Functional Nanostructures and Dynamic Materials through Self-Organization

1 Results Supramolecular chemistry is actively exploring systems undergoing self-organization.The design of molecular information controlled,"programmed"and functional self-organizing systems provides an original approach to nanoscience and nanotechnology.The spontaneous but controlled generation of well-defined,functional molecular and supramolecular architectures of nanometric size through self-organization represents a means of performing programmed engineering and processing of functional nanostruct...

Influences of Stress Wave Propagation upon Studying Dynamic Response of Materials at High Strain Rates

How the wave propagation analysis plays a key role in the studies of dynamic response of materials at high strain rates is analyzed. For the wave propagation technique, the followings are important: the loading and unloading constitutive relation presumed, the positions of the sensors embedded, the interactions between loading waves and unloading waves. For the split Hopkinson pressure bar (SHPB) technique, the assumption of one-dimensional stress wave propagation and the assumption of stress uniformity along the specimen should be satisfied. When the larger diameter bars are employed, the wave dispersion effects should be considered, including the high frequency oscillations, non-uniform stress distribution across the bar section, increase of rise time, and amplitude attenuation. The stress uniformity along the specimen is influenced by the reflection times in specimen, the wave impedance ratio of the specimen and the bar, and the waveform.

ON SOME BASIC PRINCIPLES IN DYNAMIC THEORY OF ELASTIC MATERIALS WITH VOIDS

According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In this paper, an important integral relation in terms of convolutions is given,which can be con- sidered as the generalized principle of virtual work in mechanics.Based on this relation,it is possible not on- ly to obtain the principle of virtual work and the reciprocal theorem in dynamic theory of elastic materials with voids,but also to derive systematically the complementary functionals for the eight-field,six-field, four-field and two-field simplified Gurtin-type variational principles.Furthermore,with this approach,the in- trinsic relationship among various principles can be explained clearly.

Field structure at mode Ⅲ dynamically propagating crack tip in elastic-viscoplastic materials

An elastic-viscoplastic mechanics model is used to investigate asymptotically the mode Ⅲ dynamically propagating crack tip field in elastic-viscoplastic materials. The stress and strain fields at the crack tip possess the same power-law singularity under a linear-hardening condition. The singularity exponent is uniquely determined by the viscosity coefficient of the material. Numerical results indicate that the motion parameter of the crack propagating speed has little effect on the zone structure at the crack tip. The hardening coefficient dominates the structure of the crack-tip field. However, the secondary plastic zone has little influence on the field. The viscosity of the material dominates the strength of stress and strain fields at the crack tip while it does have certain influence on the crack-tip field structure. The dynamic crack-tip field degenerates into the relevant quasi-static solution when the crack moving speed is zero. The corresponding perfectly-plastic solution is recovered from the linear-hardening solution when the hardening coefficient becomes zero.

Quasimolecular Dynamic Simulation for Bending Fracture of Laminar Composite Materials

Recently, quasimolecular dynamics has been successfully used to simulate the deformation characteristics of actual size solid materials. In quasimolecular dynamics, which is an attempt to bridge the gap between atomistic and continuum simulations, molecules are aggregated into large units, called quasimolecules, to evaluate large scale material behavior. In this paper, a 2-dimensional numerical simulation using quasimolecular dynamics was performed to investigate laminar composite material fractures and crack propagation behavior in the uniform bending of laminar composite materials. It was verified that under bending deformation laminar composite materials deform quite differently from homogeneous materials

Dynamics of a Rotating Sphere on Free Surface of Vibrated Granular Materials

We investigate the rotational dynamics of a low-density sphere on the free surface of a vertically vibrated granular material（VGM）. The dynamical behavior of the sphere is influenced by the external energy input from an electromagnetic shaker which is proportional to ε,where ε is equal to the ratio between the square of the dimensionless acceleration Γ and the square of the vibration frequency f of the container. Empirical results reveal that as the VGM transits from local-to-global convection,an increase in ε generally corresponds to an increase in the magnitudes of the rotational ω（RS） and translational v（CM） velocities of the sphere, an increase in the observed tilting angle θ（bed） of the VGM bed, and a decrease in the time t（wall） it takes the sphere to roll down the tilted VGM bed and hit the container wall. During unstable convection, an increase in ε results in a sharp decrease in the sphere＇s peak and mean ω（RS）,and a slight increase in t（wall）.For the range of ε values covered in this study, the sphere may execute persistent rotation, wobbling or jamming, depending on the vibration parameters and the resulting convective flow in the system.

