Greatly enhanced corrosion/wear resistances of epoxy coating for Mg alloy through a synergistic effect between functionalized graphene and insulated blocking layer

The poor corrosion and wear resistances of Mg alloys seriously limit their potential applications in various industries.The conventional epoxy coating easily forms many intrinsic defects during the solidification process,which cannot provide sufficient protection.In the current study,we design a double-layer epoxy composite coating on Mg alloy with enhanced anti-corrosion/wear properties,via the spin-assisted assembly technique.The outer layer is functionalized graphene(FG)in waterborne epoxy resin(WEP)and the inner layer is Ce-based conversion(Ce)film.The FG sheets can be homogeneously dispersed within the epoxy matrix to fill the intrinsic defects and improve the barrier capability.The Ce film connects the outer layer with the substrate,showing the transition effect.The corrosion rate of Ce/WEP/FG composite coating is 2131 times lower than that of bare Mg alloy,and the wear rate is decreased by~90%.The improved corrosion resistance is attributed to the labyrinth effect(hindering the penetration of corrosive medium)and the obstruction of galvanic coupling behavior.The synergistic effect derived from the FG sheet and blocking layer exhibits great potential in realizing the improvement of multi-functional integration,which will open up a new avenue for the development of novel composite protection coatings of Mg alloys.

Three-Wave Mixing of Dipole Solitons in One-Dimensional Quasi-Phase-Matched Nonlinear Crystals

A quasi-phase-matched technique is introduced for soliton transmission in a quadratic[χ^((2))]nonlinear crystal to realize the stable transmission of dipole solitons in a one-dimensional space under three-wave mixing.We report four types of solitons as dipole solitons with distances between their bimodal peaks that can be laid out in different stripes.We study three cases of these solitons:spaced three stripes apart,one stripe apart,and confined to the same stripe.For the case of three stripes apart,all four types have stable results,but for the case of one stripe apart,stable solutions can only be found atω_(1)=ω_(2),and for the condition of dipole solitons confined to one stripe,stable solutions exist only for Type1 and Type3 atω_(1)=ω_(2).The stability of the soliton solution is solved and verified using the imaginary time propagation method and real-time transfer propagation,and soliton solutions are shown to exist in the multistability case.In addition,the relations of the transportation characteristics of the dipole soliton and the modulation parameters are numerically investigated.Finally,possible approaches for the experimental realization of the solitons are outlined.

Terahertz toroidal dipole metamaterial sensors for detection of aflatoxin B1

Terahertz metamaterial biosensors have attracted significant attention in the biological field due to their advantages of label-free,real-time and in situ detection.In this paper,a highly sensitive metamaterial sensor with semi-ring mirror symmetry based on toroidal dipole resonance is designed for a new metamaterial biosensor.It is shown that a refractive index sensitivity of 337.5 GHz per refractive index unit can be achieved under an analyte of saturated thickness near a 1.33 THz transmission dip.For biosensor samples where aflatoxin B1 is dropped on the metamaterial surface in our experiment,dip amplitudes of transmission varying from 0.1904 to 0.203 and 0.2093 are observed as aflatoxin B1 concentrations are altered from 0 to 0.001μg·ml-1 and to 0.01μg·ml-1,respectively.Furthermore,when aflatoxin B1 concentrations are 0.1μg·ml-1,1μg·ml-1,10μg·ml-1 and 100μg·ml-1,dip amplitudes of 0.2179,0.226,0.2384 and 0.2527 and dip redshifts of 10.1 GHz,20.1 GHz,27.7 GHz and 37.6 GHz are respectively observed.These results illustrate high-sensitivity,label-free detection of aflatoxin B1,enriching the applications of sensors in the terahertz domain.

