The reserves of the Duobaoshan porphyry Cu-Au-Mo-Ag deposit(also referred to as the Duobaoshan porphyry Cu deposit)ranks first among the copper deposits in China and 33rd among the porphyry copper deposits in the worl...The reserves of the Duobaoshan porphyry Cu-Au-Mo-Ag deposit(also referred to as the Duobaoshan porphyry Cu deposit)ranks first among the copper deposits in China and 33rd among the porphyry copper deposits in the world.It has proven resources of copper(Cu),molybdenum(Mo),gold(Au),and silver(Ag)of 2.28×10^(6)t,80×10^(3)t,73 t,and 1046 t,respectively.The major characteristics of the Duobaoshan porphyry Cu deposit are as follows.It is located in a zone sandwiched by the Siberian,North China,and paleo-Pacific plates in an island arc tectonic setting and was formed by the Paleozoic mineralization and the Mesozoic mineralization induced by superposition and transformation.The metallogenic porphyries are the Middle Hercynian granodiorite porphyries.The alterations of surrounding rocks are distributed in a ring form.With silicified porphyries at the center,the alteration zones of K-feldspar,biotite,sericite,and propylite occur from inside to outside.This deposit is composed of 215 ore bodies(including 14 major ore bodies)in four mineralized zones.Ore body No.X in the No.3 mineralized zone has the largest resource reserves,accounting for more than 78%of the total reserves of the deposit.Major ore components include Cu,Mo,Au,Ag,Se,and Ga,which have an average content of 0.46%,0.015%,0.16 g/t,1.22 g/t,0.0003%,and 0.001%-0.003%,respectively.The ore minerals of this deposit primarily include pyrite,chalcopyrite,bornite,and molybdenite,followed by magnetite,hematite,rutile,gelenite,and sphalerite.The ore-forming fluids of this deposit were magmatic water in the early metallogenic stage and then the mixture of meteoric water and magmatic water at the late metallogenic stage.The ore-forming fluids experienced three stages.The ore-forming fluids of stageⅠhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 375-650℃,and ore-forming pressure of 110-160 MPa.The ore-forming fluids of stageⅡhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 310-350℃,and ore-forming pressure of 58-80 MPa.The ore-forming fluids of stageⅢhad a hydrochemical type of Na Cl-H_(2)O,an ore-forming temperature of 210-290℃,and ore-forming pressure of 5-12 MPa.The CuAu-Mo-Ag mineralization mainly occurred at stagesⅠandⅡ,with the ore-forming materials having a mixed crust-mantle source.The Duobaoshan porphyry Cu deposit was formed in the initial subduction environment of the Paleo-Asian Ocean Plate during the Early Ordovician.Then,due to the closure of the Mongol-Okhotsk Ocean and the subduction and compression of the Paleo-Pacific Ocean,a composite orogenic metallogenic model of the deposit was formed.In other words,it is a porphyry-epithermal copper-gold polymetallic mineralization system of composite orogeny consisting of Paleozoic island arcs and Mesozoic orogeny and extension.展开更多
The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming f...The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H20-NaCI-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The oreforming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep.展开更多
The Duobaoshan mine area in Heilongjiang is located in the northeast section of Xingmeng orogenic belt and is in the west side of Hegang Mountain-Heihe fault zone. There exist many deposits in this area,and its metall...The Duobaoshan mine area in Heilongjiang is located in the northeast section of Xingmeng orogenic belt and is in the west side of Hegang Mountain-Heihe fault zone. There exist many deposits in this area,and its metallogenic conditions are superior,which has been one of the hotspots in geological prospecting and metallogenic research in Northeast China. On the basis of previous studies,the authors used the EH-4 electromagnetic imaging system to carry out the data acquisition of three survey lines in Woduhe Village,Duobaoshan Town,Nenjiang County. Through the analysis of apparent resistivity section under TE and TM polarization modes,integrating regional geological data,it is concluded that:(1) the electrical characteristics of the metal ore in this area show a relatively low resistance,and according to its resistivity difference with surrounding rocks,the geometrical