable reservoirs.The gas enrichment in bauxites is jointly controlled by source rock,reservoir rock and fractures.This recognition provides geological basis for the exploration and development of natural gas in the Upper Carboniferous in the study area and similar bauxite systems.

Biostratigraphy,Microfacies,Sedimentary Environments and Sequence Stratigraphy of the Late Devonian-Carboniferous Deposits at the Anarak Section,Central Iran

The Late Devonian-early Carboniferous deposits of the Anarak section in northeastern Isfahan,Central Iran,evaluated based on conodont biostratigraphy,sedimentary environment and sequence stratigraphy.According to the field observations,five lithological units were identified.Investigating the conodont fauna of the Late Devonian-Carboniferous(Mississippian-Pennsylvanian)deposits of Bahram,Shishtu,and Qaleh(Sardar 1)formations in Anarak section led to the identification of 67 species of 18 conodont genera,and accordingly 22 conodont biozones were differentiated.The correlation of sea-level change curves,regarding to the conodont biofacies with the global sea-level curve,demonstrates the relative correlation in the mentioned times due to the shallow condition of the central Iran basin compared to the European and American basins.The microfacies analysis led to the identification of 12 microfacies related to the open sea,bioclastic barrier,lagoon and tidal flat sub-sedimentary environments in a homoclinal carbonate ramp environment.Based on sequence stratigraphy studies,three 3rd order sequences were identified.The first sequence,which is of the Late Devonian(upper part of the Bahram Formation,32.5 m),the second sequence(12.5 m)is the Late Devonian(uppermost part of the Bahram Formation),and the third sequence(68 m)is the early Carboniferous(the Shishtu I Formation).

Palynostratigraphy of the Zorritas Formation, Antofagasta region, Chile： Insights on the Devonian]Carboniferous boundary in western Gondwana

The Middle Member of the Zorritas Formation in the Antofagasta region of northern Chile, yielded terrestrial and marine palynomorph assemblages which span the Devonian/Carboniferous boundary. The assemblages show a clear predominance of terrestrial palynomorphs with 70 miospore species, 18 marine phytoplankton species, two non-marine algae and one chitinozoan species, all coming from 15 productive levels. Palynomorphs are poorly preserved and most of them are reworked. Three palyno- logical associations are recognized based on miospores. These are assigned to the Tournaisian-Visean, Tournaisian and probable latest Famennian. Age assignments are discussed in the frame of the spore zonal schemes established for Euramerica and western Gondwana. The stratigraphical distribution of spores allows the identification of the probable position of the Devonian/Carboniferous boundary within the Zorritas Formation. This system boundary is proposed for the first time in Palaeozoic sedimentary rocks of northern Chile. The presence of Gondwanan typical miospore species indicates affinities with this palaeocontinent even though the Tournaisian and Tournaisian-Viseao miospore associations sup- port the cosmopolitanism already suggested for the early Carboniferous flora. The significant number of reworked palynomorphs together with the sedimentological analysis of the studied sections, suggest that these deposits were severely impacted by the climatic change and major sea level fluctuations. Similar conditions were recorded in coeval western Gondwana basins.

Upper Devonian and Lower Carboniferous Sequence Stratigraphy of South China

In South China four depositional sequences are recognized in the upper part of Upper Devonian and Tournaisian. They are named SQ0 SQ1, SQ2 and SQ3 in ascending order. SQ0 is Strunian (uppermost Devonian), and the other three Tournaisian in age. These four depositional sequences appear to correlate fairly well with the four sequence recognized in Europe, North America and other areas. This may suggest that these sequences are synchronous depos- its resulted from the eustatic changes. The present study on sequence stratigraphy, biostratigraphy and event stratigraphy indicates that in neritic facies areas of South China, the Devonian-Carboniferous boundary, matching the boundary between Siphonodella praesulcata zone and S. sulcata zone in pelagic facies areas, is not only higher than the top of the Cystophrentis zone, but also higher than the top of the Devonian-Carboniferous boundary event bed. In neritic facies areas, the Devonian-Carbonifrerous boundary is marked by the most distinct transgressive surface within the Cystophrentiseudouralina interval zone, i. e. at the base of the TST of the SQ1. This boundary coincides with the top surface of the event bed resulted from the eustatic fall, and approximately corresponds to the basal part of Rseudouralina assemblage zone.