Extension of Flow Behaviour and Damage Models for Cast Iron Alloys with Strain Rate Effect

Cast iron alloys with low production cost and quite good mechanical properties are widely used in the automotive industry.To study the mechanical behavior of a typical ductile cast iron(GJS-450)with nodular graphite,uni-axial quasi-static and dynamic tensile tests at strain rates of 10^(-4),1,10,100,and 250 s^(-1)were carried out.In order to investigate the influence of stress state on the deformation and fracture parameters,specimens with various geometries were used in the experiments.Stress strain curves and fracture strains of the GJS-450 alloy in the strain rate range of 10^(-4)to 250 s^(-1)were obtained.A strain rate-dependent plastic flow model was proposed to describe the mechanical behavior in the corresponding strain-rate range.The available damage model was extended to take the strain rate into account and calibrated based on the analysis of local fracture strains.Simulations with the proposed plastic flow model and the damage model were conducted to observe the deformation and fracture process.The results show that the strain rate has obviously nonlinear effects on the yield stress and fracture strain of GJS-450 alloys.The predictions with the proposed plastic flow and damage models at various strain rates agree well with the experimental results,which illustrates that the rate-dependent plastic flow and damage models can be used to describe the mechanical behavior of cast iron alloys at elevated strain rates.The proposed plastic flow and damage models can be used to describe the deformation and fracture analysis of materials with similar properties.

Coupled Dynamic Modeling of Rolls Model and Metal Model for Four High Mill Based on Strip Crown Control

The crown is a key quality index of strip and plate, the rolling mill system is a complex nonlinear system, the strip qualities are directly affected by the dynamic characteristics of the rolling mil. At present, the studies about the dynamic modeling of the rolling mill system mainly focus on the dynamic simulation for the strip thickness control system, the dynamic characteristics of the strip along the width direction and that of the rolls along axial direction are not considered. In order to study the dynamic changes of strip crown in the roiling process, the dynamic simulation model based on strip crown control is established. The work roll and backup roll are considered as elastic continuous bodies and the work roll and backup roll are joined by a Winkler elastic layer. The rolls are considered as double freely supported beams. The change rate of roll gap is taken into consideration in the metal deformation, based on the principle of dynamic conservation of material flow, the two dimensional dynamic model of metal is established. The model of metal deformation provides exciting force for the rolls dynamic model, and the roils dynamic model and metal deformation model couple together. Then, based on the two models, the dynamic model of rolling mill system based on strip crown control is established. The Newmark-13 method is used to solve the problem, and the dynamic changes of these parameters are obtained as follows： （1） The bending of work roll and backup roll changes with time; （2） The strip crown changes with time; （3） The distribution of rolling force changes with time. Take some cold tandem rolling mill as subject investigated, simulation results and the comparisons with experimental results show that the dynamic model built is rational and correct. The proposed research provides effective theory for optimization of device and technological parameters and development of new technology, plays an important role to improve the strip control precision and strip shape quality.

Deformation Stability of GH4033 Superalloy in the Hot Continuous Rolling Process Based on Dynamic Material Model and Finite Element Model

The flow stress behavior of GH4033 superalloy was determined by the hot compression tests at the temperatures of 1223-1473 K and the total strains of 0.6 with the strain rates of 0.001-30.0 s^(-1) by using cylindrical samples.The processing maps based on the dynamic material model(DMM)combined with the corresponding microstructure observations indicate the reasonable processing domain locating at the strain rates of 0.1-1.0 s^(-1) and the deformation temperature of 1273-1423 K.Meanwhile,the numerical simulation based on finite element model(FEM)described the variation of the effective strain,effective strain rate and the temperature for the core node,and unveiled the influence of the hot rolling parameters considering the initial temperature(T_(0))range of 1223-1473 K and the first-stand biting velocity(v_(0))range of 0.15-0.35 m·s^(-1).Furthermore,the deformation stability of GH4033 superalloy in the round rod hot continuous rolling(HCR)process is described and analyzed by coupling the three-dimensional(3-D)processing map,and the spatial trajectory lines were determined by the numerically simulated temperatures,the strains and the strain rates.Finally,the results show that the hot deformation stability of GH4033 can be achieved by the rolling process parameters located at T_(0)=1423 K and v_(0)=0.25 m·s^(-1).Additionally,the practical HCR processes as T_(0)=1423 K and v_(0)=0.15,0.25,0.35 m·s^(-1) were operated to verify the influence of the hot rolling parameters on the hot deformation stability by the microstructure observation of the final products.

Modeling and Simulation of Equipment Material Inventory Control Based on System Dynamics

The paper discusses how the inventory control of army equipment material runs sytematically under the two-level maintenance system,and establishes the inventory control model based on system dynamics.On the basis of modeling and simulation,the influence of different inventory upper limit on the whole system is studied,and the optimal inventory control mechanism under the model condition is foud.In addition,through the simulation of two replenishment strategies(s,S) and(T,s,S),the advantages and disadvantages and feasibility of each replenishment strategy are analyzed.