structures and apparent resistivity parameters of the low resistivity bodies in the lower section of the survey line are defined,and the electrical anomalies can be identified;(2)faults F1 and F2 may have a good metallogenic environment,so they are recommended for further exploration;(3) low resistance metal ore bodies have good correlation with local small structures or faults,which may play an iconic role for the delineation of key target areas;(4) in the process of using apparent resistivity to define the geometric structures of ore bodies underground,comprehensive analysis integrating the advantages of TE and TM models should be carry out to achieve more reliable inversion results.展开更多
1 Geological Background of Minerlization or Geologic Setting The northeast of Yunnan1 Pb-Zn-Ag-Ge polymetallic ore district is an important part of the southwestern margin of the Yangtze block Sichuan-Yunnan-Guizhou
1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this ...1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this paper,展开更多
1 Introduction The Lehonglead-zincdeposit is a large-sized Pb-Zn depositnewly found in recent years in the Sichuan-Yunnan-Guizhou Lead-zinc Poly-metallic Mineralization Area,which occurrenceis strictly
1 Introduction The Wuzhishan lead-zinc ore-concentrated area in Puding is located in the east of the Sichuan,Guizhou and Yunnan lead-zinc metallogenic domain,with the Youjiang-Nanpan River metallogenic province to the
Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide m...Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.展开更多
The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covere...The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covered by eluvial-deluvial lateritic layer, without any mineralized outcrops. The main concealed orebody V3 is buffed in the depth of 300-500m. The orebodies are controlled by certain stratigraphic horizons, and most are cut by strata with a high angle, while a few occur along the strata. The direct wall rocks are calcisiltite, calclithite, bioclastic calcarenite,展开更多
Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological resea...Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological research and mineral exploration(Li Bile et al., 2015). The Qimantag Mountain is located in middle segment of the EKO, which has experienced the Early Paleozoic and Late Paleozoic–Early展开更多
An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits a...An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits association and zoning laws.展开更多
Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimen...Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimental Investigation of Integrated Prospecting Technology for Concealed Carbonate-Type Lead-Zinc Deposits in the Region of Sichuan, Yunnan and Guizhou Provinces". This project has been implemented by the Chengdu Center of China Geological Survey since 2013, and the project has run for 3 years. The general objective of this project is to establish an effective and adaptable integrated prospecting methodology (including geological, geophysical and geochemical techniques) in search for deep concealed lead-zinc deposits.展开更多
The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China...The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China. Sulfides minerals including sphalerite, galena and pyrite postdate or coprecipitate with gangue mainly consisting of fluorite, quartz, and barite, making this deposit distinct from most lead-zinc deposits in the SYG. This deposit is controlled by tectonic structures, and most mineralization is located along or near faults zones. Emeishan basalts near the ore district might have contributed to the formation of orebodies. The j34S values of sphalerite, galena, pyrite and barite were estimated to be 3.6‰-13.4‰, 3.7‰-9.0‰, -6.4‰ to 29.2‰ and 32.1‰34.7‰, respectively. In view of the similar δ34S values of barite and sulfates being from the Cambrian strata, the sulfur of barite was likely derived from the Cambrian strata. The homogenization temperatures (T ≈ 134--383℃) of fluid inclusions were not suitable for reducing bacteria, therefore, the bacterial sulfate reduction could not have been an efficient path to generate reduced sulfur in this district. Although thermochemical sulfate reduction process had contributed to the production of reduced sulfur, it was not the main mechanism. Considering other aspects, it can be suggested that sulfur of sulfides should have been derived from magmatic activities. The δ34S values of sphalerite were found to be higher than those of coexisting galena. The equilibrium temperatures calculated by using the sulfur isotopic composition of mineral pairs matched well with the homogenization temperature of fluid inclusions, suggesting that the sulfur isotopic composition in ore-forming fluids had reached a partial equilibrium.展开更多
