Study on interaction between the coastal water, shelf water and Kuroshio water in the Huanghai Sea and East China Sea

The main processes of interaction between the coastal water, shelf water and Kuroshio water in the Huanghai Sea (HS) and East China Sea (ECS) are analyzed based on the observation and study results in recent years. These processes include the intrusion of the Kuroshio water into the shelf area of the ECS, the entrainment of the shelf water into the Kuroshio, the seasonal process in the southern shelf area of the ECS controlled alternatively by the Taiwan Strait water and the Kuroshio water intruding into the shelf area, the interaction between the Kuroshio branch water, shelf mixed water and modified coastal water in the northeastern ECS, the water-exchange between the HS and ECS and the spread of the Changjiang diluted water.

Chemical hydrography of coastal upwelling in the East China Sea

Based on the field data obtained during cruises on the shelf of the East China Sea from 1997 to 1999, seasonal variations of coastal upwelling on the inner shelf are discussed by using cross-shelf transect profiles and horizontal distributions of chemical and hydrographic variables. Results show that the coastal upwelling was year-round, but the areas and intensities of the upwelling were quite different in season. The coastal upwelling occurred in all of the coastal areas of the region in spring and summer, but in autumn only in the area off Zhejiang Province, and in winter in the area off Fujian Prov- ince. It was the strongest in summer and the weakest in winter. Geographically, it was the strongest in the area off Zhejiang Province and the weakest in the southmost or northmost parts of the East China Sea. The estimated nutrient fluxes upward into euphotic zone through coastal upwelling were quite large, es- pecially for phosphate, which contributed significantly to primary production and improved the nutrient structure of the coastal ecosystem in the East China Sea.

Measurement of the current and spectral analysis on the continental shelf in the East China Sea

Direct measurements of current velocity and water temperature were undertaken at the mooring Sta. M (125°29.38' N, 31°49.70' E) on the continental shelf area in the East China Sea in June 1999 by R/V Xiangyanghong 14. The relationship between various time series of oceanic fluctuations is calculated by spectral analysis. The major results are as follows: (1) an average (u,v) of (6.9,-3.0 cm/s) at the 30 m depth is obtained during the 9-day observation, and that at the 45 m depth is (3.7,-1.1 cm/s), i. e., the mean flows are southeastward at both the 30 and 45 m depths;the currents become stronger gradually during the observation period; this may be mainly attributed to the transition of the tidal currents from neap to spring; (2)semidiurnal fluctuation is the most dominant in the current fluctuations, and rotates mainly clockwise; in the next place, there is also diurnal fluctuation;the local inertial period is close to the period of diurnal fluctuation, and an inertial motion is clockwise; thus, local inertial motion combines with diurnal fluctuation, and makes the spectral peaks in clockwise components much higher than those in counterclockwise ones; except for the fluctuations of above main periods, there is also the peak at 3 d period for counterclockwise compo-nents in the upper and lower layers; (3) the calculation of cross spectra between two time series of current velocities at the 30 and 45 m depths shows that both the current fluctuations at the 30 and 45 m depths are much alike, i. e., they are synchro; this shows that the flow field here is rather vertically homogeneous; (4)power spectra of tempera-ture time series at both the 30 and 45 m depths show that the semidiurnal peak is the most predominant, and the second highest peak is the diurnal period; besides spectral peaks at above periods, there are also obvious spectral peaks at 6.8 h and 2 d; (5)plots of temperature time series at 16 , 30 , 35 , 45 and 50 m depths show that the temporal variations of temperature at these depths are synchro, which are like those in the velocity field; temperature records also show a gradual rise in temperature, which are also like those in the velocity field.

