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A NEW BOUNDARY CONDITION FOR RATE-TYPE NON-NEWTONIAN DIFFUSIVE MODELS AND THE STABLE MAC SCHEME
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作者 Kun Li Youngju Lee Christina Starkey 《Journal of Computational Mathematics》 SCIE CSCD 2018年第4期605-626,共22页
We present a new Dirichlet boundary condition for the rate-type non-Newtonian diffusive constitutive models. The newly proposed boundary condition is compared with two such well-known and popularly used boundary condi... We present a new Dirichlet boundary condition for the rate-type non-Newtonian diffusive constitutive models. The newly proposed boundary condition is compared with two such well-known and popularly used boundary conditions as the pure Neumann condition and the Dirichlet condition by Sureshkumar and Beris. Our condition is demonstrated to be more stable and robust in a number of numerical test cases. A new Dirichlet boundary condition is implemented in the framework of the finite difference Marker and Cell (MAC) method. In this paper, we also present an energy-stable finite difference MAC scheme that preserves the positivity for the conformation tensor and show how the addition of the diffusion helps the energy-stability in a finite difference MAC scheme-setting. 展开更多
关键词 Boundary Conditions diffusive Complex Fluids models Positivity preserving schemes Stability of the MAC schemes
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A Comprehensive Survey of Recent Transformers in Image,Video and Diffusion Models
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作者 Dinh Phu Cuong Le Dong Wang Viet-Tuan Le 《Computers, Materials & Continua》 SCIE EI 2024年第7期37-60,共24页
Transformer models have emerged as dominant networks for various tasks in computer vision compared to Convolutional Neural Networks(CNNs).The transformers demonstrate the ability to model long-range dependencies by ut... Transformer models have emerged as dominant networks for various tasks in computer vision compared to Convolutional Neural Networks(CNNs).The transformers demonstrate the ability to model long-range dependencies by utilizing a self-attention mechanism.This study aims to provide a comprehensive survey of recent transformerbased approaches in image and video applications,as well as diffusion models.We begin by discussing existing surveys of vision transformers and comparing them to this work.Then,we review the main components of a vanilla transformer network,including the self-attention mechanism,feed-forward network,position encoding,etc.In the main part of this survey,we review recent transformer-based models in three categories:Transformer for downstream tasks,Vision Transformer for Generation,and Vision Transformer for Segmentation.We also provide a comprehensive overview of recent transformer models for video tasks and diffusion models.We compare the performance of various hierarchical transformer networks for multiple tasks on popular benchmark datasets.Finally,we explore some future research directions to further improve the field. 展开更多
关键词 TRANSFORMER vision transformer self-attention hierarchical transformer diffusion models
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Task-Oriented Semantic Communication with Foundation Models
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作者 Chen Mingkai Liu Minghao +2 位作者 Zhang Zhe Xu Zhiping Wang Lei 《China Communications》 SCIE CSCD 2024年第7期65-77,共13页
In the future development direction of the sixth generation(6G)mobile communication,several communication models are proposed to face the growing challenges of the task.The rapid development of artificial intelligence... In the future development direction of the sixth generation(6G)mobile communication,several communication models are proposed to face the growing challenges of the task.The rapid development of artificial intelligence(AI)foundation models provides significant support for efficient and intelligent communication interactions.In this paper,we propose an innovative semantic communication paradigm called task-oriented semantic communication system with foundation models.First,we segment the image by using task prompts based on the segment anything model(SAM)and contrastive language-image pretraining(CLIP).Meanwhile,we adopt Bezier curve to enhance the mask to improve the segmentation accuracy.Second,we have differentiated semantic compression and transmission approaches for segmented content.Third,we fuse different semantic information based on the conditional diffusion model to generate high-quality images that satisfy the users'specific task requirements.Finally,the experimental results show that the proposed system compresses the semantic information effectively and improves the robustness of semantic communication. 展开更多
