A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions: a spin-reorientation-like transition followed by a ferromagnetic-paramagneti...A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions: a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 50831006)the National Basic Research Program of China ("973" Project) (Grant No. 2010CB934603)
文摘A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions: a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.