Distribution of Dissolved Inorganic Arsenic and Its Seasonal Variations in the Coastal Area of the East China Sea

Water samples were collected in the coastal area of the Changjiang Estuary on four cruises from August 2002 to May 2003. The seasonal variations of dissolved inorganic arsenic （DIAs） distributions were analyzed. The results showed that the distributions of DIAs were mainly influenced by Water （KSSW）. The concentration of the total dissolved the terrestrial input and the intrusion of the Kuroshio Subsurface inorganic arsenic （TDIAs） decreased consecutively from winter to summer, while it increased in autumn. The distributions of TDIAs showed some relationships with salinity and suspended particulate matter （SPM）. The relationships between DIAs speciation （including arsenite [ As（ Ⅲ ） ] and arsenate [ As（ Ⅴ ） ]）, biological activity and the availabilities of the phosphate were investigated in the study area for the cruise August 2002. The ratio of As （Ⅲ）/TDIAs increased with the decrease of phosphate concentrations. In the bottom water, the As（ Ⅲ ）/TDIAs ratio decreased with the increasing of N/P. The concentration of TDIAs decreased 28.7% approximately after the occurrence of harmful algal blooms （HAB） because of the uptake of arsenate by algae. Further study is needed about the arsenic source/sink relationships in their vertical or horizontal profiles and the uptake mechanism during the occurrence of harmful algal blooms.

Fouling community characteristics in subtropical coastal waters of the southwestern East China Sea

A fouling study was conducted in coastal waters southwest of the East China Sea between December 2013 and November 2014. A total of 84 species of fouling organisms belonging to 69 genera, 49 families, and 10 phyla were recorded over the entire year. The community composition was dominated by coastal warm-water species belonging to typical subtropical inner bay communities. The prosperous stage of settlement lasted from April to September, and the adhesion strength of the fouling organisms was the highest in summer. Sessile suspension feeders constituted the main core of settlement for the fouling community. Amphibalanus reticulatus was the most dominant and representative species of fouling organism, and other dominant species included Caprella equilibra, Ectopleura crocea, Anthopleura nigrescens, Stylochus ijimai, Spirobranchus kraussii, Crassostrea angulata, Perna viridis, Jassa falcata, Stenothoe valida, Sphaerozius nitidus, and Biflustra grandicella. The individuals in the fouling community showed a mutual dependence or constraint relationship due to competition for settlement space and food, and they exhibited a particular spatiotemporal distribution in accordance with adaptation to environmental factors. Temperature was the most important environmental factor determining the geographic distribution of fouling organisms. The temperature characteristics of species essentially reflect the differences in the fouling community composition in various climate zones. The species number, settlement stage, and settlement rate of fouling organisms are closely related to water temperature. Local natural environmental conditions（salinity, water currents, light, etc.） as well as human activity（such as aquaculture production） are all important factors affecting the settlement of fouling organisms.

Stratigraphic Sequence and Sedimentary Systems in the Middle-Southern Continental Slope of the East China Sea from Seismic Reflection Data: Exploration Prospects of Gas Hydrate

Many evidences for gas hydrate bearing sediments had been found in the continental slope of the East China Sea,such as bottom simulating reflections(BSRs),undersea gas springs,pyrite associated with methane leakage,mud diapirs/mud volcanos,bottom-water methane anomalies and so on.In this study,six key stratigraphic interfaces including T_0(seafloor),T_1(LGM,23 kyr B.P.),T_2(2.58 Myr),T_3(5.33 Myr),T_4(11.02 Myr)and T_5(16.12 Myr)were identified,and then five third-order sequences of SQIII1 to SQIII5 were divided.However,T5 in southern continental slope is not found,which shows that the middle-northern Okinawa Trough had begun to rift in the early Miocene,earlier than the southern segment.Four system tracts including lowstand systems tract(LST),transgressive systems tract(TST),highstand systems tract(HST)and falling stage systems tract(FSST)are further divided.The marine erosion interface of 11.02 Myr and regressive unconformity interface of 23 kyr B.P.indicate two large-scale sea level drop events in the research area.Seven typical seismic facies identified in the continental slope are continental shelf-edge deltas,littoral fluvial-delta plains,incised channels or submarine canyons,slope fans,submarine fans or coastal sandbars,littoral-neritic finegrained sediments,mud volcanos and some other geological bodies respectively.The minimum water depth for hydrate occurrence in the Okinawa Trough is 630 m,and the thickness of gas hydrate stability zone in continental slope is between 0 and 590 m.The calculated bottom boundary of hydrate stability zone is slightly deeper than BSRs on the seismic sections.The re-depositional turbidite sand bodies,such as canyon channels,slope fans and submarine fans developed in Quaternary strata,are the predominant hydrate reservoirs.According to developing process,the dynamic accumulation of hydrate systems can be divided into three evolutionary stages including canyon erosion and hydrate stability zone migration stage,sediments destabilizing and methane leakage stage,and channel filling and hydrate re-occurrence stage.