A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to...A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to account for metal precipitation mechanism of the MVT ore deposits, in which fluids with metal-chloride complexes happen to mix with fluids with reduced sulfur, producing metal sulfide deposition. In this hypothesis, however, the detailed chemical kinetic process of mixing reactions, and especially the controlling factors on the metal precipitation are not yet clearly stated. In this paper, a series of mixing experiments under ambient temperature and pressure conditions were conducted to simulate the fluid mixing process, by titrating the metal-chloride solutions, doping withor without dolomite, and using NaHS solution. Experimental results, combined with the thermodynamic calculations, suggest that H_2S, rather than HS^-or S^(2-),dominated the reactions of Pb and/or Zn precipitation during the fluid mixing process, in which metal precipitation was influenced by the stability of metal complexes and the pH. Given the constant concentrations of metal and total S in fluids, the pH was a primary factor controlling the Pb and/or Zn metal precipitation. This is because neutralizing or neutralized processes for the ore-forming fluids can cause instabilities of Pb and/or Zn chloride complexes and re-distribution of sulfur species, and thus can facilitate the hydrolysis of Pb and Zn ions and precipitation of sulfides. Therefore, a weakly acidic to neutral fluid environment is most favorable for the precipitation of Pb and Zn sulfides associated with the carbonate-hosted Pb–Zn deposits.展开更多
The Lanping Basin in the Nujiang-Lancangjiang-Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of l...The Lanping Basin in the Nujiang-Lancangjiang-Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment-hosted Pb-Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India-Asia continental coUisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the oreforming elements in the east ore belt are mainly Pb-Zn -Sr-Ag, while Pb-Zn-Ag-Cu-Co elements are dominant in the west ore belt. Comparative analysis of the C-O-Sr-S-Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore- forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb-Zn mineralization age of both ore belts was contemporary and formed in the same metaliogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.展开更多
Duobaoshan is the largest porphyry-related Cu-Mo-Au orefield in northeastern(NE)Asia,and hosts a number of large-medium porphyry Cu(PCDs),epithermal Au and Fe-Cu skarn deposits.Formation ages of these deposits,from th...Duobaoshan is the largest porphyry-related Cu-Mo-Au orefield in northeastern(NE)Asia,and hosts a number of large-medium porphyry Cu(PCDs),epithermal Au and Fe-Cu skarn deposits.Formation ages of these deposits,from the oldest(Ordovician)to youngest(Jurassic),have spanned across over 300 Ma.No similar orefields of such size and geological complexity are found in NE Asia,which reflects its metallogenic uniqueness in forming and preserving porphyry-related deposits.In this study,we explore the actual number and timing of magmatic/mineralization phases,their respective magma genesis,fertility,and regional tectonic connection,together with the preservation of PCDs.We present new data on the magmatic/mineralization ages(LA-ICP-MS zircon U-Pb,pyrite and molybdenite Re-Os dating),whole-rock geochemistry,and zircon trace element compositions on four representative deposits in the Duobaoshan orefield,i.e.,Duobaoshan PCD,Tongshan PCD,Sankuanggou Fe-Cu skarn,and Zhengguang epithermal Au deposits,and compiled published ones from these and other mineral occurrences in the orefield.In terms of geochronology,we have newly summarized seven magmatic phases in the orefield:(1)Middle-Late