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Determination of Triclocarban, Triclosan and Methyl-Triclosan in Environmental Water by Silicon Dioxide/Polystyrene Composite Microspheres Solid-Phase Extraction Combined with HPLC-ESI-MS 被引量:1
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作者 Yinan Wang Pengfei Li +3 位作者 Yan Liu Bing Chen Jinyu Li Xikui Wang 《Journal of Geoscience and Environment Protection》 2013年第2期13-17,共5页
This paper developed a sensitive and efficient analytical method for triclocarban (TCC), triclosan (TCS) and Methyl-triclosan (MTCS) determination in environmental water, which involves enrichment by using silicon dio... This paper developed a sensitive and efficient analytical method for triclocarban (TCC), triclosan (TCS) and Methyl-triclosan (MTCS) determination in environmental water, which involves enrichment by using silicon dioxide/polystyrene composite microspheres solid-phase extraction and detection with HPLC-ESI-MS. The influence of several operational parameters, including the eluant and its volume, the flow rate and acidity of water sample were investigated and optimized. Under the optimum conditions, the limits of detection were 1.0 ng/L, 2.5 and 4.5 ng/L for TCC, TCS, and MTCS, respectively. The linearity of the method was observed in the range of 5-2000 ng/L, with correlation coefficients (r2) >.99. The spiked recoveries of TCC, TCS and MTCS in water sampleswereachieved in the range of 89.5% -96.8% with RSD below 5.7%. The proposed method has been successfully applied to analyze real water samples and satisfactory results were achieved. 展开更多
关键词 TRICLOCARBAN TRICLOSAN SOLID-PHASE Extraction Silicon dioxide/polystyrene Composite MICROSPHERES HPLC-ESI-MS/MS
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Lateral earth pressure of granular backfills on retaining walls with expanded polystyrene geofoam inclusions under limited surcharge loading 被引量:1
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作者 Kewei Fan Guangqing Yang +2 位作者 Weilie Zou Zhong Han Yang Shen 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第4期1388-1397,共10页
Existing studies have focused on the behavior of the retaining wall equipped with expanded polystyrene(EPS)geofoam inclusions under semi-infinite surcharge loading rather than limited surcharge loading.In this paper,t... Existing studies have focused on the behavior of the retaining wall equipped with expanded polystyrene(EPS)geofoam inclusions under semi-infinite surcharge loading rather than limited surcharge loading.In this paper,the failure mode and the earth pressure acting on the rigid retaining wall with EPS geofoam inclusions and granular backfills(henceforth referred to as EPS-wall),under limited surcharge loading are investigated through two-and three-dimensional model tests.The testing results show that different from the sliding of almost all the backfill in the EPS-wall under semi-infinite surcharge loading,only an approximately triangular backfill slides in the wall under limited surcharge loading.The distribution of the lateral earth pressure on the EPS-wall under limited surcharge loading is non-linear,and the distribution changes from the increase of the wall depth to the decrease with the increase of the limited surcharge loading.An approach based on the force equilibrium of a differential element is developed to predict the lateral earth pressure behind the EPS-wall subjected to limited surcharge loading,and its performance was fully validated by the three-dimensional model tests. 展开更多
关键词 Retaining wall Expanded polystyrene(EPS)geofoam Limited surcharge loading Lateral earth pressure Model test Prediction
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Effect of Titanium Dioxide Nanoparticles on Growth and Biomass Accumulation in Lettuce (Lactuca sativa)
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作者 Channa B. Rajashekar Brenden Armstrong 《American Journal of Plant Sciences》 CAS 2024年第1期1-13,共13页
The use of titanium dioxide nanoparticles (nTiO<sub>2</sub>) is gaining interest in agriculture because of their impact on many aspects of plant growth. The present study examines the effects of nTiO<su... The use of titanium dioxide nanoparticles (nTiO<sub>2</sub>) is gaining interest in agriculture because of their impact on many aspects of plant growth. The present study examines the effects of nTiO<sub>2</sub> (5 nm and 10 nm) applied to seeds and the seedlings as a foliar application on various aspects of growth characteristics and biomass accumulation in lettuce (Lactuca sativa, cv. Grand Rapids). Application of 10 nm nTiO<sub>2</sub> to seeds through imbibition resulted in a significant reduction in shoot biomass accumulation while 5 nm nTiO<sub>2</sub> did not affect the biomass accumulation in lettuce. The application of 10 nm nTiO<sub>2</sub> reduced the fresh shoot biomass accumulation by about 18% compared to the control plants. Other growth characteristics such as shoot dry biomass, root fresh and dry biomass, plant height, and