Self-assembly of perovskite nanocrystals:From driving forces to applications

Self-assembly of metal halide perovskite nanocrystals(NCs)into superlattices can exhibit unique collective properties,which have significant application values in the display,detector,and solar cell field.This review discusses the driving forces behind the self-assembly process of perovskite NCs,and the commonly used self-assembly methods and different self-assembly structures are detailed.Subsequently,we summarize the collective optoelectronic properties and application areas of perovskite superlattice structures.Finally,we conclude with an outlook on the potential issues and future challenges in developing perovskite NCs.

Research on the Spatio-Temporal Evolution and Driving Forces of Green Spaces in the Central Urban Area of Zunyi City

Green space,as a medium for carrying out urban functions and guiding urban development,is becoming a scarce resource along with the urbanization process and the intensification of environmental problems.In the face of the spatial mismatch between high demand and low supply,it is of great significance to clarify the evolution mechanism of green space to undertake national spatial planning,protect the natural strategic resources in the urban fringe area,and promote the sustainable development of the“three living spaces.”The study focuses on the Zunyi City Center,selecting the 20 years of rapid development following its establishment as a city as the study period.It explores the dynamic evolution of green space and the main driving forces during different periods using remote-sensing image data.The study shows that from 2003 to 2023,the total scale of green space has an obvious decreasing trend along with the expansion of the urban built-up area.A large amount of arable land is being converted to construction land,resulting in a sudden decrease in arable land area.In the past 10 years,the comprehensive land use dynamics have accelerated.Still,the spatial difference has gradually narrowed,indicating that the overall development intensity of Zunyi City’s central urban area has increased.There is a gradual spread of the trend to the hilly areas.The limiting effect of the mountainous natural environment on the city’s development has gradually diminished under the superposition of external factors,such as economic development,industrial technological upgrading,and policy orientation so the importance of the effective protection and rational utilization of urban green space has become more prominent.

Driving forces and their relative contributions to hydrocarbon expulsion from deep source rocks: A case of the Cambrian source rocks in the Tarim Basin

To thoroughly understand the dynamic mechanism of hydrocarbon expulsion from deep source rocks,in this study,five types of hydrocarbon expulsion dynamics(thermal expansion,hydrocarbon diffusion,compaction,product volume expansion,and capillary pressure difference(CPD))are studied.A model is proposed herein to evaluate the relative contribution of different dynamics for hydrocarbon expulsion using the principle of mass balance,and the model has been applied to the Cambrian source rocks in the Tarim Basin.The evaluation results show that during hydrocarbon expulsion from the source rocks,the relative contribution of CPD is the largest(>50%),followed by compaction(10%-40%),product volume expansion(5%-30%),and thermal expansion(2%-20%).The relative contribution of diffusion to hydrocarbon expulsion is minimal(<10%).These results demonstrate that CPD plays an important role in the hydrocarbon expulsion process of deep source rocks.The hydrocarbon expulsion process of source rocks can be categorized into three stages based on the contribution of different dynamics to the process:the first stage is dominated by compaction and diffusion to expel hydrocarbons,the second stage is dominated by product volume expansion and CPD,and the third stage is dominated by product volume expansion and CPD.This research offers new insights into hydrocarbon exploration in tight oil and gas reservoirs.

Thermodynamic re-assessment of the Mg-Gd-Y ternary system coupling with the driving forces for phase precipitations during aging process

