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溶胶-凝胶法制备Gd_(4)Ga_(2)O_(9):Dy^(3+)白光发射荧光粉及其性能 被引量:1
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作者 官春艳 郑启泾 +1 位作者 万正环 杨锦瑜 《材料导报》 EI CAS CSCD 北大核心 2024年第8期83-88,共6页
通过溶胶-凝胶法制备了具有白光发射的Gd_(4)Ga_(2)O_(9):x%Dy^(3+)荧光粉,利用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、能谱仪(EDS)、紫外-可见漫反射光谱(UV-Vis DRS)和荧光光谱等对产物的物相结构、形貌、组分和光学性能进行研究... 通过溶胶-凝胶法制备了具有白光发射的Gd_(4)Ga_(2)O_(9):x%Dy^(3+)荧光粉,利用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、能谱仪(EDS)、紫外-可见漫反射光谱(UV-Vis DRS)和荧光光谱等对产物的物相结构、形貌、组分和光学性能进行研究,并分析了Dy^(3+)掺杂量对样品的影响。XRD结果表明,所制备的样品为Dy^(3+)掺杂的Gd_(4)Ga_(2)O_(9)单斜晶体和少量Ga_(2)O_(3)杂质相的混合物。紫外-可见漫反射光谱结果表明制备的Dy^(3+)掺杂Gd_(4)Ga_(2)O_(9)晶体是一种光学带隙为5.29 eV的直接带隙半导体。荧光检测结果表明Dy^(3+)掺杂Gd_(4)Ga_(2)O_(9)荧光粉可被属于Gd^(3+)激发带的275 nm紫外光有效激发,并在490 nm和575 nm附近分别发射出属于Dy^(3+)的^(4)F_(9/2)→^(6)H_(15/2)和^(4)F_(9/2)→^(6)H_(13/2)跃迁的蓝色和黄色的强烈光,证实在Gd_(4)Ga_(2)O_(9):Dy^(3+)样品中存在显著的由Gd^(3+)到Dy^(3+)的能量传递发光现象。同时,对其发光机制进行了讨论。样品的发光强度随着Dy^(3+)掺杂量的变化而变化,同时影响着样品的发光颜色,Dy^(3+)掺杂量为1.5%和2%时制备的荧光粉可在紫外光激发下分别发射出CIE色坐标为(0.3362,0.3512)和(0.3381,0.3523)、相关色温为5340 K和5263 K的白色光。研究结果表明Gd_(4)Ga_(2)O_(9):Dy^(3+)是一种潜在的紫外光激发白光发射荧光材料。 展开更多
关键词 Gd_(4)Ga_(2)O_(9) dy^(3+)掺杂 白光发射 荧光性能 能量传递 直接带隙半导体
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Gd_(2)MgTiO_(6):Dy^(3+)荧光粉的制备与发光性能研究
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作者 王志文 孙顶 +1 位作者 张玉红 刘航 《日用电器》 2024年第6期97-100,104,共5页
采用高温固相法制备出一系列Dy^(3+)掺杂双钙钛矿Gd_(2)MgTiO_(6)白色荧光粉样品,通过X射线衍射仪和荧光光谱仪对荧光粉样品的晶体结构及荧光性能进行分析和表征。结果表明:在355 nm近紫外光激发下,样品发出极强的蓝光(484 nm)和黄光(57... 采用高温固相法制备出一系列Dy^(3+)掺杂双钙钛矿Gd_(2)MgTiO_(6)白色荧光粉样品,通过X射线衍射仪和荧光光谱仪对荧光粉样品的晶体结构及荧光性能进行分析和表征。结果表明:在355 nm近紫外光激发下,样品发出极强的蓝光(484 nm)和黄光(575 nm)。通过调节Dy^(3+)的浓度可以使样品发光颜色向白光区移动,因此Gd_(2)MgTiO_(6):Dy^(3+)是一种可调荧光粉。当Dy^(3+)掺杂浓度为3%时可以发出色坐标为(0.3598,0.3946)的白光。Gd_(2)MgTiO_(6)合成方法简便、组份易调控,是一种具有潜在应用价值荧光材料。 展开更多
关键词 高温固相法 dy3+掺杂 双钙钛矿 白色荧光粉
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Dy^(3+)/Eu^(3+)双掺杂CaLaGa_(3)O_(7)颜色可调荧光粉的制备与发光性能
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作者 刘云云 黄传鑫 +1 位作者 王猛 王燕 《人工晶体学报》 CAS 北大核心 2024年第9期1560-1567,共8页
本文采用高温固相法成功制备了一系列Eu^(3+)单掺和Dy^(3+)/Eu^(3+)双掺CaLaGa_(3)O_(7)单基质荧光粉。通过X射线衍射和发射光谱对荧光粉的物相及发光性能进行了表征。结果表明,所制备的样品均为四方结构,与基质晶体一致,表明成功合成了... 本文采用高温固相法成功制备了一系列Eu^(3+)单掺和Dy^(3+)/Eu^(3+)双掺CaLaGa_(3)O_(7)单基质荧光粉。通过X射线衍射和发射光谱对荧光粉的物相及发光性能进行了表征。结果表明,所制备的样品均为四方结构,与基质晶体一致,表明成功合成了Eu^(3+)单掺和Dy^(3+)/Eu^(3+)双掺杂的CaLaGa_(3)O_(7)荧光粉。在波长393 nm近紫外光激发下,Eu^(3+)∶CaLaGa_(3)O_(7)表现出Eu^(3+)的特征红光发射(5 D0→7 F2),并且发光纯度高达100%。共掺Dy^(3+)之后,Dy^(3+)/Eu^(3+)双掺CaLaGa_(3)O_(7)荧光粉不仅可以被波长393 nm的光激发还可以被波长348 nm的光激发。不管是哪个波长的光激发,Dy^(3+)/Eu^(3+)∶CaLaGa_(3)O_(7)发射光谱同时包含了Eu^(3+)的特征红光发射和Dy^(3+)的特征黄光发射(4 F_(9/2)→6 H_(13/2))。通过对发射谱和荧光寿命分析得出,双掺荧光粉中Dy^(3+)和Eu^(3+)之间存在有效的能量传递过程。进一步计算了各个样品对应的色坐标,结果表明当激发波长由348 nm改变为393 nm时,色坐标整体上从黄绿色区域移动到黄橙光区域。因此,Dy^(3+)/Eu^(3+)∶CaLaGa_(3)O_(7)是一种光色可调发光材料,在显示和固态照明方面具有良好的应用前景。 展开更多
关键词 CaLaGa_(3)O_(7) dy^(3+)/Eu^(3+)双掺杂 荧光粉 发光性能 颜色可调 高温固相法
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Sb^(3+)/Bi^(3+)掺杂对Cs_(3)DyCl_(6)钙钛矿光学性能的影响 被引量:1
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作者 周宇 王有力 《半导体技术》 CAS 北大核心 2024年第3期240-245,共6页
A_(2)B′BCl_(6)双钙钛矿因其极强的空气稳定性、出色的光学性能而被应用于发光材料。以Cs^(+)作为A^(+)、Dy^(3+)替代Pb^(2+)、Cl^(-)作为卤素合成新的镝基钙钛矿纳米晶体Cs_(3)DyCl_(6),以Sb^(3+)/Bi^(3+)作为激发剂掺杂,成功制备了... A_(2)B′BCl_(6)双钙钛矿因其极强的空气稳定性、出色的光学性能而被应用于发光材料。以Cs^(+)作为A^(+)、Dy^(3+)替代Pb^(2+)、Cl^(-)作为卤素合成新的镝基钙钛矿纳米晶体Cs_(3)DyCl_(6),以Sb^(3+)/Bi^(3+)作为激发剂掺杂,成功制备了非铅钙钛矿材料,研究了Sb^(3+)/Bi^(3+)掺杂对钙钛矿发光特性的影响。结果表明:Cs_(3)DyCl_(6)是一种具有高效激发和宽带发射特性的基质,在不添加任何激发剂的情况下就能够发出蓝绿光。在Sb^(3+)掺杂下,材料的发光向黄光方向移动,随着Sb^(3+)掺杂浓度的继续提高,发光强度开始下降,最佳掺杂比例为5%;Bi^(3+)掺杂时的Cs_(3)DyCl_(6)光学性能与Sb^(3+)掺杂下非常相似,当Bi^(3+)掺杂比例为1%时,发光强度达到最大值,Sb^(3+)/Bi^(3+)掺杂能够有效地改善Cs_(3)DyCl_(6)的光学性能。 展开更多
