Electro-oxidation of 3,4,3, 4-bis(ethylenedithio)-2,2,5,5-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)H2O. The single crystal structure of the...Electro-oxidation of 3,4,3, 4-bis(ethylenedithio)-2,2,5,5-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)H2O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω-1m-1.展开更多
基金This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034) and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy o
文摘Electro-oxidation of 3,4,3, 4-bis(ethylenedithio)-2,2,5,5-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)H2O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω-1m-1.