Based on the available experimental phase equilibrium relations and aging precipitation sequences,the Mg–Gd–Y ternary system has been thermodynamically re-assessed by means of CALPHAD technique.To simulate the experimentally reported aging precipitation sequence,α(Mg)_(SS)(supersaturated)→GP zones(D019-type,metastable)→β’-Mg_(7)Gd(c-bco,metastable)→β_(1)-Mg_(3)Gd(fcc,metastable)→β-Mg_(5)Gd(fcc,stable)near the Mg–Gd side,andα(Mg)SS(supersaturated)→β’-Mg_(7)Y(c-bco,metastable)→β-Mg_(24)Y_(5)(bcc,stable)near the Mg–Y side,the effective nucleation driving forces obtained by deducting the nucleation resistances from the thermodynamic driving forces are calculated and analyzed.Two metastable components,GP zones(D019-type)andβ’(c-bco)ordered fromα(Mg)_(SS),do not exist in the stable equilibrium phase diagram but appear in the annealing process of typical alloys.The Redlich–Kister equations are adopted to describe three solution phases,Liquid,HCP_A3 and BCC_A2.The intermediate compounds Mg_(2)Y,Mg_(24)Y_(5),Mg_(2)Gd,Mg_(3)Gd and Mg_(5)Gd are expressed by the formulas of(Mg,Y)_(2/3)(Gd,Mg,Y)_(1/3),Mg_(24/29)(Gd,Mg,Y)_(4/29)Y1/29,(Gd,Mg)_(2/3)(Gd,Mg,Y)_(1/3),(Gd,Mg)_(3/4)(Gd,Mg,Y)_(1/4)and Mg_(5/6)(Gd,Mg,Y)_(1/6),respectively.In particular,the two-sublattice models(Gd,Mg,Y)_(1/2)(Gd,Mg,Y)_(1/2),(Gd,Mg,Y)_(3/4)(Gd,Mg,Y)_(1/4)and(Gd,Mg,Y)_(7/8)(Gd,Mg,Y)_(1/8)have been respectively used to describe the stable Mg(Gd,Y)(BCC_B2)alloy compound as well as the metastable GP zones(D019-type)andβ’(c-bco)phase,in order to cope with the order-disorder transitions.A set of self-consistent thermodynamic parameters has been obtained to ensure the thermodynamic calculations well consistent with the reported experimental data,containing not only the stable equilibrium phase diagram but also the aging precipitation sequence.

Spatial patterns and driving forces of land use change in China during the early 21st century

Land use and land cover change as the core of coupled human-environment systems has become a potential field of land change science （LCS） in the study of global environmental change. Based on remotely sensed data of land use change with a spatial resolution of 1 km × 1 km on national scale among every 5 years, this paper designed a new dynamic regionalization according to the comprehensive characteristics of land use change including regional differentiation, physical, economic, and macro-policy factors as well. Spatial pattern of land use change and its driving forces were investigated in China in the early 21 st century. To sum up, land use change pattern of this period was characterized by rapid changes in the whole country. Over the agricultural zones, e.g., Huang-Huai-Hai Plain, the southeast coastal areas and Sichuan Basin, a great proportion of fine arable land were engrossed owing to considerable expansion of the built-up and residential areas, resulting in decrease of paddy land area in southern China. The development of oasis agriculture in Northwest China and the reclamation in Northeast China led to a slight increase in arable land area in northern China. Due to the ＂Grain for Green＂ policy, forest area was significantly increased in the middle and western developing regions, where the vegetation coverage was substantially enlarged, likewise. This paper argued the main driving forces as the implementation of the strategy on land use and regional development, such as policies of ＂Western Development＂, ＂Revitalization of Northeast＂, coupled with rapidly economic development during this period.

China's Urbanization in 1949–2015: Processes and Driving Forces

The pace and scale of China＇s contemporary urbanization are stunning. This paper reviews process and the underlying driving forces of China＇s urbanization between 1949-2015. Contemporary China＇s urbanization has experienced four stages, and each has had different driving forces： 1） economic re-construction and industrialization-led urbanization 0949-1977）; 2） economic reform and mar- ket-led urbanization （1978-1995）; 3） economic globalization and the global-local urbanization （1996-2010）; and 4） the land-economy- led urbanization （2010-）. These urbanization processes and driving forces will undoubtedly provide scientific reference and have sig- nificant implications for developing countries, especially African countries, to formulate their urbanization public policies.

