The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the uns...The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the unsaturated loess was investigated by laboratory experimental methods. Moreover, the temperature field, seepage field, and stability of slopes with different gradients were simulated under the effect of the freeze-thaw cycle and dry-wet alternation by using the geotechnical analysis software Geo-Studio. The research results showed(1) when the freeze-thaw cycle was repeated on the slope, with the frozen depth increasing, the melted depth did the same; besides, the closed loop of isotherms formed on the slope;(2) under the action of dry-wet circulation, the negative pore-water pressure and volumetric water content showed an upward tendency. However, owing to the different slope gradients, rainfall infiltration was not the same. As time went by, the differences of the negative pore-water pressure and volumetric water content between the slopes of different gradients continued to increase;(3) with the freeze-thaw cycle and dry-wet alternation increasing, the slope-safety factor decreased. Especially in the early period, the slope-safety factor changed remarkably. For slopes undergoing freeze-thaw action, the slope-safety factor was negatively correlated with the gradient. However, with regard to slopes undergoing dry-wet alternation, the result became more complex because the slope-safety factor was related to both seepage strength and slope grade. Accordingly, further research is needed to study the effect of seepage strength and slope grade on the stability of loess slopes.展开更多
A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles...A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles were investigated.The whiteness,water-holding capacity,storage modulus(G')and texture properties of the MPGs were significantly improved by adding 1%-2%Pickering emulsion(P<0.05).Meanwhile,Raman spectral analysis demonstrated that Pickering emulsion promoted the transformation of secondary structure,enhanced hydrogen bonds and hydrophobic interactions,and promoted the transition of disulfide bond conformation from g-g-g to g-g-t and t-g-t.At an emulsion concentration of 2%,theα-helix content decreased by 10.37%,while theβ-sheet content increased by 7.94%,compared to the control.After F-T cycles,the structure of the MPGs was destroyed,with an increase in hardness and a decrease in whiteness and water-holding capacity,however,the quality degradation of MPGs was reduced with 1%-2%Pickering emulsion.These findings demonstrated that SSOS-Pickering emulsions,as potential fat substitutes,can enhance the gel properties and the F-T stability of MPGs.展开更多
The frost deterioration and deformation of porous rock are commonly investigated under uniform freeze-thaw(FT)conditions.However,the unidirectional FT condition,which is also prevalent in engineering practice,has rece...The frost deterioration and deformation of porous rock are commonly investigated under uniform freeze-thaw(FT)conditions.However,the unidirectional FT condition,which is also prevalent in engineering practice,has received limited attention.Therefore,a comparative study on frost deformation and microstructure evolution of porous rock under both uniform and unidirectional FT conditions was performed.Firstly,frost deformation experiments of rock were conducted under cyclic uniform and unidirectional FT action,respectively.Results illustrate that frost deformation of saturated rock exhibits isotropic characteristics under uniform FT cycles,while it shows anisotropic characteristics under unidirectional FT condition with both the frost heaving strain and residual strain along FT direction much higher than those perpendicular to FT direction.Moreover,the peak value and residual value of cumulative frost strain vary as logarithmic functions with cycle number under both uniform and unidirectional FT conditions.Subsequently,the microstructure evolution of rock suffered cyclic uniform and unidirectional FT action were measured.Under uniform FT cycles,newly generated pores uniformly distribute in rock and pore structure of rock remains isotropic in micro scale,and thus the frost deformation shows isotropic characteristics in macro scale.Under unidirectional FT cycles,micro-cracks or pore belts generate with their orientation nearly perpendicular to the FT direction,and rock structure gradually becomes anisotropic in micro scale,resulting in the anisotropic characteristics of frost deformation in macro scale.展开更多
After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and t...After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and the 3D pore distribution curve before and after freezing and thawing. The fractal dimension is utilized to characterize the two-dimensional topography image and the three-dimensional pore distribution, quantitatively. The results reveal that the surface porosity and volume porosity increase as the freeze-thaw action increases. Self-similarity characteristics exist in micro-damage inside the concrete. In the fractal dimension, it is possible to characterize pore evolution quantitatively. The fractal dimension correlates with pore damage evolution. The fractal dimension effectively quantitatively characterizes micro-damage features at various scales from the local to the global level.展开更多
Due to climatic factors and rapid urbanization,the soil in the Loess Plateau,China,experiences the coupled effects of dry-wet cycles and chemical contamination.Understanding the mechanical behavior and corresponding m...Due to climatic factors and rapid urbanization,the soil in the Loess Plateau,China,experiences the coupled effects of dry-wet cycles and chemical contamination.Understanding the mechanical behavior and corresponding microstructural evolution of contaminated loess subjected to dry-wet cycles is essential to elucidate the soil degradation mechanism.Therefore,direct shear and consolidation tests were performed to investigate the variations in mechanical properties of compacted loess contaminated with acetic acid,sodium hydroxide,and sodium sulfate during dry-wet cycles.The mechanical response mechanisms were investigated using zeta potential,mineral chemical composition,and scanning electron microscopy(SEM)tests.The results indicate that the mechanical deterioration of sodium hydroxidecontaminated loess during dry-wet cycles decreases with increasing contaminant concentration,which is mainly attributed to the thickening of the electrical double layer(EDL)by Nat and the precipitation of calcite,as well as the formation of colloidal flocs induced by OH,thus inhibiting the development of large pores during the dry-wet process.In contrast,the attenuation of mechanical properties of both acetic acid-and sodium sulfate-contaminated loess becomes more severe with increasing contaminant concentration,with the latter being more particularly significant.This is primarily due to the reduction of the EDL thickness and the erosion of cement in the acidic environment,which facilitates the connectivity of pores during dry-wet cycles.Furthermore,the salt expansion generated by the drying process of saline loess further intensifies the structural disturbance.Consequently,the mechanical performance of compacted loess is sensitive to both pollutant type and concentration,exhibiting different response patterns in the dry-wet cycling condition.展开更多
The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retracti...The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retraction of the glacier has left behind an intense climatic instability that causes a high frequency of freeze-thaw cycles of great intensity;the resulting geomorphological processes are represented by the fragmentation of the bedrock that occupies the upper parts of the mountain.There is a notable lack of studies regarding the fragmentation and erosion occurring in tropical high mountains,and the associated geomorphological risks;for this reason,as a first stage of future continuous research,this study analyzes the freezing and thawing cycles that occur above 4000 m asl,through continuous monitoring of surface ground temperature.The results allow us to identify and characterize four zones:glacial,paraglacial,periglacial and proglacial.It was found that the paraglacial zone presents an intense drop of temperature,of up to~9℃ in only sixty minutes.The rock fatigue and intense freeze-thaw cycles that occur in this area are responsible for the high rate of rock disintegration and represent the main factor of the constant slope dynamics that occur at the site.This activity decreases,both in frequency and intensity,according to the distance to the glacier,which is where the temperature presents a certain degree of stability,until reaching the proglacial zone,where cycles are almost non-existent,and therefore there is no gelifraction activity.The geomorphological processes have resulted in significant alterations to the mountain slopes,which can have severe consequences in terms of risk and water.展开更多
