Porosity Evaluation and the Power Spectral Densities Analyses of Carbon-Nickel Composite Films Annealed at Different Temperatures

The densification and the fractal dimensions of carbon-nickel films annealed at different temperatures 300, 500, 800, and 1000℃ with emphasis on porosity evaluation are investigated. For this purpose, the refractive index of films is determined from transmittance spectra. Three different regimes are identified, T 〈 500℃, 500℃ 〈 T 〈 800℃ and T 〉 800℃. The Rutherford baekscattering spectra show that with increasing the annealing temperature, the concentration of nickel atoms into films decreases. It is shown that the effect of annealing temperatures for increasing films densification at T 〈 500℃ and T 〉 800℃ is greater than the effect of nickel concentrations. It is observed that the effect of decreasing nickel atoms into films at 500℃ 〈 T 〈 800℃ strongly causes improving porosity and decreasing densification. The fractal dimensions of carbon-nickel films annealed from 300 to 500℃ are increased, while from 500 to 1000℃ these characteristics are decreased. It can be seen that at 800℃, films have maximum values of porosity and roughness.

TEM Characterization of Helium Bubbles in T91 and MNHS Steels Implanted with 200 keV He Ions at Different Temperatures

Modified novel high silicon steel （MNHS, a newly developed reduced-activation martensitic alloy） and commercial alloy Tgl are implanted with 200 keV He2＋ ions to a dose of 5 × 1020 ions/m2 at 300, 450 and 560~C. Transmission electron microscopy （TEM） is used to characterize the size and morphology of He bubbles. With the increase of the implantation temperature, TEM observations indicate that bubbles increase in size and the proportion of ＇brick shaped＇ cuboid bubbles increases while the proportion of polyhedral bubbles decreases in both the steel samples. For the samples implanted at the same temperature, the average size of He bubbles in MNHS is smaller than that in T91. This might be due to the abundance of boundaries and precipitates in MNHS, which provide additional sites for the trapping of He atoms, thus reduce the susceptibility of MNHS to He embrittlement.

Viscosities and ultrasonic speeds of binary mixtures of benzene with triethylamine and tributylamine at different temperatures:An experimental and theoretical study

The viscosities, η, and ultrasonic speeds, u, of pure benzene, triethylamine, （TEA） tributylamine, （TBA）, and those of their binary mixtures, with benzene as common component, covering the whole composition range have been measured at 278.15 K, 283.15 K, 288.15 K, 293.15 K, 298.15 K, 303.15 K, 308.15 K, 313.15 K, and 318.15 K. From the experimental data the deviations in viscosity, △η, deviations in Gibbs free energy, AG, deviations in ultrasonic speed, △u, deviations in entropies, △S^＊, and deviations in enthalpies, △H^＊, of activation of viscous flow have been determined. The sign and magnitude of these parameters were found to be sensitive towards interactions prevailing in the studied systems. Further, the excess molar volumes, VE, were calculated using data for the binary mixtures. Moreover, theoretical values of viscosities and ultrasonic speeds of the binary mixtures were calculated using different empirical relations and theories. The results were in experimental and theoretical values. discussed in terms of average deviations （AD）

The Efficiency Droop of InGaN-Based Green LEDs with Different Superlattice Growth Temperatures on Si Substrates via Temperature-Dependent Electroluminescence

InGaN-based green light-emitting diodes （LEDs） with different growth temperatures of superlattice grown on Si （111） substrates are investigated by temperature-dependent electroluminescence between 100 K and 350K. It is observed that with the decrease of the growth temperature of the superlattice from 895℃ to 855℃, the forward voltage decreases, especially at low temperature. We presume that this is due to the existence of the larger average size of V-shaped pits, which is determined by secondary ion mass spectrometer measurements. Meanwhile, the sample with higher growth temperature of superlattice shows a severer efficiency droop at cryogenic temperatures （about 100 K-150 K）. Electron overflow into p-GaN is considered to be the cause of such phenomena, which is relevant to the poorer hole injection into multiple quantum wells and the more reduced effective active volume in the active region.