leaf area were not affected by the application of both 5 nm and 10 nm nTiO<sub>2</sub>. In addition, foliar application of these nanoparticles to the lettuce seedlings did not have a significant effect on most of the growth parameters examined, and the increasing concentration ranging from 5 nm/L to 400 mg/L did not produce a consistent response in lettuce. Thus, nTiO<sub>2</sub> application to lettuce seeds had a notable negative impact on shoot growth while foliar application did not have a significant effect on many plant growth characteristics. However, foliar applications produced some symptoms of toxicity to the foliage in the form of necrotic or chlorotic patches on the leaves, which were more pronounced with increasing concentrations of both 5 nm and 10 nm nTiO<sub>2</sub>. However, these symptoms were apparent at a concentration as low as 50 mg/L of nTiO<sub>2</sub>. Thus, foliar application of nTiO<sub>2</sub> may not have a significant impact on many of the growth characteristics in lettuce, but it can result in foliar toxicity. 展开更多
关键词 Growth Characteristics LETTUCE NANOPARTICLES Titanium dioxide TOXICITY
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Copper slag assisted coke reduction of phosphogypsum for sulphur dioxide preparation
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作者 Dong Ma Qinhui Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期43-53,共11页
The reduction of phosphogypsum(PG)to lime slag and SO_(2)using coke can effectively alleviate the environmental problems caused by PG.However,the PG decomposition temperature remains high and the product yield remains... The reduction of phosphogypsum(PG)to lime slag and SO_(2)using coke can effectively alleviate the environmental problems caused by PG.However,the PG decomposition temperature remains high and the product yield remains poor.By adding additives,the decomposition temperature can be further reduced and PG decomposition rate and product yield can be improved.However,the use of current additives such as Fe_(2)O_(3)and SiO_(2)brings the problem of increasing economic cost.Therefore,it is proposed to use solid waste copper slag(CS)as a new additive to reduce PG to prepare SO2,which can reduce the cost and meet the environmental benefits at the same time.The effects of proportion,temperature and thermostatic time on PG decomposition are investigated by experimental and kinetic analysis combined with FactSage thermodynamic calculations to optimize the roasting conditions.Finally,the reaction mechanism is proposed.It is found that adding CS to the coke and PG system can increase the rate of PG decomposition and SO_(2)yield while lowering the PG decomposition temperature.For example,when the CS/PG mass ratio increases from 0 to 1,PG decomposition rate increases from 83.38%to 99.35%,SO_(2)yield increases from 78.62%to 96.81%,and PG decomposition temperature decreases from 992.4℃to 949.6℃.The optimal reaction parameters are CS/PG mass ratio of 1,Coke/PG mass ratio of 0.06 at 1100℃for 20 min with 99.35%PG decomposition rate and 96.81%SO_(2) yield.The process proceeds according to the following reactions:2CaSO_(4)+ 0.7C + 0.8Fe_(2)SiO_(4)→0.8Ca_(2)SiO_(4)+ 0.2Ca_(2)Fe_(2)O_(5)+ 0.4Fe_(3)O_(4)+2SO_(2)+ 0.7CO_(2)Finally,a process for decomposing PG with coke and CS is proposed. 展开更多
关键词 PHOSPHOGYPSUM Sulfur dioxide Copper slag FLUIDIZED-BED REDUCTION Waste treatment
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Chemico-biological conversion of carbon dioxide
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作者 Liangwei Hu Junzhu Yang +3 位作者 Qi Xia Jin Zhang Hongxin Zhao Yuan Lu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期371-387,I0009,共18页
The unabated carbon dioxide(CO_(2))emission into the atmosphere has exacerbated global climate change,resulting in extreme weather events,biodiversity loss,and an intensified greenhouse effect.To address these challen... The unabated carbon dioxide(CO_(2))emission into the atmosphere has exacerbated global climate change,resulting in extreme weather events,biodiversity loss,and an intensified greenhouse effect.To address these challenges and work toward carbon(C)neutrality and reduced CO_(2)emissions,the capture and utilization of CO_(2)have become imperative in both scientific research and industry.One cutting-edge approach to achieving efficient catalytic performance involves integrating green bioconversion and chemical conversion.This innovative strategy offers several advantages,including environmental friendliness,high efficiency,and multi-selectivity.This study provides a comprehensive review of existing technical routes for carbon sequestration(CS)and introduces two novel CS pathways:the electrochemicalbiological hybrid and artificial photosynthesis systems.It also thoroughly examines the synthesis of valuable Cnproducts from the two CS systems employing different catalysts and biocatalysts.As both systems heavily rely on electron transfer,direct and mediated electron transfer has been discussed and