The influence of dissolved oxygen content on the oxidative stability of a linked polymer solution (LPS) was studied by micro-filtration, dynamic light scattering and viscosity measurements. The results showed that at ...The influence of dissolved oxygen content on the oxidative stability of a linked polymer solution (LPS) was studied by micro-filtration, dynamic light scattering and viscosity measurements. The results showed that at the same temperature, the degree of the oxidative degradation of the LPS increased and the rapidity of the oxidative degradation was accelerated with the increase of the dissolved oxygen content. Consequently, the size of linked polymer coils (LPCs) of the LPS became small, and the plugging capability of the LPS decreased. At a fixed content of dissolved oxygen, with increasing degradation temperature, almost the same results were observed, namely, an increased degree of oxidative degradation, accelerated rapidity of the oxidative degradation and decreased plugging capacity, with decreased oxidative stability of LPS. At 90 °C, in the presence of oxygen, LPS lost its plugging capability after having been degraded for a period of time. But at 40 °C, LPS with low dissolved oxygen content could be stable for a long time. The decreased plugging ability of LPS after oxidative degradation is mainly caused by the decreased size and number of the LPCs due to the breaking of hydrolyzed polyacrylamide (HPAM) molecule segments and the structural changing of HPAM molecules.展开更多
The dissolved oxygen concentration in a flow changes with distance downstream of the spillway crest and depends on the geometric configuration of the spillway and the hydraulic and operating conditions.A mathematical ...The dissolved oxygen concentration in a flow changes with distance downstream of the spillway crest and depends on the geometric configuration of the spillway and the hydraulic and operating conditions.A mathematical model was developed to simulate the turbulent structure of the flow over the spillway of the Three Gorges Dam at the 145 m reservoir water level to study the aeration characteristics and the gas transport.The model was calibrated and verified with measured data.The analysis of distribution of the aeration and the dissolved oxygen showed that the downstream water level,upstream dissolved oxygen content,and the flow discharge all affect the dissolved oxygen saturation downstream of the sluicing dam.The simulation provides guidance for controlling the dissolved oxygen supersaturation and environmentally friendly operation of the Three Gorges Dam.展开更多
文摘The influence of dissolved oxygen content on the oxidative stability of a linked polymer solution (LPS) was studied by micro-filtration, dynamic light scattering and viscosity measurements. The results showed that at the same temperature, the degree of the oxidative degradation of the LPS increased and the rapidity of the oxidative degradation was accelerated with the increase of the dissolved oxygen content. Consequently, the size of linked polymer coils (LPCs) of the LPS became small, and the plugging capability of the LPS decreased. At a fixed content of dissolved oxygen, with increasing degradation temperature, almost the same results were observed, namely, an increased degree of oxidative degradation, accelerated rapidity of the oxidative degradation and decreased plugging capacity, with decreased oxidative stability of LPS. At 90 °C, in the presence of oxygen, LPS lost its plugging capability after having been degraded for a period of time. But at 40 °C, LPS with low dissolved oxygen content could be stable for a long time. The decreased plugging ability of LPS after oxidative degradation is mainly caused by the decreased size and number of the LPCs due to the breaking of hydrolyzed polyacrylamide (HPAM) molecule segments and the structural changing of HPAM molecules.
基金Supported by the National Key Basic Research and DevelopmentProgram (973) of China (No 2006CB403304)State Key Labo-ratory of Hydroscience and Engineering Program of China (Nos2008-TC-1 and 2009-TC-2)
文摘The dissolved oxygen concentration in a flow changes with distance downstream of the spillway crest and depends on the geometric configuration of the spillway and the hydraulic and operating conditions.A mathematical model was developed to simulate the turbulent structure of the flow over the spillway of the Three Gorges Dam at the 145 m reservoir water level to study the aeration characteristics and the gas transport.The model was calibrated and verified with measured data.The analysis of distribution of the aeration and the dissolved oxygen showed that the downstream water level,upstream dissolved oxygen content,and the flow discharge all affect the dissolved oxygen saturation downstream of the sluicing dam.The simulation provides guidance for controlling the dissolved oxygen supersaturation and environmentally friendly operation of the Three Gorges Dam.
