The combustion (burning) of hydrocarbon fuels comprises oxygen mediated breaking of the carbon to carbon and carbon to hydrogen chemical bonds, leading to the formation of oxygen to carbon and oxygen to hydrogen bonds...The combustion (burning) of hydrocarbon fuels comprises oxygen mediated breaking of the carbon to carbon and carbon to hydrogen chemical bonds, leading to the formation of oxygen to carbon and oxygen to hydrogen bonds;primarily as carbon dioxide and water, respectively. The oxygen gas molecules yield considerable energy during the conversion to carbon and hydrogen bound oxygen atoms. The net energy derived from hydrocarbon combustion is normally regarded as being fully converted into heat, as a form of kinetic energy. In industrial processes, some of the resulting heat is used to raise the temperature of other materials, including water for power generation. Combustion derived heat is also used to provide a localized increase in kinetic energy (pressure) of gaseous molecules that can be directly converted into mechanical work. This is the principle of combustion driven transportation and many other power generating engines. An emerging concept is that fluids can also possess a transferrable form of kinetic energy that is unrelated to heat. This newly proposed fluid associated, non-thermal kinetic energy is derived from the environment force termed KELEA (Kinetic Energy Limiting Electrostatic Attraction). KELEA results in the loosening of the hydrogen bonding between liquid molecules and probably also imparts added motion to the molecules. It is proposed that this added non-thermal kinetic energy is carried over into the combustion products, which can consequently yield increased mechanical work. KELEA also seemingly allows for more complete combustion with reduced levels of unburnt hydrocarbons. KELEA activation of liquid fuels can be accomplished using KELEA attracting and transmitting compounds, including activated fluids, either added into or placed in close proximity to the fuel. KELEA activation of fuels, including gasoline and diesel, provides a simple method to significantly improve the efficiency of their use in power generation and in transportation. The studies are relevant to reducing the current worldwide levels of hydrocarbon usage and environmental pollution.展开更多
This paper investigated the secondary cracking of gasoline and diesel from the catalytic pyrolysis of Daqing atmospheric residue on catalyst CEP-1 in a fluidized bed reactor.The results show that the secondary crackin...This paper investigated the secondary cracking of gasoline and diesel from the catalytic pyrolysis of Daqing atmospheric residue on catalyst CEP-1 in a fluidized bed reactor.The results show that the secondary cracking reactivity of gasoline and diesel is poor,and the yield of total light olefins is only about 10%(by mass).As reaction temperature increases,ethylene yield increases,butylene yield decreases,and propylene yield shows a maximum.The optimal reaction temperature is about 670℃for the production of light olefins.With the enhance- ment of catalyst-to-oil mass ratio and steam-to-oil mass ratio,the yields of light olefins increase to some extent. About 6.30%of the mass of total aromatic rings is converted by secondary cracking,indicating that aromatic hy- drocarbons are not easy to undergo ring-opening reactions under the present experimental conditions.展开更多
This article analyzes the standards for car exhaust emissions and gasoline and diesel quality in Europe and the US. As revealed by the evolution of gasoline and diesel standards in China, the gasoline and diesel compo...This article analyzes the standards for car exhaust emissions and gasoline and diesel quality in Europe and the US. As revealed by the evolution of gasoline and diesel standards in China, the gasoline and diesel compositions of China and the exhaust gas emissions standard are closely related with the specifics of the petroleum refining industry and automotive industry in China. After studying the current situations of gasoline and diesel quality in China while taking into account the commonly accepted practice in the overseas this article raises some suggestions on development of gasoline and diesel standards in compliance with the actual conditions of China.展开更多
Aviation heavy-fuel spark ignition(SI)piston engines have been paid more and more attention in the area of small aviation.Aviation heavy-fuel refers to aviation kerosene or light diesel fuel,which is safer to use and ...Aviation heavy-fuel spark ignition(SI)piston engines have been paid more and more attention in the area of small aviation.Aviation heavy-fuel refers to aviation kerosene or light diesel fuel,which is safer to use and store compared to gasoline fuel.And diesel fuel is more suitable for small aviation application on land.In this study,numerical simulation was performed to evaluate the possibility of switching from gasoline direct injection spark ignition(DISI)to diesel DISI combustion.Diesel was injected into the cylinder by original DI system and ignited by spark.In the simulation,computational models were calibrated by test data from a DI engine.Based on the calibrated models,furthermore,the behavior of diesel DISI combustion was investigated.The results indicate that diesel DISI combustion is slower compared to gasoline,and the knock tendency of diesel in SI combustion is higher.For a diesel/air mixture with an equivalence ratio of 0.6 to 1.4,higher combustion pressure and faster burning rate occur when the equivalence ratios are 1.2 and 1.0,but the latter has a higher possibility of knock.In summary,the SI combustion of diesel fuel with a rich mixture can achieve better combustion performance in the engine.展开更多