Geochronology,Mineralogy,and Geochemistry of the Tonsteins from the Permo–Carboniferous Benxi Formation,Ordos Basin,North China Craton

Tonstein layers are found worldwide in the Permo-Carboniferous coal-bearing strata.This study investigates the geochronology,mineralogy,and geochemistry of four tonstein samples from the Permo-Carboniferous Benxi Formation,Ordos Basin,North China Craton(NCC).The typical features of the studied tonsteins include thin beds,lateral continuity,angular quartz grains,and euhedral zircons with similar U-Pb ages,indicating a significant pyroclastic origin.In addition,the tonstein samples have low TiO_(2)/Al_(2)O_(3)ratios(<0.02)and rare earth elements and yttrium(REY)concentrations with obvious negative Eu anomalies,indicating that the tonsteins have a felsic magma origin.Moreover,compared with the mean composition of clay shale,the studied tonsteins are characterized by high concentrations of the elements Nb and Ta,which may affect the concentration of the corresponding elements in surrounding coal seams.The zircon U-Pb ages of the tonsteins(293.9-298.8 Ma)provide a precise chronological framework on the Benxi Formation in the Ordos Basin,constraining the Gzhelian-Aselian stages.The tonsteins were probably sourced from arc volcanism along the western margin of the NCC during the early Permian,implying that the Alxa Terrane had not amalgamated with the NCC at that time.

Ramp facies in an intracratonic basin:A case study from the Upper Devonian and Lower Carboniferous in central Hunan,southern China

Detailed studies on Late Devonian to Early Carboniferous carbonate rocks in central Hunan, southern China have led to the recognition of 25 lithofacies which can be grouped into： （I） inner ramp peritidal platform, （2） inner ramp organic hank and mound, （3） mid ramp, （4） outer ramp, and （5） shelf basin facies associations. The peritidal platform facies association dominates the Zimenqiao Formation （Namurian A or late Datangian） and is characterized by gypsum and dolostone-containing sequences, indicating a peritidal platform environment. The other four facies associations dominate the Menggongao Formation （late Famennian）, Liujiatang Formation （Tournaisian or Yangruanian）, Shidengzi Formations （early Visean or early Datangian）. Five upward-shallowing cycles were distinguished in these three Formations. The predominant facies associations developed in each Formation demonstrate an overall transgression-regression cycle in the Late Devonian to Early Carboniferous in central Hunan. The overall transgressive sequence was preserved in the Shaodong, Menggongao, and Liujiatang Formations, and the overall regressive sequence was preserved in the Liujiatang, Shidengzi, Ceshui and Zimenqiao Formations.

On the Devonian-Carboniferous Boundary in Neritic Facies Areas of South China:A Viewpoint of Integrated StratigraPhy

Biostratigraphical data indicate that in the neritic facies areas of South China, the Devonian -Carboniferous boundary (DCB), matching the boundary between conodont Siphonodella praesulcata zone and S. sulcata zone, should be drawn between rugose coral Cystophrentis zone and Pseudouralina zone, i.e. the Cystophrentis\ Pseudouralina inter val-zone. The top of the sea level fall event bed near the DCB is lower than the boundary between S. praesulcata and S. sulcata zones, but higher than the top of the Cysto phrentis zone. Sequence stratigraphical study shows that the sea level fall event bed near the DCB constitutes the shelf margin system tract (SMST) of a depositional sequence (SQ1) in both neritic and pelagic facies areas. The top surfaces of SMST of SQ1 is slightly lower than the base of S. sulcata zone in the pelagic facies areas. In neritic facies areas of South China, therefore, the Devonian - Carboniferous boundary is marked by the most distinct transgressive surface within the Cystophrentis\ Pseudouralina interval-zone, i.e. the base of the TST of SQ1. This boundary coincides with the top surface of the event bed resulted from the eustatic fall, and approximately corresponds to the base of Pseudouralina assemblage zone.