关键词 钙钛矿 镝基 掺杂 Sb^(3+)/Bi^(3) 光学性能
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SrLaLiTeO_(6):Dy^(3+),Eu^(3+)荧光粉的制备及发光性能研究
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作者 龚劲松 朱齐 +4 位作者 郑小州 夏鹏举 刘凯 徐慢 戴武斌 《武汉工程大学学报》 CAS 2024年第3期274-279,共6页
白光发光二极管(LED)的商业合成方案缺少红光成分,导致合成的白光色温较高、显色性差,因此开发性能优异的单相暖白光荧光粉成为白光LED领域研究的重要课题。以Dy^(3+)和Eu^(3+)为掺杂剂,SrLaLiTeO_(6)(SLLT)为基质,采用固相反应法制备了... 白光发光二极管(LED)的商业合成方案缺少红光成分,导致合成的白光色温较高、显色性差,因此开发性能优异的单相暖白光荧光粉成为白光LED领域研究的重要课题。以Dy^(3+)和Eu^(3+)为掺杂剂,SrLaLiTeO_(6)(SLLT)为基质,采用固相反应法制备了SrLaLiTeO6:Dy^(3+),Eu^(3+)无机荧光粉,并通过X射线衍射仪、荧光分光光度计和色度坐标分析荧光粉的晶体结构及光学性能。结果表明:Dy^(3+)和Eu^(3+)成功进入SLLT晶体,无杂质产生;SLLT:0.07Dy^(3+),yEu^(3+)荧光粉在351 nm激发下能够同时发射蓝、黄、红光,证明了Dy^(3+)和Eu^(3+)之间存在能量传递,弥补了单掺Dy^(3+)荧光粉缺乏红色发射的缺陷;Eu^(3+)离子最佳掺杂浓度为0.05,此时的色度坐标为(0.391 9,0.380 9),色温为3 733 K,接近暖白光区域。因此,SrLaLiTeO_(6):Dy^(3+),Eu^(3+)荧光粉是一种性能优异的暖白光LED荧光粉。 展开更多
关键词 荧光粉 发光性能 SrLaLiTeO_(6):dy^(3+) Eu^(3+) 暖白光 固相反应
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Effect of Dy doping on magnetostrictive and mechanical properties of Fe83Ga17 alloy 被引量:2
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作者 Xin-lei Wang Yuan Liu +2 位作者 Xiang Chen Hua-wei Zhang Yan-xiang Li 《China Foundry》 SCIE 2020年第3期198-205,共8页
Fe83Ga17 alloy is a kind of promising magnetostrictive alloys with high magnetostrictive properties and a low saturation magnetic field.As-cast Fe83Ga17 Dyx(x=0,0.05,0.1,0.2,0.4)polycrystalline alloys were prepared by... Fe83Ga17 alloy is a kind of promising magnetostrictive alloys with high magnetostrictive properties and a low saturation magnetic field.As-cast Fe83Ga17 Dyx(x=0,0.05,0.1,0.2,0.4)polycrystalline alloys were prepared by arc melting.Effect of Dy doping on the microstructure,magnetostrictive and mechanical properties of as-cast Fe83Ga17 alloy was investigated.Results show that Dy-doped alloys exhibit a dual-phase structure containing the A2 matrix and Dy-rich precipitates(Fe56Ga34Dy10).Both magnetostriction and mechanical properties of Fe83Ga17 alloys are improved by Dy doping.A small amount of Dy addition(x=0.2)significantly causes Fe83Ga17 alloy to transform from typical brittle material(fracture strainε<1%)to plastic material(ε≈11%).Correspondingly,the fracture mode transforms from intergranular fracture to dimple fracture.At the same time,the ultimate tensile strength and the magnetostriction rise up to 209 MPa and 64 ppm,respectively.Dy-rich precipitates disperse along the grain boundries and inside the grains,which plays an important role in the grain refinement and solution strengthening,and therefore,contribute to the enhancement of mechanical properties of the alloy.The improvement of magnetostriction could be attributed to the large lattice distortion induced by Dy atoms entering into the A2 matrix.Doping Dy into Fe-Ga alloys provides an effective solution to the brittleness in their applications. 展开更多
关键词 Fe-Ga alloys dy doping mechanical properties MAGNETOSTRICTION
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Effects of cooling rate on the microstructure and electrical properties of Dy_2O_3-doped ZnO-based varistor ceramics 被引量:4