Human Driving Forces:Analysis of Rocky Desertification in Karst Region in Guanling County,Guizhou Province

Karst rocky desertification is one of the major ecological and environmental problems that threaten the sustainable development of southwestern China. It is caused by irrational and intensive land-use patterns in karst geo-ecological environment. Therefore, it is vital to identify how human forces work on this degraded environment. Based on the soil erosion information in 2000 and remote sensing images of Guanling County collected in 2000 and 2007, four grades of karst rocky desertification data in 14 villages of Guanling County were extracted. Impacts of population, affluence, and other human forces on karst rocky desertification were analyzed using STIRPAT model. The results show that:1) Factors of population and affluence had strong influence on karst rocky desertification. In the STIRPAT model analysis, the population and affluence coefficients were positive, indicating that the increase in population and affluence would lead to more serious desertification. 2) Factors of farmer correlated with karst rocky desertification negatively, especially the way of viewing the relationship between people and nature, and the level of knowledge about rocky desertification. Government behavior was not a significant factor in this analysis. 3) The findings provide evidence that STIRPAT model can be used to analyze the relationship between human driving forces and rocky desertification.

Changes in cultivated land patterns and driving forces in the Three Gorges Reservoir area, China, from 1992 to 2015

Changes of cultivated land patterns caused by major water conservation projects are rarely reported. We selected the Three Gorges Reservoir area in China to study the change in area and landscape pattern of the cultivated land in the head,central, and tail areas of the reservoir that took place between 1992 and 2015;we then studied the spatial distribution of the cultivated land in the three parts of the reservoir;finally, we studied the driving forces behind the changes in the cultivated land. The results derived are as follows.(1) During the construction of the Three Gorges Project(TGP, 1992–2015), the area of cultivated land around the reservoir decreased by30.23 million ha. This reduction occurred in phases:the most severe change in cultivated land occurred during the later stage of the project(2002–2010);only 0.62 million ha of cultivated land did not change between 1992 and 2015.(2) Spatial pattern analysis showed that the cultivated land in the three parts of the reservoir changed from a northern distribution to a southern distribution;thus, the area of cultivated land in the north decreased over the time period. The area of cultivated land in the head and tail areas decreased by varying degrees, while it increased in the central area over the 23 years, indicating that the change in cultivated land showed regional differences.(3) The TGP, the policy of reverting farmland to forest,and urbanization were the main driving factors for the change of cultivated land, but there were differences in their impacts at different stages.(4) According to the patch dynamics of the land cover change, the degree of change gradually intensified during the early and later stages of the project and then stabilized during the operational period. Our research provides scientific support for the protection of cultivated land resources and food security in the reservoir area and for the coordination of social and economic development, which is of great significance to sustainable development in the reservoir area.

Understanding cultivated land dynamics and its driving forces in northern China during 1983-2001

Based on the long-term serial NOAA/NDVI dataset during 1983-1999 and SPOT/VGT dataset in 2001, the land use/cover change information in the 13 provinces of northern China was extracted based on the analysis of the cultivated landscape characteristics at first, then the effects of human activities on cultivated land process were explored by GIS and the driving forces of cultivated land change were investigated. The conclusions can be drawn as follows： （1） The constant increase of weak ecological function land as desert and cultivated land and the decrease of the ecological function land of forest and shrub were the main characteristics of the land use/cover change in the 13 provinces from 1983 to 1999, which showed the effects on the ecological adjustment fimction. However, such situations were changed to some extent in the 2000s because of the eco-construction policy of the government. （2） From 1983 to 2001, the Barycenter of cultivated land tended to move from northeast to southwest with the topography and transportation situations being the main influences on the cultivated land distribution. It is found that the cultivated land use intensity decreased noticably with the increase of distance from the main communication arteries. （3） The improvement of the people＇s living standard is closely related with the cultivated land change. The structural adjustment in the agricultural land caused by economic development and the improvement of the people＇s living standard ig an important factor affecting the cultivated land change in northern China from 1983 to 2001

Analysis of Major Driving Forces of Ecological Footprint Based on the STRIPAT Model and RR Method:A Case of Sichuan Province,Southwest China

