A Cd(Ⅱ)-nitronyl nitroxide radical complex with dicyanoaurate(Ⅰ) bridges [Cd(NIT4Py)2][Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure a...A Cd(Ⅱ)-nitronyl nitroxide radical complex with dicyanoaurate(Ⅰ) bridges [Cd(NIT4Py)2][Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure analysis. Crystal data for the complex: triclinic, space group P, a=0.720 9(11) nm, b=0.960 3(15) nm, c=1.284(2) nm, α=75.38(2)°, β=85.46(2)°, γ=68.38(2)°, V=0.800(2) nm3, Z=1, and R1 [I>2σ(I)]=0.055 8. The title complex consists of infinite one-dimensional chains of [Cd(NIT4Py)2][Au(CN)2]2, in which [Cd(NIT4Py)2] moieties are conne-cted by [Au(CN)2]- μ2-bridging ligands. Each cadmium(Ⅱ) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.展开更多
文摘A Cd(Ⅱ)-nitronyl nitroxide radical complex with dicyanoaurate(Ⅰ) bridges [Cd(NIT4Py)2][Au(CN)2]2, was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure analysis. Crystal data for the complex: triclinic, space group P, a=0.720 9(11) nm, b=0.960 3(15) nm, c=1.284(2) nm, α=75.38(2)°, β=85.46(2)°, γ=68.38(2)°, V=0.800(2) nm3, Z=1, and R1 [I>2σ(I)]=0.055 8. The title complex consists of infinite one-dimensional chains of [Cd(NIT4Py)2][Au(CN)2]2, in which [Cd(NIT4Py)2] moieties are conne-cted by [Au(CN)2]- μ2-bridging ligands. Each cadmium(Ⅱ) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.