In this paper, we study the best-mixture ratio of biodiesel-ethanol-diesel for diesel engines. The simulation results show that the integrated indexes including engine power, cost-effectiveness and emission properties...In this paper, we study the best-mixture ratio of biodiesel-ethanol-diesel for diesel engines. The simulation results show that the integrated indexes including engine power, cost-effectiveness and emission properties are rather better with different optimizing index when the ratio of bio-diesel, ethanol and diesel are 71.58:2.72:25.70 and 50:2.4127:47.5873.展开更多
Energy efficiency and environmental impact have become dominant topics in internal combustion engines development. Among many strategies to improve power and emissions outputs from diesel engines is the partial mix of...Energy efficiency and environmental impact have become dominant topics in internal combustion engines development. Among many strategies to improve power and emissions outputs from diesel engines is the partial mix of hydrogen and air as fresh charge components to form extremely lean and homogenous mixture, which resist the spontaneous combustion, while diesel fuel is injected directly inside combustion chamber using the conventional fuel injection systems. This contribution presents an analytical and experimental investigation for the effects of adding hydrogen on diesel engines power output and the reduction of emissions. Parametric analysis is used based on lamped parameters modeling of intake manifold to estimate in cylinder trapped charge. The fuel energy flow to engine cylinders is compared for a range of loads and concentrations to simulate relevant case studies. Diesel fuel reduction for significant range of part-load operation can be achieved by introducing hydrogen, along with power improvement emission reductions are affected positively as well. This is achievable without compromising the engine maximum efficiency, given that most engines are operated at small and part-load during normal driving conditions, which allow for introducing more hydrogen instead of large quantities of excess air during such operation conditions that also can be further improved by charge boosting.展开更多
Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios （M15,M20,M30,M50,M85 and M100） were tested over the New European Driving Cycle （NEDC）.Vo...Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios （M15,M20,M30,M50,M85 and M100） were tested over the New European Driving Cycle （NEDC）.Volatile organic compounds （VOCs） were sampled by Tenax TA and analyzed by thermal desorption-gas chromatograph/mass spectrometer （TD-GC/MS）.Carbonyls were trapped on dinitrophenylhydrazine （DNPH） cartridges and analyzed by high performance liquid chromatography （HPLC）.The results showed that total emissions of VOCs and BTEX （benzene,toluene,ethylbenzene,p,m,o-xylene） from all vehicles fueled with methanol/gasoline blends were lower than those from vehicles fueled with only gasoline.Compared to the baseline,the use of M85 decreased BTEX emissions by 97.4%,while the use of M15 decreased it by 19.7%.At low-to-middle mixing ratios （M15,M20,M30 and M50）,formaldehyde emissions showed a slight increase while those of high mixing ratios （M85 and M100） were three times compared with the baseline gasoline only.When the vehicles were retrofitted with new three-way catalytic converters （TWC）,emissions of carbon monoxide （CO）,total hydrocarbon （THC）,and nitrogen oxides （NOx） were decreased by 24%–50%,10%–35%,and 24%–58% respectively,compared with the cars using the original equipment manufacture （OEM） TWC.Using the new TWC,emissions of formaldehyde and BTEX were decreased,while those of other carbonyl increased.It is necessary that vehicles fueled with methanol/gasoline blends be retrofitted with a new TWC.In addition,the specific reactivity of emissions of vehicles fueled with M15 and retrofitted with the new TWC was reduced from 4.51 to 4.08 compared to the baseline vehicle.This indicates that the use of methanol/gasoline blend at a low mixing ratio may have lower effect on environment than gasoline.展开更多
We studied engine-out soot samples collected from a heavy-duty direct-injection diesel engine and port-fuel injection gasoline spark-ignition engine. The two types of soot samples were characterized using Raman spectr...We studied engine-out soot samples collected from a heavy-duty direct-injection diesel engine and port-fuel injection gasoline spark-ignition engine. The two types of soot samples were characterized using Raman spectroscopy with different laser powers. A Matlab program using least-square-method with trust-region-reflective algorithm was developed for curve fitting. A DOE(design of experiments) method was used to avoid local convergence. The method was used for two-band fitting and three-band fitting. The fitting results were used to determine the intensity ratio of D(for "Defect" or "Disorder") and G(for"Graphite") Raman bands. It is found that high laser power may cause oxidation of soot sample, which gives higher D/G intensity ratio. Diesel soot has consistently higher amorphous/graphitic carbon ratio, and thus higher oxidation reactivity, compared to gasoline soot, which is reflected by the higher D/G intensity ratio in Raman spectra measured under the same laser power.展开更多
