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Flight Time Minimization of UAV for Cooperative Data Collection in Probabilistic LoS Channel
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作者 Yan Li Shaoyi Xu +1 位作者 Yunpu Wu Dongji Li 《China Communications》 SCIE CSCD 2024年第2期210-226,共17页
This paper investigates the data collection in an unmanned aerial vehicle(UAV)-aided Internet of Things(IoT) network, where a UAV is dispatched to collect data from ground sensors in a practical and accurate probabili... This paper investigates the data collection in an unmanned aerial vehicle(UAV)-aided Internet of Things(IoT) network, where a UAV is dispatched to collect data from ground sensors in a practical and accurate probabilistic line-of-sight(LoS) channel. Especially, access points(APs) are introduced to collect data from some sensors in the unlicensed band to improve data collection efficiency. We formulate a mixed-integer non-convex optimization problem to minimize the UAV flight time by jointly designing the UAV 3D trajectory and sensors’ scheduling, while ensuring the required amount of data can be collected under the limited UAV energy. To solve this nonconvex problem, we recast the objective problem into a tractable form. Then, the problem is further divided into several sub-problems to solve iteratively, and the successive convex approximation(SCA) scheme is applied to solve each non-convex subproblem. Finally,the bisection search is adopted to speed up the searching for the minimum UAV flight time. Simulation results verify that the UAV flight time can be shortened by the proposed method effectively. 展开更多
关键词 data collection flight time probabilistic line-of-sight channel unlicensed band unmanned aerial vehicle
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Time-of-Flight透散射介质成像技术综述 被引量:1
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作者 王霞 张艺馨 +1 位作者 赵雨薇 金伟其 《红外与激光工程》 EI CSCD 北大核心 2023年第2期370-381,共12页
Time-of-Flight (ToF)成像是利用光在目标和相机之间的飞行时间来获取场景的深度信息,具有体积小、成本低、实时成像等优势。在散射环境中,由于散射介质对光的散射作用,ToF成像受到多径干扰的影响,深度测量误差较大,限制了ToF相机在散... Time-of-Flight (ToF)成像是利用光在目标和相机之间的飞行时间来获取场景的深度信息,具有体积小、成本低、实时成像等优势。在散射环境中,由于散射介质对光的散射作用,ToF成像受到多径干扰的影响,深度测量误差较大,限制了ToF相机在散射场景中的应用。ToF透散射介质成像技术是校正因散射光引起的多径干扰效应,从传感器接收到的混叠信号中分离出目标分量,实现散射场景中的深度信息恢复,其在雾天自动驾驶、水下勘测、生物医学等领域具有广阔的应用前景。依据ToF成像系统的不同,详细介绍了PL-ToF和CW-ToF成像的基本原理,阐述和分析了散射场景中ToF稳态成像和瞬态成像的机理和特点,分别回顾和总结了ToF稳态成像和瞬态成像的透散射介质成像研究现状,并介绍了ToF透散射介质成像的应用前景,最后依据现有ToF透散射介质成像技术的优缺点,对未来发展趋势进行了展望。 展开更多
关键词 成像系统 透散射介质成像 time-of-flight相机 稳态成像 瞬态成像
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Analyzing crude oils from the Junggar Basin(NW China) using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry(GC×GC-TOFMS) 被引量:1
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作者 Yuce Wang Wanyun Ma +2 位作者 Ni Zhou Jiangling Ren Jian Cao 《Acta Geochimica》 EI CAS CSCD 2017年第1期66-73,共8页
As a new technology of analyzing crude oils, comprehensive two-dimensional gas chromatography cou- pled with time-of-flight mass spectrometry (GCxGC- TOFMS) has received much research attention. Here we present a ca... As a new technology of analyzing crude oils, comprehensive two-dimensional gas chromatography cou- pled with time-of-flight mass spectrometry (GCxGC- TOFMS) has received much research attention. Here we present a case study in the Junggar Basin of NW China. Results show that the hydrocarbons, including saturates and aromatics, were all well-separated without large co- elution, which cannot be realized by conventional one-dimensional GC-MS. The GC×GC technique is especially effective for analyzing aromatics and low-to-middle- molecular-weight hydrocarbons, such as diamondoids. The geochemical characteristics of crude oils in the study area were investigated through geochemical parameters extracted by GC×GC-TOFMS, improving upon the understanding obtained by GC-MS. Thus, the work here represents a new successful application of GC×GC- TOFMS, showing its broad usefulness in petroleum geochemistry. 展开更多
关键词 Comprehensive two dimensional gas chromatography coupled with time of flight mass spectrometry (GCxGC TOFMS) Petroleum geochemistry Biomarkers Diamondoid Junggar Basin
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FPGA-based High-precision Measurement Algorithm for the Ultrasonic Echo Time of Flight 被引量:3
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作者 王伯雄 张金 《Journal of Measurement Science and Instrumentation》 CAS 2010年第2期103-107,共5页