Effects of thawing-induced softening on fracture behaviors of frozen rock

Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to temperature.In this study,the potential thawing-induced softening effects on the fracture behaviors of frozen rock is evaluated by testing the tension fracture toughness(KIC)of frozen rock at different temperatures(i.e.-20℃,-15℃,-12℃,-10℃,-8℃,-6℃,-4℃,-2℃,and 0℃).Acoustic emission(AE)and digital image correlation(DIC)methods are utilized to analyze the microcrack propagation during fracturing.The melting of pore ice is measured using nuclear magnetic resonance(NMR)method.The results indicate that:(1)The KIC of frozen rock decreases moderately between-20℃ and-4℃,and rapidly between-4℃ and 0℃.(2)At-20℃ to-4℃,the fracturing process,deduced from the DIC results at the notch tip,exhibits three stages:elastic deformation,microcrack propagation and microcrack coalescence.However,at-4℃e0℃,only the latter two stages are observed.(3)At-4℃e0℃,the AE activities during fracturing are less than that at-20℃ to-4℃,while more small events are reported.(4)The NMR results demonstrate a reverse variation trend in pore ice content with increasing temperature,that is,a moderate decrease is followed by a sharp decrease and-4℃ is exactly the critical temperature.Next,we interpret the thawing-induced softening effect by linking the evolution in microscopic structure of frozen rock with its macroscopic fracture behaviors as follow:from-20℃ to-4℃,the thickening of the unfrozen water film diminishes the cementation strength between ice and rock skeleton,leading to the decrease in fracture parameters.From-4℃ to 0℃,the cementation effect of ice almost vanishes,and the filling effect of pore ice is reduced significantly,which facilitates microcrack propagation and thus the easier fracture of frozen rocks.

Tannins from Acacia mangium Bark as Natural Dyes for Textiles:Characteristics and Applications

Tannins are capable of producing natural dyes with antioxidant and antibacterial propertis,while synthetic dyes are commonly used in the textile industry,causing environmental issues like water pollution.This research aims to utilize waste tannins as natural dyes as an alternative to synthetic dyes.This study examined the effect of the extraction method on tannin properties such as phenolic content,antioxidants,and antibacterial activity.In addition,Pyrolysis Gas Chromatography‒Mass Spectrometry(Py-GCMS)analysis was used to identify the effect of extraction temperature on the chemical elucidation of tannin.The effect of tannin concentration was evaluated against four bacteria that are usually found on human skin:Staphylococcus epidermidis,Bacillus subtilis,Propionibacterium acnes,and Staphylococcus aureus.Extraction temperature significantly influences the chemical composition of tannin,which leads to different antioxidant properties.The maximum antibacterial properties of tannin were obtained at 90℃with the inhibition zone in the range of 0.9–1.0 mm against four bacteria,tannin yield of 26.59%,Gallic Acid Equivalents or total phenolic content(GAE)of 40.30 mg/g,and Radical Scavenging Activity or antioxidant activity(RSA)of 89.88%.Moreover,the concentration of tannin was significantly linear with its antibacterial properties.Tannin was successfully applied to the textile by using alum as a mordanting agent to create an antibacterial textile.The textile’s bacterial structure damage was analyzed under Field Emission Scanning Electron Microscopy(FESEM).After 50 washings,tannin-textiles with alum-modified properties remained stable compared to those without alum,with S.aureus and S.epidermidis being the most vulnerable bacteria,as confirmed by FESEM images.Hence,tannin is a feasible alternative to harmful and nondegradable synthetic dyes and antibacterial agents.

Evaluation of a new method for quantification of heat tolerance in different wheat cultivars

Heat stress seriously affects wheat production in many regions of the world. At present, heat tolerance research remains one of the least understood fields in wheat genetics and breeding and there is a lack of effective methods to quantify heat stress and heat tolerance in different wheat cultivars. The objective of this study was to use various wheat cultivars to evaluate stress intensity(δ) and a new method for quantification of heat tolerance and compare this technique with three other currently utilized methods. This new parameter for heat tolerance quantification is referred to as the heat tolerance index(HTI) and is an indicator of both yield potential and yield stability. Heat treatments were applied in a controlled setting when anthesis had been reached for 80% of the wheat. The stress intensity evaluation indicated heat shock was the main factor associated with kernel weight reduction while grain yield reduction was mainly associated with chronic high temperature. The methods evaluation showed that a temperature difference of 5°C from natural temperatures was a suitable heat treatment to compare to the untreated controls. HTI was positively correlated with yield under heat stress(r=0.8657, δ=0.15, in 2009–2010; r=0.8418, δ=0.20, in 2010–2011; P<0.01), and negatively correlated with yield reduction rate(r=–0.8344, in 2009–2010; r=–0.7158, in 2010–2011; P<0.01). The results of this study validated the use of HTI and temperature difference control for quantifying wheat heat tolerance that included the yield potential and the stability of different wheat cultivars under heat stress. Additionally, 10 wheat cultivars showed high HTI and should be further tested for their heat confirming characteristics for use in wheat heat tolerance breeding.