summarized in detail.Additionally,this study explores the conditions suitable for different catalysts and assesses the strengths and weaknesses of biocatalysts.We also explored the biocompatibility of the electrode materials and developed novel materials.These materials were specifically engineered to combine with enzymes or microbial cells to solve the biocompatibility problem,while improving the electron transfer efficiency of both.Furthermore,this review summarizes the relevant systems developed in recent years for manufacturing different products,along with their respective production efficiencies,providing a solid database for development in this direction.The novel chemical-biological combination proposed herein holds great promise for the future conversion of CO_(2)into advanced organic compounds.Additionally,it offers exciting prospects for utilizing CO_(2)in synthesizing a wide range of industrial products.Ultimately,the present study provides a unique perspective for achieving the vital goals of“peak shaving”and C-neutrality,contributing significantly to our collective efforts to combat climate change and its associated challenges. 展开更多
关键词 Carbon dioxide Bioelectric synthesis Artificial photosynthesis Synthetic product
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Exploring the relationship between ambient sulfur dioxide and semen quality parameters:A systematic review and meta-analysis
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作者 Seyed Sobhan Bahreiny Mojtaba Aghaei +3 位作者 Mohammad Reza Dabbagh Hamid Ghorbani Moslem Javidan Reza Mohammadpour Fard 《Asian pacific Journal of Reproduction》 CAS 2024年第1期12-21,共10页
Objective:To investigate the relationship between ambient sulfur dioxide(SO2)exposure and semen quality parameters.Methods:A systematic literature search was conducted to identify relevant studies investigating the as... Objective:To investigate the relationship between ambient sulfur dioxide(SO2)exposure and semen quality parameters.Methods:A systematic literature search was conducted to identify relevant studies investigating the association between SO2 exposure and semen quality parameters.This search encompassed the timeframe from January 2000 to May 2023 and included electronic databases such as Web of Science,Google Scholar,PubMed,Cochrane,and Scopus.Pooled effect estimates with 95%confidence intervals(CI)were calculated using percent changes(PC).The meta-analysis included seven studies with 6711 participants and 15087 semen samples.Results:The results revealed a significant negative association between ambient SO2 exposure and certain semen quality parameters.In particular,SO2 exposure was associated with a significant decrease in progressive motility(PC=0.032;95%CI:-0.063 to-0.001;P=0.044)and sperm concentration(PC=-0.020;95%CI:-0.036 to-0.005;P=0.012).However,no statistically significant associations were observed for total sperm count(PC=-0.038;95%CI:-0.079 to 0.003;P=0.070),seminal fluid volume(PC=-0.009;95%CI:-0.048 to-0.030;P=0.662)and sperm motility(PC=-0.17;95%CI:-0.363 to 0.022;P=0.830).In addition,the results of the subgroup analysis revealed specific variables that were associated with the decrease in relevant sperm parameters.Conclusions:This systematic review and meta-analysis provides compelling evidence supporting a consistent negative association between exposure to ambient SO2 and semen quality parameters. 展开更多
关键词 Semen quality Sulfur dioxide Ambient air pollution META-ANALYSIS
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CAS-ESM2.0 Dataset for the Carbon Dioxide Removal Model Intercomparison Project(CDRMIP)
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作者 Jiangbo JIN Duoying JI +9 位作者 Xiao DONG Kece FEI Run GUO Juanxiong HE Yi YU Zhaoyang CHAI He ZHANG Dongling ZHANG Kangjun CHEN Qingcun ZENG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第5期989-1000,共12页
Understanding the response of the Earth system to varying concentrations of carbon dioxide(CO_(2))is critical for projecting possible future climate change and for providing insight into mitigation and adaptation stra... Understanding the response of the Earth system to varying concentrations of carbon dioxide(CO_(2))is critical for projecting possible future climate change and for providing insight into mitigation and adaptation strategies in the near future.In this study,we generate a dataset by conducting an experiment involving carbon dioxide removal(CDR)—a potential way to suppress global warming—using the Chinese Academy of Sciences Earth System Model version 2.0(CASESM2.0).A preliminary evaluation is provided.The model is integrated from 200–340 years as a 1%yr^(−1) CO_(2) concentration increase experiment,and then to~478 years as a carbon dioxide removal experiment until CO_(2) returns to its original value.Finally,another 80 years is integrated in which CO_(2) is kept constant.Changes in the 2-m temperature,precipitation,sea surface temperature,ocean temperature,Atlantic meridional overturning circulation(AMOC),and sea surface height are all analyzed.In the ramp-up period,the global mean 2-m temperature and precipitation both increase while the AMOC weakens.Values of all the above variables change in the opposite direction in the ramp-down period,with a delayed peak relative to the CO_(2) peak.After CO_(2) returns to its original value,the global mean 2-m temperature is still~1 K higher than in the original state,and precipitation is~0.07 mm d^(–1) higher.At the end of the simulation,there is a~0.5°C increase in ocean temperature and a 1 Sv weakening of the AMOC.Our model simulation produces similar results to those of comparable experiments previously reported in the literature. 展开更多