The Ecological Footprint(EF) equation provides useful accounting to analyze the relationship between human activities and the environment.Knowledge of the specific forces driving EF is not fully understood but the STIRPAT model provides a simple framework for decomposing the impact of human activities on environment.We applied the EF model in Sichuan Province,China to assess the impact of human activities.The per capita EF increased by 2 fold in the 14 years between 1995 and 2008,but ecological capacity decreased in the same period,suggesting that the biologically productive area of Sichuan Province is inadequate to sustain human activities.According to the refined STIRPAT model,the hypothesized driving forces of EF include population size(P),GDP per capita(A1),quadratic term of GDP per capita(A2),percentage of GDP from industry(T1) and urbanization rate(T2).However,the multi-collinearity among these drivers could be a substantial problem which may reveal negative effect in the final results.Application of the Ridge Regression(RR) method to fit the STIRPAT model had the advantage of being able to avoid the collinearity among independent variables.The results showed that population is the principal driving force of EF variation in Sichuan Province and that urbanization and industrialization also have a positive association with the EF.Analysis of affluence elasticity(EEA) showed that the relationship betweenEF and economic growth was not curvilinear,suggesting that variation of EF does not follow an Environmental Kuznets Curve relative to economic growth in Sichuan Province.

On arable land changes in Shandong Province and their driving forces

The decrease of total cultivated area and the lower per capita available arable land resource are now serious problems in Shandong Province, a major agricultural province in China. These problems will become more serious along with the further development of economy. In this paper, based on the statistical information at provincial and county levels, the changes of arable land in Shandong Province and their driving forces during the last 50 years are analyzed. The general changing trends of arable land and per capita available arable land are reducing, and the trends of decrease will continue when the economy is developing. The result of GIS spatial analysis shows that the change of the arable land use in Shandong Province has a regional difference. Eight variables having influences on cultivated land change are analyzed by principal component analysis. The results show that the dynamic development of economy, pressure of social system and progress of scientific techniques in agriculture are the main causes for cultivated land reduction. The principal factors which can be considered as driving forces for arable land change include per capita net living space, total population and per ha grain yield. By using regressive equation, along with analysis on population growth and economic development, cultivated areas in Shandong Province in 2005 and 2010 are predicted respectively. The predicted cultivated areas in Shandong will be 6435.47 thousand hain 2005 and 6336.23 thousand ha in 2010 respectively.

DYNAMICS OF SANDY DESERTIFICATION AND ITS DRIVING FORCES IN WESTERN JILIN PROVINCE

By establishing the interpreting elements, and applying supervised classification, the sandy desertific- ation was interpreted and the desertified land areas of the counties in the western Jilin Province in 1986 and in 2000 were obtained. Taking Tongyu and Qian’an as examples, the natural driving forces and man-made driving forces were analyzed. The paper comes the conclusions that the material sources and the warming and dry climate are the internal causes of potential land desertification; the irrational human activities, such as destroying forest and reclaiming the grassland, are the external causes of potential land desertification; while more rational human activities, such as planting trees and restoring grassland can reverse the land desertification. Furthermore, the countermeasures and suggestions for the development of agriculture and animal husbandry in the western Jilin Province are put forward.

Measuring Spatio-temporal Characteristics of City Expansion and Its Driving Forces in Shanghai from 1990 to 2015

Urbanization has both direct and indirect impacts on land use change, and analyzing spatio-temporal characteristics of land use change is essential for understanding these impacts. By comparing Landsat TM images, this paper examines the changes of land use structure and landscape patterns in Shanghai from 1990 to 2015. It finds that the city doubled in size, with the growth of isolated construction land being most significant among eight land use types. A land use change matrix was established and landscape indices were selected to evaluate the change of spatial structure in Shanghai. In order to identify the main driving forces of city expansion in Shanghai, this research ran partial least square regression models to assess the impact of 10 social-economic factors on land use change of Shanghai from 1990 to 2015. It then conducted bivariate correlation analysis to explore the drivers of change of various land use types: urban settlement, rural settlement and isolated construction land. Besides quantitative analysis, this paper analyzes the influence of policy-dimensional factors in land use change. It concludes with future potential research topics on land use change in a rapidly urbanizing context.