Fractal Nature of Crack Growth under Different Temperature

We have studied numerically a simple crack growth model in a two-dimensional triangular lattice of bonds and nodes which incorporates the surface of a growing crack bond-breaking probability P-i similar to exp{(-V-i+E(i))phi(T)}, where E(i) is elastic energy stored in the i-th bond. Different energy temperature factors phi(T) are employed during crack formation and propagation process with a uniform dilation strain case and a shear case and with periodic boundary condition in the horizontal direction. Our results show that the patterns of the cracks generated are fractal structure and the effective fractal dimensionalities decrease with the increase of the temperature factor phi(T)(the absolute temperature T decreasing). In the paper we also discuss the relation between the effective fractal dimension D-eff (the radius R(g) of gyration) and the fractal dimensions D (the radius R of circular), and also give their modification values Omega about two kinds of methods in the lattice model.

Generation of Higher Terahertz Harmonics in Nonlinear Paraelectrics under Focusing in a Wide Temperature Range

It is theoretically investigated the generation of higher harmonics of two-dimensional and three-dimensional terahertz electromagnetic beams in nonlinear crystals. The attention is paid to crystalline paraelectrics like SrTiO3 under the temperatures 60 - 200 K, these crystals possess the cubic nonlinearity. The bias electric field is applied to provide the dominating quadratic nonlinearity. The initial focusing of the beams not only increases the efficiency of generation of higher harmonics, but alto makes possible to select maxima of different higher harmonics at some distances from the input. At lower temperatures the nonlinearity behaves at smaller input amplitudes, whereas at higher temperatures the harmonic generation can be observed at higher frequencies up to 1.5 THz. In three-dimensional beams the peak amplitudes of higher harmonics can be bigger than in two-dimensional beams, but the ratios of these peak values to the maximum values of the focused first harmonic are smaller than in two-dimensional beams.

Reinforced temperature control of a reactive double dividing-wall distillation column

The mass and thermal coupling makes the control of the reactive double dividing-wall distillation column(R-DDWDC) an especially challenging issue with a highly interactive nature. With reference to the separation of an ideal endothermic quaternary reversible reaction with the most unfavorable ranking of relative volatilities(A + B ■ C + D with α_(A)>α_(C)>α_(D)>α_(B)), the operation rationality of the R-DDWDC is studied in this contribution. The four-point single temperature control system leads to great steady-state discrepancies in the compositions of products C and D and the reason stems essentially from the failure in keeping strictly the stoichiometric ratio between reactants A and B. A temperature plus temperature cascade control scheme is then employed to reinforce the stoichiometric ratio control and helps to secure a substantial abatement in the steady-state discrepancies. A temperature difference plus temperature cascade control scheme is finally synthesized and leads even to better performance than the most effective double temperature difference control scheme. These outcomes reveal not only the operation feasibility of the R-DDWDC but also the general significance of the proposed temperature difference plus temperature cascade control scheme to the inferential control of any other complicated distillation columns.

In Tube Condensation:Changing the Pressure Drop into a Temperature Difference for a Wire-on-Tube Heat Exchanger

A theoretical study based on the Penalty factor(PF)method by Cavallini et al.is conducted to show that the pressure drop occurring in a wire-on-tube heat exchanger can be converted into a temperature difference for two types of refrigerants R-134a and R-600a typically used for charging refrigerators and freezers.The following conditions are considered:stratified or stratified-wavyflow condensation occurring inside the smooth tube of a wire-on-tube condenser with diameter 3.25,4.83,and 6.299 mm,condensation temperatures 35℃,45℃,and 54.4℃ and cover refrigerant massflow rate spanning the interval from 1 to 7 kg/hr.The results show that the PF variation is not linear with vapor quality and attains a maximum when the vapor quality is 0.2 and 0.18 for the R-134a and R-600a refrigerants,respectively.The PF increases with the refrigerant massflow rate if the inner diameter and saturation temperature constant,and it decreases on increasing the inner diameter to 6.299 mm for constant refrigerant massflow rate and saturation temperature.The PF for R-600a is higher than that for R-134a due to the lower saturation pressure in thefirst case.Furthermore,a stratifiedflow produces higher PF in comparison to the annularflow due to the effect of the surface tension.

Structural,electrochemical and cycling properties of Nb^(5+)doped LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)cathode materials at different calcination temperatures for lithium-ion batteries

LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)cathode material is prepared by sol-gel method and the effects of Nb^(5+)doping and different calcination temperatures on cathode materials were deeply investigated.Structural and morphological characterizations revealed that the optimal content of 1 mol%Nb^(5+)can stabilize layered structures,mitigate Ni^(2+)migration to Li layers,improve lithium diffusion capacity,and reduce lattice expansion/shrinkage while cycling.And calcination temperature at 800℃can not only ensure good morphology,but also suppress the mixed discharge of lithium and nickel in the internal structure.Electrochemical performance evaluation revealed that Nb^(5+)doping improves the discharge-specific capacity of the material,which is conducive to ameliorating its rate capability and cycle performance.And the material at 800℃exhibits the highest discharge specific capacity,the best magnification performance,low polarizability,and the best cycle reversibility.