关键词 CAS-ESM2.0 CDRMIP carbon dioxide removal AMOC temperature PRECIPITATION sea surface height
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Effects of drip and flood irrigation on carbon dioxide exchange and crop growth in the maize ecosystem in the Hetao Irrigation District,China
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作者 LI Chaoqun HAN Wenting PENG Manman 《Journal of Arid Land》 SCIE CSCD 2024年第2期282-297,共16页
Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation metho... Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation methods on carbon dioxide(CO_(2))exchange and crop growth in this region.The experimental site was divided into drip and flood irrigation zones.The irrigation schedules of this study aligned with the local commonly used irrigation schedule.We employed a developed chamber system to measure the diurnal CO_(2)exchange of maize plants during various growth stages under both drip and flood irrigation methods.From May to September in 2020 and 2021,two sets of repeated experiments were conducted.In each experiment,a total of nine measurements of CO_(2)exchange were performed to obtain carbon exchange data at different growth stages of maize crop.During each CO_(2)exchange measurement event,CO_(2)flux data were collected every two hours over a day-long period to capture the diurnal variations in CO_(2)exchange.During each CO_(2)exchange measurement event,the biological parameters(aboveground biomass and crop growth rate)of maize and environmental parameters(including air humidity,air temperature,precipitation,soil water content,and photosynthetically active radiation)were measured.The results indicated a V-shaped trend in net ecosystem CO_(2)exchange in daytime,reducing slowly at night,while the net assimilation rate(net primary productivity)exhibited a contrasting trend.Notably,compared with flood irrigation,drip irrigation demonstrated significantly higher average daily soil CO_(2)emission and greater average daily CO_(2)absorption by maize plants.Consequently,within the maize ecosystem,drip irrigation appeared more conducive to absorbing atmospheric CO_(2).Furthermore,drip irrigation demonstrated a faster crop growth rate and increased aboveground biomass compared with flood irrigation.A strong linear relationship existed between leaf area index and light utilization efficiency,irrespective of the irrigation method.Notably,drip irrigation displayed superior light use efficiency compared with flood irrigation.The final yield results corroborated these findings,indicating that drip irrigation yielded higher harvest index and overall yield than flood irrigation.The results of this study provide a basis for the selection of optimal irrigation methods commonly used in the Hetao Irrigation District.This research also serves as a reference for future irrigation studies that consider measurements of both carbon emissions and yield simultaneously. 展开更多
关键词 carbon dioxide exchange maize growth drip irrigation harvest index net primary productivity Hetao Irrigation District
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Study of the Conversion of Postconsumer Polystyrene on CeO2/HZSM-5 Type Materials
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作者 Mirna Oliveira Sant’Ana Anne Michelle Garrido Pedrosa Marcelo José Barros de Souza 《Journal of Materials Science and Chemical Engineering》 2024年第4期29-41,共13页
The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO<sub>2</sub>, 10% CeO<sub>2</sub>/HZSM-5 and 20% CeO<sub>2</sub>/HZSM-5, wh... The catalytic conversion of polystyrene (PS) was studied in the presence of the materials type HZSM-5, CeO<sub>2</sub>, 10% CeO<sub>2</sub>/HZSM-5 and 20% CeO<sub>2</sub>/HZSM-5, which were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption at 77K. The catalytic tests were performed via thermogravimetric analysis (TG) at heating rates of 5, 10 and 20˚C min<sup>−1</sup> in a temperature range from 30˚C to 900˚C. For the tests, a ratio of 30% by mass of each catalytic material mixed with PS was used and the activation energy of the degradation process was determined by the Vyazovkin method. The obtained results showed that the addition of the catalyst to the PS in general reduced its degradation temperature. The 10% CeO<sub>2</sub>/HZSM-5 catalyst showed greater efficiency, as it resulted in lower activation energy for PS degradation. Thus, the combination of CeO<sub>2</sub> with HZSM-5 resulted in materials with potential for application in the catalytic degradation of polystyrene and the results indicate that the production of a composite material can be a good strategy to generate an increase in catalytic activity and a decrease in energy process activation. 展开更多