pCO_2 distribution and CO_2 flux on the inner continental shelf of the East China Sea during summer 2011

Measurements ofpH, total alkalinity （TA）, partial pressure of CO2 （pCO2） and air-sea CO2 flux （FCO2） were conducted for the inner continental shelf of the East China Sea （ECS） during August 2011. Variations in pCO2 distribution and FCO2 magnitude during the construction of the Three Gorges Dam （TGD） （2003-2009）, and the potential effects of the TGD on the air-sea CO2 exchange were examined. Results showed that the ECS acts as an overall CO2 sink during summer, with pCO2 ranging from 107 to 585 p.atm and an average FCO2 of -6.39 mmol/（m2·d）. Low pCO2 （〈350 μatm） levels were observed at the central shelf （28°-32°N, 123°-125.5°E） where most CO2-absorption occurred. HighpCO2 （〉420 μatm） levels were found in the Changjiang estuary and Hangzhou Bay which acted as the main CO2 source. A negative relationship between pCO2 and salinity （R2=0.722 0） in the estuary zone indicated the predominant effect of the Changjiang Diluted Water （CDW） on the seawater CO2 system, whereas a positive relationship （R2=0.744 8） in the offshore zone revealed the influence of the Taiwan Current Warm Water （TCWW）. Together with the historical data, our results indicated that the CO2 sink has shown a shift southwest while FC02 exhibited dramatic fluctuation during the construction of the TGD, which is located in the middle reaches of the Changjiang. These variations probably reflect fluctuation in the Changjiang runoff, nutrient import, phytoplankton productivity, and sediment input, which are likely to have been caused by the operations of the TGD. Nevertheless, the potential influence of the TGD on the CO2 flux in the ECS is worthy of further study.

Comprehensive Investigation of Submarine Slide Zones and Mass Movements at the Northern Continental Slope of South China Sea

Multi-beam bathymetry and seismic sequence surveys in the northern slope of the South China Sea reveal detailed geomorphology and seismic stratigraphy characteristics of canyons, gullies, and mass movements. Modern canyons and gullies are roughly elongated NNW–SSW with U-shaped cross sections at water depths of 400–1000 m. Mass movements include slide complexes, slide scars, and debris/turbidity flows. Slide complexes and slide scars are oriented in the NE–SW direction and cover an area of about 1790 and 926 km^2, respectively. The debris/turbidity flows developed along the lower slope. A detailed facies analysis suggests that four seismic facies exist, and the late Cenozoic stratigraphy above the acoustic basement can be roughly subdivided into three sequences separated by regional unconformities in the study area. The occurrence of gas hydrates is marked by seismic velocity anomalies, bottom-simulating reflectors, gas chimneys, and pockmarks in the study area. Seismic observations suggest that modern canyons and mass movements formed around the transition between the last glacial period and the current interglacial period. The possible existence and dissociation of gas hydrates and the regional tectonic setting may trigger instability and mass movements on the seafloor. Canyons may be the final result of gas hydrate dissociation. Our study aims to contribute new information that is applicable to engineering construction required for deep-water petroleum exploration and gas hydrate surveys along any marginal sea.