Cambrian(506-491 Ma),(2)Early and Middle Ordovician(485-471 Ma and~462 Ma),(3)Late Ordovician(450-447 Ma),(4)Early Carboniferous and Late-Carboniferous to Early Permian(351-345 and 323-291 Ma),(5)Middle-Late Triassic(244-223 Ma),(6)Early-Middle and Late Jurassic(178-168 Ma and~150 Ma),and(7)Early Cretaceous(~112 Ma).Three of these seven major magmatic phases were coeval with ore formation,including(1)Early Ordovician(485-473 Ma)porphyry-type Cu-Mo-(Au),(2)Early-Middle Triassic(246-229 Ma)porphyry-related epithermal Au-(Cu-Mo),and(3)Early Jurassic(177-173 Ma)Fe-Cu skarn mineralization.Some deposits in the orefield,notably Tongshan and Zhengguang,were likely formed by more than one mineralization events.In terms of geochemistry,ore-causative granitoids in the orefield exhibit adakite-like or adakite-normal arc transitional signatures,but those forming the porphyry-/epithermal-type Cu-Mo-Au mineralization are largely confined to the former.The varying but high Sr/Y,Sm/Yb and La/Yb ratios suggest that the ore-forming magmas were mainly crustal sourced and formed at different depths(clinopyroxene-/amphibole-/garnet-stability fields).The adakite-like suites may have formed by partial melting of the thickened lower crust at 35-40 km(for the Early Ordovician arc)and>40 km(for the Middle-Late Triassic arc)depths.The Early Jurassic Fe-Cu skarn orecausative granitoids show an adakitic-normal arc transitional geochemical affinity.These granitoids were likely formed by partial melting of the juvenile lower crust(35-40 km depth),and subsequently modified by assimilation and fractional crystallization(AFC)processes.In light of the geological,geochronological and geochemical information,we proposed the following tectonometallogenic model for the Duobaoshan orefield.The Ordovician Duobaoshan may have been in a continental arc setting during the subduction of the Paleo-Asian Ocean,and formed the porphyry-related deposits at Duobaoshan,Tongshan and Zhengguang.Subduction may have ceased in the latest Ordovician,and the regional tectonics passed into long subsidence and extension till the latest Carboniferous.This extensional tectonic regime and the Silurian terrestrial-shallow marine sedimentation had likely buried and preserved the Ordovician Duobaoshan magmatic-hydrothermal system.The south-dipping Mongol-Okhotsk Ocean subduction from north of the orefield had generated the Middle-Late Triassic continental arc magmatism and the associated Tongshan PCD and Zhengguang epithermal Au mineralization(which superimposed on the Ordovician PCD system).The Middle Jurassic closure of Mongol-Okhotsk Ocean in the northwestern Amuria block(Erguna terrane),and the accompanying Siberia-Amuria collision,may have placed the Paleo-Pacific subduction system in NE China(including the orefield)under compression,and formed the granodiorite-tonalite and Fe-Cu skarn deposits at Sankuanggou and Xiaoduobaoshan.From the Middle Jurassic,the consecutive accretion of Paleo-Pacific arc terranes(e.g.,Sikhote-Alin and Nadanhada)onto the NE Asian continental margin may have gradually distant the Duobaoshan orefield from the subduction front,and consequently arc-type magmatism and the related mineralization faded.The minor Late Jurassic and Cretaceous unmineralized magmatism in the orefield may have triggered mainly by the far-field extension led by the post-collisional(Siberia-Amuria)gravitational collapse and/or Paleo-Pacific backarc-basin opening.展开更多
基金funded by the National Scientific and Technological Basic Resources Investigation Program(2022FY101800)a project of the National Natural Science Foundation of China(42102087)+1 种基金a project of the China Postdoctoral Science Foundation(2022M712966)a major project of the Ministry of Science and Technology of the People’s Republic of China(2021QZKK0304)。