关键词 HZSM-5 Zeolite Cerium Oxide polystyrene PYROLYSIS
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Performance Evaluation of Novel Eco-Materials Composed of Millet Husks, Rice Husks, and Polystyrene
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作者 Paul Damien Amadji Edem Chabi +2 位作者 Valéry Kouandété Doko Céphas Houndedji Emmanuel Olodo 《Open Journal of Composite Materials》 2024年第1期33-43,共11页
Managing agricultural waste and expanded polystyrene (EPS) poses significant environmental and economic challenges. This study aims to create composites from millet husks, rice husks, and recycled EPS, using a manufac... Managing agricultural waste and expanded polystyrene (EPS) poses significant environmental and economic challenges. This study aims to create composites from millet husks, rice husks, and recycled EPS, using a manufacturing method that involves dissolving the polystyrene in a solvent followed by cold pressing. Various particle sizes and two binder dosages were investigated to assess their influence on the physico-mechanical properties of the composites. The mechanical properties obtained range from 2.54 to 4.47 MPa for the Modulus of Rupture (MOR) and from 686 to 1400 MPa for the Modulus of Elasticity in Bending (MOE). The results indicate that these composites have potential for applications in the construction sector, particularly for wood structures and interior decoration. Moreover, surface treatments could enhance their durability and mechanical properties. This research contributes to the valorization of agricultural and plastic waste as eco-friendly and economical construction materials. 展开更多
关键词 Bio-Based Composites Millet Husk Rice Husk Expanded polystyrene Waste Valorization Sustainable Construction
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Solubility of iron(Ⅲ) and nickel(Ⅱ) acetylacetonates in supercritical carbon dioxide
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作者 Haixin Sun Jianlei Qi +4 位作者 Jianfei Sun Lin Li Kunpeng Yu Jintao Wu Jianzhong Yin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期29-34,共6页
As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates hav... As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range. 展开更多
关键词 Iron(III)acetylacetonate Nickel(II)acetylacetonate Supercritical carbon dioxide Solubility measurement Correlation model Phase equilibrium
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Grafting modification on the surface of titanium dioxide by polystyrene
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作者 WeiWu ShouciLu +2 位作者 JianfengChen LeiShao CheeKingTan 《Journal of University of Science and Technology Beijing》 CSCD 2003年第6期52-56,共5页
Based on the technology of titanium dioxide grafting modification withpolystyrene (PS), the modification mechanisms are studied and the polystyrene-grafting states on thesurface of titanium dioxide have been set up. U... Based on the technology of titanium dioxide grafting modification withpolystyrene (PS), the modification mechanisms are studied and the polystyrene-grafting states on thesurface of titanium dioxide have been set up. Under the synergistic actions of mechanical force,chemistry and heat, macromolecular free radicals of PS are created, at the same time, the O-O bondsof titanium dioxide are broken and the oxide free radicals produced, and the numbers of oxygen atomare increased and crystal lattice defects rich electrons are formed on the surface of titaniumdioxide. The radical polymerization is the main reaction between PS and titanium dioxide and C-Obonds form in the process of modification. Multi-sites chemical adsorption also exists besidesgrafting between PS and titanium dioxide. 展开更多
关键词 titanium dioxide polystyrene grafting modification CHARACTERIZATION radical polymerization reaction
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High Frequency Discharge Plasma Induced Grafting of Polystyrene onto Titanium Dioxide Powder
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作者 钟少锋 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第2期303-306,共4页
Grafting of polystyrene (PS) onto titanium dioxide powder was investigated. The graft polymerization reaction was induced by high frequency discharge produced N2 plasma treatment of the surfaces of titanium dioxide.... Grafting of polystyrene (PS) onto titanium dioxide powder was investigated. The graft polymerization reaction was induced by high frequency discharge produced N2 plasma treatment of the surfaces of titanium dioxide. IR, XPS and TGA results show that PS was grafted on the titanium dioxide powder. And the crystal structure of the titanium dioxide powder observed by XRD was unchanged after plasma treatment. 展开更多