Sandstone is the fundamental material in various engineering and construction projects.However,the mechanical integrity of sandstone can be compromised by initial unloading damage resulting from activities such as eng...Sandstone is the fundamental material in various engineering and construction projects.However,the mechanical integrity of sandstone can be compromised by initial unloading damage resulting from activities such as engineering excavations.Furthermore,this degradation is further exacerbated under periodic dry-wet environmental conditions.This study investigated the effects of dry-wet cycles and unloading on the mechanical properties of jointed fine sandstone using uniaxial and triaxial compression tests.These tests were performed on rock samples subjected to varying unloading degrees and different numbers of dry-wet cycles.The results demonstrate that with an increase in the unloading degree from 0%to 70%,there is a corresponding decrease in peak stress ranging from 10%to 33%.Additionally,the cohesion exhibits a reduction of approximately 20%to 25%,while the internal friction angle experiences a decline of about 3.5%to 6%.These findings emphasize a significant unloading effect.Moreover,the degree of peak stress degradation in unloading jointed fine sandstone diminishes with an increase in confining pressure,suggesting that confining pressure mitigates the deterioration caused by dry-wet cycles.Additionally,as the number of dry-wet cycles increases,there is a notable decline in the mechanical properties of the sandstone,evidencing significant dry-wet degradation.Utilizing the Drucker Prager criterion,this study establishes a strength criterion and fracture criterion,denoted as σ_(1)(m,n) and K_(T)^(Ⅱ)(m, n), to quantify the combined impacts of dry-wet cycles and unloading on jointed fine sandstone,which provides a comprehensive understanding of its mechanical behavior under such conditions.展开更多
Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern const...Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern construction as well. However, ignimbrites are particularly vulnerable to atmospheric conditions, such as freeze-thaw cycles, due to their high porosity, which is a result of their formation process. When water enters the pores of the ignimbrites, it can freeze during cold weather. As the water freezes and expands, it generates internal stress within the stone, causing micro-cracks to develop. Over time, repeated freeze-thaw (F-T) cycles lead to the growth of these micro-cracks into larger cracks, compromising the structural integrity of the ignimbrites and eventually making them unsuitable for use as building materials. The determination of the long-term F-T performance of ignimbrites can be established after long F-T experimental processes. Determining the long-term F-T performance of ignimbrites typically requires extensive experimental testing over prolonged freeze-thaw cycles. To streamline this process, developing accurate predictive equations becomes crucial. In this study, such equations were formulated using classical regression analyses and artificial neural networks (ANN) based on data obtained from these experiments, allowing for the prediction of the F-T performance of ignimbrites and other similar building stones without the need for lengthy testing. In this study, uniaxial compressive strength, ultrasonic propagation velocity, apparent porosity and mass loss of ignimbrites after long-term F-T were determined. Following the F-T cycles, the disintegration rate was evaluated using decay function approaches, while uniaxial compressive strength (UCS) values were predicted with minimal input parameters through both regression and ANN analyses. The ANN and regression models created for this purpose were first started with a single input value and then developed with two and three combinations. The predictive performance of the models was assessed by comparing them to regression models using the coefficient of determination (R2) as the evaluation criterion. As a result of the study, higher R2 values (0.87) were obtained in models built with artificial neural network. The results of the study indicate that ANN usage can produce results close to experimental outcomes in predicting the long-term F-T performance of ignimbrite samples.展开更多
Moraines,characterized by the accumulation of rock and soil debris transported by glacial activity,present unique challenges for tunnel construction,particularly in portal sections,due to prevailing geographical and c...Moraines,characterized by the accumulation of rock and soil debris transported by glacial activity,present unique challenges for tunnel construction,particularly in portal sections,due to prevailing geographical and climatic conditions that facilitate freeze-thaw action.Despite these challenges,there is a dearth of studies investigating the influence of freeze-thaw action and water content on the mechanical properties of moraines,and no research on calculating surrounding rock pressure in moraine tunnels subjected to freeze-thaw conditions.In this study,direct shear tests under freeze-thaw cycles were conducted to examine the effects of freeze-thaw cycles and water content on the mechanical properties of frozen moraine.A comprehensive parameter K,integrating the number of freeze-thaws and water content,was introduced to model cohesion c.Drawing on Terzaghi Theory,we propose an improved algorithm for calculating surrounding rock pressure at the portal section of moraine tunnels.Using a tunnel as a case study,surrounding rock pressure was calculated under various conditions to validate the Improved Algorithm's efficacy.The results show that:(1)Strength loss exhibits a linear trend with the number of freeze-thaw cycles at water content levels of 4%and 8%,while at 12%water content,previous freeze-thaw cycles induce more significant damage to the soil.(2)Moraine saturation peaks between 8%and 12%water content.Following repeated freeze-thaw cycles,moraine shear strength initially increases before decreasing with varying water content.(3)The internal friction angle of moraine experiences slight reductions with prolonged freeze-thaw cycles,but both freeze-thaw cycles and water content significantly influence cohesion.(4)Vertical surrounding rock pressure increases after the initial freeze-thaw cycle,particularly with higher water content,although freeze-thaw cycles have minimal effect on it.(5)Freeze-thaw cycles lead to a substantial increase in lateral surrounding rock pressure,necessitating reinforced support structures at the arch wall,arch waist,and arch foot in engineering projects to mitigate freeze-thaw effects.This study provides a foundation for designing and selecting tunnel support structures in similar geological conditions.展开更多
Chloride (Cl−) ion erosion effects can seriously impact the safety and service life of marine liquefied natural gas(LNG) storage tanks and other polar offshore structures. This study investigates the impact of differe...Chloride (Cl−) ion erosion effects can seriously impact the safety and service life of marine liquefied natural gas(LNG) storage tanks and other polar offshore structures. This study investigates the impact of different low-temperaturecycles (20°C, –80°C, and −160°C) and concrete specimen crack widths (0, 0.3, and 0.6 mm) on the Cl−ion diffusion performance through rapid erosion tests conducted on pre-cracked concrete. The results show thatthe minimum temperature and crack width of freeze-thaw cycles enhance the erosive effect of chloride ions. TheCl− ion concentration and growth rate increased with the increasing crack width. Based on the experimental modeland in accordance with Fick’s second law of diffusion, the Cl− ion diffusion equation was modified by introducingcorrection factors in consideration of the freeze-thaw temperature, crack width, and their coupling effect.The experimental and fitting results obtained from this model can provide excellent reference for practical engineeringapplications.展开更多