Petrogenesis of the Carboniferous Intrusive Rock in the Xiaobaishitou District of East Tianshan,Northwest China:Magma Evolution and Tectonic Significance

The Xiaobaishitou gabbro-diorite pluton comprises a medium-grained gabbro-diorite suite and a fine-grained diorite suite,which intrude the Kawabulag Group in the East Tianshan Orogen of the Central Asian Orogenic Belt(CAOB).A combination of mineral chemistry,zircon U-Pb age,whole-rock geochemistry,Sr-Nd isotopes,and in situ zircon Hf isotopes for newly found gabbro-diorite from the Xiaobaishitou district in the Central Tianshan Terrane(CTT)is presented to investigate the petrogenesis and tectonic or even crustal evolution of the East Tianshan Orogen.Laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS)zircon U-Pb analyses indicate that the gabbro-diorite was formed at 324.7±2.4 Ma.The isolated clinopyroxene formed under higher P-T-fO_(2)melt conditions(10.7–14.6 kbar;1199–1269℃;high fO_(2))than those for the hornblende,plagioclase,and zircon(557–687℃;moderate fO_(2))in the gabbro-diorite,which reveals a multilevel,magmatic storage system.The gabbro-diorite is characterized by fractioned REE patterns,enriched LILEs(e.g.,Ba and Pb),negative anomalies of HFSEs(e.g.,Nb and Ta),and low La/Yb and Sr/Y ratios,which are typically indicative of crustal contamination and accounted for by subduction-related fluids.The rock also characterized by typical features of high compatible elements(MgO=3.14–11.65 wt%,Cr=1–157 ppm,Ni=6–830 ppm),high Mg^(#)(47–74),positiveε_(Hf)(t)values(+5.1 to+10.3)andε_(Nd)(t)values(+2.3 to+4.4).These features suggest that the Xiaobaishitou gabbro-diorite was most likely derived from metasomatic mantle and contaminated minor crustal components.Taking into account the spatial and temporal distribution of the Carboniferous magmatic rocks in the CTT,we suggest the formation of the Xiaobaishitou gabbro-diorite was attributed to southward subduction of the Kangguer Ocean.

Tectonic evolution and accumulation characteristics of Carboniferous shale gas in Yadu-Ziyun-Luodian aulacogen, Guizhou Province, South China

The Yadu-Ziyun-Luodian aulacogen(YZLA) developed into being NW-trending in the Late Paleozoic,and was considered as an important passive continental margin aulacogen in Guizhou Province, South China. This tectonic zone is considered a large intracontinental thrust-slip tectonic unit, which has undergone a long period of development. It was ultimately determined in the Yanshanian, where the typical Upper Paleozoic marine shales were deposited. In 2021, Well QSD-1 was deployed in the Liupanshui area at the northwest margin of the aulacogen, and obtained a daily shale gas flow of 11011 m3in the Carboniferous Dawuba Formation. It thus achieved a breakthrough in the invesgation of shale gas in the Lower Carboniferous in South China, revealing relatively good gas-bearing properties and broad exploration prospects of the aulacogen. Being different from the Lower Paleozoic strata in the Sichuan Basin and the Yichang area of the Middle Yangtze, the development of the Carboniferous Dawuba Formation in the aulacogen exhibits the following characteristics:(1) The Lower Carboniferous shale is thick and widely distributed, with interbedded shale and marlstone of virous thickness;(2) The total organic carbon(TOC) content of the shale in the Dawuba Formation ranges from 1% to 5%, with an average of 2%, and the thermal maturity of organic matter(Ro) varies from 1% to 4%, with an average of2.5%, indicating good hydrocarbon generation capacity;(3) The main shale in the aulacogen was formed during the fault subsidence stage from the Middle Devonian to the Early Permian. Although the strong compression and deformation during the late Indosinian-Himalayan played a certain role in destroying the formed shale gas reservoirs, comparative analysis suggests that the area covered by the current Triassic strata has a low degree of destruction. It therefore provides good conditions for shale gas preservation,which can be regarded as a favorable area for the next exploration.

Geological characterization and exploration potential of shale gas in the Carboniferous Jiusi Formation,northern Guizhou and Yunnan provinces,SW China

Dark mudstones and shales of the Carboniferous Jiusi Formation are widely developed in northern Guizhou and Yunnan provinces, SW China. However, the distribution, reservoir characterization, and exploration potential of organic-rich shales in this area are yet to be quantified, thus limiting the prospect of shale gas in this area. This study investigates the basic geological conditions of Jiusi shale gas, using core data, well-logs, and some other test data, obtaining the following results. The organic-rich shales are mainly composed of deltaic-to-shallow-shelf deposits, with thickness ranging from 0 to 450 m, and above 350 m around the subsidence center. The organic matter is mainly type Ⅱ kerogen with TOC content of mostly 1%–2%, indicating a moderate maturity. The argillaceous shale reservoirs are indicative of strong heterogeneity, high clay minerals content, low porosity, low permeability, high specific surface area, and relatively developed secondary porosity. The gas-log anomaly intervals obtained from the survey wells have a cumulative thickness that is apparently greater than 200 m, and a few shale intervals showing high desorbed and adsorbed gas contents. Due to complex structures in the study area, conditions responsible for shale gas occurrence and trapping are generally moderate. However, areas having wide and gentle folds with moderate depth of burial reveals relatively favorable conditions of hydrocarbon traps. In contrast with typical marine-continental transitional shales, the Jiusi shale have better geological conditions for shale gas preservation. The analysis of the geological framework and hydrocarbon potential of Carboniferous Jiusi Formation provide more insight for the exploration of Carboniferous shale gas in southern China.