关键词 diffusion model foundation model joint source-channel coding task-oriented semantic communication
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Periodic Solution for Diffusive Predator-Prey System with Functional Response 被引量:4
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作者 Li Bi\|wen 1,2 , Cheng Jian 1 1. Department of Mathematics, Hubei Normal University, Huangshi 435002, Hubei,China 2. School of Mathematics and Statistics, Wuhan University, Wuhan 430072, Hubei,China 《Wuhan University Journal of Natural Sciences》 CAS 2002年第3期267-273,共7页
In this paper, a three species diffusive predator-prey model with functional response is studied, where all parameters are time dependent. By using the continuation theorem of coincidence degree theory, the existence ... In this paper, a three species diffusive predator-prey model with functional response is studied, where all parameters are time dependent. By using the continuation theorem of coincidence degree theory, the existence of a positive periodic solution for this system is established. 展开更多
关键词 diffusive model functional nesponse positive periodic solution continuation theorem of coincidence degree fopological degree
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In vitro evaluation of transdermal permeation effects of Fu’s cupping therapy via six diffusion kinetics models 被引量:1
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作者 Wei-Jie Xie Yu-Mei Wu +4 位作者 Shuai-Shuai Chen Jian Xu Fang-Fang Yang Yong-Ping Zhang Xiao-Bo Sun 《Traditional Medicine Research》 2019年第1期42-53,共12页
In this study,six kinetics models of indomethacin hydrophilic gel patch transdermal in vitro release was established,including zero-level,first-order,Higuchi-level,Ritger-Peppas,Weibull and Hixcon-Crowell dynamic equa... In this study,six kinetics models of indomethacin hydrophilic gel patch transdermal in vitro release was established,including zero-level,first-order,Higuchi-level,Ritger-Peppas,Weibull and Hixcon-Crowell dynamic equations.The chemical permeation enhancers,including 3%and 5%Azone,and iontophoresis were used as the control.Transdermal diffusion tests were performed in vitro and indomethacin was quantified by high performance liquid chromatography system.The transdermal parameter of the Higuchi and Weibull dynamic equations,indicated that Fu’s cupping therapy(FCT)could significantly improve Higuchi and Weibull kinetic parameters in vitro transdermal,increased transdermal rate and permeability coefficient,reduced lagging time.Additionally,statistical analysis speculated the skin barrier function could be restored after 46 h treatment.Hence,as a new physical transdermal drug delivery technology,transdermal permeation effects produced by FCT are obvious,which has the characteristics of traditional Chinese medicine and has important clinical application value. 展开更多
关键词 Indomethacin Diffusion kinetics models Fu’s cupping therapy Transdermal permeation technology Chemical penetration enhancers Traditional Chinese medicine
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Construction of Clonal Growth Models in Trifolium repens
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作者 HUBaozhong LI Fenglan HU Xiaomei HU Guofu YUAN Qiang 《Journal of Northeast Agricultural University(English Edition)》 CAS 2009年第4期14-18,共5页
The suitability of models for describing the clonal growth of Trifolium repens population was discussed. The results showed that deterministic models were inadequate for describing its clonal growth, but the diffusion... The suitability of models for describing the clonal growth of Trifolium repens population was discussed. The results showed that deterministic models were inadequate for describing its clonal growth, but the diffusion models and the randomwalk models suited for the clonal growth characteristics of the population. And it was found that random-walk models were better than diffusion models for describing a population in an environment with rich natural resources, and the latter was better in a poor environment. 展开更多
关键词 Trifolium repens clonal growth model diffusion model random-walk model
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Investigation in Mathematical Models of Chloride Diffusion Coefficient in Concrete Exposed to Marine Environment
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作者 Farhad Nabavi Shami Nejadi Bijan Samali 《Journal of Civil Engineering and Architecture》 2014年第4期456-463,共8页