Oil leakages cause environmental pollution,economic losses,and even engineering safety accidents.In cold regions,researchers urgently investigate the movement of oil spill in soils exposed to freeze-thaw cycles.In thi...Oil leakages cause environmental pollution,economic losses,and even engineering safety accidents.In cold regions,researchers urgently investigate the movement of oil spill in soils exposed to freeze-thaw cycles.In this study,a series of laboratory model experiments were carried out on the migration of oil leakage under freeze-thaw action,and the distributions of the soil temperature,unfrozen water content,and displacement were analyzed.The results showed that under freeze-thaw action,liquid water in soils migrated to the freezing front and accumulated.After the pipe cracked,oil pollutants first gathered at one side of the leak hole,and then moved around.The pipe wall temperature affected the soil temperature field,and the thermal influence range below and transverse the pipe wall(35–40 cm)was larger than that above the pipe wall(8 cm)owing to the soil surface temperature.The leaked oil's temperature would make the temperature of the surrounding soil rise.Oil would inhibit the cooling of the soils.Besides,oil migration was significantly affected by the gravity and water flow patterns.The freeze-thaw action would affect the migration of the oil,which was mainly manifested as inhibiting the diffusion and movement of oil when soils were frozen.Unfrozen water transport caused by freeze-thaw cycles would also inhibit oil migration.The research results would provide a scientific reference for understanding the relationship between the movement of oil pollutants,water,and soil temperature,and for establishing a waterheat-mass transport model in frozen soils.展开更多
The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled ...The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled fine aggregate(SRFA)obtained from recycled fine aggregate concrete(RFAC)subjected to freeze-thaw(FT)cycles.Before and after carbonation,the properties of SRFA were evaluated.Carbonated second-generation recycled fine aggregate(CSRFA)at five substitution rates(0%,25%,50%,75%,100%)to replace SRFA was used to prepare carbonated second-generation recycled fine aggregate concrete(CSRFAC).The water absorption,porosity and mechanical properties of CSRFAC were tested,and its frost-resisting durability was evaluated.The results showed after carbonation treatment,the physical properties of SRFA was improved and met the requirements of II aggregate.The micro-hardness of the interfacial transition zone and attached mortar in CSRFA was 50.5%and 31.2%higher than that in SRFA,respectively.With the increase of CSRFA replacement rate,the water absorption and porosity of CSRFAC gradually decreased,and the mechanical properties and frost resistance of CSRFAC were gradually improved.Carbonation treatment effectively repairs the damage of SRFA caused by FT cycles and improves its application potential.展开更多
Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned mines.Its realization requires better understanding of the dynamic performance and durability of reservoir rock.Thi...Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned mines.Its realization requires better understanding of the dynamic performance and durability of reservoir rock.This paper conducted ultrasonic detection,split Hopkinson pressure bar(SHPB)impact,mercury intrusion porosimetry(MIP),and backscatter electron observation(BSE)tests to investigate the dynamical behaviour and microstructure of sandstone with cyclical dry-wet damage.A coupling FEM-DEM model was constructed for reappearing mesoscopic structure damage.The results show that dry-wet cycles decrease the dynamic compressive strength(DCS)with a maximum reduction of 39.40%,the elastic limit strength is reduced from 41.75 to 25.62 MPa.The sieved fragments obtain the highest crack growth rate during the 23rd dry-wet cycle with a predictable life of 25 cycles for each rock particle.The pore fractal features of the macropores and micro-meso pores show great differences between the early and late cycles,which verifies the computational statistics analysis of particle deterioration.The numerical results show that the failure patterns are governed by the strain in pre-peak stage and the shear cracks are dominant.The dry-wet cycles reduce the energy transfer efficiency and lead to the discretization of force chain and crack fields.展开更多
Arctic sea ice is broadly regarded as an indicator and amplifier of global climate change.The rapid changes in Arctic sea ice have been widely concerned.However,the spatiotemporal changes in the horizontal and vertica...Arctic sea ice is broadly regarded as an indicator and amplifier of global climate change.The rapid changes in Arctic sea ice have been widely concerned.However,the spatiotemporal changes in the horizontal and vertical dimensions of Arctic sea ice and its asymmetry during the melt and freeze seasons are rarely quantified simultaneously based on multiple sources of the same long time series.In this study,the spatiotemporal variation and freeze-thaw asymmetry of Arctic sea ice were investigated from both the horizontal and vertical dimensions during 1979–2020 based on remote sensing and assimilation data.The results indicated that Arctic sea ice was declining at a remarkably high rate of–5.4×10^(4) km^(2)/a in sea ice area(SIA)and–2.2 cm/a in sea ice thickness(SIT)during 1979 to 2020,and the reduction of SIA and SIT was the largest in summer and the smallest in winter.Spatially,compared with other sub-regions,SIA showed a sharper declining trend in the Barents Sea,Kara Sea,and East Siberian Sea,while SIT presented a larger downward trend in the northern Canadian Archipelago,northern Greenland,and the East Siberian Sea.Regarding to the seasonal trend of sea ice on sub-region scale,the reduction rate of SIA exhibited an apparent spatial heterogeneity among seasons,especially in summer and winter,i.e.,the sub-regions linked to the open ocean exhibited a higher decline rate in winter;however,the other sub-regions blocked by the coastlines presented a greater decline rate in summer.For SIT,the sub-regions such as the Beaufort Sea,East Siberian Sea,Chukchi Sea,Central Arctic,and Canadian Archipelago always showed a higher downward rate in all seasons.Furthermore,a striking freeze-thaw asymmetry of Arctic sea ice was also detected.Comparing sea ice changes in different dimensions,sea ice over most regions in the Arctic showed an early retreat and rapid advance in the horizontal dimension but late melting and gradual freezing in the vertical dimension.The amount of sea ice melting and freezing was disequilibrium in the Arctic during the considered period,and the rate of sea ice melting was 0.3×10^(4) km^(2)/a and 0.01 cm/a higher than that of freezing in the horizontal and vertical dimensions,respectively.Moreover,there were notable shifts in the melting and freezing of Arctic sea ice in 1997/2003 and 2000/2004,respectively,in the horizontal/vertical dimension.展开更多
For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were c...For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were conducted. After freezethaw, nuclear magnetic resonance(NMR) tests and impact loading tests were carried out, from which microscopic damage characteristics of sandstone and dynamic mechanical parameters were obtained. The results indicate that the porosity increases with the increase of cycle number, the rate of porosity growth descends at the beginning of freeze-thaw, yet accelerates after a certain number of cycles. The proportion of pores with different sizes changes dynamically and the multi-scale distribution of pores tends to develop on pore structure with the continuing impact of freeze-thaw and thawing. Dynamic compressive stress-strain curve of sandstone undergoing freeze-thaw can be divided into four phases, and the phase of compaction is inconspicuous compared with the static curve. Elastic modulus and dynamic peak intensity of sandstone gradually decrease with freeze-thaw cycles, while peak strain increases. The higher the porosity is, the more serious the degradation of dynamic intensity is. The porosity is of a polynomial relationship with the dynamic peak intensity.展开更多
