Water-solid interactions play a key role in determining the efficacy of inert dusts. The critical water activity(Awc) for phase transition in amorphous materials is an important characteristic of amorphous inert dusts...Water-solid interactions play a key role in determining the efficacy of inert dusts. The critical water activity(Awc) for phase transition in amorphous materials is an important characteristic of amorphous inert dusts used as grain protectants. As water activity(Aw) rises above Awc, amorphous dusts undergo a transition from glassy or vitreous state to rubbery state. Such a transition induces dramatic changes in material properties, texture and structure, and hence impact their performance as grain protectants. Full Dynamic Dewpoint Isotherms(DDI) of a synthetic amorphous zeolite intended for grain protection were generated using the Vapor Sorption Analyzer(VSA) to determine Awcby investigating the relationship between moisture content and Awat constant temperatures. Sorption experimental data was fitted using three sorption isotherm models: Guggenheim-Anderson-de Boer(GAB), Double Log Polynomial(DLP),and Brunauer-Emmet-Teller(BET). DLP model was the best model to estimate zeolite and wheat sorption isotherms. Full sorption isotherms of zeolite and wheat obtained at 25, 35, and 45 °C clearly showed the hysteresis phenomenon. The hysteresis loops were of type H3 for wheat, and of type H4 for zeolite powder. The intensity of hysteresis remained unchanged for wheat. However, the intensity of hysteresis decreased with increasing temperatures during water adsorption by porous zeolite powder. Monolayer moisture content values for each sorption direction were provided only by GAB and BET models and indicated a decrease in monolayer moisture content with an increase in temperature. The net isosteric heats of sorption and the differential enthalpy of zeolite estimated by the Clausius–Clapeyron equation and determined graphically decreased with increasing moisture content. Conversely, differential entropy of zeolite decreased with increasing zeolite moisture content. The optimal moisture content of inert dust for grain treatment was dependent on wheat moisture content and wheat storage temperature. This is the first time that a synthetic amorphous dust is being investigated for grain protection.Our results recommend the application of inert dusts at the optimal moisture content to mitigate moisture migration within the system "wheat-dust", thus ensuring dust maximal efficacy.展开更多
Hydraulic fracturing is among the approaches used to optimize production from a gas condensate reservoir. A detailed economic analysis is required to evaluate the profitability and feasibility of hydraulic fracturing ...Hydraulic fracturing is among the approaches used to optimize production from a gas condensate reservoir. A detailed economic analysis is required to evaluate the profitability and feasibility of hydraulic fracturing as an optimization option in a gas condensate reservoir operating below dewpoint. The objective of this research is to evaluate the economic benefits derivable from the use of hydraulic fracturing to improve gas and liquid recovery from a gas condensate reservoir operating below dewpoint. This research considers the use of four profit indicators to ascertain the profitability of hydraulic fracturing in a gas condensate reservoir operating below dewpoint by increasing the fracture halflength, fracture width and fracture permeability. The production data of the reservoir was obtained and the economic calculations done on excel spreadsheet and plots generated. The four profit indicators considered in the research are Net Present Value, Payout, Discounted Cash Flow Rate of Return and Profit per Dollar Invested. The economic justification was done by carrying out a comparative economic analysis from the result obtained when the reservoir of study was unfractured with that obtained when the reservoir was fractured at various fracture parameters. The economic analysis was done considering a royalty and tax rate of 18.5% and 30% respectively and a gas price of $2/MSCF and condensate price of $30/bbl. This is done so as to find out if the additional cost of hydraulic fracturing can be offset by the recovery from the reservoir when its pressure declined below dewpoint. The result obtained showed that the additional recovery due to hydraulic fracturing by increasing the fracture halflength, fracture width and fracture permeability was not enough to justify the application of hydraulic fracturing when the reservoir pressure declined below dewpoint.展开更多
