We report the rational design of a dual stimulus-activated quaternary chiral emission nematic liquid crystals(Q-N*-LCs)containing light-driven chiral dopant R-S-R-1,a static chiral dopant S-2 and an achiral Nile Red(N...We report the rational design of a dual stimulus-activated quaternary chiral emission nematic liquid crystals(Q-N*-LCs)containing light-driven chiral dopant R-S-R-1,a static chiral dopant S-2 and an achiral Nile Red(NR)in a nematic liquid crystal(SLC1717).The dopant R-S-R-1 acts as a dynamic chiral donor and an energy donor,and the achiral NR serves as a circularly polarized luminescence(CPL)emitter and energy acceptor.Interestingly,this kind of Q-N*-LCs appears reversal CPL emission direction(L-CPL)using 365 nm UV light irradiation compared with the initial state(R-CPL).Most importantly,the“On-Off”CPL switch behavior of Q-N*-LCs can be repeatedly driven by revoking or rearranging the applied direct current(DC)electric field.An OR chiral information logic gate demonstrates that this dual driven Q-N*-LCs can be potentially used for chiral information storage and coding.展开更多
基金supported by the National Natural Science Foundation of China (21975118,92156014)
文摘We report the rational design of a dual stimulus-activated quaternary chiral emission nematic liquid crystals(Q-N*-LCs)containing light-driven chiral dopant R-S-R-1,a static chiral dopant S-2 and an achiral Nile Red(NR)in a nematic liquid crystal(SLC1717).The dopant R-S-R-1 acts as a dynamic chiral donor and an energy donor,and the achiral NR serves as a circularly polarized luminescence(CPL)emitter and energy acceptor.Interestingly,this kind of Q-N*-LCs appears reversal CPL emission direction(L-CPL)using 365 nm UV light irradiation compared with the initial state(R-CPL).Most importantly,the“On-Off”CPL switch behavior of Q-N*-LCs can be repeatedly driven by revoking or rearranging the applied direct current(DC)electric field.An OR chiral information logic gate demonstrates that this dual driven Q-N*-LCs can be potentially used for chiral information storage and coding.