In order to study the deterioration characteristics of the microscopic structure of sandstones in freeze-thaw cycles, tests of180 freeze-thaw cycles were performed on sandstone specimens. The nuclear magnetic resonan...In order to study the deterioration characteristics of the microscopic structure of sandstones in freeze-thaw cycles, tests of180 freeze-thaw cycles were performed on sandstone specimens. The nuclear magnetic resonance (NMR) technique was applied tothe measurement of sandstone specimens and analysis of the magnetic resonance imaging. Then, the fractal theory was employed tocompute the fractal dimension values of pore development of rocks after different freeze-thaw cycles. The results show that the massand porosity of rocks grow with the increase of freeze-thaw cycles. According to the NMR T2 distribution of sandstones, the poresizes of rock specimens increase after 180 freeze-thaw cycles, especially that of the medium-sized and small-sized pores. The spatialdistribution of sandstone pores after freeze-thaw cycles has fractal features within certain range, and the fractal dimension ofsandstones tends to increase gradually.展开更多
A laboratory simulated freeze-thaw was conducted to determine the effects of freeze-thaw on soil nutrient availability in temperate semi-arid regions. Soil samples were collected from sandy soils (0-20 cm) of three ...A laboratory simulated freeze-thaw was conducted to determine the effects of freeze-thaw on soil nutrient availability in temperate semi-arid regions. Soil samples were collected from sandy soils (0-20 cm) of three typical ecosystems (grassland, Mongolian pine plantation and poplar plantation) in southeastern Keerqin Sandy Lands of China and subjected to freeze-thaw treatment (-12℃ for 10 days, then r 20℃ for 10 days) or incubated at constant temperature (20℃ for 20 days). Concentrations of the soil NO3^--N, NH4^+-N, NaHCO3 extractable inorganic P (LPi) and microbial biomass P (MBP) were determined on three occasions: at the start of the incubation, immediate post-thawing and at the 10th day post-thawing. The results showed that soil net nitrification and N mineralization rates at three sites were negatively affected by freeze-thaw treatment, and decreased by 50%-85% as compared to the control, of which the greatest decline occurred in the soil collected from poplar plantation. In contrast, the concentration of soil NH4^+-N, NaHCO3 extractable inorganic P (LPi) and microbial biomass P were insignificantly influenced by freeze-thaw except that LPi and NH4^+-N showed a slight increase immediate post-thawing. The effects of freeze-thaw on soil N transformation were related to soil biological processes and the relatively constant available P was ascribed to severe soil aridity.展开更多
According to the winter temperature of Peking,the freeze-thaw(FT) condition in laboratory was determined.Seven groups of epoxy asphalt concrete(EAC) specimen were exposed to different FT cycles.The flexural modulu...According to the winter temperature of Peking,the freeze-thaw(FT) condition in laboratory was determined.Seven groups of epoxy asphalt concrete(EAC) specimen were exposed to different FT cycles.The flexural modulus and fracture energy(G_F) of EAC exposed to different FT cycles were obtained through the 3-point bending test.Meanwhile,the plane strain fracture toughness(K_(IC)) of EAC was obtained through numerical simulation.The results show that the flexural modulus of the FT conditioned EAC samples decreases with the increase of FT cycles.The FT damage of flexural modulus is 60%after 30 FT cycles.Nevertheless,with the increase of FT cycles,the G_F and K_(IC) of EAC decrease first and then increase after 15 FT cycles.展开更多
A theoretical prediction method based on the change of concrete material is proposed to evaluate the ultimate bending moment of concrete beams which have undergone freeze-thaw cycles (PTCs). First, the freeze-thaw d...A theoretical prediction method based on the change of concrete material is proposed to evaluate the ultimate bending moment of concrete beams which have undergone freeze-thaw cycles (PTCs). First, the freeze-thaw damage on concrete material is analyzed and the residual compressive strength is chosen to indicate the freeze-thaw damage. Then, the equivalent block method is employed to simplify the compressive stress-strain curve of the freeze-thaw damaged concrete and the mathematical expression for the ultimate bending moment is obtained. Comparisons of the predicted results with the test data indicate that the ultimate bending moment of concrete beams affected by FTC attack can be predicted by this proposed method. However, the bond-slip behavior and the randomness of freeze-thaw damage will affect the accuracy of the predicted results, especially when the residual compressive strength is less than 50%.展开更多
In order to effectively assess the mechanical properties of concrete with freeze-thaw and seawater erosion, tests about basic mechanical properties of concrete after freeze-thaw and seawater erosion are conducted base...In order to effectively assess the mechanical properties of concrete with freeze-thaw and seawater erosion, tests about basic mechanical properties of concrete after freeze-thaw and seawater erosion are conducted based on the large-scale static and dynamic stiffness servo test set. 50, 100, 200 and 300 cycles of freeze-thaw cycling are made on normal concrete, and the artificial seawater is produced. The reasonable wet and dry accelerate system is selected. 10, 20, 30, 40, 50 and 60 cycles of wet and dry cycling are made to concrete after freeze-thaw cycling. The degeneration law of the concrete elastic modulus and compressive strength is studied. The Ottosen tri-axial strength criterion considering cycles of freeze-thaw and wet and dry cycling is deduced based on uniaxial mechanical properties of concrete and damage theory. Experimental results show that with the increase in the number of wet and dry cycles and freeze-thaw cycles, the concrete axial compressive strength and the elastic modulus decline gradually. Tensile and compressive meridians of concrete shrink gradually. The research can be referenced for anti-crack design of actual structures eroded by seawater at cold regions.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 51769013)
文摘The typical loess on high slopes along the BaoLan High-speed Rail, China, was selected as the research object. The influence of the freeze-thaw cycle and dry-wet alternation on the shear-strength parameters of the unsaturated loess was investigated by laboratory experimental methods. Moreover, the temperature field, seepage field, and stability of slopes with different gradients were simulated under the effect of the freeze-thaw cycle and dry-wet alternation by using the geotechnical analysis software Geo-Studio. The research results showed(1) when the freeze-thaw cycle was repeated on the slope, with the frozen depth increasing, the melted depth did the same; besides, the closed loop of isotherms formed on the slope;(2) under the action of dry-wet circulation, the negative pore-water pressure and volumetric water content showed an upward tendency. However, owing to the different slope gradients, rainfall infiltration was not the same. As time went by, the differences of the negative pore-water pressure and volumetric water content between the slopes of different gradients continued to increase;(3) with the freeze-thaw cycle and dry-wet alternation increasing, the slope-safety factor decreased. Especially in the early period, the slope-safety factor changed remarkably. For slopes undergoing freeze-thaw action, the slope-safety factor was negatively correlated with the gradient. However, with regard to slopes undergoing dry-wet alternation, the result became more complex because the slope-safety factor was related to both seepage strength and slope grade. Accordingly, further research is needed to study the effect of seepage strength and slope grade on the stability of loess slopes.