关键词 high frequency discharge PLASMA titanium dioxide graft polymerization PS surface modification
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Progress and prospect of carbon dioxide capture, utilization and storage in CNPC oilfields 被引量:2
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作者 SONG Xinmin WANG Feng +2 位作者 MA Desheng GAO Ming ZHANG Yunhai 《Petroleum Exploration and Development》 2023年第1期229-244,共16页
The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industri... The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industrial application.The breakthrough understanding of CO_(2) flooding mechanism and field practice in recent years and the corresponding supporting technical achievements of CCUS-EOR project are systematically described.The future development prospects are also pointed out.After nearly 60 years of exploration,the theory of CO_(2) flooding and storage suitable for continental sedimentary reservoirs in China has been innovatively developed.It is suggested that C7–C15 are also important components affecting miscibility of CO_(2) and crude oil.The mechanism of rapid recovery of formation energy by CO_(2) and significant improvement of block productivity and recovery factor has been verified in field tests.The CCUS-EOR reservoir engineering design technology for continental sedimentary reservoir is established.The technology of reservoir engineering parameter design and well spacing optimization has been developed,which focuses on maintaining miscibility to improve oil displacement efficiency and uniform displacement to improve sweep efficiency.The technology of CO_(2) capture,injection and production process,whole-system anticorrosion,storage monitoring and other whole-process supporting technologies have been initially formed.In order to realize the efficient utilization and permanent storage of CO_(2),it is necessary to take the oil reservoir in the oil-water transition zone into consideration,realize the large-scale CO_(2) flooding and storage in the area from single reservoir to the overall structural control system.The oil reservoir in the oil-water transition zone is developed by stable gravity flooding of injecting CO_(2) from structural highs.The research on the storage technology such as the conversion of residual oil and CO_(2) into methane needs to be carried out. 展开更多
关键词 carbon dioxide carbon dioxide capture EOR-utilization and storage oil displacement mechanism storage mechanism injection-production process EOR
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Pulsed electrolysis of carbon dioxide by large-scale solid oxide electrolytic cells for intermittent renewable energy storage 被引量:2
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作者 Anqi Wu Chaolei Li +5 位作者 Beibei Han Wu Liu Yang Zhang Svenja Hanson Wanbing Guan Subhash C.Singhal 《Carbon Energy》 SCIE CSCD 2023年第4期2-12,共11页
CO_(2) electrolysis with solid oxide electrolytic cells(SOECs)using intermittently available renewable energy has potential applications for carbon neutrality and energy storage.In this study,a pulsed current strategy... CO_(2) electrolysis with solid oxide electrolytic cells(SOECs)using intermittently available renewable energy has potential applications for carbon neutrality and energy storage.In this study,a pulsed current strategy is used to replicate intermittent energy availability,and the stability and conversion rate of the cyclic operation by a large-scale flat-tube SOEC are studied.One hundred cycles under pulsed current ranging from -100 to -300 mA/cm^(2) with a total operating time of about 800 h were carried out.The results show that after 100 cycles,the cell voltage attenuates by 0.041%/cycle in the high current stage of−300 mA/cm^(2),indicating that the lifetime of the cell can reach up to about 500 cycles.The total CO_(2) conversion rate reached 52%,which is close to the theoretical value of 54.3% at -300 mA/cm^(2),and the calculated efficiency approached 98.2%,assuming heat recycling.This study illustrates the significant advantages of SOEC in efficient electrochemical energy conversion,carbon emission mitigation,and seasonal energy storage. 展开更多
关键词 carbon dioxide cyclic electrolysis pulse current solid oxide electrolytic cells
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Anti-Melanogenesis Activity of Supercritical Carbon Dioxide Extract from Perilla frutescens Seeds 被引量:1
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作者 Satoshi Suzuki Hitomi Fujisawa +1 位作者 Junpei Abe Ken-ichi Kimura 《Advances in Biological Chemistry》 CAS 2023年第1期42-55,共14页