Based on the evaluation of advantages and disadvantages of high-precision digital time interval measuring algorithms, and combined with the principle of the typical time-difference ultrasonic flow measurement, the req... Based on the evaluation of advantages and disadvantages of high-precision digital time interval measuring algorithms, and combined with the principle of the typical time-difference ultrasonic flow measurement, the requirements for the measurement of echo time of flight put forward by the ultrasonic flow measurement are analyzed. A new high-precision time interval measurement algorithm is presented, which combines the pulse counting method with the phase delay interpolation. The pulse counting method is used to ensure a large dynamic measuring range, and a double-edge triggering counter is designed to improve the accuracy and reduce the counting quantization error. The phase delay interpolation is used to reduce the quantization error of pulse counting for further improving the time measurement resolution. Test data show that the systexn for the measurement of the ultrasonic echo time of flight based on this algorithm and implemented on an Field Programmable Gate Army(FleA) needs a relatively short time for measurement, and has a measurement error of less than 105 ps. 展开更多
关键词 ultrasonic flow measurement time of flight phase delay interpolation
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High Accuracy Time of Flight Measurement Using Digital Signal Processing Techniques for Subsea Applications 被引量:2
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作者 Muhammad Ashraf Hamza Qayyum 《Journal of Signal and Information Processing》 2011年第4期330-335,共6页
The techniques widely used in ultrasonic measurements are based on the determination of the time of flight (T.o.F). A short train of waves is transmitted and same transducer is used for reception of the reflected sign... The techniques widely used in ultrasonic measurements are based on the determination of the time of flight (T.o.F). A short train of waves is transmitted and same transducer is used for reception of the reflected signal for the pulse-echo measurement applications. The amplitude of the received waveform is an envelope which starts from zero reaches to a peak and then dies out. The echoes are mostly detected by simple threshold crossing technique, which is also cause of error. In this paper digital signal processing is used to calculate the time delay in reception i.e. T.o.F, for which a maximum similarity between the reference and the delayed echo signals is obtained. To observe the effect of phase uncertainties and frequency shifts (Doppler), this processing is carried out, both directly on the actual wave shape and after extracting the envelopes of the reference and delayed echo signals. Several digital signal processing algorithms are considered and the effects of different factors such as sampling rate, resolution of digitization and S/N ratio are analyzed. Result show accuracy, computing time and cost for different techniques. 展开更多
关键词 SONAR SIGNAL PROCESSING time of flight
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A New Method for Detecting Internal Defects in Composite Materials Based on Time of Flight 被引量:1
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作者 ZHI Fan ZHANG Ying +2 位作者 SUN Jianbo LUO Ming LU Wu 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2022年第3期314-325,共12页
Carbon-fiber reinforced polymer composites have been widely used to achieve the light-weighted design and high performance due to superior performance. Internal defects in the composite materials are the main factors ... Carbon-fiber reinforced polymer composites have been widely used to achieve the light-weighted design and high performance due to superior performance. Internal defects in the composite materials are the main factors that determine their performance,which makes reliable and effective detection methods of internal defects essential. Nondestructive testing(NDT)methods are the most widely-used way due to their tremendous advantages. Though the theoretical background is found,experimental results could be quite complicated and confusing,especially for composite materials with complex defects characteristics. In this paper,experimental study on internal defects in composite materials based on the time of flight(ToF)are investigated. The Gaussian echo model and the parameter estimation methods are established to build a theoretical model for measurements. Then,the distance amplitude correction(DAC)method is proposed to effectively improve the signal-to-noise ratio(SNR)and to reduce distortion of the signal during measurements. Finally,the ToF is adopted to determine depth of internal defects. Experiment study is conducted to investigate the porosity defects and the anti-impact performance of composite materials,as well as defects in objects with various thicknesses. Experimental results show that the proposed method is quite helpful for obtaining the intuition and deep understanding of internal defects,thus contributing to the determination of product performance and its improvement. 展开更多
关键词 ultrasonic non-destructive testing time of flight porosity defects anti-impact performance distance amplitude correction(DAC)method
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Design and simulation of time-of-flight neutron reflectometer 被引量:2
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作者 LI Xinxi WANG Yan HUANG Chaoqiang CHEN Bo 《Nuclear Science and Techniques》 SCIE CAS CSCD 2010年第3期157-160,共4页