Theoretical investigation of excited dipole bound states of alkali-containing diatomic anions

Information about electronic excited states of molecular anions plays an important role in investigating electron attachment and detachment processes.Here we present a high-level theoretical study of the electronic structures of 12 alkali-metal-containing diatomic anions MX-(MX = LiH,LiF,LiCl,NaF,NaCl,NaBr,RbCl,KCl,KBr,RbI,KI and CsI).The equation-of-motion electron-attachment coupled-cluster singles and doubles(EOM-EA-CCSD) method is used to calculate the electron binding energies(EBEs) of 10 electronic excited states of each of the 12 molecule anions.With addition of different s-/p-/d-type diffusion functions in the basis set,we have identified possible excited dipole bound states(DBSs) of each anion.With the investigation of EBEs on the 12 MXs with dipole moment(DM) up to 12.1 D,we evaluate the dependence of the number of anionic excited DBSs on molecular DM.The results indicate that there are at least two or three DBSs of anions with a molecular DM larger than 7 D and a molecule with DM > 10 D can sustain a π-DBS of the anion.Our study has some implications for the excited DBS electronic states of alkali-metal-containing diatomic molecules.

A nanobody-based blocking enzyme-linked immunosorbent assay for detecting antibodies against pseudorabies virus glycoprotein E

Pseudorabies(PR)is an acute infectious disease of pigs caused by the PR virus(PRV)and results in great economic losses to the pig industry worldwide.PRV glycoprotein E(gE)-based enzyme-linked immunosorbent assay(ELISA)has been used to distinguish gE-deleted vaccine-immunized pigs from wild-type virus-infected pigs to eradicate PR in some countries.Nanobody has the advantages of small size and easy genetic engineering and has been a promising diagnostic reagent.However,there were few reports about developing nanobody-based ELISA for detecting anti-PRV-gE antibodies.In the present study,the recombinant PRV-gE was expressed with a bacterial system and used to immunize the Bactrian camel.Then,two nanobodies against PRV-gE were screened from the immunized camel by phage display technique.Subsequently,two nanobody-HRP fusion proteins were expressed with HEK293T cells.The PRV-gE-Nb36-HRP fusion protein was selected as the probe for developing the blocking ELISA(bELISA)to detect anti-PRV-gE antibodies.Through optimizing the conditions of bELISA,the amount of coated antigen was 200 ng per well,and dilutions of the fusion protein and tested pig sera were separately 1:320 and 1:5.The cut-off value of bELISA was 24.20%,and the sensitivity and specificity were 96.43 and 92.63%,respectively.By detecting 233 clinical pig sera with the developed bELISA and a commercial kit,the results showed that the coincidence rate of two assays was 93.99%.Additionallly,epitope mapping showed that PRV-gE-Nb36 recognized a conserved conformational epitope in different reference PRV strains.Simple,great stability and low-cost nanobody-based bELISA for detecting anti-PRV-gE antibodies were developed.The bELISA could be used for monitoring and eradicating PR.

Impact of a Magnetic Dipole on Heat Transfer in Non-Conducting Magnetic Fluid Flow over a Stretching Cylinder

The thermal behavior of an electrically non-conducting magnetic liquid flowing over a stretching cylinder under the influence of a magnetic dipole is considered.The governing nonlinear differential equations are solved numerically using a finite element approach,which is properly validated through comparison with earlier results available in the literature.The results for the velocity and temperature fields are provided for different values of the Reynolds number,ferromagnetic response number,Prandtl number,and viscous dissipation parameter.The influence of some physical parameters on skin friction and heat transfer on the walls of the cylinder is also investigated.The applicability of this research to heat control in electronic devices is discussed to a certain extent.

Optimal preparation of Bose and Fermi atomic gas mixtures of ^(87)Rb and ^(40)K in a crossed optical dipole trap

We report on the optimal production of the Bose and Fermi mixtures with ^(87) Rb and ^(40)K in a crossed optical dipole trap(ODT).We measure the atomic number and lifetime of the mixtures in combination of the spin state |F=9/2,m_(F)=9/2> of^(40)K and |1,1>of ^(87) Rb in the ODT,which is larger and longer compared with the combination of the spin state |9/2,9/2> of^(40)K and 12,2) of ^(87)Rb in the ODT.We observe the atomic numbers of ^(87)Rb and ^(40)K shown in each stage of the sympathetic cooling process while gradually reducing the depth of the optical trap.By optimizing the relative loading time of atomic mixtures in the MOT,we obtain the large atomic number of ^(40)K(~6 ×10^(6)) or the mixtures of atoms with an equal number(~1.6 × 10^(6)) at the end of evaporative cooling in the ODT.We experimentally investigate the evaporative cooling in an enlarged volume of the ODT via adding a third laser beam to the crossed ODT and found that more atoms(8 × 10^(6)) and higher degeneracy(T/T_(F)=0.25) of Fermi gases are obtained.The ultracold atomic gas mixtures pave the way to explore phenomena such as few-body collisions and the Bose-Fermi Hubbard model,as well as for creating ground-state molecules of ^(87)Rb^(40)K.