文摘The reserves of the Duobaoshan porphyry Cu-Au-Mo-Ag deposit(also referred to as the Duobaoshan porphyry Cu deposit)ranks first among the copper deposits in China and 33rd among the porphyry copper deposits in the world.It has proven resources of copper(Cu),molybdenum(Mo),gold(Au),and silver(Ag)of 2.28×10^(6)t,80×10^(3)t,73 t,and 1046 t,respectively.The major characteristics of the Duobaoshan porphyry Cu deposit are as follows.It is located in a zone sandwiched by the Siberian,North China,and paleo-Pacific plates in an island arc tectonic setting and was formed by the Paleozoic mineralization and the Mesozoic mineralization induced by superposition and transformation.The metallogenic porphyries are the Middle Hercynian granodiorite porphyries.The alterations of surrounding rocks are distributed in a ring form.With silicified porphyries at the center,the alteration zones of K-feldspar,biotite,sericite,and propylite occur from inside to outside.This deposit is composed of 215 ore bodies(including 14 major ore bodies)in four mineralized zones.Ore body No.X in the No.3 mineralized zone has the largest resource reserves,accounting for more than 78%of the total reserves of the deposit.Major ore components include Cu,Mo,Au,Ag,Se,and Ga,which have an average content of 0.46%,0.015%,0.16 g/t,1.22 g/t,0.0003%,and 0.001%-0.003%,respectively.The ore minerals of this deposit primarily include pyrite,chalcopyrite,bornite,and molybdenite,followed by magnetite,hematite,rutile,gelenite,and sphalerite.The ore-forming fluids of this deposit were magmatic water in the early metallogenic stage and then the mixture of meteoric water and magmatic water at the late metallogenic stage.The ore-forming fluids experienced three stages.The ore-forming fluids of stageⅠhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 375-650℃,and ore-forming pressure of 110-160 MPa.The ore-forming fluids of stageⅡhad a hydrochemical type of H_(2)O-CO_(2)-Na Cl,an ore-forming temperature of 310-350℃,and ore-forming pressure of 58-80 MPa.The ore-forming fluids of stageⅢhad a hydrochemical type of Na Cl-H_(2)O,an ore-forming temperature of 210-290℃,and ore-forming pressure of 5-12 MPa.The CuAu-Mo-Ag mineralization mainly occurred at stagesⅠandⅡ,with the ore-forming materials having a mixed crust-mantle source.The Duobaoshan porphyry Cu deposit was formed in the initial subduction environment of the Paleo-Asian Ocean Plate during the Early Ordovician.Then,due to the closure of the Mongol-Okhotsk Ocean and the subduction and compression of the Paleo-Pacific Ocean,a composite orogenic metallogenic model of the deposit was formed.In other words,it is a porphyry-epithermal copper-gold polymetallic mineralization system of composite orogeny consisting of Paleozoic island arcs and Mesozoic orogeny and extension.
基金This research is supported by the National Natural Science Foundation of China (No. 40672061) ; 'National Science Support Plan Program' (2006BAB01A06) ; 'National Basic Research Program of China' (No.2007CB411304 No. 2001 CB409806).
文摘The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H20-NaCI-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The oreforming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep.
基金Supported by National Key Basic Research Program of China(973 Program)(No.3B813C254423)
文摘The Duobaoshan mine area in Heilongjiang is located in the northeast section of Xingmeng orogenic belt and is in the west side of Hegang Mountain-Heihe fault zone. There exist many deposits in this area,and its metallogenic conditions are superior,which has been one of the hotspots in geological prospecting and metallogenic research in Northeast China. On the basis of previous studies,the authors used the EH-4 electromagnetic imaging system to carry out the data acquisition of three survey lines in Woduhe Village,Duobaoshan Town,Nenjiang County. Through the analysis of apparent resistivity section under TE and TM polarization modes,integrating regional geological data,it is concluded that:(1) the electrical characteristics of the metal ore in this area show a relatively low resistance,and according to its resistivity difference with surrounding rocks,the geometrical structures and apparent resistivity parameters of the low resistivity bodies in the lower section of the survey line are defined,and the electrical anomalies can be identified;(2)faults F1 and F2 may have a good metallogenic environment,so they are recommended for further exploration;(3) low resistance metal ore bodies have good correlation with local small structures or faults,which may play an iconic role for the delineation of key target areas;(4) in the process of using apparent resistivity to define the geometric structures of ore bodies underground,comprehensive analysis integrating the advantages of TE and TM models should be carry out to achieve more reliable inversion results.