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作者 LIU Hongyu KONG Hui +3 位作者 JIANG Dongmei SHI Wangzhou MA Xueming ZHANG Huining 《Rare Metals》 SCIE EI CAS CSCD 2007年第1期39-44,共6页
The microstructure, electrical properties, and density of Dy2O3-doped ZnO-based varistor ceramics, prepared using high-energy ball milling (HEBM) and sintered at 800℃, were investigated by increasing the cooling ra... The microstructure, electrical properties, and density of Dy2O3-doped ZnO-based varistor ceramics, prepared using high-energy ball milling (HEBM) and sintered at 800℃, were investigated by increasing the cooling rate in the order of H (slow cooling in furnace) → L (cooling in furnace) → K (cooling in air). With the increase in cooling rate, the grain size and density decreased, the breakdown voltage (VImA/mm) increased, and the nonlinear coefficient (α) and leakage current (IL) exhibited extremum. The sample with the cooling type L showed the best properties with the breakdown voltage of 2650 V/ram, o:of 20.3, IL of 5.2 laA, and density of 5.42 g/cm^3. The barrier height (ФB), donor concentration (Nd), density of the interface states (Nd), and barrier width (ω) all exhibited extremum during the alteration in cooling rate. The different relative amount of Bi-rich phase and its distribution as well as the characteristic parameters of grain boundary, resulting from the alteration of cooling rate, led to the changes in the properties of varistor ceramics. 展开更多
关键词 VARISTOR ZNO dy2O3 MICROSTRUCTURE electrical properties high-energy ball milling low-temperature sintering
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A comparison study of alkali metal-doped g-C_3N_4 for visible-light photocatalytic hydrogen evolution 被引量:25
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作者 Jing Jiang Shaowen Cao +1 位作者 Chenglong Hu Chunhua Chen 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第12期1981-1989,共9页
Photocatalytic hydrogen production based on semiconductor photocatalysts has been considered as one of the most promising strategies to resolve the global energy shortage.Graphitic carbon nitride(g‐C3N4)has been a st... Photocatalytic hydrogen production based on semiconductor photocatalysts has been considered as one of the most promising strategies to resolve the global energy shortage.Graphitic carbon nitride(g‐C3N4)has been a star visible‐light photocatalyst in this field due to its various advantages.However,pristine g‐C3N4usually exhibits limited activity.Herein,to enhance the performance of g‐C3N4,alkali metal ion(Li+,Na+,or K+)‐doped g‐C3N4are prepared via facile high‐temperature treatment.The prepared samples are characterized and analyzed using the technique of XRD,ICP‐AES,SEM,UV‐vis DRS,BET,XPS,PL,TRPL,photoelectrochemical measurements,photocatalytic tests,etc.The resultant doped photocatalysts show enhanced visible‐light photocatalytic activities for hydrogen production,benefiting from the increased specific surface areas(which provide more active sites),decreased band gaps for extended visible‐light absorption,and improved electronic structures for efficient charge transfer.In particular,because of the optimal tuning of both microstructure and electronic structure,the Na‐doped g‐C3N4shows the most effective utilization of photogenerated electrons during the water reduction process.As a result,the highest photocatalytic performance is achieved over the Na‐doped g‐C3N4photocatalyst(18.7?mol/h),3.7times that of pristine g‐C3N4(5.0?mol/h).This work gives a systematic study for the understanding of doping effect of alkali metals in semiconductor photocatalysis. 展开更多