Degradation of RC (reinforced concrete) in maritime structures has become a worldwide problem due to its excessive costs of maintenance, repair and replacement in addition to its environmental impacts and safety iss... Degradation of RC (reinforced concrete) in maritime structures has become a worldwide problem due to its excessive costs of maintenance, repair and replacement in addition to its environmental impacts and safety issues. Degradation of both concrete and steel which is the main reason of reduction in the service life of RC structures strongly depends on the diffusion process of moisture and aggressive species. In this paper, the major and popular mathematical models of diffusion process in concrete are surveyed and investigated. Predominantly in these models, the coefficient of chloride diffusion into the concrete is assumed to be constant. Whereas, experimental records indicate that diffusion coefficient is a function of time. Subsequently, data analysis and comparisons between the existing analytical models for predicting the diffusion coefficient with the existing experimental database are carried out in this study. Clearly, these comparisons reveal that there are gaps between the existing mathematical models and previously recorded experimental results. Perhaps, these gaps may be interpreted as influence of the other affecting parameters on the diffusion coefficient such as temperature, aggregate size and relative humidity in addition to the water cement ratio. Accordingly, the existing mathematical models are not adequate enough to predict the diffusion coefficient precisely and further studies need to be performed. 展开更多
关键词 Chloride diffusion coefficient corrosion of steel in concrete mathematical model of diffusion.
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A multilayer network diffusion-based model for reviewer recommendation
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作者 黄羿炜 徐舒琪 +1 位作者 蔡世民 吕琳媛 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期700-717,共18页
With the rapid growth of manuscript submissions,finding eligible reviewers for every submission has become a heavy task.Recommender systems are powerful tools developed in computer science and information science to d... With the rapid growth of manuscript submissions,finding eligible reviewers for every submission has become a heavy task.Recommender systems are powerful tools developed in computer science and information science to deal with this problem.However,most existing approaches resort to text mining techniques to match manuscripts with potential reviewers,which require high-quality textual information to perform well.In this paper,we propose a reviewer recommendation algorithm based on a network diffusion process on a scholar-paper multilayer network,with no requirement for textual information.The network incorporates the relationship of scholar-paper pairs,the collaboration among scholars,and the bibliographic coupling among papers.Experimental results show that our proposed algorithm outperforms other state-of-the-art recommendation methods that use graph random walk and matrix factorization and methods that use machine learning and natural language processing,with improvements of over 7.62%in recall,5.66%in hit rate,and 47.53%in ranking score.Our work sheds light on the effectiveness of multilayer network diffusion-based methods in the reviewer recommendation problem,which will help to facilitate the peer-review process and promote information retrieval research in other practical scenes. 展开更多
关键词 reviewer recommendation multilayer network network diffusion model recommender systems complex networks
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A turbulent mass diffusivity model for analyzing the mixing characteristics in an impinging stream-rotating packed bed
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作者 Chao Zhang Youzhi Liu +4 位作者 Weizhou Jiao Guisheng Qi Zhiguo Yuan Qiaoling Zhang Hongyan Shen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期133-143,共11页