基金supported by the National Natural Science Foundation of China(U20A2067,32272360)。
文摘A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles were investigated.The whiteness,water-holding capacity,storage modulus(G')and texture properties of the MPGs were significantly improved by adding 1%-2%Pickering emulsion(P<0.05).Meanwhile,Raman spectral analysis demonstrated that Pickering emulsion promoted the transformation of secondary structure,enhanced hydrogen bonds and hydrophobic interactions,and promoted the transition of disulfide bond conformation from g-g-g to g-g-t and t-g-t.At an emulsion concentration of 2%,theα-helix content decreased by 10.37%,while theβ-sheet content increased by 7.94%,compared to the control.After F-T cycles,the structure of the MPGs was destroyed,with an increase in hardness and a decrease in whiteness and water-holding capacity,however,the quality degradation of MPGs was reduced with 1%-2%Pickering emulsion.These findings demonstrated that SSOS-Pickering emulsions,as potential fat substitutes,can enhance the gel properties and the F-T stability of MPGs.
基金This research was supported by the National Natural Science Foundation of China(52108370)Jiangxi Provincial Natural Science Foundation(No.20212BAB214062,20224BAB204061).
文摘The frost deterioration and deformation of porous rock are commonly investigated under uniform freeze-thaw(FT)conditions.However,the unidirectional FT condition,which is also prevalent in engineering practice,has received limited attention.Therefore,a comparative study on frost deformation and microstructure evolution of porous rock under both uniform and unidirectional FT conditions was performed.Firstly,frost deformation experiments of rock were conducted under cyclic uniform and unidirectional FT action,respectively.Results illustrate that frost deformation of saturated rock exhibits isotropic characteristics under uniform FT cycles,while it shows anisotropic characteristics under unidirectional FT condition with both the frost heaving strain and residual strain along FT direction much higher than those perpendicular to FT direction.Moreover,the peak value and residual value of cumulative frost strain vary as logarithmic functions with cycle number under both uniform and unidirectional FT conditions.Subsequently,the microstructure evolution of rock suffered cyclic uniform and unidirectional FT action were measured.Under uniform FT cycles,newly generated pores uniformly distribute in rock and pore structure of rock remains isotropic in micro scale,and thus the frost deformation shows isotropic characteristics in macro scale.Under unidirectional FT cycles,micro-cracks or pore belts generate with their orientation nearly perpendicular to the FT direction,and rock structure gradually becomes anisotropic in micro scale,resulting in the anisotropic characteristics of frost deformation in macro scale.
基金Funded by the Key Project of Science and Technology Research in Higher Educational Institutions of Inner Mongolia Autonomous Region (No.NJZZ22518)Inner Mongolia Natural Science Foundation Project (No.2022MS05043)Inner Mongolia Autonomous Region Water Conservancy Research Special Project(No.NSK2016-S11)。
文摘After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and the 3D pore distribution curve before and after freezing and thawing. The fractal dimension is utilized to characterize the two-dimensional topography image and the three-dimensional pore distribution, quantitatively. The results reveal that the surface porosity and volume porosity increase as the freeze-thaw action increases. Self-similarity characteristics exist in micro-damage inside the concrete. In the fractal dimension, it is possible to characterize pore evolution quantitatively. The fractal dimension correlates with pore damage evolution. The fractal dimension effectively quantitatively characterizes micro-damage features at various scales from the local to the global level.
基金supported by the Second Tibet Plateau Scientific Expedition and Research Program(Grant No.2019QZKK0905)the Key Program of the National Natural Science Foundation of China(Grant No.41931285)the Key Research and Development Program of Shaanxi Province(Grant No.2019ZDLSF05-07).
文摘Due to climatic factors and rapid urbanization,the soil in the Loess Plateau,China,experiences the coupled effects of dry-wet cycles and chemical contamination.Understanding the mechanical behavior and corresponding microstructural evolution of contaminated loess subjected to dry-wet cycles is essential to elucidate the soil degradation mechanism.Therefore,direct shear and consolidation tests were performed to investigate the variations in mechanical properties of compacted loess contaminated with acetic acid,sodium hydroxide,and sodium sulfate during dry-wet cycles.The mechanical response mechanisms were investigated using zeta potential,mineral chemical composition,and scanning electron microscopy(SEM)tests.The results indicate that the mechanical deterioration of sodium hydroxidecontaminated loess during dry-wet cycles decreases with increasing contaminant concentration,which is mainly attributed to the thickening of the electrical double layer(EDL)by Nat and the precipitation of calcite,as well as the formation of colloidal flocs induced by OH,thus inhibiting the development of large pores during the dry-wet process.In contrast,the attenuation of mechanical properties of both acetic acid-and sodium sulfate-contaminated loess becomes more severe with increasing contaminant concentration,with the latter being more particularly significant.This is primarily due to the reduction of the EDL thickness and the erosion of cement in the acidic environment,which facilitates the connectivity of pores during dry-wet cycles.Furthermore,the salt expansion generated by the drying process of saline loess further intensifies the structural disturbance.Consequently,the mechanical performance of compacted loess is sensitive to both pollutant type and concentration,exhibiting different response patterns in the dry-wet cycling condition.
基金support from the Programa de Apoyos para la Superación del Personal Académico (DGAPA)the support by the Alexander von Humboldt Foundationpart of the SIREI project num 531062023178 developed at CCT-UV
文摘The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retraction of the glacier has left behind an intense climatic instability that causes a high frequency of freeze-thaw cycles of great intensity;the resulting geomorphological processes are represented by the fragmentation of the bedrock that occupies the upper parts of the mountain.There is a notable lack of studies regarding the fragmentation and erosion occurring in tropical high mountains,and the associated geomorphological risks;for this reason,as a first stage of future continuous research,this study analyzes the freezing and thawing cycles that occur above 4000 m asl,through continuous monitoring of surface ground temperature.The results allow us to identify and characterize four zones:glacial,paraglacial,periglacial and proglacial.It was found that the paraglacial zone presents an intense drop of temperature,of up to~9℃ in only sixty minutes.The rock fatigue and intense freeze-thaw cycles that occur in this area are responsible for the high rate of rock disintegration and represent the main factor of the constant slope dynamics that occur at the site.This activity decreases,both in frequency and intensity,according to the distance to the glacier,which is where the temperature presents a certain degree of stability,until reaching the proglacial zone,where cycles are almost non-existent,and therefore there is no gelifraction activity.The geomorphological processes have resulted in significant alterations to the mountain slopes,which can have severe consequences in terms of risk and water.