In this paper,a time of flight neutron reflectometer model is proposed.According to the original objective inputting physical parameters and expectations,computer simulation was done by McStas package.With the open sl... In this paper,a time of flight neutron reflectometer model is proposed.According to the original objective inputting physical parameters and expectations,computer simulation was done by McStas package.With the open slit, neutron flux at sample position was about 1×10~5 n·cm^(-2)·S^(-1),and the optimal resolution could reach 0.5%.The results show that the model has a good performance.The design of this model can be an instruction for neutron reflectometer construction or project analysis in the future. 展开更多
关键词 反射模型 中子通量 飞行时间 设计 仿真 计算机模拟 最佳分辨率 物理参数
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Automatic Feature Point Detection and Tracking of Human Actions in Time-of-flight Videos 被引量:8
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作者 Xiaohui Yuan Longbo Kong +1 位作者 Dengchao Feng Zhenchun Wei 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2017年第4期677-685,共9页
Detecting feature points on the human body in video frames is a key step for tracking human movements. There have been methods developed that leverage models of human pose and classification of pixels of the body imag... Detecting feature points on the human body in video frames is a key step for tracking human movements. There have been methods developed that leverage models of human pose and classification of pixels of the body image. Yet, occlusion and robustness are still open challenges. In this paper, we present an automatic, model-free feature point detection and action tracking method using a time-of-flight camera. Our method automatically detects feature points for movement abstraction. To overcome errors caused by miss-detection and occlusion, a refinement method is devised that uses the trajectory of the feature points to correct the erroneous detections. Experiments were conducted using videos acquired with a Microsoft Kinect camera and a publicly available video set and comparisons were conducted with the state-of-the-art methods. The results demonstrated that our proposed method delivered improved and reliable performance with an average accuracy in the range of 90 %.The trajectorybased refinement also demonstrated satisfactory effectiveness that recovers the detection with a success rate of 93.7 %. Our method processed a frame in an average time of 71.1 ms. 展开更多
关键词 Feature point human pose detection joint detection time-of-flight(ToF) videos
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Liquid chromatography coupled with time-of-flight and ion trap mass spectrometry for qualitative analysis of herbal medicines 被引量:11
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作者 Xiao-Fei Chen Hai-Tang Wu +2 位作者 Guang-Guo Tan Zhen-Yu Zhu Yi-Feng Chai 《Journal of Pharmaceutical Analysis》 SCIE CAS 2011年第4期235-245,共11页
With the expansion of herbal medicine (HM) market, the issue on how to apply up-to- date analytical tools on qualitative analysis of HMs to assure their quality, safety and efficacy has been arousing great attention... With the expansion of herbal medicine (HM) market, the issue on how to apply up-to- date analytical tools on qualitative analysis of HMs to assure their quality, safety and efficacy has been arousing great attention. Due to its inherent characteristics of accurate mass measurements and multiple stages analysis, the integrated strategy of liquid chromatography (LC) coupled with time-of-flight mass spectrometry (TOF-MS) and ion trap mass spectrometry (IT-MS) is well-suited to be performed as qualitative analysis tool in this field. The purpose of this review is to provide an overview on the potential of this integrated strategy, including the review of general features of LC-IT-MS and LC-TOF-MS, the advantages of their combination, the common procedures for structure elucidation, the potential of LC-hybrid-IT-TOF/MS and also the summary and discussion of the applications of the integrated strategy for HM qualitative analysis (2006-2011). The advantages and future developments of LC coupled with IT and TOF-MS are highlighted. 展开更多
关键词 High-performanceliquid chromatography(HPLC) time-of-flight massspectrometry(TOF-MS) Ion trap massspectrometry (IT-MS) Herbal medicine (HM)
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Calculation of the reactor neutron time of flight spectrum by convolution technique
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作者 程金星 欧阳晓平 +2 位作者 郑毅 张安慧 欧阳茂解 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第8期2881-2884,共4页