Perilla frutescens seed (PFS) oil is reported to inhibit skin photoaging;however, its effect on melanogenesis has not yet been investigated. Herein, we tested the anti-melanogenesis activity of an oil-based extract fr... Perilla frutescens seed (PFS) oil is reported to inhibit skin photoaging;however, its effect on melanogenesis has not yet been investigated. Herein, we tested the anti-melanogenesis activity of an oil-based extract from PFS with supercritical carbon dioxide (scCO<sub>2</sub>). In a cell culture system, B16 mouse melanoma cells were treated with the PFS scCO<sub>2</sub> extract and other samples. The PFS scCO<sub>2</sub> extract decreased melanin production by approximately 90% in B16 mouse melanoma cells without cytotoxicity at 100 μg/mL. This effect was greater than that of the well-known melanogenesis inhibitor, kojic acid. Although a hexane-extracted PFS oil and a squeezed PFS oil also decreased melanin production in the B16 cells, the inhibitory effect of the PFS scCO<sub>2</sub> extract was higher than both of these. Chemical analysis of the PFS scCO<sub>2</sub> extract and squeezed PFS oil showed that almost 90% of the components of both oils were α-linolenic acid, linoleic acid, and oleic acid. Furthermore, the ratio of those three fatty acids across both samples was almost the same. When the three fatty acids were mixed in the same ratio as in the PFS scCO<sub>2</sub> extract, the IC<sub>50</sub> of the mixture for melanin production in B16 melanoma cells was identical to that of the PFS scCO<sub>2</sub> extract. However, the IC<sub>50</sub> of the squeezed PFS oil was approximately 6.6 times higher than that of the mixture. Although those fatty acids are the main inhibitory ingredients against melanin production in all of the extracts, some factor(s) in the squeezed PFS reduce their affinity with the cells. These results indicated that the PFS scCO<sub>2</sub> extract could be a superior melanogenesis inhibitor. Although its main ingredients are probably the same as those of the squeezed PFS oil, it is necessary to extract with scCO<sub>2</sub> for stronger anti-melanogenesis activity. 展开更多
关键词 Perilla frutescens MELANOGENESIS Supercritical Carbon dioxide B16 Mouse Melanoma Cells
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Micro-interface enhanced mass transfer sodium carbonate absorption carbon dioxide reaction 被引量:1
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作者 Hu Shen Yingyu Xu +4 位作者 Jigang An Bowen Jiang Jinnan Sun Guoqiang Yang Zhibing Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第12期208-223,共16页
Micro-interface intensified reactor(MIR)can be applied in series/parallel in the absorption of CO_(2)in industrial gases by Na_(2)CO_(3)due to the ability to produce large numbers of stable microbubbles.This work focu... Micro-interface intensified reactor(MIR)can be applied in series/parallel in the absorption of CO_(2)in industrial gases by Na_(2)CO_(3)due to the ability to produce large numbers of stable microbubbles.This work focuses on the variation pattern of mass transfer characteristics parameters of the reaction gas in Na_(2)CO_(3) solution under the influence of different solution properties and operating parameters in the reaction of CO_(2)absorption by Na2CO3.The mass transfer characteristics parameters include bubble Sauter mean diameter,gas holdup,interfacial area,liquid side mass transfer coefficient,and liquid side volume mass transfer coefficient kLa.The solution properties and operating parameters include Na2CO3 concentration(0.05–2.0 mol·L^(-1)),superficial gas velocity(0.00221–0.01989 m·s^(-1)),superficial liquid velocity(0.00332–0.02984 m·s^(-1)),and ionic strength(1.42456–1.59588 mol·kg^(-1)).And volumetric mass transfer coeffi-cients kLa and superficial reaction rates r of the MIR and the bubble column reactor are compared in the reaction of sodium carbonate absorption of carbon dioxide,and the former shows a greater improvement under different solution properties and operating parameters.The enhanced role of MIR in mass transfer in non-homogeneous reactions is verified and the feasibility of industrial practical applications of MIR is demonstrated. 展开更多
关键词 Carbon dioxide ABSORPTION MICROBUBBLE Bubble Sauter mean diameter Interfacial area Mass transfer
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Effects of zinc on χ-Fe_(5)C_(2) for carbon dioxide hydrogenation to olefins:Insights from experimental and density function theory calculations 被引量:1
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作者 Xianglin Liu Minjie Xu +2 位作者 Chenxi Cao Zixu Yang Jing Xu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期206-214,共9页