Carboniferous Post-collisional Rift Volcanism of the Tianshan Mountains, Northwestern China

The Tianshan Carboniferous post-collisional rift volcanic rocks occur in northwestern China as a large igneous province. Based on petrogeochemical data, the Tianshan Carboniferous post-collisional rift basic lavas can be classified into two major magma types: (1) the low-Ti/Y type situated in the eastern-central Tianshan area, which exhibits low Ti/Y (<500), Ce/Yb (<15) and SiO2 (43-55%), and relatively high Fe2O3T (6.4-11.5%); (2) the high-Ti/Y type situated in the western Tianshan area, which has high Ti/Y (>500), Ce/Yb (>11) and SiO2 (49-55%), and relatively low Fe2O3T (5.8-7.8%). Elemental data suggest that chemical variations of the low-Ti/Y and high-Ti/Y lavas cannot be explained by fractional crystallization from a common parental magma. The Tianshan Carboniferous basic lavas originated most likely from an OIB-like asthenospheric mantle source (87Sr/86Sr(t) ≈ 0.703-0.705, eNd(0 = +4 to +7). The crustal contamination and continental lithospheric mantle have also contributed significantly to the formation of the basic lavas of the Tianshan Carboniferous post-collisional rift. The silicic lavas were probably generated by partial melting of the crust. The data of this study show that spatial petrogeochemical variations exist in the Carboniferous post-collisional rift volcanics province in the Tianshan region. Occurrence of the thickest volcanics dominated by tholeiitic lavas may imply that the center of the mantle-melting anomaly (mantle plume) was in the eastern Tianshan area at that time. The basic volcanic magmas in the eastern Tianshan area were generated by a relatively high degree of partial melting of the mantle source around the spinel-garnet transition zone, whereas the alkaline basaltic lavas are of the dominant magma type in the western Tianshan area, which were generated by a low degree of partial melting of the mantle source within the stable garnet region, thus the basic lavas of the western Tianshan area might have resulted from relatively thick lithosphere and low geothermal gradient.

Relationships between Basic and Silicic Magmatism in Continental Rift Settings:A Petrogeochemical Study of Carboniferous Post-collisional Rift Silicic Volcanics in Tianshan,NW China

Petrogeochemical data are reported for silicic volcanic rocks from the Tianshan Carboniferous rift, with the aim of discussing the petrogenesis of silicic magmas. Incompatible element vs. incompatible element diagrams display smooth positive trends for the Tianshan Carboniferous rift-related volcanic rocks; the isotope ratios of the silicic lavas [^87Sr/^86S（t）=0.699880.70532; eNd（t）=4.76-8.00; ^206pb/^204pb（t）=17.435-18.017; ^207Pb/^204Pb（t）=15.438-15.509; ^208Pb/^204Pb（t） = 37.075-37.723] encompass those of the basic lavas. These data suggest a genetic link between rhyolites and basalts, but are not definitive in establishing whether silicic rocks are related to basalts through fractional crystallization or partial melting. Geochemical modeling of incompatible vs. compatible elements excludes the possibility that silicic melts are generated by the melting of basaltic rocks, and indicates a derivation by fractional crystallization plus moderate assimilation of wall rocks （AFC） starting from intermediate rocks to silicic rocks. Continuous AFC from basalt to rhyolite, with small rates of crustal assimilation, best explains the geochemical data. The presence or absence of bimodal volcanism （the ＂Daly Gap＂） might be related to cooling rates of magma chambers. In central and eastern Tianshan, the crust was thinner and the cooling rates of the magma chamber within the crust were greater. These conditions resulted in a rapid fall in temperature within the magma reservoir and caused a narrow temperature interval over which intermediate melts formed, effectively reducing the volume of the intermediate melts.