文摘1 Geological Background of Minerlization or Geologic Setting The northeast of Yunnan1 Pb-Zn-Ag-Ge polymetallic ore district is an important part of the southwestern margin of the Yangtze block Sichuan-Yunnan-Guizhou
基金financially supported by grants from the Commonweal Project from the Ministry of Land and Resources (No.201511015)China Geological Survey (No.DD2016027-2)
文摘1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this paper,
基金supported by the Funds for the programs of the National Natural Science Foundation (Noes. 41572060, U1133602)Projects of YM Lab (2011)Innovation Team of Yunnan province and KMUST (2008,2012)
文摘1 Introduction The Lehonglead-zincdeposit is a large-sized Pb-Zn depositnewly found in recent years in the Sichuan-Yunnan-Guizhou Lead-zinc Poly-metallic Mineralization Area,which occurrenceis strictly
基金funded by the national key basic research development program (2014 cb440905)key project of national natural science funds (41430315)
文摘1 Introduction The Wuzhishan lead-zinc ore-concentrated area in Puding is located in the east of the Sichuan,Guizhou and Yunnan lead-zinc metallogenic domain,with the Youjiang-Nanpan River metallogenic province to the
文摘Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.
文摘The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covered by eluvial-deluvial lateritic layer, without any mineralized outcrops. The main concealed orebody V3 is buffed in the depth of 300-500m. The orebodies are controlled by certain stratigraphic horizons, and most are cut by strata with a high angle, while a few occur along the strata. The direct wall rocks are calcisiltite, calclithite, bioclastic calcarenite,
基金financially supported by the Yunnan Copper (Group) Co., LTD (grant No.20150104)
文摘Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological research and mineral exploration(Li Bile et al., 2015). The Qimantag Mountain is located in middle segment of the EKO, which has experienced the Early Paleozoic and Late Paleozoic–Early
文摘An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits association and zoning laws.
基金granted by the China State Mineral Resources Investigation Program (Grant No.12120113050700)
文摘Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimental Investigation of Integrated Prospecting Technology for Concealed Carbonate-Type Lead-Zinc Deposits in the Region of Sichuan, Yunnan and Guizhou Provinces". This project has been implemented by the Chengdu Center of China Geological Survey since 2013, and the project has run for 3 years. The general objective of this project is to establish an effective and adaptable integrated prospecting methodology (including geological, geophysical and geochemical techniques) in search for deep concealed lead-zinc deposits.
基金granted by the Key Research Program of the Chinese Academy of Sciences (KZCX2-YW-Q04-05)a Special Research Fund of the SKLOG, IGCAS (KCZX20090103)
文摘The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China. Sulfides minerals including sphalerite, galena and pyrite postdate or coprecipitate with gangue mainly consisting of fluorite, quartz, and barite, making this deposit distinct from most lead-zinc deposits in the SYG. This deposit is controlled by tectonic structures, and most mineralization is located along or near faults zones. Emeishan basalts near the ore district might have contributed to the formation of orebodies. The j34S values of sphalerite, galena, pyrite and barite were estimated to be 3.6‰-13.4‰, 3.7‰-9.0‰, -6.4‰ to 29.2‰ and 32.1‰34.7‰, respectively. In view of the similar δ34S values of barite and sulfates being from the Cambrian strata, the sulfur of barite was likely derived from the Cambrian strata. The homogenization temperatures (T ≈ 134--383℃) of fluid inclusions were not suitable for reducing bacteria, therefore, the bacterial sulfate reduction could not have been an efficient path to generate reduced sulfur in this district. Although thermochemical sulfate reduction process had contributed to the production of reduced sulfur, it was not the main mechanism. Considering other aspects, it can be suggested that sulfur of sulfides should have been derived from magmatic activities. The δ34S values of sphalerite were found to be higher than those of coexisting galena. The equilibrium temperatures calculated by using the sulfur isotopic composition of mineral pairs matched well with the homogenization temperature of fluid inclusions, suggesting that the sulfur isotopic composition in ore-forming fluids had reached a partial equilibrium.