Long-term Dynamics of Cultivated Land Resources and Their Driving Forces of Guyuan City in Upper Reaches of Jinghe River

The land use patterns in Guyuan City,Ningxia Hui Autonomous Region of China,have changed greatly over the years,due to population growth and farming and stock raising development.This study,using 50-year statis-tical data of cultivated land and 14-year spatial data of land use pattern,analyzed the developmental stages,the char-acter,and the spatial variance of farmland in the city,and discussed the driving forces of cultivated land changes based on empirical and conceptual statistical models.First,the change of cultivated land area went through different stages of rapid increase,fluctuating change,decrease and rapid decrease from 1949 to 2004,additionally,social and economic policies in different stages had an important impact on farmland variance.Second,from 1986 to 2000,the quantity of cultivated land increased,but its quality decreased.Third,social and economic factors are determinant factors in culti-vated land transition.Five constructed paths explain cultivated land transition.Factors that have direct or indirect ef-fects on farmland include the economy(Xeco),the population(Xpop),agricultural output(Xagr),and scientific input(Xsci).The sequence of impact was Xeco>Xpop>Xsci>Xagr.Among all these impacts,Xeco was the major positive one,and Xpop was the major negative one.It is urgent to take measures or adopt a policy to stop the vicious cycle in eco-environment and agriculture production.Otherwise,negative patterns of farmland use will increase,and high-quality cultivated land will continue to decline.

Land use and land cover change and its driving forces in Maqu County, China in the past 25 years

Maqu County is located in the northeast Qinghai-Tibetan Plateau, and it is the main watershed for the Yellow River. The ecosystem there is extremely vulnerable and sensitive to climate change and human activities, which have caused significant deterioration of the eco-environment in this region. In order to restore the ecological environment, a government project to restore the grazing areas to grassland was implemented in Maqu County in early 2004. This study evaluates the effects of that restoration project on land use and land cover change （LUCC）, and explores the driving forces of LUCC in Maqu County. In the study we used Landsat images obtained in 1989, 2004, 2009, and 2014 to establish databases of land use and land cover. Then we derived LUCC information by overlaying these layers using GIS software. Finally, we analyzed the main forces responsible for LUCC. The results showed that forests, high-coverage grasslands, and marshes experienced the most significant decreases during 1989–2004, by 882.8 ha, 35,250.4 ha, and 2,753.4 ha, respectively. However, moderate- and low-coverage grasslands and sand lands showed the opposite trend, increasing by 12,529.7 ha, 25,491.0 ha, and 577.5 ha, respectively. LUCC in 2004–2009 showed that ecological degradation slowed compared with 1989？2004. During 2009–2014, high- and moderate-coverage grasslands increased obviously, but low-coverage grasslands, marshes, unused lands, sand lands, and water areas showed the opposite trend. These results suggested that the degradation of the eco-environment was obvious before 2009, showing a decrease in the forests, grasslands, and water areas, and an increase in unused lands. The ecological degradation was reversed after 2009, as was mainly evidenced by increases in high- and mod-erate-coverage grasslands, and the shrinkage rate of marshes decreased obviously. These results showed that the project of restoring grazing lands to grassland had a positive effect on the LUCC. Other major factors that influence the LUCC include increasing temperature, variation in the seasonal frozen soil environment, seasonal overgrazing, and pest and rodent damage.

Status of CO_2 emissions,driving forces and mitigation countermeasures of Tianjin,China

Climate change is a long-term and important challenge facing the whole world. Mitigation of CO2 emissions is one of important measures responding to climate change. The task of responding to climate change facing each city is very urgent. The total amount of Tianjin City＆#39;s CO2 emissions from energy use and industrial processes is large and the amount of CO2 emissions per capita from fossil fuel combustion is quite high. Mitigation of CO2 emission in Tianjin City encounters many difficulties such as increasing population, rapidly growing economy, heavy industrial structure, backward tertiary industry, low level of energy efficiency and product technologies, and energy structure relying mainly on coal. This paper analyzes Tianjin City＆#39;s general situation of economic and social developments, estimates Tianjin City＆#39;s status of CO2 emissions using 2006 IPCC Guidelines for National Greenhouse Gas Inventories, analyzes Tianjin City＆#39;s driving forces of CO2 emissions by methodology to analyze the driving forces of energy-related CO2 emissions, and puts forward countermeasures mitigating CO2 emissions in Tianjin City, such as strictly controlling increasing population, expediting industrial structure adjustment, insisting on strategy of energy conserving, vigorously enhancing energy efficiency, exploiting and using clean and renewable energy, advancing energy structure adjustments, and actively developing carbon capture and storage （CCS） technologies.