关键词 g‐C3N4 Alkali metal doping Photocatalytic hydrogen production Visible light Charge transfer
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Defect engineering on BiFeO_(3) through Na and V codoping for aqueous Na-ion capacitors
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作者 Wenyun Wang Chao Yang +4 位作者 Shangjing Yu Daotong Han Wentao Qi Rui Ling Guangqiang Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期453-463,I0011,共12页
Sodium with low cost and high abundance is considered as a substitute element of lithium for batteries and supercapacitors,which need the appropriate host materials to accommodate the relatively large Na^(+) ions.Comp... Sodium with low cost and high abundance is considered as a substitute element of lithium for batteries and supercapacitors,which need the appropriate host materials to accommodate the relatively large Na^(+) ions.Compared to Li^(+) storage,Na^(+) storage makes higher demands on the structural optimization of perovskite bismuth ferrite(BiFeO_(3)).We propose a novel strategy of defect engineering on BiFeO_(3) through Na and V codoping for high-efficiency Na^(+) storage,to reveal the roles of oxygen vacancies and V ions played in the enhanced electrochemical energy storage performances of Na-ion capacitors.The formation of the oxygen vacancies in the Na and V codoped BiFeO_(3)(denoted as NV-BFO),is promoted by Na doping and suppressed by V doping,which can be demonstrated by XPS and EPR spectra.By the first-principles calculations,the oxygen vacancies and V ions in NV-BFO are confirmed to substantially lower the Na^(+)migration energy barriers through the space and electric field effects,to effectively promote the Na^(+) transport in the crystals.Electrochemical kinetic analysis of the NV-BFO//NV-BFO capacitors indicates the dominant capacitive-controlled capacity,which depends on fast Na^(+) deintercalation-intercalation process in the NV-BFO electrode.The NV-BFO//NV-BFO capacitors open up a new avenue for developing highperformance Na-ion capacitors. 展开更多
关键词 BiFeO_(3) Na^(+) storage V doping Oxygen vacancy CAPACITOR
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Photoelectrocatalytic activity of immobilized Yb doped WO3 photocatalyst for degradation of methyl orange dye 被引量:4
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作者 S.V.Mohite V.V.Ganbavle K.Y.Rajpure 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2017年第3期440-447,共8页
Pure WOand Yb:WOthin films have been synthesized by spray pyrolysis technique. Effect of Yb doping concentration on photoelectrochemical, structural, morphological and optical properties of thin films are studied. X-r... Pure WOand Yb:WOthin films have been synthesized by spray pyrolysis technique. Effect of Yb doping concentration on photoelectrochemical, structural, morphological and optical properties of thin films are studied. X-ray diffraction analysis shows that all thin films are polycrystalline nature and exhibit monoclinic crystal structure. The 3 at% Yb:WOfilm shows superior photoelectrochemical(PEC) performance than that of pure WOfilm and it shows maximum photocurrent density(Iph= 1090 μA/cm) having onset potentials around +0.3 V/SCE in 0.01 M HClO. The photoelectrocatalytic process is more effective than that of the photocatalytic process for degradation of methyl orange(MO) dye. Yb doping in WOphotocatalyst is greatly effective to degrade MO dye. The enhancement in photoelectrocatalytic activity is mainly due to the suppressing the recombination rate of photogenerated electron-hole pairs. The mineralization of MO dye in aqueous solution is studied by measuring chemical oxygen demand(COD) values. 展开更多