Numerical Analysis of the Magnetic Dipole Effect on a Radiative Ferromagnetic Liquid Flowing over a Porous Stretched Sheet

The effects of a magnetic dipole on a nonlinear thermally radiative ferromagnetic liquidflowing over a stretched surface in the presence of Brownian motion and thermophoresis are investigated.By means of a similarity transformation,ordinary differential equations are derived and solved afterwards using a numerical(the BVP4C)method.The impact of various parameters,namely the velocity,temperature,concentration,is presented graphically.It is shown that the nanoparticles properties,in conjunction with the magnetic dipole effect,can increase the thermal conductivity of the engineered nanofluid and,consequently,the heat transfer.Comparison with earlier studies indicates high accuracy and effectiveness of the numerical approach.An increase in the Brow-nian motion parameter and thermophoresis parameter enhances the concentration and the related boundary layer.The skin-friction rises when the viscosity parameter is increased.A larger value of the ferromagnetic para-meter results in a higher skin-friction and,vice versa,in a smaller Nusselt number.

Characteristics and triggering mechanisms of early negative Indian Ocean Dipole

Negative Indian Ocean Dipole(nIOD)can exert great impacts on global climate and can also strongly influence the climate in China.Early nIOD is a major type of nIOD,which can induce more pronounced climate anomalies in summer than La Niña-related nIOD.However,the characteristics and triggering mechanisms of early nIOD are unclear.Our results based on reanalysis datasets indicate that the early nIOD and La Niña-related nIOD are the two major types of nIOD,and the former accounts for over one third of all the nIOD events in the past six decades.These two types of nIODs are similar in their intensities,but are different in their spatial patterns and seasonal cycles.The early nIOD,which develops in spring and peaks in summer,is one season earlier than the La Niña-related nIOD.The spatial pattern of the wind anomaly associated with early nIOD exhibits a winter monsoon-like pattern,with strong westerly anomalies in the equatorial Indian Ocean and eastly anomalies in the northern Indian Ocean.Opposite to the triggering mechanism of early positve IOD,the early nIOD is induced by delayed Indian summer monsoon onset.The results of this study are helpful for improving the prediction skill of IOD and its climate impacts.

Correlation of Rainfall Anomalies in Rwanda from September to December (SOND) with Indian Ocean Dipole (IOD) and El Nino Southern Oscillation (ENSO) Events

Understanding the relationship between rainfall anomalies and large-scale systems is critical for driving adaptation and mitigation strategies in socioeconomic sectors. This study therefore aims primarily to investigate the correlation between rainfall anomalies in Rwanda during the months of September to December (SOND) with the occurrences of Indian Ocean Dipole (IOD) and El Nino Southern Oscillation (ENSO) events. The study is useful for early warning and forecasting of negative effects associated with extreme rainfall anomalies across the country, using Climate Hazards Group InfraRed Precipitation with Station (CHIRPS), the National Centers for Environmental Prediction (NCEP) National Center for Atmospheric Research (NCAR) reanalysis sea surface temperature and ERA5 reanalysis datasets, during the period of 1983-2021. Both empirical orthogonal function (EOF), correlation analysis and composite analysis were used to delineate variability, relationship and the related atmospheric circulation between Rwanda seasonal rainfall September to December (SOND) with Indian Ocean Dipole (IOD) and El-Nino Southern Oscillation (ENSO). The results for Empirical Orthogonal Function (EOF) for the reconstructed rainfall data set showed three modes. EOF-1, EOF-2 and EOF-3 with their total variance of 63.6%, 16.5% and 4.8%, Indian ocean dipole (IOD) events resulted to a strong positive correlation of rainfall anomalies and Dipole model index (DMI) (r = 0.42, p value = 0.001, DF = 37) significant at 95% confidence level. The composite analysis for the reanalysis dataset was carried out to show the circulation patterns during four different events correlated with September to December seasonal rainfall in Rwanda using T-test at 95% confidence level. Wind anomaly revealed that there was a convergence of south westerly winds and easterly wind over the study area during positive Indian Ocean Diploe (PIOD) and PIOD with El Nino concurrence event years. The finding of this study will contribute to the enhancement of SOND seasonal rainfall forecasting and the reduction of vulnerability during IOD (ENSO) event years.