It is a very complex and time-consuming process to simulate the nuclear reactor neutron spectrum from the reactor core to the export channel by applying a Monte Carlo program. This paper presents a new method to calcu... It is a very complex and time-consuming process to simulate the nuclear reactor neutron spectrum from the reactor core to the export channel by applying a Monte Carlo program. This paper presents a new method to calculate the neutron spectrum by using the convolution technique which considers the channel transportation as a linear system and the transportation scattering as the response function. It also applies Monte Carlo Neutron and Photon Transport Code (MCNP) to simulate the response function numerically. With the application of convolution technique to calculate the spectrum distribution from the core to the channel, the process is then much more convenient only with the simple numerical integral numeration. This saves computer time and reduces some trouble in re-writing of the MCNP program. 展开更多
关键词 convolution technique neutron transportation time of flight response function time spectrum
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Estimation of Standard Operation Time of Flight Legs Based on Clustering and Probability Analysis
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作者 Yuan Ligang Hu Minghua +1 位作者 Xie Hua Li Yinfeng 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2016年第4期491-501,共11页
A clustering algorithm and a probability statistics method were applied to different phases of a flight to analyze operation time during aircraft ground taxiing and airborne flight.And the clustering pattern,distribut... A clustering algorithm and a probability statistics method were applied to different phases of a flight to analyze operation time during aircraft ground taxiing and airborne flight.And the clustering pattern,distribution characteristics and dynamically changing rules of the two phases were identified.Further,an estimate method was established to measure operation time of flight legs,with creative steps of calculating individual segment separately and then integrating them accordingly.The method can both objectively and dynamically measure operation time,and accurately reflect real situation.It helps to better utilize airport slot resources and provides a strong support for air traffic flow management when scheduling flight plan in strategic and pre-tactic phases. 展开更多
关键词 flight leg standard operation time CLUSTERING probability analysis
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A novel sample preparation method of matrix-assisted laser desorption/ionization time of flight mass spectrometry for polystyrene
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作者 Shu Zhang Zhen Wen Zhao +3 位作者 Lei Xiong Bin Xin Wei Hua Hu Shao Xiang Xiong 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第6期718-721,共4页
A novel sample preparation method of matrix-assisted laser desorption/ionization mass spectrometry for polystyrene was reported. Compared to the conventional dried-droplet method, the efficiency of ionization and sign... A novel sample preparation method of matrix-assisted laser desorption/ionization mass spectrometry for polystyrene was reported. Compared to the conventional dried-droplet method, the efficiency of ionization and signal intensity of mass spectra were improved. The mechanism was also analyzed. 展开更多
关键词 POLYSTYRENE Matrix-assisted laser desorption/ionization time of flight mass spectrometry Three-layer method
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Two-dimensional gel electrophoresis and surface-enhanced laser desorption ionization-time of flight-mass spectrometry for detection of protein expression profiles in the hippocampus following closed brain injury 被引量:2
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作者 Qingming Shu Zhiqiang Li +3 位作者 Shuwang Yang Lingzhi Li Xiao Bai Yongliang Zhang 《Neural Regeneration Research》 SCIE CAS CSCD 2010年第23期1795-1801,共7页
Gene expression profile changes in brain regions following traumatic brain injury at the gene level cannot sufficiently elucidate gene expression time, expression amount, protein post-translational processing or modif... Gene expression profile changes in brain regions following traumatic brain injury at the gene level cannot sufficiently elucidate gene expression time, expression amount, protein post-translational processing or modification. Therefore, it is necessary to quantitatively analyze the gene expression profile using proteomic techniques. In the present study, we established a rat model of closed brain injury using Marmarou's weight-drop device, and investigated hippocampal differential protein expression using two-dimensional gel electrophoresis and surface-enhanced laser desorption ionization-time of flight-mass spectrometry. A total of 364 protein peaks were detected on weak cation exchange-2 protein chips, including 37 differential protein peaks. 345 protein peaks were detected on immobilized metal affinity capture arrays-Cu, including 12 differential protein peaks Further examination of these differential proteins revealed that glucose-regulated protein and proteasome subunit alpha type 3 expression were significantly upregulated post-injury. These results indicate that brain injury can alter protein expression in the hippocampus, and that glucose-regulated protein and proteasome subunit alpha type 3 are closely associated with the occurrence and development of traumatic brain injury. 展开更多