关键词 DEGRADATION Photocatalytic activity Methyl orange dye Thin film Yb doped WO3 Spray pyrolysis technique
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Promoted CO2 electroreduction over indium-doped SnP3: A computational study 被引量:2
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作者 Yuefeng Zhang Wenchao Zhang +1 位作者 Yuezhan Feng Jianmin Ma 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第9期1-6,I0001,共7页
It is generally considered that the hydrogenation of CO2 is the critical bottleneck of the CO2 electroreduction.In this work,with the aid of density functional theory(DFT)calculations,the catalytic hydrogenation of CO... It is generally considered that the hydrogenation of CO2 is the critical bottleneck of the CO2 electroreduction.In this work,with the aid of density functional theory(DFT)calculations,the catalytic hydrogenation of CO2 molecules over Indium-doped SnP3 catalyst were systematically studied.Through doping with indium(In)atom,the energy barrier of CO2 protonation is reduced and OCHO*species could easily be generated.This is mainly due to the p orbital of In exhibits strong hybridization with the p orbital of O,indicating that there is a strong interaction between OCHO*and In-doped SnP3 catalyst.As a result,In-doped SnP3 possesses high-efficiency and high-selectivity for converting CO2 into HCOOH with a low limiting potential of-0.17 V.Our findings will offer theoretical guidance to CO2 electroreduction. 展开更多
关键词 CO2 electroreduction SnP3 Indium metal doping Formic acid First principles
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Intense up-conversion emissions of yb3+/Dy3+ co-doped A12O3 nanopowders prepared by non-aqueous sol-gel method* 被引量:2
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作者 李成仁 李淑凤 +3 位作者 董斌 孙景昌 卜晓峰 范旭楠 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第9期505-508,共4页
yb3+/Dy3+ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results... yb3+/Dy3+ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results show that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663 nm, corresponding to 4C9/2→ 6H13/2, 4C9/2→ 6Hll/2, 4115/2 → 6H13/2, and 4F9/2 →6Hll/2 transitions of Dy3+, respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion emissions. The energy transition between Yb3+ and Dy3+ is discussed. 展开更多
关键词 yb3+/dy3 co-doped A1203 nanopowders non-aqueous sol-gel method photo- lumi-nescence spectra up-conversion emission
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In^(3+)、Sb^(3+)、Bi^(3+)掺杂对双钙钛矿Cs_(2)NaDyCl_(6)发光性能的调控
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作者 周宇 王有力 《半导体技术》 CAS 北大核心 2024年第6期538-543,共6页
A2B′BCl_(6)型双钙钛矿因其极强的空气稳定性和出色的光学性能而被应用于发光材料。使用Na离子替代式掺杂合成非铅体系钙钛矿材料Cs_(2)NaDyCl_(6),引入In^(3+)、Sb^(3+)和Bi^(3+)等掺杂元素对双钙钛矿Cs_(2)NaDyCl_(6)发光性能进行调... A2B′BCl_(6)型双钙钛矿因其极强的空气稳定性和出色的光学性能而被应用于发光材料。使用Na离子替代式掺杂合成非铅体系钙钛矿材料Cs_(2)NaDyCl_(6),引入In^(3+)、Sb^(3+)和Bi^(3+)等掺杂元素对双钙钛矿Cs_(2)NaDyCl_(6)发光性能进行调控。结果表明:通过In^(3+)的掺杂,拓宽了材料的发射区间,进一步提高了其光学性能;Bi^(3+)掺杂能够使钙钛矿的发射光发生红移现象,Sb^(3+)掺杂可以使钙钛矿的发射光发生蓝移现象,Sb^(3+)和Bi^(3+)共同掺杂能够平衡钙钛矿在可见光区域的发射;在In^(3+)、Sb^(3+)、Bi^(3+)三种元素的共同掺杂下,Cs_(2)NaDy_(0.445)In_(0.445)Cl_(6)∶0.1Bi 0.01Sb成功实现了白光发射,在265 nm波长激发下,其CIE色坐标为(0.34,0.35),色温达到5314 K,显色指数高达94。 展开更多