Clinical Nursing Intervention of Moxibustion on Abdominal Distension Symptoms in Heart Failure (Heart and Kidney Yang Deficiency and Blood Stasis Blocking Collaterals Syndrome)

Objective:To investigate the clinical nursing intervention effect of moxibustion on abdominal distension symptoms in heart failure(heart and kidney yang deficiency and blood stasis blocking collaterals syndrome).Methods:62 patients with heart failure(heart and kidney yang deficiency and blood stasis blocking collaterals syndrome)admitted to our hospital from February 2023 to February 2024 were selected and divided into the observation group(n=31)and the control group(n=31)by using the random numerical table method.The control group adopted conventional nursing interventions,and the observation group received the nursing program of the control group with the addition of moxibustion nursing interventions.The nursing effectiveness,quality of life scores,and nursing satisfaction were compared between the two groups.Results:The nursing effectiveness of the observation group was significantly higher than the control group(P<0.05);the quality of life score of the observation group was significantly higher than the control group(P<0.05);the nursing satisfaction of the observation group was significantly higher than that of the control group(P<0.05).Conclusion:The use of moxibustion nursing intervention in patients with heart failure(heart and kidney yang deficiency and blood stasis blocking collaterals syndrome)can effectively relieve the symptoms of abdominal distension,improve patients'quality of life,and increase nursing satisfaction,which has promotion and application values.

The Role of Topography and Diabatic Heating in the Formation of Dipole Blocking in the Atmosphere

In this paper, the nonlinear stationary waves forced by topography and diabatic heating are investigated. It is pointed out that (1) the nonlinear interaction of different stationary waves forced only by topography might form dipole blocking in the atmosphere, this might explain the dipole blocking appeared in the Pacific and Atlantic regions; (2) the dipole blocking could not be caused by the nonlinear interaction of the different stationary waves forced by the diabatic heating alone; (3) the nonlinear interaction of the diffferent stationary waves forced by both topography and diabatic heating could initiate dipole blocking in the atmosphere. In winter, the dipole blocking mainly occurs in the west regions of the Pacific and the Atlantic, and the heat source over the western part of the two oceans is advantageous to the formation of dipole blocking in the west of two oceans. However, in summer, the dipole blocking could be formed in the east part of the two oceans, and the heat source over the eastern part of two continents is favourable for the formation of dipole blocking in the east regions of two oceans.

Recent Progress in Interfacial Dipole Engineering for Perovskite Solar Cells

Design and modification of interfaces have been the main strategies in developing perovskite solar cells(PSCs). Among the interfacial treatments, dipole molecules have emerged as a practical approach to improve the efficiency and stability of PSCs due to their unique and versatile abilities to control the interfacial properties. Despite extensive applications in conventional semiconductors, working principles and design of interfacial dipoles in the performance/stability enhancement of PSCs are lacking an insightful elucidation. In this review, we first discuss the fundamental properties of electric dipoles and the specific roles of interfacial dipoles in PSCs. Then we systematically summarize the recent progress of dipole materials in several key interfaces to achieve efficient and stable PSCs. In addition to such discussions, we also dive into reliable analytical techniques to support the characterization of interfacial dipoles in PSCs. Finally, we highlight future directions and potential avenues for research in the development of dipolar materials through tailored molecular designs. Our review sheds light on the importance of continued efforts in this exciting emerging field, which holds great potential for the development of high-performance and stable PSCs as commercially demanded.