文摘The combustion (burning) of hydrocarbon fuels comprises oxygen mediated breaking of the carbon to carbon and carbon to hydrogen chemical bonds, leading to the formation of oxygen to carbon and oxygen to hydrogen bonds;primarily as carbon dioxide and water, respectively. The oxygen gas molecules yield considerable energy during the conversion to carbon and hydrogen bound oxygen atoms. The net energy derived from hydrocarbon combustion is normally regarded as being fully converted into heat, as a form of kinetic energy. In industrial processes, some of the resulting heat is used to raise the temperature of other materials, including water for power generation. Combustion derived heat is also used to provide a localized increase in kinetic energy (pressure) of gaseous molecules that can be directly converted into mechanical work. This is the principle of combustion driven transportation and many other power generating engines. An emerging concept is that fluids can also possess a transferrable form of kinetic energy that is unrelated to heat. This newly proposed fluid associated, non-thermal kinetic energy is derived from the environment force termed KELEA (Kinetic Energy Limiting Electrostatic Attraction). KELEA results in the loosening of the hydrogen bonding between liquid molecules and probably also imparts added motion to the molecules. It is proposed that this added non-thermal kinetic energy is carried over into the combustion products, which can consequently yield increased mechanical work. KELEA also seemingly allows for more complete combustion with reduced levels of unburnt hydrocarbons. KELEA activation of liquid fuels can be accomplished using KELEA attracting and transmitting compounds, including activated fluids, either added into or placed in close proximity to the fuel. KELEA activation of fuels, including gasoline and diesel, provides a simple method to significantly improve the efficiency of their use in power generation and in transportation. The studies are relevant to reducing the current worldwide levels of hydrocarbon usage and environmental pollution.
基金Supported by the Major Research Plan of Ministry of Education of China(No.307008).
文摘This paper investigated the secondary cracking of gasoline and diesel from the catalytic pyrolysis of Daqing atmospheric residue on catalyst CEP-1 in a fluidized bed reactor.The results show that the secondary cracking reactivity of gasoline and diesel is poor,and the yield of total light olefins is only about 10%(by mass).As reaction temperature increases,ethylene yield increases,butylene yield decreases,and propylene yield shows a maximum.The optimal reaction temperature is about 670℃for the production of light olefins.With the enhance- ment of catalyst-to-oil mass ratio and steam-to-oil mass ratio,the yields of light olefins increase to some extent. About 6.30%of the mass of total aromatic rings is converted by secondary cracking,indicating that aromatic hy- drocarbons are not easy to undergo ring-opening reactions under the present experimental conditions.
文摘This article analyzes the standards for car exhaust emissions and gasoline and diesel quality in Europe and the US. As revealed by the evolution of gasoline and diesel standards in China, the gasoline and diesel compositions of China and the exhaust gas emissions standard are closely related with the specifics of the petroleum refining industry and automotive industry in China. After studying the current situations of gasoline and diesel quality in China while taking into account the commonly accepted practice in the overseas this article raises some suggestions on development of gasoline and diesel standards in compliance with the actual conditions of China.
基金Project(2018JJ2041)supported by the Science and Technology Project in Hunan Province,ChinaProject(szjj2019-008)supported by the Open Research Subject of Key Laboratory of Fluid and Power Machinery,Ministry of Education,China。
文摘Aviation heavy-fuel spark ignition(SI)piston engines have been paid more and more attention in the area of small aviation.Aviation heavy-fuel refers to aviation kerosene or light diesel fuel,which is safer to use and store compared to gasoline fuel.And diesel fuel is more suitable for small aviation application on land.In this study,numerical simulation was performed to evaluate the possibility of switching from gasoline direct injection spark ignition(DISI)to diesel DISI combustion.Diesel was injected into the cylinder by original DI system and ignited by spark.In the simulation,computational models were calibrated by test data from a DI engine.Based on the calibrated models,furthermore,the behavior of diesel DISI combustion was investigated.The results indicate that diesel DISI combustion is slower compared to gasoline,and the knock tendency of diesel in SI combustion is higher.For a diesel/air mixture with an equivalence ratio of 0.6 to 1.4,higher combustion pressure and faster burning rate occur when the equivalence ratios are 1.2 and 1.0,but the latter has a higher possibility of knock.In summary,the SI combustion of diesel fuel with a rich mixture can achieve better combustion performance in the engine.