Finite Element Analysis of Large Size Chromium Oxide Green Bodies During Firing

To prevent dense chromium oxide covers from cracking during firing,such as internal cracking,surface cracking and fracture,the firing process of dense chromium oxide products was simulated,and the performance parameters at several specific temperatures before and after densification of chromium oxide green bodies were tested.The temperature difference and the stress difference of chromium oxide green bodies were calculated by Finite Element Software at heating and cooling rates of 10,20,30 and 40℃·h^(-1),respectively.The results show that large temperature difference and thermal stress difference are the main causes of internal cracking,surface cracking and fracture of the brick.Suitable heating rates reduce or avoid internal cracking of the brick.When the heating rate is 30℃·h^(-1) below 1450℃and 10℃·h^(-1) above 1450℃,the temperature difference and the thermal stress difference in the brick are below 4℃and 4 MPa,respectively,and there is no internal crack in the brick after firing.The initial cooling stage is the key stage that causes cracking or fracture of bricks.When the cooling rate is 20℃·h^(-1) above 1450℃,the thermal stress difference in the brick is less than 4 MPa,which can significantly reduce the surface cracks and fracture of the brick.

Improved spatial resolution in soil moisture retrieval at arid mining area using apparent thermal inertia

A surface soil moisture model with improved spatial resolution was developed using remotely sensed apparent thermal inertia（ATI）.The model integrates the surface temperature derived from TM/ETM＋ image and the mean surface temperature from MODIS images to improve the spatial resolution of soil temperature difference based on the heat conduction equation,which is necessary to calculate the ATI.Consequently,the spatial resolution of ATI and SMC can be enhanced from 1 km to 120 m（TM） or 60m（ETM＋）.Moreover,the enhanced ATI has a much stronger correlation coefficient（R^2） with SMC（0.789） than the surface reflectance（0.108） or the ATI derived only from MODIS images（0.264）.Based on the regression statistics of the field SMC measurement and enhanced ATI,a linear regression model with an RMS error of 1.90%was found.

Seasonal Variation of the East Asian Subtropical Westerly Jet and Its Association with the Heating Field over East Asia

The structure and seasonal variation of the East Asian Subtropical Westerly Jet （EAWJ） and associations with heating fields over East Asia are examined by using NCEP/NCAR reanalysis data. Obvious differences exist in the westerly jet intensity and location in different regions and seasons due to the ocean-land distribution and seasonal thermal contrast, as well as the dynamic and thermodynamic impacts of the Tibetan Plateau. In winter, the EAWJ center is situated over the western Pacific Ocean and the intensity is reduced gradually from east to west over the East Asian region. In summer, the EAWJ center is located over the north of the Tibetan Plateau and the jet intensity is reduced evidently compared with that in winter. The EAWJ seasonal evolution is characterized by the obvious longitudinal inconsistency of the northward migration and in-phase southward retreat of the EAWJ axis. A good correspondence between the seasonal variations of EAWJ and the meridional differences of air temperature （MDT） in the mid-upper troposphere demonstrates that the MDT is the basic reason for the seasonal variation of EAWJ. Correlation analyses indicate that the Kuroshio Current region to the south of Japan and the Tibetan Plateau are the key areas for the variations of the EAWJ intensities in winter and in summer, respectively. The strong sensible and latent heating in the Kuroshio Current region is closely related to the intensification of EAWJ in winter. In summer, strong sensible heating in the Tibetan Plateau corresponds to the EAWJ strengthening and southward shift, while the weak sensible heating in the Tibetan Plateau is consistent with the EAWJ weakening and northward migration.