Circulation Patterns Linked to the Positive Sub-Tropical Indian Ocean Dipole

The positive phase of the subtropical Indian Ocean dipole(SIOD)is one of the climatic modes in the subtropical southern Indian Ocean that influences the austral summer inter-annual rainfall variability in parts of southern Africa.This paper examines austral summer rain-bearing circulation types(CTs)in Africa south of the equator that are related to the positive SIOD and the dynamics through which specific rainfall regions in southern Africa can be influenced by this relationship.Four austral summer rain-bearing CTs were obtained.Among the four CTs,the CT that featured(i)enhanced cyclonic activity in the southwest Indian Ocean;(ii)positive widespread rainfall anomaly in the southwest Indian Ocean;and(iii)low-level convergence of moisture fluxes from the tropical South Atlantic Ocean,tropical Indian Ocean,and the southwest Indian Ocean,over the south-central landmass of Africa,was found to be related to the positive SIOD climatic mode.The relationship also implies that positive SIOD can be expected to increase the amplitude and frequency of occurrence of the aforementioned CT.The linkage between the CT related to the positive SIOD and austral summer homogeneous regions of rainfall anomalies in Africa south of the equator showed that it is the principal CT that is related to the inter-annual rainfall variability of the south-central regions of Africa,where the SIOD is already known to significantly influence its rainfall variability.Hence,through the large-scale patterns of atmospheric circulation associated with the CT,the SIOD can influence the spatial distribution and intensity of rainfall over the preferred landmass through enhanced moisture convergence.

A Perspective on the Evolution of Atmospheric Blocking Theories:From Eddy-Mean flow Interaction to Nonlinear Multiscale Interaction

In this paper,we first review the research advancements in blocking dynamics and highlight the merits and drawbacks of the previous theories of atmospheric blocking.Then,the dynamical mechanisms of atmospheric blocking are presented based on a nonlinear multi-scale interaction(NMI)model.Previous studies suggested that the eddy deformation(e.g.,eddy straining,wave breaking,and eddy merging)might lead to the formation and maintenance of atmospheric blocking.However,the results were speculative and problematic because the previous studies,based on the time-mean eddy-mean flow interaction model,cannot identify the causal relationship between the evolution of atmospheric blocking and the eddy deformation.Based on the NMI model,we indicate that the onset,growth,maintenance,and decay of atmospheric blocking is mainly produced by the spatiotemporal evolution of pre-existing upstream synoptic-scale eddies,whereas the eddy deformation is a concomitant phenomenon of the blocking formation.The lifetime of blocking is mainly determined by the meridional background potential vorticity gradient(PVy)because a small PVyfavors weak energy dispersion and strong nonlinearity to sustain the blocking.But the zonal movement of atmospheric blocking is associated with the background westerly wind,PVy,and the blocking amplitude.Using this NMI model,a bridge from the climate change to sub-seasonal atmospheric blocking and weather extremes might be established via examining the effect of climate change on PVy.Thus,it is expected that using the NMI model to explore the dynamics of atmospheric blocking and its change is a new direction in the future.

Controlling Magnetic and Electric Nondipole Effects with Synthesized Two Perpendicularly Propagating Laser Fields

Nondipole effects are ubiquitous and crucial in light-matter interaction.However,they are too weak to be directly observed.In strong-field physics,motion of electrons is mainly confined in transverse plane of light fields,which suppresses the significance of nondipole effects.Here,we present a theoretical study on enhancing and controlling the nondipole effect by using the synthesized two perpendicularly propagating laser fields.We calculate the three-dimensional photoelectron momentum distributions of strong-field tunneling ionization of hydrogen atoms using the classical trajectory Monte Carlo model and show that the nondipole effects are noticeably enhanced in such laser fields due to their remarkable influences on the sub-cycle photoelectron dynamics.In particular,we reveal that the magnitudes of the magnetic and electric components of nondipole effects can be separately controlled by modulating the ellipticity and amplitude of driving laser fields.This novel scenario holds promising applications for future studies with ultrafast structured light fields.