基金supported jointly by the National Key R&D Program of China (No. 2016YFC0600408)the National Natural Science Foundation of China (Nos. 41572060, 41773054, U1133602, 41802089)+3 种基金China Postdoctoral Science Foundation (No. 2017M610614)projects of YM Lab (2011)Innovation Team of Yunnan Province and KMUST (2008 and 2012)Yunnan and Kunming University of Science and Technology Postdoctoral Sustentation Fund
文摘A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to account for metal precipitation mechanism of the MVT ore deposits, in which fluids with metal-chloride complexes happen to mix with fluids with reduced sulfur, producing metal sulfide deposition. In this hypothesis, however, the detailed chemical kinetic process of mixing reactions, and especially the controlling factors on the metal precipitation are not yet clearly stated. In this paper, a series of mixing experiments under ambient temperature and pressure conditions were conducted to simulate the fluid mixing process, by titrating the metal-chloride solutions, doping withor without dolomite, and using NaHS solution. Experimental results, combined with the thermodynamic calculations, suggest that H_2S, rather than HS^-or S^(2-),dominated the reactions of Pb and/or Zn precipitation during the fluid mixing process, in which metal precipitation was influenced by the stability of metal complexes and the pH. Given the constant concentrations of metal and total S in fluids, the pH was a primary factor controlling the Pb and/or Zn metal precipitation. This is because neutralizing or neutralized processes for the ore-forming fluids can cause instabilities of Pb and/or Zn chloride complexes and re-distribution of sulfur species, and thus can facilitate the hydrolysis of Pb and Zn ions and precipitation of sulfides. Therefore, a weakly acidic to neutral fluid environment is most favorable for the precipitation of Pb and Zn sulfides associated with the carbonate-hosted Pb–Zn deposits.
基金granted by the National Natural Science Foundation of China(grants No.41302067,41472067 and 41403043)the Fundamental Research Funds of Chinese Academy of Geological Sciences(grant No.YYWF201614 and 09 program of Institute of Geomechanics)IGCP/SIDA–600,and China Geological Survey(grant No.DD20160053)
文摘The Lanping Basin in the Nujiang-Lancangjiang-Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment-hosted Pb-Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India-Asia continental coUisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the oreforming elements in the east ore belt are mainly Pb-Zn -Sr-Ag, while Pb-Zn-Ag-Cu-Co elements are dominant in the west ore belt. Comparative analysis of the C-O-Sr-S-Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore- forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb-Zn mineralization age of both ore belts was contemporary and formed in the same metaliogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.
