采用水热法,以硫酸铝(Al2(SO4)3·18H2O)为原料、尿素为沉淀剂,在一定的醇水比例下(体积比2:1),制备出具有不同形貌的氧化铝前驱体,用SEM、XRD和TG-DSC分析对粉体的微观结构及热分解过程进行了研究。结果表明:相同条件下,水热处理...采用水热法,以硫酸铝(Al2(SO4)3·18H2O)为原料、尿素为沉淀剂,在一定的醇水比例下(体积比2:1),制备出具有不同形貌的氧化铝前驱体,用SEM、XRD和TG-DSC分析对粉体的微观结构及热分解过程进行了研究。结果表明:相同条件下,水热处理温度影响氧化铝前驱体的微观形貌及向α-Al2O3转变的温度,随水热处理温度的提高,其相结构由无定型态向结晶度高的薄水铝石相转变,而其煅烧产物向α-Al2O3转变的温度逐渐升高。利用Doyle-Ozawa法和Kissinger法计算经水热温度为100、140和160℃处理获得产物热分解过程的表观活化能,通过该两种方法得到的表面活化能平均值分别为150.68、155.46、171.09 k J/mol。用Kissinger法确定了反应级数、频率因子和不同水热处理温度下产物的热分解速率方程。展开更多
The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis(TGA-DTA) technique with heating rates of 5,10,15 and 25 K...The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis(TGA-DTA) technique with heating rates of 5,10,15 and 25 K·min 1.The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric(TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method.The thermal decomposition mechanism of abietic acid was studied with four integral methods(atava-esták,MacCallum-Tanner,ordinary integral and Agrawal).The results show that the thermal decomposition mechanism is nucleation and growth,and the mechanism function is Avrami-Erofeev equation with n equates 1/2.The activation energy and the pre-exponential factor are 64.04 kJ·mol-1 and 5.89×10 5 s-1,respectively.展开更多
The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffractio...The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry (TG-DTG). The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg(OH)2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies (E) were calculated by Flynn-Wall-Ozawa method. It is obtained from Coats-Redfern’s equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.展开更多
文摘采用水热法,以硫酸铝(Al2(SO4)3·18H2O)为原料、尿素为沉淀剂,在一定的醇水比例下(体积比2:1),制备出具有不同形貌的氧化铝前驱体,用SEM、XRD和TG-DSC分析对粉体的微观结构及热分解过程进行了研究。结果表明:相同条件下,水热处理温度影响氧化铝前驱体的微观形貌及向α-Al2O3转变的温度,随水热处理温度的提高,其相结构由无定型态向结晶度高的薄水铝石相转变,而其煅烧产物向α-Al2O3转变的温度逐渐升高。利用Doyle-Ozawa法和Kissinger法计算经水热温度为100、140和160℃处理获得产物热分解过程的表观活化能,通过该两种方法得到的表面活化能平均值分别为150.68、155.46、171.09 k J/mol。用Kissinger法确定了反应级数、频率因子和不同水热处理温度下产物的热分解速率方程。
基金Supported by the National＇Natural Science Foundation of China （20976031, 31060102）, the Natural Science Foundation of Guangxi Autonomous Region （2011GXNSFD018011,0991030, 2010GXNSFA013042）, the Science and Technology Program Foundation of Wuzhou City （200901011）, the Scientific and Technological Project of Guangxi （1099060-2）, the Scientific Research Innovative Foundation of Doctor Candidate （105930901008）.
文摘The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis(TGA-DTA) technique with heating rates of 5,10,15 and 25 K·min 1.The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric(TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method.The thermal decomposition mechanism of abietic acid was studied with four integral methods(atava-esták,MacCallum-Tanner,ordinary integral and Agrawal).The results show that the thermal decomposition mechanism is nucleation and growth,and the mechanism function is Avrami-Erofeev equation with n equates 1/2.The activation energy and the pre-exponential factor are 64.04 kJ·mol-1 and 5.89×10 5 s-1,respectively.
基金Project(20876160) supported by the National Natural Science Foundation of China
文摘The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry (TG-DTG). The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg(OH)2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies (E) were calculated by Flynn-Wall-Ozawa method. It is obtained from Coats-Redfern’s equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.