The Subsurface and Surface Indian Ocean Dipoles and Their Association with ENSO in CMIP6 models

This study assesses the reproducibility of 31 historical simulations from 1850 to 2014 in the Coupled Model Intercomparison Project phase 6(CMIP6) for the subsurface(Sub-IOD) and surface Indian Ocean Dipole(IOD) and their association with El Ni?o-Southern Oscillation(ENSO). Most CMIP6 models can reproduce the leading east-west dipole oscillation mode of heat content anomalies in the tropical Indian Ocean(TIO) but largely overestimate the amplitude and the dominant period of the Sub-IOD. Associated with the much steeper west-to-east thermocline tilt of the TIO, the vertical coupling between the Sub-IOD and IOD is overly strong in most CMIP6 models compared to that in the Ocean Reanalysis System 4(ORAS4). Related to this, most models also show a much tighter association of Sub-IOD and IOD events with the canonical ENSO than observations. This explains the more(less) regular Sub-IOD and IOD events in autumn in those models with stronger(weaker) surface-subsurface coupling in TIO. Though all model simulations feature a consistently low bias regarding the percentage of the winter–spring Sub-IOD events co-occurring with a Central Pacific(CP) ENSO, the linkage between a westward-centered CP-ENSO and the Sub-IOD that occurs in winter–spring, independent of the IOD, is well reproduced.

Current bifurcation, reversals and multiple mobility transitions of dipole in alternating electric fields

Anomalous transports of dipole in alternating electric fields are investigated by means of numerical calculation of its average angular velocity(or current). Our results show that the alternating electric fields can make the dipole exhibit many interesting transport behaviors. There exist current bifurcation and multiple current reversal phenomena about frequency of the alternating electric fields in the system in the absence of constant bias force, while many platforms appear in the curve of its average angular velocity vs. the force, i.e., multiple mobility transitions phenomenon in the presence of the constant force, dependent on frequencies of the alternating electric fields. Further investigation indicates that the multiple mobility transitions are attributed to the traveling forces on the dipole. Intrinsic physical mechanism and conditions for the characteristic dynamical behaviors to occur are also discussed in detail. These findings will possess crucial significance for optimizing heating control in the alternating electric fields.

Induced dipole dominant giant electrorheological fluid

Traditional dielectric electrorheological fluid(ER)is based on the interaction of dielectric particle polarization,and the yield stress is low,which cannot meet the application requirements.The giant ER(GER)effect is caused by orientations and interactions of polar molecules adsorbed on the particle surfaces.Despite the high yield stress,these polar molecules are prone to wear and fall off,resulting in a continuous reduction in shear stress of GER liquid,which is also not suitable for application.Here we introduce a new type of ER fluid called induced dipole dominant ER fluid(ID-ER),of which the particles contain oxygen vacancies or conductor microclusters both prepared by high energy ball milling(HEBM)technique.In the electric field E,oxygen vacancies or conductor microclusters form induced dipoles.Because the local electric field E_(loc) in the gaps between particles can be two to three orders of magnitude larger than E,the induced dipole moments must be large.The strong interactions of these induced dipoles make the yield stress of the ID-ER fluid reaching more than 100 kPa.Since there are oxygen vacancies or conductor microclusters everywhere in the particles,the particles will not lose the function due to surface wear during use.The experimental results show that the ID-ER fluid possesses the advantages of high shear stress,low current density,short response time,good temperature stability,long service life,and anti-settlement,etc.The comprehensive performance is much better than the existing ER materials,and also the preparation method is simple and easy to repeat,thus it should be a new generation of ER fluid suitable for practical applications.

Impact of Southern Indian ocean dipole via the ITCZ on winter and spring precipitation in China

本文分析了1979-2021年南印度洋冬季海表面温度特征,印度洋热带辐合带(ITCZ)位置变化及其对中国冬春季降水的影响.EOF分析第一模态表明南印度洋冬季海表面温度异常显示西南-东北反相分布,即南印度洋偶极子模态(SIOD).分离厄尔尼诺-南方涛动(ENSO)信号后,纯SIOD事件对同年冬季和次年春季的印度洋ITCZ位置(35°-75°E平均)均有影响,冬季,纯正(负)SIOD事件使印度洋ITCZ往南(北)移动.春季,SIOD则使印度洋ITCZ移动方向与冬季相反,且移动幅度更大.冬,春季长江中下游地区(MLYR)的降水量与印度洋ITCZ位置分别呈正,负相关.同时,在纯正(负)SIOD事件下,冬,春季MLYR的降水分别减少,增加,可见印度洋ITCZ位置变化可能是SIOD影响MLYR冬,春季降水的媒介之一.