On the relationship between convection intensity of South China Sea summer monsoon and air-sea temperature difference in the tropical oceans

The annual, interannual and inter-decadal variability of convection intensity of South China Sea (SCS) summer monsoon and air-sea temperature difference in the tropical ocean is analyzed, and their relationship is discussed using two data sets of 48-a SODA (simple ocean data assimilation) and NCEP/NCAR. Analyses show that in wintertime Indian Ocean (WIO), springtime central tropical Pacific (SCTP) and summertime South China Sea-West Pacific (SSCSWP), air-sea temperature difference is significantly associated with the convection intensity of South China Sea summer monsoon. Correlation of the inter-decadal time scale (above 10 a) is higher and more stable. There is inter-decadal variability of correlation in scales less than 10 a and it is related with the air-sea temperature difference itself for corresponding waters. The inter-decadal variability of the convection intensity during the South China Sea summer monsoon is closely related to the inter-decadal variability of the general circulation of the atmosphere. Since the late period of the 1970s, in the lower troposphere, the cross-equatorial flow from the Southern Hemisphere has intensified. At the upper troposphere layer, the South Asian high and cross-equatorial flow from the Northern Hemisphere has intensified at the same time. Then the monsoon cell has also strengthened and resulted in the reinforcing of the convection of South China Sea summer monsoon.

Synthesis of Large-scale Multistream Heat Exchanger Networks Based on Stream Pseudo Temperature

Effective temperature level of stream, namely stream pseudo temperature, is determined by its actual temperature and heat transfer temperature difference contribution value. Heat transfer temperature difference con-tribution value of a stream depends on its heat transfer film coefficient, cost per unit heat transfer area, actual tem-perature, and so on. In the determination of the suitable heat transfer temperature difference contribution values of the stream, the total annual cost of multistream heat exchanger network (MSHEN) is regarded as an objective func-tion, and genetic/simulated annealing algorithm (GA/SA) is adopted for optimizing the heat transfer temperature difference contribution values of the stream. The stream pseudo temperatures are subsequently obtained. On the ba-sis of stream pseudo temperature, optimized MSHEN can be attained by the temperature-enthalpy (T-H) diagram method. This approach is characterized with fewer decision variables and higher feasibility of solutions. The calcu-lation efficiency of GA/SA can be remarkably enhanced by this approach and more probability is shown in search-ing the global optimum solution. Hence this approach is presented for solving industrial-sized MSHEN which is difficult to deal by traditional algorithm. Moreover, in the optimization of stream heat transfer temperature differ-ence contribution values, the effects of the stream temperature, the heat transfer film coefficient, and the construc-tion material of heat exchangers are considered, therefore this approach can be used to optimize and design heat exchanger network (HEN) with unequal heat transfer film coefficients and different of construction materials. The performance of the proposed approach has been demonstrated with three examples and the obtained solutions are compared with those available in literatures. The results show that the large-scale MSHEN synthesis problems can be solved to obtain good solutions with the modest computational effort.

An Assessment of the Quality of Surface Sensible Heat Flux Derived from Reanalysis Data through Comparison with Station Observations in Northwest China

The present study compares seasonal and interdecadal variations in surface sensible heat flux over Northwest China between station observations and ERA-40 and NCEP-NCAR reanalysis data for the period 1960-2000. While the seasonal variation in sensible heat flux is found to be consistent between station observations and the two reanalysis datasets, both land-air temperatures difference and surface wind speed show remarkable systematic differences. The sensible heat flux displays obvious interdecadal variability that is season-dependent. In the ERA-40 data, the sensible heat flux in spring, fall, and winter shows interdecadal variations that are similar to observations. In the NCEP-NCAR reanalysis data, sensible heat flux variations are inconsistent with and sometimes even opposite to observations. While surface wind speeds from the NCEP-NCAR reanalysis data show interdecadal changes consistent with station observations, variations in land-air temperature difference differ greatly from the observed dataset. In terms of land-air temperature difference and surface wind speed, almost no consistency with observations can be identified in the ERA-40 data, apart from the land-air temperature difference in fall and winter. These inconsistencies pose a major obstacle to the application in climate studies of surface sensible heat flux derived from reanalysis data.

Difference in the Interdecadal Variability of Spring and Summer Sensible Heat Fluxes over Northwest China

The present study investigates the difference in interdecadal variability of the spring and summer sensible heat fluxes over Northwest China by using station observations from 1960 to 2000. It was found that the spring sensible heat flux over Northwest China was greater during the period from the late 1970s to the 1990s than during the period from the 1960s to the mid-1970s. The summer sensible heat flux was smaller in the late 1980s through the 1990s than it was in the 1970s through the early 1980s. Both the spring and summer land-air temperature differences over Northwest China displayed an obvious interdecadal increase in the late 1970s. Both the spring and summer surface wind speeds experienced an obvious interdecadal weakening in the late 1970s. The change in the surface wind speed played a more important role in the interdecadal variations in sensible heat flux during the summer, whereas the change in the land-air temperature difference was more important for the interdecadal variations in sensible heat flux in the spring. This difference was related to seasonal changes in the mean land-air temperature difference and the surface wind speed. Further analysis indicated that the increase in the spring land surface temperature in Northwest China was related to an increase in surface net radiation.