关键词 双钙钛矿 掺杂 发光性能 In^(3+) Sb^(3+) Bi^(3+)
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O-doping strategy enabling enhanced chemical/electrochemical stability of Li_(3)InCl_(6) for superior solid-state battery performance
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作者 Qiyue Luo Chen Liu +7 位作者 Lin Li Ziling Jiang Jie Yang Shaoqing Chen Xia Chen Long Zhang Shijie Cheng Chuang Yu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第12期484-494,共11页
Solid-state electrolytes with high oxidation stability are crucial for achieving high power density allsolid-state lithium batteries.Halide electrolytes are promising candidates due to their outstanding compatibility ... Solid-state electrolytes with high oxidation stability are crucial for achieving high power density allsolid-state lithium batteries.Halide electrolytes are promising candidates due to their outstanding compatibility with cathode materials and high Li^(+)conductivity.However,the electrochemical stability of chloride electrolytes is still limited,leaving them unsuitable for ultrahigh voltage operation.Besides,chemical compatibility issue between sulfide and halide electrolytes affects the electrochemical performance of all-solid-state batteries.Herein,Li-ion conductor Li_(3+x)InCl_(6-x)O_(x) is designed to address these challenges.Li_(3.25)InCl_(5.75)O_(0.25)shows a Li-ion conductivity of 0.90 mS cm^(-1)at room temperature,a high onset oxidation voltage of 3.84 V,fewer by-products at ultrahigh operation voltage,and good chemical compatibility with Li_(5.5)PS_(4.5)Cl_(1.5).The Li_(3.25)InCl_(5.75)O_(0.25)@LiNi_(0.7)Co_(0.1)Mn_(0.2)O_(2)-Li_(3.25)InCl_(5.75)O_(0.25)-VGCF/Li_(3.25)InCl_(5.75)O_(0.25)/Li_(5.5)PS_(4.5)Cl_(1.5)/Li-In battery delivers good electrochemical performances at high operating voltage.This work provides a simple,economical,and effective strategy for designing high-voltage all-solid-state electrolytes. 展开更多
关键词 Li_(3)InCl_(6) O doping Wide electrochemical window Chemical stability Interfacial stability Superior electrochemical performance
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Enhancing potassium-ion storage of Bi_(2)S_(3) through external–internal dual synergism: Ti_(3)C_(2)T_(x) compositing and Cu^(2+) doping
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作者 Dawei Sha Yurong You +5 位作者 Rongxiang Hu Jianxiang Ding Xin Cao Yuan Zhang Long Pan ZhengMing Sun 《Carbon Energy》 SCIE EI CAS CSCD 2024年第9期39-51,共13页
Potassium-ion batteries(PIBs)offer a cost-effective and resource-abundant solution for large-scale energy storage.However,the progress of PIBs is impeded by the lack of high-capacity,long-life,and fast-kinetics anode ... Potassium-ion batteries(PIBs)offer a cost-effective and resource-abundant solution for large-scale energy storage.However,the progress of PIBs is impeded by the lack of high-capacity,long-life,and fast-kinetics anode electrode materials.Here,we propose a dual synergic optimization strategy to enhance the K^(+)storage stability and reaction kinetics of Bi_(2)S_(3) through two-dimensional compositing and cation doping.Externally,Bi_(2)S_(3) nanoparticles are loaded onto the surface of three-dimensional interconnected Ti_(3)C_(2)T_(x) nanosheets to stabilize the electrode structure.Internally,Cu^(2+)doping