Emission of volatile organic compounds (VOCs) during drying of wood particles for particleboard manufacture, or for production of refined biofuels, is a potential environmental problem. The aim of this work is to stud...Emission of volatile organic compounds (VOCs) during drying of wood particles for particleboard manufacture, or for production of refined biofuels, is a potential environmental problem. The aim of this work is to study the emissions of VOCs during drying, and the influence on the emissions by different drying parameters.The experiments have mainly been done in a batch fluidized bed dryer, but measurements have also been done in a, pilot scale, continuous fluidized bed dryer. The parameters studied are air flow rate through the bed, air temperature, air dewpoint, and bed height. Since the present trend in biofuels and particle drying is towards very high dewpoints during drying, some measurements have been made at dewpoints up to 95℃, corresponding to a water content of 3.2 kg water per kilogram dry air. The emissions have been measured in two different ways,online during drying with a flame ionization detector and through wood analyses of the terpene content in the wood particles before and after drying. Substantial work has been made in developing the latter method as well as developing the drying equipment to be able to produce a wide range of conditions of the drying medium. It was shown that the VOCs emitted, during wood particle drying, mainly consist of terpenes. The behavior of the emissions was typical, at first contact with the drying gas a sharp peak in the release rate was detected. After that,the release rate stabilizes and declines slowly to a point where the material temperature increases and results in a second small peak in the release rate. Typically 80%-90% of the initial terpene content in the material was emitted during drying to low moisture content and it is not possible to significantly influence this release by changing the drying conditions. Up to 50% of the emitted terpenes are released during a very short period after contact with the drying medium. This fact could be utilized by employing a 2-step drying process. The fact that the VOC concentration in the inert gas gets much higher when drying at higher dewpoints could be taken into consideration when dealing with closed loop applications where the inert gas after the dryer is burnt.展开更多
用ASAP-2010型物理吸附仪、Autopore IV 9500型压汞仪研究了亚露点硫磺回收催化剂的比表面积、孔容积、孔径分布和孔喉比。结果表明,3种催化剂的小孔分布曲线近似为正态分布且孔径分布相似,为3.6nm左右;3种催化剂的孔型均为墨水瓶状;样...用ASAP-2010型物理吸附仪、Autopore IV 9500型压汞仪研究了亚露点硫磺回收催化剂的比表面积、孔容积、孔径分布和孔喉比。结果表明,3种催化剂的小孔分布曲线近似为正态分布且孔径分布相似,为3.6nm左右;3种催化剂的孔型均为墨水瓶状;样品C的大孔平均孔径最大;3种催化剂的孔体积差异主要体现在大孔孔隙率上。展开更多
基金funded by the Plant Biosecurity Cooperative Research Center (Department of Industry and Science, Australian Government. Grant No. 63058)。
文摘Water-solid interactions play a key role in determining the efficacy of inert dusts. The critical water activity(Awc) for phase transition in amorphous materials is an important characteristic of amorphous inert dusts used as grain protectants. As water activity(Aw) rises above Awc, amorphous dusts undergo a transition from glassy or vitreous state to rubbery state. Such a transition induces dramatic changes in material properties, texture and structure, and hence impact their performance as grain protectants. Full Dynamic Dewpoint Isotherms(DDI) of a synthetic amorphous zeolite intended for grain protection were generated using the Vapor Sorption Analyzer(VSA) to determine Awcby investigating the relationship between moisture content and Awat constant temperatures. Sorption experimental data was fitted using three sorption isotherm models: Guggenheim-Anderson-de Boer(GAB), Double Log Polynomial(DLP),and Brunauer-Emmet-Teller(BET). DLP model was the best model to estimate zeolite and wheat sorption isotherms. Full sorption isotherms of zeolite and wheat obtained at 25, 35, and 45 °C clearly showed the hysteresis phenomenon. The hysteresis loops were of type H3 for wheat, and of type H4 for zeolite powder. The intensity of hysteresis remained unchanged for wheat. However, the intensity of hysteresis decreased with increasing temperatures during water adsorption by porous zeolite powder. Monolayer moisture content values for each sorption direction were provided only by GAB and BET models and indicated a decrease in monolayer moisture content with an increase in temperature. The net isosteric heats of sorption and the differential enthalpy of zeolite estimated by the Clausius–Clapeyron equation and determined graphically decreased with increasing moisture content. Conversely, differential entropy of zeolite decreased with increasing zeolite moisture content. The optimal moisture content of inert dust for grain treatment was dependent on wheat moisture content and wheat storage temperature. This is the first time that a synthetic amorphous dust is being investigated for grain protection.Our results recommend the application of inert dusts at the optimal moisture content to mitigate moisture migration within the system "wheat-dust", thus ensuring dust maximal efficacy.