关键词 surface-enhanced laser desorption ionization-time of flight-mass spectrometry two-dimensional gel electrophoresis HIPPOCAMPUS PROTEOMICS brain injury neural regeneration
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Resonance-Enhanced Multiphoton Ionization Combined with Time-of-Flight MS for Study on Dehydro-aromatization of Methane over Mo/HZSM-5 被引量:1
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作者 WANGBingxing XIEYan +2 位作者 WANGLi baijILING HEGuozhong 《催化学报》 SCIE CAS CSCD 北大核心 2003年第4期241-242,共2页
关键词 MO/HZSM-5 多光子电离 甲烷 飞行时间质谱 脱氢芳构化反应 分子筛负载钼催化剂
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Screening for Plant Toxins in Honey and Herbal Beverage by Ultrahigh-Performance Liquid Chromatography-Ion Mobility-Quadrupole Time of Flight Mass Spectrometry
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作者 Qiaozhen Guo Yi Yang +2 位作者 Jiang Li Bing Shao Jing Zhang 《American Journal of Analytical Chemistry》 2022年第3期108-134,共27页
The standards of plant toxins were separated by a C18 column with gradient elution with 0.1% formic acid/water (V/V) and 0.1% formic acid/acetonitrile (V/V) as mobile phase and acquired by ion mobility-quadrupole time... The standards of plant toxins were separated by a C18 column with gradient elution with 0.1% formic acid/water (V/V) and 0.1% formic acid/acetonitrile (V/V) as mobile phase and acquired by ion mobility-quadrupole time of flight mass spectrometry (IM-QTOF MS) in positive ion mode. A database of 308 plant toxins including retention time, collision cross-section (CCS) and its fragment ions was established. Honey dissolved in water or herbal beverage was extracted by acetonitrile and purified with PSA sorbent, and then acquired by ultrahigh-performance liquid chromatography IM-QTOFMS. The acquired data were processed by comparing with the database we established to confirm the target compounds. The average recoveries for samples at two levels ranged from 60.6% - 120.1%, with relative standard deviation (n = 6) less than 25%. The limit of quantitation for plant toxins ranged from 1 - 20 μg/kg. The developed screening method was used in determination of honey, herbal beverage and honey flavored tea beverage samples. The results showed that berberine was detected in one honey with 1 μg/kg and caffeine was present in some beverages with the concentration from 200 and 5500 μg/kg. This method could meet the requirement for rapid screening of plant toxins in honey and herbal beverage. It can be used for the quality control of honey and herbal beverage in enterprises or quality inspection departments. It also can be used in the rapid screening of food poisoning. 展开更多
关键词 SCREENING Plant Toxins HONEY Herbal Beverage Ultrahigh-Performance Liquid Chromatography ion Mobility-Quadrupole time of flight Mass Spectrometry
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Implementation of spatial touch system using time-of-flight camera
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作者 AHN Yang-Keun PARK Young-Choong CHOI Kwang-Soon PARK Woo-Chool SEO Hae-Moon JUNG Kwang-Mo 《重庆邮电大学学报(自然科学版)》 北大核心 2009年第2期222-227,共6页
Recently developed time-of-flight principle based depth-sensing video camera technologies provide precise per-pixel range data in addition to color video. Such cameras will find application in robotics and vision-base... Recently developed time-of-flight principle based depth-sensing video camera technologies provide precise per-pixel range data in addition to color video. Such cameras will find application in robotics and vision-based human computer interaction scenarios such as games and gesture input systems. Time-of-flight principle range cameras are becoming more and more available. They promise to make the 3D reconstruction of scenes easier, avoiding the practical issues resulting from 3D imaging techniques based on triangulation or disparity estimation. A spatial touch system was presented which uses a depth-sensing camera to touch spatial objects and details on its implementation, and how this technology will enable new spatial interactions was speculated. 展开更多
关键词 飞行时间 输入系统 空间对象 照相机 三维成像技术 空间相互作用 彩色图像 人机交互
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Simulation Analysis of the Effect of Relaxation Time on Flight Delays Propagation
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作者 QUE Zufu YAO Hongguang 《International English Education Research》 2016年第7期79-82,共4页