acts as active sites to accelerate K^(+)storage kinetics.Various theoretical simulations and ex situ techniques are used to elucidate the external–internal dual synergism.During discharge,Ti_(3)C_(2)T_(x) and Cu^(2+)collaboratively facilitate K+intercalation.Subsequently,Cu^(2+)doping primarily promotes the fracture of Bi2S3 bonds,facilitating a conversion reaction.Throughout cycling,the Ti_(3)C_(2)T_(x) composite structure and Cu^(2+)doping sustain functionality.The resulting Cu^(2+)-doped Bi2S3 anchored on Ti_(3)C_(2)T_(x)(C-BT)shows excellent rate capability(600 mAh g^(-1) at 0.1 A g^(–1);105 mAh g^(-1) at 5.0 A g^(-1))and cycling performance(91 mAh g^(-1) at 5.0 A g^(-1) after 1000 cycles)in half cells and a high energy density(179 Wh kg–1)in full cells. 展开更多
关键词 Bi_(2)S_(3) cation doping potassium-ion batteries synergic mechanism Ti_(3)C_(2)T_(x)compositing
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Sb^(3+)/Bi^(3+)掺杂对Cs_(2)ADyCl_(6)(A=Li,Na,K)发光性能的影响
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作者 周宇 王有力 《半导体技术》 CAS 北大核心 2024年第5期425-431,共7页
A2B′BCl_(6)型双钙钛矿因其极强的空气稳定性和出色的光学特性而被应用于发光材料。以Cs^(+)作为A^(+),Dy^(3+)替代Pb^(2+),Cl^(-)作为卤素制备新的镝基钙钛矿纳米晶体Cs_(3)DyCl_(6),使用Li、Na、K离子替代式掺杂合成Cs_(2)ADyCl_(6)(... A2B′BCl_(6)型双钙钛矿因其极强的空气稳定性和出色的光学特性而被应用于发光材料。以Cs^(+)作为A^(+),Dy^(3+)替代Pb^(2+),Cl^(-)作为卤素制备新的镝基钙钛矿纳米晶体Cs_(3)DyCl_(6),使用Li、Na、K离子替代式掺杂合成Cs_(2)ADyCl_(6)(A=Li,Na,K)非铅体系钙钛矿材料,通过掺杂Sb^(3+)/Bi^(3+)作为激发剂实现了不同发光性能的调控。结果表明:Cs_(2)NaDyCl_(6)发射曲线更加平滑且在蓝光与黄光区域均可实现发射,表现出优异的光学特性;通过Sb^(3+)/Bi^(3+)掺杂,双钙钛矿的光学特性得到显著提升,Na^(+)和Sb^(3+)的共同作用可以使钙钛矿材料发光产生蓝移,而Na^(+)与Bi^(3+)的共同作用则可以使其发光产生红移。 展开更多
关键词 双钙钛矿 掺杂 激发 发光性能 Sb^(3+)/Bi^(3+) Na^(+)
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Synthesis, Electrical and Magnetic Properties of Fe304 Doped by Dy^3+ 被引量:1
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作者 Wang Jingping Hao Xianfeng +3 位作者 Lü Minfeng Liu Jianfen Xing Xianran Meng Jian 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第4期505-505,共1页
The Dy^3+ -doped Fe3O4 samples were synthesized by sol-gel method, and the effects of dopant on the electrical and magnetic properties were investigated. According to XRD analysis, the high concentration doping of dy... The Dy^3+ -doped Fe3O4 samples were synthesized by sol-gel method, and the effects of dopant on the electrical and magnetic properties were investigated. According to XRD analysis, the high concentration doping of dysprosium ions in Fe3O4 can not be obtained due to the difference of ionic radius, and Fe^3 + ions are replaced by only a small amount of dysprosium ions. The magnetic property was characterized by VSM. The substitution results in the change of saturation magnetization, which may be due to the complex effects of increasing magnetization resulted from Dy^3+ substitution and decreasing magnetization resulted from the impurity. The electrical property was characterized by four-probe method. With the increasing eoped content, magnetoresistance also increases, then decreases, and increases again. The spin-polarization of doped samples is lower than that of Fe3O4. Lower spin-polarization results in lower tunneling magnetoresistance. Fortunately, barrier was obtained by the second phase at the same time when sample was synthesized. The increase of appropriate barrier height leads to the change of tunneling magnetoresistance. 展开更多
关键词 FE3O4 dy-doped citrate precursor technique electrical and magnetic properties rare earths