In this study,the fluid flow and mixing process in an impinging stream-rotating packed bed(IS-RPB)is simulated by using a new three-dimensional computational fluid dynamics model.Specifically,the gaseliquid flow is si... In this study,the fluid flow and mixing process in an impinging stream-rotating packed bed(IS-RPB)is simulated by using a new three-dimensional computational fluid dynamics model.Specifically,the gaseliquid flow is simulated by the Euler-Euler model,the hydrodynamics of the reactor is predicted by the RNG k-εmethod,and the high-gravity environment is simulated by the sliding mesh model.The turbulent mass transfer process is characterized by the concentration variance c^(2) and its dissipation rateεc formulations,and therefore the turbulent mass diffusivity can be directly obtained.The simulated segregation index Xs is in agreement with our previous experimental results.The simulated results reveal that the fringe effect of IS can be offset by the end effect at the inner radius of RPB,so the investigation of the coupling mechanism between IS and RPB is critical to intensify the mixing process in IS-RPB. 展开更多
关键词 Impinging stream-rotating packed bed Turbulent mass diffusivity model Computational fluid dynamics Mixing performance Segregation index
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Research on Restoration of Murals Based on Diffusion Model and Transformer
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作者 Yaoyao Wang Mansheng Xiao +2 位作者 Yuqing Hu Jin Yan Zeyu Zhu 《Computers, Materials & Continua》 SCIE EI 2024年第9期4433-4449,共17页
Due to the limitations of a priori knowledge and convolution operation,the existing image restoration techniques cannot be directly applied to the cultural relics mural restoration,in order to more accurately restore ... Due to the limitations of a priori knowledge and convolution operation,the existing image restoration techniques cannot be directly applied to the cultural relics mural restoration,in order to more accurately restore the original appearance of the cultural relics mural images,an image restoration based on the denoising diffusion probability model(Denoising Diffusion Probability Model(DDPM))and the Transformer method.The process involves two steps:in the first step,the damaged mural image is firstly utilized as the condition to generate the noise image,using the time,condition and noise image patch as the inputs to the noise prediction network,capturing the global dependencies in the input sequence through the multi-attentionmechanismof the input sequence and feedforward neural network processing,and designing a long skip connection between the shallow and deep layers in the Transformer blocks between the shallow and deep layers using long skip connections to fuse the feature information of global and local outputs to maintain the overall consistency of the restoration results;In the second step,taking the noisy image as a condition to direct the diffusion model to back sample to generate the restored image.Experiment results show that the PSNR and SSIM of the proposedmethod are improved by 2%to 9%and 1%to 3.3%,respectively,which are compared to the comparison methods.This study proposed synthesizes the advantages of the diffusionmodel and deep learningmodel to make themural restoration results more accurate. 展开更多
关键词 TRANSFORMER deep learning noise estimation network diffusion model mural restoration
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BeFOI: A Novel Method Based on Conditional Diffusion Model for Medical Image Denoising
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作者 Huijie Hu Zhen Huang 《Journal of Electronic Research and Application》 2024年第2期158-165,共8页
The progress in medical imaging technology highlights the importance of image quality for effective diagnosis and treatment.Yet,noise during capture and transmission can compromise image accuracy and reliability,compl... The progress in medical imaging technology highlights the importance of image quality for effective diagnosis and treatment.Yet,noise during capture and transmission can compromise image accuracy and reliability,complicating clinical decisions.The rising interest in diffusion models has led to their exploration of denoising images.We present Be-FOI(Better Fluoro Images),a weakly supervised model that uses cine images to denoise fluoroscopic images,both DR types.Trained through precise noise estimation and simulation,BeFOI employs Markov chains to denoise using only the fluoroscopic image as guidance.Our tests show that BeFOI outperforms other methods,reducing noise and enhancing clar-ity and diagnostic utility,making it an effective post-processing tool for medical images. 展开更多
关键词 Diffusion model DENOISING Medical images
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Effect of Seed Coat on Drying Kinetics of Kidney Bean Seed
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作者 杨俊红 郭锦棠 +3 位作者 段增宾 刘冰 褚治德 吴树民 《Transactions of Tianjin University》 EI CAS 2002年第4期273-276,共4页