Study on the Dynamic Behavior of Tungsten Alloy at Strain Rates up to 5 000 s^(-1)

The dynamic stress-strain curves of 93% tungsten (W) alloy in the forged state at strain rates up to (5 000 s^(-1)) and in the temperature range from 223 K to 473 K were measured with the split Hopkinson pressure bar (SHPB) technique. Based on the above experimental data a dynamic constitutive equation considering the effects of strain rate, temperature and the special microstructure of such a kind of W-alloy was proposed. The numerical simulation for the experimental process with this constitutive equation was also carried out, the results show that the constitutive relationship constructed in this paper is very satisfactory for representing the dynamic responsive behavior of material..

Synergistic Dual Dynamic Bonds in Covalent Adaptable Networks

Covalent adaptable networks(CANs),comprising polymer networks crosslinked by dynamic covalent bonds(DCBs),have garnered considerable attention as sustainable materials.Mastering the stress relaxation of CANs is essential for controlling their viscoelastic properties.An unexpected acceleration of stress relaxation has been observed in CANs containing dual dynamic bonds.The dynamic behavior of the second dynamic bonds can accelerate stress relaxation and lower the relaxation activation energy of dual dynamic CANs compared to analogous CANs that rely on only one type of DCB.These findings complement current approaches that utilize catalysts or adjust network parameters.In this minireview,we summarize the synergistic acceleration effects in various CANs containing dual dynamic bonds.We classify these effects based on the second dynamic bonds,including noncovalent bonds,mechanical bonds,and the second DCBs.We also discuss the mechanisms behind this synergy.Finally,we highlight the challenges and offer perspectives on harnessing the synergistic effects of these dual dynamic systems to expand the chemistry and applications of CANs.

Dynamic polymeric materials based on reversible B–O bonds with dative boron–nitrogen coordination

To minimize the environmental pollution caused by polymeric waste,materials based dynamic chemistry have attracted extensive attention around the world.Various dynamic covalent bonds or noncovalent interactions have been employed to design multifunctional polymers with recyclability,reprocessablility,and sustainability.Among them,polymers based on reversible boron–oxygen(B–O)bonds have been widely investigated because of their unique properties.Particularly,lots of scientists have demonstrated that the combination with boron–nitrogen(B–N)coordination can effectively accelerate the dynamicity as well as enhance the stability of B–O bonds.Therefore,numerous polymers containing dynamic B–O bonds with dative B–N coordination have been designed and synthesized in recent years.These polymers exhibit excellent versatility and great potential for diverse applications such as biosensors,battery electrolytes,and artificial skins.This review provides an overview of the comprehensive influence of dynamic B–N coordination chemistry on B–O bonds in organoboron species and highlights the developments in the area of constructing boron‐containing polymeric materials with this interesting linkage.The design guidelines,existing challenges,and future perspectives in this burgeoning field are discussed and proposed.

Dynamically Securing the Data by^(1)O_(2)Sensitization of Fluorescent Composites with a High Latency and Uncrackable Features

Dynamic fluorescent materials play a crucial role in secure inks for data encryption;however,they are still plagued by issues such as photodegradation,poor latency,and susceptibility to unauthorized access.Herein,we propose a photochemically modulated dynamic fluorescent encryption system based on^(1)O_(2)sensitization of fluorescent composites,comprising a^(1)O_(2)-sensitive fluorophore(F2)and non-emissive polymers.After UV irradiation,in-situ generated^(1)O_(2)from the polymer effectively binds with F2 to form endoperoxides(F2EPO),resulting in a significant redshift in emission,up to 150 nm.The^(1)O_(2)concentration is closely related to the irradiation time,rendering different fluorescent colors in a time-gated fashion.Moreover,the emission of F2EPO can be regulated by polymer chemical structure,molecular weight,and crosslinking density.Relying on these merits,we develop a dynamic data encryption method with various non-emissive polymers as the data storage media,UV light irradiation as the data encoder,and F2 as the data decoder.UV light irradiation of diverse polymer solutions generates^(1)O_(2)at different concentrations,effectively encoding the data,which remains invisible under both UV and natural lights.The addition of F2 to these irradiated polymer solutions produces different redshifted fluorescence,enabling secure data decryption.Attributing to the non-emissive nature of the polymers,time-gated readout fashion,excellent latency of^(1)O_(2),and subtle interactions between^(1)O_(2)and F2,this data encryption is nearly undecipherable.This work offers an advantage data encryption approach beyond the reach of conventional fluorophores.

DETERMINATION OF MATERIAL PARAMETERS FOR COMPUTER SIMULATION OF SUPERPLASTIC FORMING PROCESSES

In order to analyze and simulate the complex super-plastic forming process by computer, a method of equal height bulging for determining material parameters m and K of the superplastic alloy is presented. The formulae related to the method are deduced in this paper. The accuracy of the method is available for evaluating the examples used in simulating the superplastic sheet-metal bulging processes.