Production of light olefins from CO_(2), the primary greenhouse gases, is of great importance to mitigate the adverse effects of CO_(2) emission on environment and to supply the value-added products from nonpetroleum ... Production of light olefins from CO_(2), the primary greenhouse gases, is of great importance to mitigate the adverse effects of CO_(2) emission on environment and to supply the value-added products from nonpetroleum resource. However, development of robust catalyst with controllable selectivity and stability remains a challenge. Herein, we report that Zn-promoted Fe catalyst can boost the stable and selective production of light olefins from CO_(2). Specifically, the Zn-promoted Fe exhibits a highly stable activity and olefin selectivity over 200 h time-on-stream compared to the unpromoted Fe catalyst, primarily owing to the preservation of active χ-Fe_(5)C_(2) phase. Structural characterizations of the spent catalysts suggest that Zn substantially regulates the content of iron carbide on the surface and suppresses the reoxidation of bulk iron carbide during the reaction. DFT calculations confirm that adsorption of surface carbon atoms and graphene-like carbonaceous species are not thermochemically favored on Zn-promoted Fe catalyst. Carbon deposition by CAC coupling reactions of two surface carbon atoms and dehydrogenation of CH intermediate are also inhibited. Furthermore, the effects of Zn on antioxidation of iron carbide were also investigated. Zn favored the hydrogenation of surface adsorbed oxygen atoms to H_(2)O and the desorption of H_(2)O, which reduces the possibility of surface carbide being oxidized by the chemisorbed oxygen. 展开更多
关键词 Reaction engineering χ-Fe_(5)C_(2) Zn promoter Carbon dioxide HYDROGENATION Density function theory
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Defect engineering of high-loading single-atom catalysts for electrochemical carbon dioxide reduction 被引量:1
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作者 Yang Li Zhenjiang He +3 位作者 Feixiang Wu Shuangyin Wang Yi Cheng Sanping Jiang 《Materials Reports(Energy)》 2023年第2期124-141,I0003,共19页
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)provides an attractive approach to carbon capture and utilization for the production high-value-added products.However,CO_(2)RR still suffers from poor select... Electrochemical carbon dioxide reduction reaction(CO_(2)RR)provides an attractive approach to carbon capture and utilization for the production high-value-added products.However,CO_(2)RR still suffers from poor selectivity and low current density due to its sluggish kinetics and multitudinous reaction pathways.Single-atom catalysts(SACs)demonstrate outstanding activity,excellent selectivity,and remarkable atom utilization efficiency,which give impetus to the search for electrocatalytic processes aiming at high selectivity.There appears significant activity in the development of efficient SACs for CO_(2)RR,while the density of the atomic sites remains a considerable barrier to be overcome.To construct high-metal-loading SACs,aggregation must be prevented,and thus novel strategies are required.The key to creating high-density atomically dispersed sites is designing enough anchoring sites,normally defects,to stabilize the highly mobile separated metal atoms.In this review,we summarized the advances in developing high-loading SACs through defect engineering,with a focus on the synthesis strategies to achieve high atomic site loading.Finally,the future opportunities and challenges for CO_(2)RR in the area of high-loading single-atom electrocatalysts are also discussed. 展开更多
关键词 Single-atom catalysts High loading ELECTROCATALYSIS Carbon dioxide reduction(CO_(2)RR) Transition metals
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Indian Solar Panel Initiatives in Reducing Carbon Dioxide Emissions
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作者 Manoj K. Khanna Sarika Malik +1 位作者 Hemant Kumar   Suruchi 《Energy and Power Engineering》 CAS 2023年第4期191-203,共13页
Environmental degradation and the emission of greenhouse gases particularly carbon dioxide have expanded problems to human wellness and to the atmosphere. The second-most populated country in the globe, India, is amon... Environmental degradation and the emission of greenhouse gases particularly carbon dioxide have expanded problems to human wellness and to the atmosphere. The second-most populated country in the globe, India, is among the primary users of conventional resources, which leads to global warming. The growth rate is anticipated to raise more before 2050, which will cause the brisk industrial expansion and rising energy demand to both increases. In order to reduce carbon emissions and meet energy requirements, many countries use alternate usage of renewable energy particularly solar energy. In this review we aim to study solar panel schemes initiated by India, mainly focusing on National Solar Mission. This study also reviews the present solar installed capacity, solar panel scheme 2022, and initiatives and outcomes of solar panels in residences and offices. This study reviewed that by using solar panel resources, the (MNRE) Ministry of New and Renewable Energy hopes to help the Indian Government reach its purpose of 100 GW solar installed capacity by end of 2022. Despite having an amazing 40 GW of solar power installed capacity till December 2021, India is still far from reaching its own goal of 100 GW by March 2023 as per NSM. In essence, this means that India will need to change a few of its ongoing plans further. 展开更多
关键词 Renewable Energy Solar Panel Carbon dioxide Emission Schemes of the Indian Government INITIATIVES
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