文摘In this paper, we study the best-mixture ratio of biodiesel-ethanol-diesel for diesel engines. The simulation results show that the integrated indexes including engine power, cost-effectiveness and emission properties are rather better with different optimizing index when the ratio of bio-diesel, ethanol and diesel are 71.58:2.72:25.70 and 50:2.4127:47.5873.
文摘Energy efficiency and environmental impact have become dominant topics in internal combustion engines development. Among many strategies to improve power and emissions outputs from diesel engines is the partial mix of hydrogen and air as fresh charge components to form extremely lean and homogenous mixture, which resist the spontaneous combustion, while diesel fuel is injected directly inside combustion chamber using the conventional fuel injection systems. This contribution presents an analytical and experimental investigation for the effects of adding hydrogen on diesel engines power output and the reduction of emissions. Parametric analysis is used based on lamped parameters modeling of intake manifold to estimate in cylinder trapped charge. The fuel energy flow to engine cylinders is compared for a range of loads and concentrations to simulate relevant case studies. Diesel fuel reduction for significant range of part-load operation can be achieved by introducing hydrogen, along with power improvement emission reductions are affected positively as well. This is achievable without compromising the engine maximum efficiency, given that most engines are operated at small and part-load during normal driving conditions, which allow for introducing more hydrogen instead of large quantities of excess air during such operation conditions that also can be further improved by charge boosting.
基金supported by the National Natural Science Foundation of China(No.50876013)
文摘Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios （M15,M20,M30,M50,M85 and M100） were tested over the New European Driving Cycle （NEDC）.Volatile organic compounds （VOCs） were sampled by Tenax TA and analyzed by thermal desorption-gas chromatograph/mass spectrometer （TD-GC/MS）.Carbonyls were trapped on dinitrophenylhydrazine （DNPH） cartridges and analyzed by high performance liquid chromatography （HPLC）.The results showed that total emissions of VOCs and BTEX （benzene,toluene,ethylbenzene,p,m,o-xylene） from all vehicles fueled with methanol/gasoline blends were lower than those from vehicles fueled with only gasoline.Compared to the baseline,the use of M85 decreased BTEX emissions by 97.4%,while the use of M15 decreased it by 19.7%.At low-to-middle mixing ratios （M15,M20,M30 and M50）,formaldehyde emissions showed a slight increase while those of high mixing ratios （M85 and M100） were three times compared with the baseline gasoline only.When the vehicles were retrofitted with new three-way catalytic converters （TWC）,emissions of carbon monoxide （CO）,total hydrocarbon （THC）,and nitrogen oxides （NOx） were decreased by 24%–50%,10%–35%,and 24%–58% respectively,compared with the cars using the original equipment manufacture （OEM） TWC.Using the new TWC,emissions of formaldehyde and BTEX were decreased,while those of other carbonyl increased.It is necessary that vehicles fueled with methanol/gasoline blends be retrofitted with a new TWC.In addition,the specific reactivity of emissions of vehicles fueled with M15 and retrofitted with the new TWC was reduced from 4.51 to 4.08 compared to the baseline vehicle.This indicates that the use of methanol/gasoline blend at a low mixing ratio may have lower effect on environment than gasoline.
文摘We studied engine-out soot samples collected from a heavy-duty direct-injection diesel engine and port-fuel injection gasoline spark-ignition engine. The two types of soot samples were characterized using Raman spectroscopy with different laser powers. A Matlab program using least-square-method with trust-region-reflective algorithm was developed for curve fitting. A DOE(design of experiments) method was used to avoid local convergence. The method was used for two-band fitting and three-band fitting. The fitting results were used to determine the intensity ratio of D(for "Defect" or "Disorder") and G(for"Graphite") Raman bands. It is found that high laser power may cause oxidation of soot sample, which gives higher D/G intensity ratio. Diesel soot has consistently higher amorphous/graphitic carbon ratio, and thus higher oxidation reactivity, compared to gasoline soot, which is reflected by the higher D/G intensity ratio in Raman spectra measured under the same laser power.