Kidney bean seed was dried in a laboratory scale fixed bed. The effect of seed coat on drying dynamic characteristics and the changes of seed coat structure were investigated. A mathematical model was established to s... Kidney bean seed was dried in a laboratory scale fixed bed. The effect of seed coat on drying dynamic characteristics and the changes of seed coat structure were investigated. A mathematical model was established to simulate the drying process and determine the moisture diffusivity. Numerical results agree well with the experimental data. The average moisture diffusivity of the seed with separated coat is 1.67 times larger than that of the seed with coat, and the moisture diffusivity of seed cotyledon is 3.2 times larger than that of the seed coat. It is proved that the seed coat is the most main resistance of mass transfer and is also one of the key points of the optimization of heat and mass transfer for seed drying. 展开更多
关键词 seed drying seed coat effect internal moisture diffusion model moisture diffusivity
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A rapid and accurate direct measurement method of underground coal seam gas content based on dynamic diffusion theory 被引量:6
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作者 Yanwei Liu Yang Du +4 位作者 Zhiqiang Li Fajun Zhao Weiqin Zuo Jianping Wei Hani Mitri 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2020年第6期799-810,共12页
Coal seam gas content is frequently measured in quantity during underground coal mining operation and coalbed methane(CBM)exploration as a significant basic parameter.Due to the calculation error of lost gas and resid... Coal seam gas content is frequently measured in quantity during underground coal mining operation and coalbed methane(CBM)exploration as a significant basic parameter.Due to the calculation error of lost gas and residual gas in the direct method,the efficiency and accuracy of the current methods are not inadequate to the large area multi-point measurement of coal seam gas content.This paper firstly deduces a simplified theoretical dynamic model for calculating lost gas based on gas dynamic diffusion theory.Secondly,the effects of various factors on gas dynamic diffusion from coal particle are experimentally studied.And sampling procedure of representative coal particle is improved.Thirdly,a new estimation method of residual gas content based on excess adsorption and competitive adsorption theory is proposed.The results showed that the maximum error of calculating the losing gas content by using the new simplified model is only 4%.Considering the influence of particle size on gas diffusion law,the particle size of the collected coal sample is below 0.25 mm,which improves the measurement speed and reflects the safety representativeness of the sample.The determination time of gas content reduced from 36 to 3 h/piece.Moreover,the absolute error is 0.15–0.50 m^3/t,and the relative error is within 5%.A new engineering method for determining the coal seam gas content is developed according to the above research. 展开更多
关键词 Coal seam gas content Dynamic diffusion model Determination method Lost gas content Desorption characteristics
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A novel diffusion model considering curvature radius at the bonding interface in a titanium/steel explosive clad plate 被引量:5
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作者 Hai-tao Jiang Qiang Kang Xiao-qian Yan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第9期956-965,共10页
This article introduces an element diffusion behavior model for a titanium/steel explosive clad plate characterized by a typical curved interface during the heat-treatment process. A series of heat-treatment experimen... This article introduces an element diffusion behavior model for a titanium/steel explosive clad plate characterized by a typical curved interface during the heat-treatment process. A series of heat-treatment experiments were conducted in the temperature range from 750℃ to 950℃, and the effects of heat-treatment parameters on the microstructural evolution and diffusion behavior were investigated by optical microscopy, scanning electron microscopy, X-ray diffraction analysis, and electron-probe microanalysis. Carbon atoms within the steel matrix were observed to diffuse toward the titanium matrix and to aggregate at the bonding interface at 850℃ or lower; in contrast, when the temperature exceeded 850℃, the mutual diffusion of Ti and Fe occurred, along with the diffusion of C atoms, resulting in the for- marion of Ti-Fe intermetallics (Fe2Ti/FeTi). The diffusion distances of C, Ti, and Fe atoms increased with increasing heating temperature and/or holding time. On the basis of this diffusion behavior, a novel diffusion model was proposed. This model considers the effects of various factors, including the curvature radius of the curved interface, the diffusion coefficient, the heating temperature, and the holding rime. The experimental results show good agreement with the calculated values. The proposed model could clearly provide a general prediction of the elements' diffusion at both straight and curved interfaces. 展开更多