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Optics and Spectral Investigation in Dy^(3+)-Doped Borate Glasses 被引量:2
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作者 Hou Yanyan Yang Hongxia +4 位作者 Lin Hai Ma Tiecheng Zhai Bin Wang Xiaojun Liu Xingren 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第6期661-661,共1页
Dy^3+-doped borate glasses (LBLB) with high effective visible fluorescence emission were synthesized. The absorption spectrum and fluorescence spectrum of this glass were measured and analyzed. By using J-O theory,... Dy^3+-doped borate glasses (LBLB) with high effective visible fluorescence emission were synthesized. The absorption spectrum and fluorescence spectrum of this glass were measured and analyzed. By using J-O theory, the oscillator strengths for some absorption transitions were calculated according to the absorption spectra. The intensity parameters Ω1 (t = 2, 4, 6) of Dy^3+ were determined by using a least-squares fitting approach, and the values are 4.04 × 10^-20, 1.30 × 10^-20 and 1.82 × 10^-20 cm, respectively. The root-mean-square deviation δrma was calculated. Under UV light excitation, Dy^3+-doped borate glasses (LBLB) emit intense yellowish white lights. The excitation spectrum indicates that argon laser is the effective excitation source in Dy^3+-doped LBLB glasses 展开更多
关键词 inorganic nonmetallic materials dy^3 ions borate glasses optical parameters luminescence spectra rare earths
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砂磨固相法快速制备Ca掺杂的BaTiO_(3)陶瓷及其结构和电性能研究
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作者 林彤 郭全胜 潘瑞琨 《湖北大学学报(自然科学版)》 CAS 2025年第1期153-162,共10页
Ca^(2+)可掺杂在BaTiO_(3)(BT)陶瓷的A及B位。本文中系统研究B位掺杂Ca元素对BaTiO_(3)陶瓷的相结构与微观形貌、介电性能、可靠性和铁电性能的影响。采用砂磨-固相反应-造粒-压片方法制备BaTi_(1-x)Ca_(x)O_(3)-x(BTC-x,其中x=0,0.01,0... Ca^(2+)可掺杂在BaTiO_(3)(BT)陶瓷的A及B位。本文中系统研究B位掺杂Ca元素对BaTiO_(3)陶瓷的相结构与微观形貌、介电性能、可靠性和铁电性能的影响。采用砂磨-固相反应-造粒-压片方法制备BaTi_(1-x)Ca_(x)O_(3)-x(BTC-x,其中x=0,0.01,0.02,0.03,0.04)陶瓷样品。随着Ca掺杂量的增加,陶瓷样品的晶粒尺寸先增大后减小,样品居里温度T_(c)持续降低,其中BTC-1样品具有较高和较宽的介电峰及极小的损耗。利用高温阻抗谱对样品进行了可靠性分析,可知BTC-2的电学失效的风险最分散。由P-E电滞回线可知:在掺杂样品中,BTC-2的P_(max)值最大,归因于其内部可供极化的空间电荷浓度高。综上所述,当Ca元素在BT的B位掺杂量较低时,BTC材料具有良好的介电性能及可靠性,能应用于片式多层陶瓷电容器(Multi-layer Ceramic Capacitors,MLCC)行业。 展开更多
关键词 固相烧结 B位掺杂 BaTiO_(3)陶瓷 介电性能
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碱金属离子共掺Sr_(3)Ga_(2)Ge_(4)O_(14)∶Dy^(3+)发光性能研究
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作者 白鑫 杨伟斌 +4 位作者 熊飞兵 李明明 胡正开 郭益升 傅兴宇 《人工晶体学报》 北大核心 2024年第1期97-106,共10页
本文采用高温固相法制备了一系列新型Sr_(3-x)Ga_(2)Ge_(4)O_(14)∶xDy^(3+)(x=0~0.40)(摩尔分数)及Sr_(2.68)Ga_(2)Ge_(4)O_(14)∶0.16Dy^(3+),0.16M^(+)(M=Li、Na、K)荧光粉。EDS能谱分析证实该荧光粉中存在Sr、Ga、Ge、O、Dy元素。系... 本文采用高温固相法制备了一系列新型Sr_(3-x)Ga_(2)Ge_(4)O_(14)∶xDy^(3+)(x=0~0.40)(摩尔分数)及Sr_(2.68)Ga_(2)Ge_(4)O_(14)∶0.16Dy^(3+),0.16M^(+)(M=Li、Na、K)荧光粉。EDS能谱分析证实该荧光粉中存在Sr、Ga、Ge、O、Dy元素。系列Sr_(3-x)Ga_(2)Ge_(4)O_(14)∶xDy^(3+)在350 nm光激发下产生了以568 nm为主波长,对应于^(4)F_(9/2)→^(6)H_(13/2)跃迁的强黄光发射。荧光粉的发射光谱显示,其发射强度随Dy^(3+)浓度的增加而变化,且当x=0.16时达到最强。共掺杂碱金属M(M=Li、Na、K)作为电荷补偿离子,其中Li^(+)对增加Dy^(3+)的发射强度效果最明显,使得荧光粉的发射强度提高到没有电荷补偿离子时的2倍。此外,随着Dy3+掺杂浓度的提高,荧光粉的荧光寿命不断减少。最后探讨了荧光粉Sr_(2.68)Ga_(2)Ge_(4)O_(14)∶0.16Dy^(3+),0.16Li^(+)的CIE色度坐标和热稳定性,其CIE色度坐标为(0.3719,0.4046),位于黄色区域,在453 K的发光强度约为其室温发光强度的95.5%。因此,Dy^(3+),Li^(+)共掺杂Sr_(3-x)Ga_(2)Ge_(4)O_(14)荧光粉是潜在的显示器件和白光LED器件候选材料。 展开更多
关键词 Sr_(3-x)Ga_(2)Ge_(4)O_(14)∶xdy^(3+) 高温固相法 电荷补偿剂 光致发光 热稳定性 荧光寿命
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