Permo-Carboniferous Radiolarians from the Wupata'erkan Group,Western South Tianshan, Xinjiang, China

The Wupata'erkan Group, also called Wupata'erkan Formation, distributed in the South Tianshan, Xinjiang, China, mainly consists of gray and dark gray fine-grained clastic rocks, interlayered with volcanic rocks, carbonates and cherts. Some ultra-basic rocks (blocks) punctuate the formation. The formation was variously assigned to Silurian-Middle Devonian, Silurian-Lower Devonian, and pre-Devonian, mainly based on Atrypa bodini Mansuy, Hypothyridina parallelepipedia (Brour.) and Prismatophyllum hexagonum Yoh collected from the limestone interlayers, respectively. However, radiolarian fossils obtained from 24 chert specimens of the Wupata'erkan Group, mainly include Albaillella sp. cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon, Albaillella sp. cf. A. indensis Won, Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto, Albaillella sp. and Latentifistulidae gen. et. sp. indet., are earliest Carboniferous and Late Permian. The earliest Carboniferous assemblage is characterized by Albaillella sp. cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon and Albaillella sp. cf. A. indensis Won, and the Late Permian assemblage by Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto. This new stratigraphic evidence indicates that the Wupata'erkan Group is possibly composed of rocks with different ages from Silurian to Permian, and therefore, it is probably an ophiolite melange. The discovery of Late Permian Albaillella sp. cf. A. excelsa provides more reliable evidence supporting the existence of a Permian relic ancient oceanic basin in the western part of Xinjiang South Tianshan.

Geochemistry of Carboniferous Sandstones (Sardar Formation), East-Central Iran: Implication for Provenance and Tectonic Setting

Geochemical analysis of sandstones from the Sardar Formation （from two stratigraphic successions） in east-central Iran were used for identification of geochemical characterization of sandstones, provenance and tectonic setting. Sandstones in the two lithostratigraphic successions have similar chemical compositions suggesting a common provenance. Bulk-rock geochemistry analysis of Carboniferous sandstones from Sardar Formation indicates that they are mainly quartz dominated and are classified as quartzarenites, sublitharenites and subarkoses, derived from acid igneous to intermediate igneous rocks. Discrimination function analysis indicates that the sandstones of Sardar Formation were derived from quartzose sedimentary provenance in a recycled orogenic setting. Also, major and trace elements in sandstones of Sardar Formation （e.g., K2O/Na2O vs. SiO2 ） indicate deposition in a stable passive continental margin （PM）. Chemical index of alteration （CIA） for these rocks （65%） suggests a moderate to relatively high degree of weathering in the source area.

Paleoecology of Late Carboniferous Phylloid Algae in Southern Guizhou,SW China

Phylloid algae arc important rcef-builders in the late Carboniferous. This paper focuses on the paleoecology of phylloid algae in the Late Carboniferous on well-exposed reefs in Ziyun County, Guizhou Province. Phylloid algae growing closely packed arc attached via holdfast or similar structure to substrate. They were growing in environments such as shallow water, photic zone and below the wave base with medium energy currents. They have a variety of morphological forms, such as single cup-shaped, cabbage-shaped and clustering cup-shaped. The thalli arc of certain tenacity and intensity. In the areas dominated by phylloid algae, other marine orgam＇sms arc relatively scarce. Obviously, phylloid algae arc stronger competitors for living space than other co-occurring organisms.

Early Carboniferous Radiolarian Fauna from Heiyingshan South of the Tianshan Mountains and Its Geotectonic Significance

Abundant and well-preserved fossil radiolarians found from the Artencasher Formation, Heiyingshan of Baicheng County, Xinjiang Uygur Autonomous Region, are identified, including 15 species and 2 unnamed species in 9 genera. The fauna is dominated by the Family Entactiniidae of Spumellaria. According to the faunal characteristics, the radiolarians may be divided into five assemblages, namely, the Triaenosphaera sicarius, Entatinosphaera palimbola, Entactinia vulgaris, Belowea cf. variabilis and Archocyrtium sp assemblages. The fauna may be correlated with that from the Early Carboniferous of Frankenwald and Rein in Germany. Thus, ophiolite was formed in the Carboniferous, while the age of collision between the ***Ili plate and the Tarim plate is Early Carboniferous.