关键词 explosive bonding metal cladding diffusion models INTERFACES heat treatment
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Predicting and controlling interfacial microstructure of magnesium/aluminum bimetallic structures for improved interfacial bonding 被引量:7
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作者 Ziang Zhu Renhai Shi +2 位作者 Andrew D.Klarner Alan A.Luo Yiqing Chen 《Journal of Magnesium and Alloys》 SCIE EI CAS 2020年第3期578-586,共9页
In this study,an overcasting process followed by a low-temperature(200°C)annealing schedule has been developed to bond magnesium to aluminum alloys.ProCAST software was used to optimize the process parameters dur... In this study,an overcasting process followed by a low-temperature(200°C)annealing schedule has been developed to bond magnesium to aluminum alloys.ProCAST software was used to optimize the process parameters during the overcasting process which lead to Mg/Al bimetallic structures to be successfully produced without formation of Mg-Al intermetallic phases.Detailed microstructure evolution during annealing,including the formation and growth of Al-Mg interdiffusion layer and intermetallic phases(Al12Mg17 and Al3Mg2),was experimentally observed for the first time with direct evidence,and predicted using Calculation of Phase Diagrams(CALPHAD)modeling.Maximum interfacial strength was achieved when the interdiffusion layer formed at the Mg/Al interface reached a maximum thickness the without formation of brittle intermetallic compounds.The precise diffusion modeling of the Mg/Al interface provides an efficient way to optimize and control the interfacial microstructure of Mg/Al bimetallic structures for improved interfacial bonding. 展开更多
关键词 Bimetallic structure Interfacial bonding CALPHAD and diffusion modeling Aluminum alloys Magnesium alloys.
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STABILITY OF INNOVATION DIFFUSION MODEL WITH NONLINEAR ACCEPTANCE 被引量:5
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作者 于宇梅 王稳地 《Acta Mathematica Scientia》 SCIE CSCD 2007年第3期645-655,共11页
In this article, an innovation diffusion model with the nonlinear acceptance is proposed to describe the dynamics of three competing products in a market. It is proved that the model admits a unique positive equilibri... In this article, an innovation diffusion model with the nonlinear acceptance is proposed to describe the dynamics of three competing products in a market. It is proved that the model admits a unique positive equilibrium, which is globally stable by excluding the existence of periodic solutions and by using the theory of three dimensional competition systems. 展开更多
关键词 Global stability nonlinear acceptance innovation diffusion model
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A Numerical Algorithm Based on Quadratic Finite Element for Two-Dimensional Nonlinear Time Fractional Thermal Diffusion Model 被引量:3
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作者 Yanlong Zhang Baoli Yin +2 位作者 Yue Cao Yang Liu Hong Li 《Computer Modeling in Engineering & Sciences》 SCIE EI 2020年第3期1081-1098,共18页
In this article,a high-order scheme,which is formulated by combining the quadratic finite element method in space with a second-order time discrete scheme,is developed for looking for the numerical solution of a two-d... In this article,a high-order scheme,which is formulated by combining the quadratic finite element method in space with a second-order time discrete scheme,is developed for looking for the numerical solution of a two-dimensional nonlinear time fractional thermal diffusion model.The time Caputo fractional derivative is approximated by using the L2-1formula,the first-order derivative and nonlinear term are discretized by some second-order approximation formulas,and the quadratic finite element is used to approximate the spatial direction.The error accuracy O(h3+t2)is obtained,which is verified by the numerical results. 展开更多
关键词 Quadratic finite element two-dimensional nonlinear time fractional thermal diffusion model L2-1formula.