Multi-scales Analysis of Driving Forces on Land Use/Cover Change in China:Taking Farmland Returning to Forest or Grassland as a Case

Increasing populations are causing an increase in food demands, and the area of cultivated land expands every year. Inappropriate land transition from ecology to production results in the constant decline of the ecological security level and influences the regional sustainable development. Adjusting unreasonable land use mode and reconstructing natural land cover are important ways to maintain and improve the ecological environment. Also reclaiming farmland as areas for forests and grasslands (FRFG) is another way. Successful implementation of FRFG in China is the result of comprehensive effect of the multi-scales driving forces. This paper analyses the driving forces of FRFG in China on a national (country) –regional (province) – local (county) – household (farmer) level scale, and the results are: driving forces at the national scale include ecological and food security and the western development of China; at the regional scale, ecological and economic benefits become the main factors to influence the dimension of FRFG under the same policy. The driving forces can be divided into 6 types: industrial structure adjustment, water source protection, flood prevention, the Three-Gorge Project protection, reduction of the amount of sediment flowing into the Yellow River and wind erosion desertification prevention. The driving forces at the local scale can be divided into 12 types with developing leading industries, increasing farmers’ income and improving agricultural production conditions as the main types; at the household scale, the nationalpolicy meeting farmers’ demands and the optimization of individual interests are all driving forces.

Characteristics and Driving Forces of Spatial Expansion of Oasis Cities and Towns in Hexi Corridor, Gansu Province, China

This paper presents an integrated study of urban spatial expansion in the Hexi Corridor, Gansu Province, China based on TM, ETM remote sensing data in 1987, 1990, 1995, 2000, 2006 and 2011. The study explores the characteristics of urban spatial expansion and dynamic mechanism by using expansion speed index, expansion intensity index, compact index, fractal dimension, and extended flexibility index. We built the index system of influencing factors of urban spatial expansion by using the grey incidence model. The results showed that urban spatial expansion rate in the Hexi Corridor has been on the upward trend since 1987. Expansion intensity showed an obvious upward trend, however, the upward trend varied in different urban areas. In addition, the urban structure was loose relatively, but the urban compactness was more obvious. The urban spatial form tended to be simple, and the urban land use tended to become more intensive. Urban spatial expansion experienced several stages: padding internally, external expansion and padding internally. The main driving factors of urban spatial expansion are not the urban water resources and the oasis scale, but one or several factors such as economy, traffic, population, resource and national policy.

Study on the Characteristics and Driving Forces of Changes of the Urban Land-Use Structure in Wuhan in 1990s

On the basis of the information entropy and equilibrium degree of urban land-use spatial structure, the paper analyzes the characteristics and rules of urban land-use spatial structure changes in Wuhan in 1990s, in which the types of land-use are shrinking and urban land-use changes are disequilibria. With PCA and GRA employed, the driving forces have also been analyzed. The driving force of city welfare and social structure, the towing force of city industrial structure transition, and the pressing force of city construction and reconstruction are main momentum factors. Moreover, the latter forces are more significant.

Research on driving forces for rural settlement land changes in China

During the rapid urbanization period, the contradiction between demand for the construction land and the preservation of cultivated land for food security is getting more and more serious in China. With the urbanization the rural settlement land is increasing instead of decreasing; This paper aims at.finding the driving forces for rural settlement land expanston. Based on land use change survey data （1996-2006） by the Ministry of Land and Resources P. R. C., this paper find, that per capita area for rural settlement land is more than per capita area for city; township and industrial land in each province except Tibet. Besides, rural settlement land area and per capita rural settlement land area are increasing while the rural poputation is decreasing in most provinces. The main problems of rural settlement land use are low efficiency, high vacancy rate, chaotic layout and illegal occupancy. Then the driving forces [br rural settlement land expansion, including economic development, family income, family scale, psychological factors, urbanization, transportation, lack of planning, limited circulation of dwelling-house land and imperfect sociat security, ate explored based on above analysis, Finalty, policy recommendations, in view of different influencing factors, are put forward to control the disorder expansion of rural setttement land.