Relaxation time of flights is one of the main factors that affect the diffusion of flight delays, but the specific relationship between them is ambiguous.?Gaining a clear idea of their relationship conduces to the co... Relaxation time of flights is one of the main factors that affect the diffusion of flight delays, but the specific relationship between them is ambiguous.?Gaining a clear idea of their relationship conduces to the control of flight delays.?Through the establishment of the aviation network model and simulation analysis of the effect of relaxation time on delay spread, it can be found that the relaxation time is inversely proportional to the total delay time and the number of airports that have been delayed due to the delay spread, and there is no evident linear relationship between the relaxation time and the average delay time.?This demonstrates that increasing the relaxation time properly can reduce the propagation of flight delays and improve the punctuality rate of flights. 展开更多
关键词 Aviation network Relaxation time flight delays ongitudinal diffusion
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New Fragmentation Pathways for Cephalosporins by Electrospray Ionization Quadrupole Time-of-flight Mass Spectrometry
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作者 WANGYing-wu GUJing-kai +2 位作者 J.PaulFawcett ZHONGDa-fang ZHOUHui 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第3期376-379,共4页
关键词 CEPHALOSPORINS time-of-flight mass spectrometry Fragmentation pathway
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CO<sub>2</sub>Absorption Solvent Degradation Compound Identification Using Liquid Chromatography-Mass Spectrometry Quadrapole-Time of Flight (LCMSQTOF) 被引量:1
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作者 Nurida Mohd Yusop Voon Chang Hong +1 位作者 Chan Zhe Phak Zaimi Naim 《Journal of Analytical Sciences, Methods and Instrumentation》 2020年第3期78-95,共18页
The degradation of the alkanolamine solvent used in the removal of acid gases from natural gas streams due to exposure to contaminants, thermal degradation and presence of oxygen or oxygen containing compounds will ch... The degradation of the alkanolamine solvent used in the removal of acid gases from natural gas streams due to exposure to contaminants, thermal degradation and presence of oxygen or oxygen containing compounds will change the solvent properties, such as heat transfer coefficient, diffusion coefficient, and mass transfer coefficient of the solvent. Therefore, characterization and quantification of amine degradation product becomes one of the important analyses to determine alkanolamine solvent’s health. In order to identify degradation products of alkanolamine solvent, analytical strategies by using mass spectrometry (MS) as detector have been studied extensively. In this work, due to the low concentration of the amine degradation product, a method was developed for identification of alkanolamine degradation products using LCMS-QTOF technique. A strategy for identification of trace degradation products has been identified. Six (6) alkanolamine degradation products had been identified by using LCMS-QTOF targeted analysis in the blended alkanolamine solvent used in natural gas processing plant. Another fifteen (15) molecular formulas having similarity in chemical structure to alkanolamine degradation products were identified using untargeted analysis strategy, as possible compounds related to degradation products. Using LCMS-QTOF via targeted and untargeted analysis strategy, without tedious column separation and reference standard, enables laboratory to provide a quick and indicative information for alkanolamine solvent’s organic degradation compounds identification in CO<sub>2</sub> adsorption, within reasonable analysis time. 展开更多
关键词 CO2 Absorption Solvent Degradation Compound Liquid Chromatography-Mass Spectrometry Quadrupole-time of flight (LCMSQTOF)
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Studies on Fragmentation Regularity of 5-Methoxycarbonyl- 4-substituted-6-methyl-3,4-dihydropyrimidin-2(1H)-ones by Time-of-flight Mass Spectrometry
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作者 LIQian-rong SALEHIHojatollah +1 位作者 YINHao GUOQing-xiang 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第6期729-733,共5页
The electron impact time-of-flight(TOF) mass spectra of the title compounds were studied to establish their fragmentation processes. With the high resolution of the TOF instrument, the exact mass for each fragment was... The electron impact time-of-flight(TOF) mass spectra of the title compounds were studied to establish their fragmentation processes. With the high resolution of the TOF instrument, the exact mass for each fragment was determined. These data were used to infer the molecular formulas and the elemental compositions for all the molecular ions and fragments through software interpretation. By further applying the fragmentation regularity, the majority of ions were fully assigned. The main fragmentation pathways of the title compounds include the formation of molecular ions by the loss of R 1 groups in the 4-position and the ester groups in the 5-position. The formed ion can be further fragmented by the elimination of MeOH. 展开更多
关键词 3 4-Dihydropyrimidinone time-of-flight mass spectrometry Electron impact
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