基金financially supported by the National Natural Science Foundation of China(42177166).
文摘Sandstone is the fundamental material in various engineering and construction projects.However,the mechanical integrity of sandstone can be compromised by initial unloading damage resulting from activities such as engineering excavations.Furthermore,this degradation is further exacerbated under periodic dry-wet environmental conditions.This study investigated the effects of dry-wet cycles and unloading on the mechanical properties of jointed fine sandstone using uniaxial and triaxial compression tests.These tests were performed on rock samples subjected to varying unloading degrees and different numbers of dry-wet cycles.The results demonstrate that with an increase in the unloading degree from 0%to 70%,there is a corresponding decrease in peak stress ranging from 10%to 33%.Additionally,the cohesion exhibits a reduction of approximately 20%to 25%,while the internal friction angle experiences a decline of about 3.5%to 6%.These findings emphasize a significant unloading effect.Moreover,the degree of peak stress degradation in unloading jointed fine sandstone diminishes with an increase in confining pressure,suggesting that confining pressure mitigates the deterioration caused by dry-wet cycles.Additionally,as the number of dry-wet cycles increases,there is a notable decline in the mechanical properties of the sandstone,evidencing significant dry-wet degradation.Utilizing the Drucker Prager criterion,this study establishes a strength criterion and fracture criterion,denoted as σ_(1)(m,n) and K_(T)^(Ⅱ)(m, n), to quantify the combined impacts of dry-wet cycles and unloading on jointed fine sandstone,which provides a comprehensive understanding of its mechanical behavior under such conditions.
文摘Ignimbrites have been widely used as building materials in many historical and touristic structures in the Kayseri region of Türkiye. Their diverse colours and textures make them a popular choice for modern construction as well. However, ignimbrites are particularly vulnerable to atmospheric conditions, such as freeze-thaw cycles, due to their high porosity, which is a result of their formation process. When water enters the pores of the ignimbrites, it can freeze during cold weather. As the water freezes and expands, it generates internal stress within the stone, causing micro-cracks to develop. Over time, repeated freeze-thaw (F-T) cycles lead to the growth of these micro-cracks into larger cracks, compromising the structural integrity of the ignimbrites and eventually making them unsuitable for use as building materials. The determination of the long-term F-T performance of ignimbrites can be established after long F-T experimental processes. Determining the long-term F-T performance of ignimbrites typically requires extensive experimental testing over prolonged freeze-thaw cycles. To streamline this process, developing accurate predictive equations becomes crucial. In this study, such equations were formulated using classical regression analyses and artificial neural networks (ANN) based on data obtained from these experiments, allowing for the prediction of the F-T performance of ignimbrites and other similar building stones without the need for lengthy testing. In this study, uniaxial compressive strength, ultrasonic propagation velocity, apparent porosity and mass loss of ignimbrites after long-term F-T were determined. Following the F-T cycles, the disintegration rate was evaluated using decay function approaches, while uniaxial compressive strength (UCS) values were predicted with minimal input parameters through both regression and ANN analyses. The ANN and regression models created for this purpose were first started with a single input value and then developed with two and three combinations. The predictive performance of the models was assessed by comparing them to regression models using the coefficient of determination (R2) as the evaluation criterion. As a result of the study, higher R2 values (0.87) were obtained in models built with artificial neural network. The results of the study indicate that ANN usage can produce results close to experimental outcomes in predicting the long-term F-T performance of ignimbrite samples.
基金jointly supported by the National Natural Science Foundation of China(Grant Number 12262018)the Technology Funding Scheme of China Construction Second Engineering Bureau LTD(Grant Number 2020ZX150002)Special Funds for Guiding Local Scientific and Technological Development by The Central Government(Grant Number 22ZY1QA005)。
文摘Moraines,characterized by the accumulation of rock and soil debris transported by glacial activity,present unique challenges for tunnel construction,particularly in portal sections,due to prevailing geographical and climatic conditions that facilitate freeze-thaw action.Despite these challenges,there is a dearth of studies investigating the influence of freeze-thaw action and water content on the mechanical properties of moraines,and no research on calculating surrounding rock pressure in moraine tunnels subjected to freeze-thaw conditions.In this study,direct shear tests under freeze-thaw cycles were conducted to examine the effects of freeze-thaw cycles and water content on the mechanical properties of frozen moraine.A comprehensive parameter K,integrating the number of freeze-thaws and water content,was introduced to model cohesion c.Drawing on Terzaghi Theory,we propose an improved algorithm for calculating surrounding rock pressure at the portal section of moraine tunnels.Using a tunnel as a case study,surrounding rock pressure was calculated under various conditions to validate the Improved Algorithm's efficacy.The results show that:(1)Strength loss exhibits a linear trend with the number of freeze-thaw cycles at water content levels of 4%and 8%,while at 12%water content,previous freeze-thaw cycles induce more significant damage to the soil.(2)Moraine saturation peaks between 8%and 12%water content.Following repeated freeze-thaw cycles,moraine shear strength initially increases before decreasing with varying water content.(3)The internal friction angle of moraine experiences slight reductions with prolonged freeze-thaw cycles,but both freeze-thaw cycles and water content significantly influence cohesion.(4)Vertical surrounding rock pressure increases after the initial freeze-thaw cycle,particularly with higher water content,although freeze-thaw cycles have minimal effect on it.(5)Freeze-thaw cycles lead to a substantial increase in lateral surrounding rock pressure,necessitating reinforced support structures at the arch wall,arch waist,and arch foot in engineering projects to mitigate freeze-thaw effects.This study provides a foundation for designing and selecting tunnel support structures in similar geological conditions.
基金the Key Laboratory of Intelligent Health Perception and Lakes,Ministry of Education,Hubei University of Technology(No.2020EJB004)National Natural Science Foundation of China(No.51508171)Natural Science Foundation of Hubei Province(No.2020CFB860).
文摘Chloride (Cl−) ion erosion effects can seriously impact the safety and service life of marine liquefied natural gas(LNG) storage tanks and other polar offshore structures. This study investigates the impact of different low-temperaturecycles (20°C, –80°C, and −160°C) and concrete specimen crack widths (0, 0.3, and 0.6 mm) on the Cl−ion diffusion performance through rapid erosion tests conducted on pre-cracked concrete. The results show thatthe minimum temperature and crack width of freeze-thaw cycles enhance the erosive effect of chloride ions. TheCl− ion concentration and growth rate increased with the increasing crack width. Based on the experimental modeland in accordance with Fick’s second law of diffusion, the Cl− ion diffusion equation was modified by introducingcorrection factors in consideration of the freeze-thaw temperature, crack width, and their coupling effect.The experimental and fitting results obtained from this model can provide excellent reference for practical engineeringapplications.