On the Carboniferous Sequence Stratigraphy in the Tazhong Area, Xinjiang——A Model of the Sequence Stratigraphy Framework of Intracratonic Depressional Basins

The Carboniferous prototype sedimentary basin in the Tazhong (Central Tarimbasin) area is recognized as a compressive intracratonic depressional one. Three type Ⅰ sequenceboundaries and three type Ⅱ sequence boundaries can be identified in the CarboniferousSystem, which can accordingly be divided into five sedimentary sequences. These sequencespossess stratigraphic characters of the standard sequence and correspond to the depositionalstratigraphic unit of a third-order eustatic cycle. They can be regionally or globally correlatedwith each other. The framework of sequence stratigraphy of the intracratonict basin in thestudy area distinctly differs from that of the passive continental-margin basin in the lack ofdepositional systems of early-middle lowstand, poor development of the deeply incised valleyand condensed section of the maximum sea-flood, good development of type Ⅱ sequenceboundaries and coastal plain depositional systems coexisting with shelf-type fan deltas underwet climatic conditions, Which consequently led to the formation of a paralic lithofacies frame-work.

Prospects of Carboniferous Shale Gas Exploitation in the Eastern Qaidam Basin

Shale gas is a resource of emerging importance in the energy field.Many countries in the world have been making big financial investments in this area.Carboniferous shale in the eastern Qaidam Basin shows good exploration prospects,but limited research and exploration work for shale oil and gas resources has been undertaken.Geochemical analyses were performed on shale derived from the Upper Carboniferous Hurleg Formation in the eastern Qaidam Basin,Qinghai Province,and secondary electron imaging capability of a Field Emission scanning electron microscope （FE-SEM） was used to characterize the microstructure of the shale.The reservoir and exploitation potential of the studied shale was assessed by comparison with research results obtained from the Barnett Formation shale in Fort Worth Basin,North America and the Basin shale of Sichuan province.The results indicate that the eastern Qaidam Basin Carboniferous shale is high-quality source rock.There are four major microstructural types in the study area：matrix intergranular pores,dissolution pores,intergranular pores,and micro-fractures.The size of the micropores varies from 6-633 nm,the majority of which is between 39-200 nm,with a relatively small number of micro-scale pores ranging from 0.13-1 μtm.The pore characteristics of the studied shales are similar to the North American and Sichuanese shales,indicating that they have good reservoir potential.No micropores are present in the organic matter,which is induced by its composition; instead we found an important lamellar structure in the organic matter.These micropores and microfractures are abundant,and are connected to natural visible cracks that form the network pore system,which controls the storage and migration of shale gas.This connectivity is favorable for shale gas exploitation,providing great scientific potential and practical value.

Carboniferous Highly Fractionated I-type Granites from the Kalamaili Fault Zone, Eastern Xinjiang, NW China: Petrogenesis and Tectonic Implications

Carboniferous magmatism is one of the most important tectonothermal events in the Central Asian Orogenic Belt(CAOB). However, the final closure time of the Kalamaili Ocean between East Junggar and Harlik Mountain is still debated. Early Carboniferous(332 Ma) and late Carboniferous(307-298 Ma) granitic magmatism from Kalamaili fault zone have been recognized by LA-ICP-MS zircon U-Pb dating. They are both metaluminous highly fractionated I-type and belong to the high-K calc-alkaline. The granitoids for early Carboniferous have zircon εHf(t) values of-5.1 to +8.5 with Hf model ages(TDM2) of 1.78-0.83 Ga, suggesting a mixed magma source of juvenile material with old continental crust. Furthermore, those for late Carboniferous have much younger heterogeneous zircon εHf(t) values(+5.1 to +13.6) with Hf model ages(TDM2=1.03-0.45 Ga) that are also indicative of juvenile components with a small involvement of old continental crust. Based on whole-rock geochemical and zircon isotopic features, these high-K granitoids were derived from melting of heterogeneous crustal sources or through mixing of old continental crust with juvenile components and minor AFC(assimilation and fractional crystallization). The juvenile components probably originated from underplated basaltic magmas in response to asthenospheric upwelling. These Carboniferous highly fractionated granites in the Kalamaili fault zone were probably emplaced in a post-collisional extensional setting and suggested vertical continental crustal growth in the southern CAOB, which is the same or like most granitoids in CAOB. This study provides new evidence for determining the post-accretionary evolution of the southern CAOB. In combination with data from other granitoids in these two terranes, the Early Carboniferous Heiguniangshan pluton represents the initial record of post-collisional environment, suggesting that the final collision between the East Junggar and Harlik Mountain might have occurred before 332 Ma.