文摘Hydraulic fracturing is among the approaches used to optimize production from a gas condensate reservoir. A detailed economic analysis is required to evaluate the profitability and feasibility of hydraulic fracturing as an optimization option in a gas condensate reservoir operating below dewpoint. The objective of this research is to evaluate the economic benefits derivable from the use of hydraulic fracturing to improve gas and liquid recovery from a gas condensate reservoir operating below dewpoint. This research considers the use of four profit indicators to ascertain the profitability of hydraulic fracturing in a gas condensate reservoir operating below dewpoint by increasing the fracture halflength, fracture width and fracture permeability. The production data of the reservoir was obtained and the economic calculations done on excel spreadsheet and plots generated. The four profit indicators considered in the research are Net Present Value, Payout, Discounted Cash Flow Rate of Return and Profit per Dollar Invested. The economic justification was done by carrying out a comparative economic analysis from the result obtained when the reservoir of study was unfractured with that obtained when the reservoir was fractured at various fracture parameters. The economic analysis was done considering a royalty and tax rate of 18.5% and 30% respectively and a gas price of $2/MSCF and condensate price of $30/bbl. This is done so as to find out if the additional cost of hydraulic fracturing can be offset by the recovery from the reservoir when its pressure declined below dewpoint. The result obtained showed that the additional recovery due to hydraulic fracturing by increasing the fracture halflength, fracture width and fracture permeability was not enough to justify the application of hydraulic fracturing when the reservoir pressure declined below dewpoint.
文摘Emission of volatile organic compounds (VOCs) during drying of wood particles for particleboard manufacture, or for production of refined biofuels, is a potential environmental problem. The aim of this work is to study the emissions of VOCs during drying, and the influence on the emissions by different drying parameters.The experiments have mainly been done in a batch fluidized bed dryer, but measurements have also been done in a, pilot scale, continuous fluidized bed dryer. The parameters studied are air flow rate through the bed, air temperature, air dewpoint, and bed height. Since the present trend in biofuels and particle drying is towards very high dewpoints during drying, some measurements have been made at dewpoints up to 95℃, corresponding to a water content of 3.2 kg water per kilogram dry air. The emissions have been measured in two different ways,online during drying with a flame ionization detector and through wood analyses of the terpene content in the wood particles before and after drying. Substantial work has been made in developing the latter method as well as developing the drying equipment to be able to produce a wide range of conditions of the drying medium. It was shown that the VOCs emitted, during wood particle drying, mainly consist of terpenes. The behavior of the emissions was typical, at first contact with the drying gas a sharp peak in the release rate was detected. After that,the release rate stabilizes and declines slowly to a point where the material temperature increases and results in a second small peak in the release rate. Typically 80%-90% of the initial terpene content in the material was emitted during drying to low moisture content and it is not possible to significantly influence this release by changing the drying conditions. Up to 50% of the emitted terpenes are released during a very short period after contact with the drying medium. This fact could be utilized by employing a 2-step drying process. The fact that the VOC concentration in the inert gas gets much higher when drying at higher dewpoints could be taken into consideration when dealing with closed loop applications where the inert gas after the dryer is burnt.
文摘用ASAP-2010型物理吸附仪、Autopore IV 9500型压汞仪研究了亚露点硫磺回收催化剂的比表面积、孔容积、孔径分布和孔喉比。结果表明,3种催化剂的小孔分布曲线近似为正态分布且孔径分布相似,为3.6nm左右;3种催化剂的孔型均为墨水瓶状;样品C的大孔平均孔径最大;3种催化剂的孔体积差异主要体现在大孔孔隙率上。
