This paper has expounded the derivation of the Electron Cyclic Donate-Accept Catalysis Mechanism-ECDAM or Electron Orbital Deformation-Reversion Cyclic Catalysis Mechanism-EODRM and its three main arguments as well as...This paper has expounded the derivation of the Electron Cyclic Donate-Accept Catalysis Mechanism-ECDAM or Electron Orbital Deformation-Reversion Cyclic Catalysis Mechanism-EODRM and its three main arguments as well as three argument verifications. These three main arguments are: 1) There is a demarcation between catalysts and poisons, or promoters and poisons. 2) The relative activities of catalysts or poisons of poisons are closely related to the Electrical Negativity Values-ENV of catalysts or poison. 3) The activities or ENVs of catalysts are closely related to the chemical states of substance being added. The ECDAM or EODRM can also be extended to iron or metal base catalyst for selecting promoter, support and judging poison. It can also be extended to the study of the fire retardant of carbon materials. The author holds that the catalytic phenomenon should be physical phenomenon rather than chemical phenomenon or not completely chemical phenomenon at least.展开更多
多相催化反应机理、贵金属催化剂载体材料选用、铁基氨合成催化剂中氧化铝的毒害作用、钌基氨合成催化剂等多个问题值得再研究。由于根本不可信的化学反应模式循环催化机理(Cyclic Catalytic Mechanism of Chemical Reaction ModelCRMM...多相催化反应机理、贵金属催化剂载体材料选用、铁基氨合成催化剂中氧化铝的毒害作用、钌基氨合成催化剂等多个问题值得再研究。由于根本不可信的化学反应模式循环催化机理(Cyclic Catalytic Mechanism of Chemical Reaction ModelCRMM)长期占了主导思想,并被催化学术界推崇为"principle";基础理论出错,结果导致科研和生产中出现许多问题,大量资源被糟蹋,尤其是贵金属催化剂。展开更多
This is a validation article. The experimental results such as the relative catalytic activities of Fe, Co, Ni, Cu, Ag and SiO2 poisoning in the carbothermic reduction iron oxide show that the Electron Cyclic Donate-A...This is a validation article. The experimental results such as the relative catalytic activities of Fe, Co, Ni, Cu, Ag and SiO2 poisoning in the carbothermic reduction iron oxide show that the Electron Cyclic Donate-Accept Catalytic Mechanism-ECDAM or Electron Obital Deformation-Recovery cycle Catalysis Mechanism-EODRM are credible, and the Chemical Reaction Model Catalytic Cyclic Mechanism-CRMM such as the Oxygen Transfer Mechanism-OTT that is long and wide spread in the literature is completely unreliable. Because the Fe, Co, Ni, Cu, Ag were unlikely to react cyclic oxidation—reduction reaction with the carbon in the carbon reduction reaction tank.展开更多
文摘This paper has expounded the derivation of the Electron Cyclic Donate-Accept Catalysis Mechanism-ECDAM or Electron Orbital Deformation-Reversion Cyclic Catalysis Mechanism-EODRM and its three main arguments as well as three argument verifications. These three main arguments are: 1) There is a demarcation between catalysts and poisons, or promoters and poisons. 2) The relative activities of catalysts or poisons of poisons are closely related to the Electrical Negativity Values-ENV of catalysts or poison. 3) The activities or ENVs of catalysts are closely related to the chemical states of substance being added. The ECDAM or EODRM can also be extended to iron or metal base catalyst for selecting promoter, support and judging poison. It can also be extended to the study of the fire retardant of carbon materials. The author holds that the catalytic phenomenon should be physical phenomenon rather than chemical phenomenon or not completely chemical phenomenon at least.
文摘多相催化反应机理、贵金属催化剂载体材料选用、铁基氨合成催化剂中氧化铝的毒害作用、钌基氨合成催化剂等多个问题值得再研究。由于根本不可信的化学反应模式循环催化机理(Cyclic Catalytic Mechanism of Chemical Reaction ModelCRMM)长期占了主导思想,并被催化学术界推崇为"principle";基础理论出错,结果导致科研和生产中出现许多问题,大量资源被糟蹋,尤其是贵金属催化剂。
文摘This is a validation article. The experimental results such as the relative catalytic activities of Fe, Co, Ni, Cu, Ag and SiO2 poisoning in the carbothermic reduction iron oxide show that the Electron Cyclic Donate-Accept Catalytic Mechanism-ECDAM or Electron Obital Deformation-Recovery cycle Catalysis Mechanism-EODRM are credible, and the Chemical Reaction Model Catalytic Cyclic Mechanism-CRMM such as the Oxygen Transfer Mechanism-OTT that is long and wide spread in the literature is completely unreliable. Because the Fe, Co, Ni, Cu, Ag were unlikely to react cyclic oxidation—reduction reaction with the carbon in the carbon reduction reaction tank.