Influence of Specimen Size on Compression Behavior of Cement Paste and Mortar under High Strain Rates

Static and dynamic compression tests were carried out on mortar and paste specimens of three sizes（Ф68 mm×32 mm,Ф59 mm×29.5 mm and Ф32 mm×16 mm）to study the influence of specimen size on the compression behavior of cement-based materials under high strain rates.The static tests were applied using a universalservo-hydraulic system,and the dynamic tests were applied by a spilt Hopkinson pressure bar（SHPB）system.The experimentalresults show that for mortar and paste specimens,the dynamic compressive strength is greater than the quasi-static one,and the dynamic compressive strength for specimens of large size is lower than those of smallsize.However,the dynamic increase factors（DIF）has an opposite trend.Obviously,both strain rate and size effect exist in mortar and paste.The test results were then analyzed using Weibull,Carpinteriand Ba？ant＇s size effect laws.A good agreement between these three laws and the test results was reached on the compressive strength.However,for the experimentalresults of paste and cement mortar,the size effect is not evident for the peak strain and elastic modulus of paste and cement mortar.

Strain-rate Sensitivity of Aluminum 2024-T6/TiB_2 Composites and Aluminum 2024-T6

Strain-rate sensitivities of 55vol%-65vol% aluminum 2024-T6/TiB2 composites and the corresponding aluminum 2024-T6 matrix were investigated using split Hopkinson pressure bar method. The experimental results showed that 55vol%-65vol% aluminum 2024-T6/TiB2 composites exhibited significant strain-rate sensitivities, which were three times higher than the strain-rate sensitivity of the aluminum 2024-T6 matrix. The strain-rate sensitivity of the aluminum 2024-T6 matrix composites rose obviously with increasing reinforcement content（up to 60%）, which agreed with that from the previous researches. But it decreased as the ceramic reinforcement content reached 65%. After high strain rates compression, a large number of dislocations and micro-cracks were found inside the matrix and the Ti B2 particles, respectively. These micro-cracks can accelerate the brittle fracture of the composites. The aluminum 2024-T6/Ti B2 composites showed various fracture characteristics and shear instability was the predominant failure mechanism under dynamic loading.

Investigation on method for measuring dynamic shear modulus of underwater acoustic structure materials

A new method is described to measure the dynamic shear modulus of underwater acoustic structure materials in a small anechoic water tank by using a broadband parametric source, a precise coordinate installation and techniques of signal processing in the frequency range of 20 kHz - 100 kHz. The typical size of material samples is 500×500 mm2. Basic principles, experiment installation and measured results are also presented

Strengthening and toughening styrene-butadiene rubber by mechanically interlocked cross-links

Styrene-butadiene rubber(SBR)is an indispensable material in modern society,and the necessity for enhanced mechanical properties in SBR persists,particularly to withstand the rigors of challenging environmental conditions.To surmount the limitations of conventional cross-linking modes,mechanical bonds stabilized by host-guest recognition are incorporated as the cross-linking points of SBR to form mechanically interlocked networks(MINs).Compared with covalently cross-linked network,the representative MIN exhibits superior mechanical performance in terms of elongation(1392%)and breaking strength(4.6 MPa),whose toughness has surged by 17 times.Dissociation of host-guest recognition and subsequent sliding motion provide an effective energy dissipation mechanism,and the release of hidden length is also beneficial to enhance toughness.Furthermore,the introduction of the rotaxane cross-links made the network more pliable and possess damping and elastic properties,which can return to initial state with one minute rest interval.We aspire that this direct introduction method can serve as a blueprint,offering valuable insights for the enhancement of mechanical properties in conventional commercial polymer materials.

Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond

Supramolecular polymer networks(SPNs)are celebrated for their dynamic nature,yet they often exhibit inadequate mechanical properties.Thus far,the quest to bolster the mechanical resilience of SPNs while preserving their dynamic character presents a formidable challenge.Herein,we introduce[2]rotaxane into SPN to serve as another cross-link,which could effectively enhance the mechanical robustness of the polymer network without losing the dynamic properties.Compared with SPN,the dually cross-linked network(DPN)demonstrates superior breaking strength,Young’s modulus,puncture force and toughness,underscoring its superior robustness.Furthermore,the cyclic tensile tests reveal that the energy dissipation capacity of DPN rivals,and in some cases surpasses,that of SPN,owing to the efficient energy dissipation pathway facilitated by[2]rotaxane.In addition,benefiting from stable topological structure of[2]rotaxane,DPN exhibits accelerated recovery from deformation,indicating superior elasticity compared to SPN.This strategy elevates the performance of SPNs across multiple metrics,presenting a promising avenue for the development of high-performance dynamic materials.