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Anisotropic diffusion of volatile pollutants at air-water interface 被引量:2
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作者 Li-ping CHEN Jing-tao CHENG Guang-fa DENG 《Water Science and Engineering》 EI CAS CSCD 2013年第2期153-163,共11页
The volatile pollutants that spill into natural waters cause water pollution. Air pollution arises from the water pollution because of volatilization. Mass exchange caused by turbulent fluctuation is stronger in the d... The volatile pollutants that spill into natural waters cause water pollution. Air pollution arises from the water pollution because of volatilization. Mass exchange caused by turbulent fluctuation is stronger in the direction normal to the air-water interface than in other directions due to the large density difference between water and air. In order to explore the characteristics of anisotropic diffusion of the volatile pollutants at the air-water interface, the relationship between velocity gradient and mass transfer rate was established to calculate the turbulent mass diffusivity. A second-order accurate smooth transition differencing scheme (STDS) was proposed to guarantee the boundedness for the flow and mass transfer at the air-water interface. Simulations and experiments were performed to study the trichloroethylene (C2HC13) release. By comparing the anisotropic coupling diffusion model, isotropic coupling diffusion model, and non-coupling diffusion model, the features of the transport of volatile pollutants at the air-water interface were determined. The results show that the anisotropic coupling diffusion model is more accurate than the isotropic coupling diffusion model and non-coupling diffusion model. Mass transfer significantly increases with the increase of the air-water relative velocity at a low relative velocity. However, at a higher relative velocity, an increase in the relative velocity has no effect on mass transfer. 展开更多
关键词 volatile pollutant interfacial mass transfer anisotropic diffusion STDS anisotropic coupling diffusion model
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Valuing Credit Default Swap under a double exponential jump diffusion model 被引量:2
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作者 YANG Rui-cheng PANG Maooxiu JIN Zhuang 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2014年第1期36-43,共8页
This paper discusses the valuation of the Credit Default Swap based on a jump market, in which the asset price of a firm follows a double exponential jump diffusion process, the value of the debt is driven by a geomet... This paper discusses the valuation of the Credit Default Swap based on a jump market, in which the asset price of a firm follows a double exponential jump diffusion process, the value of the debt is driven by a geometric Brownian motion, and the default barrier follows a continuous stochastic process. Using the Gaver-Stehfest algorithm and the non-arbitrage asset pricing theory, we give the default probability of the first passage time, and more, derive the price of the Credit Default Swap. 展开更多
关键词 Credit Default Swap Brownian motion double exponential jump diffusion model
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Dynamic behaviors of water contained in calcium-silicate-hydrate gel at different temperatures studied by quasi-elastic neutron scattering spectroscopy 被引量:2
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作者 易洲 邓沛娜 +1 位作者 张丽丽 李华 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第10期271-278,共8页
The dynamic behaviors of water contained in calcium-silicate-hydrate(C-S-H) gel with different water content values from 10%to 30%(by weight),are studied by using an empirical diffusion model(EDM) to analyze the... The dynamic behaviors of water contained in calcium-silicate-hydrate(C-S-H) gel with different water content values from 10%to 30%(by weight),are studied by using an empirical diffusion model(EDM) to analyze the experimental data of quasi-elastic neutron scattering(QENS) spectra at measured temperatures ranging from 230 K to 280 K.In the study,the experimental QENS spectra with the whole Q-range are considered.Several important parameters including the bound/immobile water elastic coefficient A,the bound water index BWI,the Lorentzian with a half-width at half-maximum(HWHM) Γ;(Q) and Γ;(Q),the self-diffusion coefficients D;and D;of water molecules,the average residence times τ;and τ;,and the proton mean squared displacement(MSD)(u;) are obtained.The results show that the QENS spectra can be fitted very well not only for small Q(≤1 A;) but also for large Q.The bound/immobile water fraction in a C-S-H gel sample can be shown by the fitted BWI.The distinction between bound/immobile and mobile water,which includes confined water and ultra-confined water,can be seen by the fitted MSD.All the MSD tend to be the smallest value below 0.25 A;(the MSD of bound/immobile water) as the Q increases to 1.9 A;no matter what the temperature and water content are.Furthermore,by the abrupt changes of the fitted values of D;,τ;,and Γ;(Q),a crossover temperature at 250 K,namely the liquid-to-crystal-like transition temperature,can be identified for confined water in large gel pores(LGPs) and/or small gel pores(SGPs) contained in the C-S-H gel sample with 30% water content. 展开更多
关键词 dynamics of water quasi-elastic neutron scattering spectra empirical diffusion model C–S–H gel pastes
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