基金the Science and Technology program of Gansu Province(Grant No.23ZDFA017)the National Natural Science Foundation of China(Grant Nos.U21A2012,42101136)the Program for Top Leading Talents of Gansu Province(Granted to Dr.MingYi Zhang).
文摘Oil leakages cause environmental pollution,economic losses,and even engineering safety accidents.In cold regions,researchers urgently investigate the movement of oil spill in soils exposed to freeze-thaw cycles.In this study,a series of laboratory model experiments were carried out on the migration of oil leakage under freeze-thaw action,and the distributions of the soil temperature,unfrozen water content,and displacement were analyzed.The results showed that under freeze-thaw action,liquid water in soils migrated to the freezing front and accumulated.After the pipe cracked,oil pollutants first gathered at one side of the leak hole,and then moved around.The pipe wall temperature affected the soil temperature field,and the thermal influence range below and transverse the pipe wall(35–40 cm)was larger than that above the pipe wall(8 cm)owing to the soil surface temperature.The leaked oil's temperature would make the temperature of the surrounding soil rise.Oil would inhibit the cooling of the soils.Besides,oil migration was significantly affected by the gravity and water flow patterns.The freeze-thaw action would affect the migration of the oil,which was mainly manifested as inhibiting the diffusion and movement of oil when soils were frozen.Unfrozen water transport caused by freeze-thaw cycles would also inhibit oil migration.The research results would provide a scientific reference for understanding the relationship between the movement of oil pollutants,water,and soil temperature,and for establishing a waterheat-mass transport model in frozen soils.
基金financially sponsored by Qing Lan Project in Jiangsu Province of China(2023)Scientific Research Project of Taizhou Polytechnic College(TZYKY-22-4).
文摘The reuse of waste recycled concrete from harsh environments has become a research hotspot in the field of construction.This study investigated the repair effect of carbonation treatment on second-generation recycled fine aggregate(SRFA)obtained from recycled fine aggregate concrete(RFAC)subjected to freeze-thaw(FT)cycles.Before and after carbonation,the properties of SRFA were evaluated.Carbonated second-generation recycled fine aggregate(CSRFA)at five substitution rates(0%,25%,50%,75%,100%)to replace SRFA was used to prepare carbonated second-generation recycled fine aggregate concrete(CSRFAC).The water absorption,porosity and mechanical properties of CSRFAC were tested,and its frost-resisting durability was evaluated.The results showed after carbonation treatment,the physical properties of SRFA was improved and met the requirements of II aggregate.The micro-hardness of the interfacial transition zone and attached mortar in CSRFA was 50.5%and 31.2%higher than that in SRFA,respectively.With the increase of CSRFA replacement rate,the water absorption and porosity of CSRFAC gradually decreased,and the mechanical properties and frost resistance of CSRFAC were gradually improved.Carbonation treatment effectively repairs the damage of SRFA caused by FT cycles and improves its application potential.
基金the National Natural Science Foundation of China(Nos.52374147,42372328,and U23B2091)National Key Research and Development Program of China(No.2023YFC3804200)Xinjiang Uygur Autonomous Region Science and Technology Major Program(No.2023A01002).
文摘Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned mines.Its realization requires better understanding of the dynamic performance and durability of reservoir rock.This paper conducted ultrasonic detection,split Hopkinson pressure bar(SHPB)impact,mercury intrusion porosimetry(MIP),and backscatter electron observation(BSE)tests to investigate the dynamical behaviour and microstructure of sandstone with cyclical dry-wet damage.A coupling FEM-DEM model was constructed for reappearing mesoscopic structure damage.The results show that dry-wet cycles decrease the dynamic compressive strength(DCS)with a maximum reduction of 39.40%,the elastic limit strength is reduced from 41.75 to 25.62 MPa.The sieved fragments obtain the highest crack growth rate during the 23rd dry-wet cycle with a predictable life of 25 cycles for each rock particle.The pore fractal features of the macropores and micro-meso pores show great differences between the early and late cycles,which verifies the computational statistics analysis of particle deterioration.The numerical results show that the failure patterns are governed by the strain in pre-peak stage and the shear cracks are dominant.The dry-wet cycles reduce the energy transfer efficiency and lead to the discretization of force chain and crack fields.
基金The Chinese Academy of Sciences(CAS)Key Deployment Project of Centre for Ocean Mega-Research of Science under contract No.COMS2020Q07the Open Fund Project of Key Laboratory of Marine Environmental Information Technology,Ministry of Natural Resourcesthe National Natural Science Foundation of China under contract No.41901133.
文摘Arctic sea ice is broadly regarded as an indicator and amplifier of global climate change.The rapid changes in Arctic sea ice have been widely concerned.However,the spatiotemporal changes in the horizontal and vertical dimensions of Arctic sea ice and its asymmetry during the melt and freeze seasons are rarely quantified simultaneously based on multiple sources of the same long time series.In this study,the spatiotemporal variation and freeze-thaw asymmetry of Arctic sea ice were investigated from both the horizontal and vertical dimensions during 1979–2020 based on remote sensing and assimilation data.The results indicated that Arctic sea ice was declining at a remarkably high rate of–5.4×10^(4) km^(2)/a in sea ice area(SIA)and–2.2 cm/a in sea ice thickness(SIT)during 1979 to 2020,and the reduction of SIA and SIT was the largest in summer and the smallest in winter.Spatially,compared with other sub-regions,SIA showed a sharper declining trend in the Barents Sea,Kara Sea,and East Siberian Sea,while SIT presented a larger downward trend in the northern Canadian Archipelago,northern Greenland,and the East Siberian Sea.Regarding to the seasonal trend of sea ice on sub-region scale,the reduction rate of SIA exhibited an apparent spatial heterogeneity among seasons,especially in summer and winter,i.e.,the sub-regions linked to the open ocean exhibited a higher decline rate in winter;however,the other sub-regions blocked by the coastlines presented a greater decline rate in summer.For SIT,the sub-regions such as the Beaufort Sea,East Siberian Sea,Chukchi Sea,Central Arctic,and Canadian Archipelago always showed a higher downward rate in all seasons.Furthermore,a striking freeze-thaw asymmetry of Arctic sea ice was also detected.Comparing sea ice changes in different dimensions,sea ice over most regions in the Arctic showed an early retreat and rapid advance in the horizontal dimension but late melting and gradual freezing in the vertical dimension.The amount of sea ice melting and freezing was disequilibrium in the Arctic during the considered period,and the rate of sea ice melting was 0.3×10^(4) km^(2)/a and 0.01 cm/a higher than that of freezing in the horizontal and vertical dimensions,respectively.Moreover,there were notable shifts in the melting and freezing of Arctic sea ice in 1997/2003 and 2000/2004,respectively,in the horizontal/vertical dimension.