基金funded by the China Geological Survey,the Chinese Ministry of Science and Technology(2017YFC0601304)the Cu-Mo-Au-Ag Metallogenic Regularity in Duobaoshan-Sankuanggou Belt Project(DT-2017-SJC-12)。
文摘Duobaoshan is the largest porphyry-related Cu-Mo-Au orefield in northeastern(NE)Asia,and hosts a number of large-medium porphyry Cu(PCDs),epithermal Au and Fe-Cu skarn deposits.Formation ages of these deposits,from the oldest(Ordovician)to youngest(Jurassic),have spanned across over 300 Ma.No similar orefields of such size and geological complexity are found in NE Asia,which reflects its metallogenic uniqueness in forming and preserving porphyry-related deposits.In this study,we explore the actual number and timing of magmatic/mineralization phases,their respective magma genesis,fertility,and regional tectonic connection,together with the preservation of PCDs.We present new data on the magmatic/mineralization ages(LA-ICP-MS zircon U-Pb,pyrite and molybdenite Re-Os dating),whole-rock geochemistry,and zircon trace element compositions on four representative deposits in the Duobaoshan orefield,i.e.,Duobaoshan PCD,Tongshan PCD,Sankuanggou Fe-Cu skarn,and Zhengguang epithermal Au deposits,and compiled published ones from these and other mineral occurrences in the orefield.In terms of geochronology,we have newly summarized seven magmatic phases in the orefield:(1)Middle-Late Cambrian(506-491 Ma),(2)Early and Middle Ordovician(485-471 Ma and~462 Ma),(3)Late Ordovician(450-447 Ma),(4)Early Carboniferous and Late-Carboniferous to Early Permian(351-345 and 323-291 Ma),(5)Middle-Late Triassic(244-223 Ma),(6)Early-Middle and Late Jurassic(178-168 Ma and~150 Ma),and(7)Early Cretaceous(~112 Ma).Three of these seven major magmatic phases were coeval with ore formation,including(1)Early Ordovician(485-473 Ma)porphyry-type Cu-Mo-(Au),(2)Early-Middle Triassic(246-229 Ma)porphyry-related epithermal Au-(Cu-Mo),and(3)Early Jurassic(177-173 Ma)Fe-Cu skarn mineralization.Some deposits in the orefield,notably Tongshan and Zhengguang,were likely formed by more than one mineralization events.In terms of geochemistry,ore-causative granitoids in the orefield exhibit adakite-like or adakite-normal arc transitional signatures,but those forming the porphyry-/epithermal-type Cu-Mo-Au mineralization are largely confined to the former.The varying but high Sr/Y,Sm/Yb and La/Yb ratios suggest that the ore-forming magmas were mainly crustal sourced and formed at different depths(clinopyroxene-/amphibole-/garnet-stability fields).The adakite-like suites may have formed by partial melting of the thickened lower crust at 35-40 km(for the Early Ordovician arc)and>40 km(for the Middle-Late Triassic arc)depths.The Early Jurassic Fe-Cu skarn orecausative granitoids show an adakitic-normal arc transitional geochemical affinity.These granitoids were likely formed by partial melting of the juvenile lower crust(35-40 km depth),and subsequently modified by assimilation and fractional crystallization(AFC)processes.In light of the geological,geochronological and geochemical information,we proposed the following tectonometallogenic model for the Duobaoshan orefield.The Ordovician Duobaoshan may have been in a continental arc setting during the subduction of the Paleo-Asian Ocean,and formed the porphyry-related deposits at Duobaoshan,Tongshan and Zhengguang.Subduction may have ceased in the latest Ordovician,and the regional tectonics passed into long subsidence and extension till the latest Carboniferous.This extensional tectonic regime and the Silurian terrestrial-shallow marine sedimentation had likely buried and preserved the Ordovician Duobaoshan magmatic-hydrothermal system.The south-dipping Mongol-Okhotsk Ocean subduction from north of the orefield had generated the Middle-Late Triassic continental arc magmatism and the associated Tongshan PCD and Zhengguang epithermal Au mineralization(which superimposed on the Ordovician PCD system).The Middle Jurassic closure of Mongol-Okhotsk Ocean in the northwestern Amuria block(Erguna terrane),and the accompanying Siberia-Amuria collision,may have placed the Paleo-Pacific subduction system in NE China(including the orefield)under compression,and formed the granodiorite-tonalite and Fe-Cu skarn deposits at Sankuanggou and Xiaoduobaoshan.From the Middle Jurassic,the consecutive accretion of Paleo-Pacific arc terranes(e.g.,Sikhote-Alin and Nadanhada)onto the NE Asian continental margin may have gradually distant the Duobaoshan orefield from the subduction front,and consequently arc-type magmatism and the related mineralization faded.The minor Late Jurassic and Cretaceous unmineralized magmatism in the orefield may have triggered mainly by the far-field extension led by the post-collisional(Siberia-Amuria)gravitational collapse and/or Paleo-Pacific backarc-basin opening.