基金Project(2013YQ17046310)supported by the National Key Scientific Instrument and Equipment Development Project of ChinaProject(2013M542138)supported by China Postdoctoral Science FoundationProjects(20130162110010,20130162120012)supported by Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were conducted. After freezethaw, nuclear magnetic resonance(NMR) tests and impact loading tests were carried out, from which microscopic damage characteristics of sandstone and dynamic mechanical parameters were obtained. The results indicate that the porosity increases with the increase of cycle number, the rate of porosity growth descends at the beginning of freeze-thaw, yet accelerates after a certain number of cycles. The proportion of pores with different sizes changes dynamically and the multi-scale distribution of pores tends to develop on pore structure with the continuing impact of freeze-thaw and thawing. Dynamic compressive stress-strain curve of sandstone undergoing freeze-thaw can be divided into four phases, and the phase of compaction is inconspicuous compared with the static curve. Elastic modulus and dynamic peak intensity of sandstone gradually decrease with freeze-thaw cycles, while peak strain increases. The higher the porosity is, the more serious the degradation of dynamic intensity is. The porosity is of a polynomial relationship with the dynamic peak intensity.
基金Projects(41502327,51474252)supported by the National Natural Science Foundation of ChinaProject(2013YQ17046310)supported by the National Key Scientific Instrument and Equipment Development Project of China+1 种基金Project(20130162120012)supported by the Special Research Fund for the Doctoral Program of Higher Education of ChinaProject(2015CX005)supported by Innovation Driven Plan of Central South University,China
文摘In order to study the deterioration characteristics of the microscopic structure of sandstones in freeze-thaw cycles, tests of180 freeze-thaw cycles were performed on sandstone specimens. The nuclear magnetic resonance (NMR) technique was applied tothe measurement of sandstone specimens and analysis of the magnetic resonance imaging. Then, the fractal theory was employed tocompute the fractal dimension values of pore development of rocks after different freeze-thaw cycles. The results show that the massand porosity of rocks grow with the increase of freeze-thaw cycles. According to the NMR T2 distribution of sandstones, the poresizes of rock specimens increase after 180 freeze-thaw cycles, especially that of the medium-sized and small-sized pores. The spatialdistribution of sandstone pores after freeze-thaw cycles has fractal features within certain range, and the fractal dimension ofsandstones tends to increase gradually.
基金the grants from the National Natural Science Foundation of China (No. 30471377)the National Key Basic Research Program of China (No. 2007CB106803)the National Key Technologies R & D Program of China (No. 2006BAD26B0201-1)
文摘A laboratory simulated freeze-thaw was conducted to determine the effects of freeze-thaw on soil nutrient availability in temperate semi-arid regions. Soil samples were collected from sandy soils (0-20 cm) of three typical ecosystems (grassland, Mongolian pine plantation and poplar plantation) in southeastern Keerqin Sandy Lands of China and subjected to freeze-thaw treatment (-12℃ for 10 days, then r 20℃ for 10 days) or incubated at constant temperature (20℃ for 20 days). Concentrations of the soil NO3^--N, NH4^+-N, NaHCO3 extractable inorganic P (LPi) and microbial biomass P (MBP) were determined on three occasions: at the start of the incubation, immediate post-thawing and at the 10th day post-thawing. The results showed that soil net nitrification and N mineralization rates at three sites were negatively affected by freeze-thaw treatment, and decreased by 50%-85% as compared to the control, of which the greatest decline occurred in the soil collected from poplar plantation. In contrast, the concentration of soil NH4^+-N, NaHCO3 extractable inorganic P (LPi) and microbial biomass P were insignificantly influenced by freeze-thaw except that LPi and NH4^+-N showed a slight increase immediate post-thawing. The effects of freeze-thaw on soil N transformation were related to soil biological processes and the relatively constant available P was ascribed to severe soil aridity.
基金The National Natural Science Foundation of China(No.51378122)
文摘According to the winter temperature of Peking,the freeze-thaw(FT) condition in laboratory was determined.Seven groups of epoxy asphalt concrete(EAC) specimen were exposed to different FT cycles.The flexural modulus and fracture energy(G_F) of EAC exposed to different FT cycles were obtained through the 3-point bending test.Meanwhile,the plane strain fracture toughness(K_(IC)) of EAC was obtained through numerical simulation.The results show that the flexural modulus of the FT conditioned EAC samples decreases with the increase of FT cycles.The FT damage of flexural modulus is 60%after 30 FT cycles.Nevertheless,with the increase of FT cycles,the G_F and K_(IC) of EAC decrease first and then increase after 15 FT cycles.
基金The National Natural Science Foundation of China(No.5097822451378104)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘A theoretical prediction method based on the change of concrete material is proposed to evaluate the ultimate bending moment of concrete beams which have undergone freeze-thaw cycles (PTCs). First, the freeze-thaw damage on concrete material is analyzed and the residual compressive strength is chosen to indicate the freeze-thaw damage. Then, the equivalent block method is employed to simplify the compressive stress-strain curve of the freeze-thaw damaged concrete and the mathematical expression for the ultimate bending moment is obtained. Comparisons of the predicted results with the test data indicate that the ultimate bending moment of concrete beams affected by FTC attack can be predicted by this proposed method. However, the bond-slip behavior and the randomness of freeze-thaw damage will affect the accuracy of the predicted results, especially when the residual compressive strength is less than 50%.
基金The Natural Science Foundation of Shandong Province(No.ZR2009FQ020)the Ph.D.Programs Foundation of Ministry of Education of China(No.20100131120042)
文摘In order to effectively assess the mechanical properties of concrete with freeze-thaw and seawater erosion, tests about basic mechanical properties of concrete after freeze-thaw and seawater erosion are conducted based on the large-scale static and dynamic stiffness servo test set. 50, 100, 200 and 300 cycles of freeze-thaw cycling are made on normal concrete, and the artificial seawater is produced. The reasonable wet and dry accelerate system is selected. 10, 20, 30, 40, 50 and 60 cycles of wet and dry cycling are made to concrete after freeze-thaw cycling. The degeneration law of the concrete elastic modulus and compressive strength is studied. The Ottosen tri-axial strength criterion considering cycles of freeze-thaw and wet and dry cycling is deduced based on uniaxial mechanical properties of concrete and damage theory. Experimental results show that with the increase in the number of wet and dry cycles and freeze-thaw cycles, the concrete axial compressive strength and the elastic modulus decline gradually. Tensile and compressive meridians of concrete shrink gradually. The research can be referenced for anti-crack design of actual structures eroded by seawater at cold regions.