Characteristics and evaluation of Mesozoic source rocks in the southeastern East China Sea continental shelf

Source rocks are the material basis of oil and gas generation and determine the potential resources of exploration blocks and have important research value. This paper studies the lithology, thickness, and geochemistry of Mesozoic source rocks in the southeastern East China Sea continental shelf. The results show that the Mesozoic source rocks are mainly dark mudstone and coal-bearing strata. The total thickness of Lower–Middle Jurassic source rocks ranges from 100 m to 700 m, and that of Lower Cretaceous source rocks ranges from 50 m to 350 m. The overall thickness of Mesozoic source rocks is distributed in the NE direction and their thickness center is located in the Jilong Depression. The Lower–Middle Jurassic source rocks are mainly developed shallow marine dark mudstone and transitional coal measure strata. Those of the Lower Cretaceous are mainly mudstone of a fan delta front. Lower –Middle Jurassic and Lower Cretaceous hydrocarbon source rocks are dominated by type III kerogen, with Lower –Middle Jurassic hydrocarbon source rocks having high organic matter abundance and being medium –good hydrocarbon source rocks, while Lower Cretaceous hydrocarbon source rocks have relatively poor quality. From northwest to southeast, the vitrinite reflectance Ro of Mesozoic source rocks increases gradually. Source rocks in the study area are divided into three types. The first hydrocarbon-generating area is mainly located in the southeastern region of the study area, and the Jilong Depression is the hydrocarbongenerating center. The results of this study can provide a basis for exploration of Mesozoic oil and gas resources in the southeastern East China Sea continental shelf.

Geothermal investigation of the thickness of gas hydrate stability zone in the north continental margin of the South China Sea

The exploration of unconventional and/or new energy resources has become the focus of energy research worldwide,given the shortage of fossil fuels.As a potential energy resource,gas hydrate exists only in the environment of high pressure and low temperature,mainly distributing in the sediments of the seafloor in the continental margins and the permafrost zones in land.The accurate determination of the thickness of gas hydrate stability zone is essential yet challenging in the assessment of the exploitation potential.The majority of previous studies obtain this thickness by detecting the bottom simulating reflectors（BSRs） layer on the seismic profiles.The phase equilibrium between gas hydrate stable state with its temperature and pressure provides an opportunity to derive the thickness with the geothermal method.Based on the latest geothermal dataset,we calculated the thickness of the gas hydrate stability zone（GHSZ） in the north continental margin of the South China Sea.Our results indicate that the thicknesses of gas hydrate stability zone vary greatly in different areas of the northern margin of the South China Sea.The thickness mainly concentrates on 200–300 m and distributes in the southwestern and eastern areas with belt-like shape.We further confirmed a certain relationship between the GHSZ thickness and factors such as heat flow and water depth.The thickness of gas hydrate stability zone is found to be large where the heat flow is relatively low.The GHSZ thickness increases with the increase of the water depth,but it tends to stay steady when the water depth deeper than 3 000 m.The findings would improve the assessment of gas hydrate resource potential in the South China Sea.

Vertical Structure of the Tidal Currents on the Continental Shelf of the East China Sea

The available data on tidal currents spanning periods greater than six months for the continental shelf of the East China Sea (26°30.052′N, 122°35.998′E) were analyzed using several methods. Tidal Current Harmonic Analysis results demonstrated that semi-diurnal tides dominated the current movement. The tidal currents of the principal diurnal and semidiurnal rotated clockwise with depth, with the deflection of the major semi-axes to the right in the upper layer and to the left in the lower layer. The vertical structures of two principal semi-diurnal constituents-M2 and S2-were similar, which indicates that the tidal currents are mainly barotropic in this area. The main features of the variation of the four principal tidal constituents with depth demonstrate that the currents in this region are influenced by the upper and lower boundary layers. Therefore, the tidal constituents of the shallow water are similar. Different vertical modes were calculated based on the Empirical Orthogonal Function (EOF) analysis of the Eastern and Northern components of the tidal currents, with a variance contribution for the zero-order model of at least 90%. The variance contribution of the baroclinic model is minimal, which further reveals a strong barotropic character for the tidal currents of this region.

Distribution and Characteristics of Hazardous Geological Features in the Marine Coastal and Offshore Areas of Zhejiang Province, East China Sea

Newly acquired high-resolution shallow seismic profiles(7069 km in length) in the coastal and offshore areas of Zhejiang Province, East China Sea, China, have revealed eight marine hazardous geological features: shallow gas, sand ridges, erosion ditches, scarps, irregular bedrock features, underwater shoals, buried paleo-channels, and submarine deltas. Based on the seismic profiles, we have constructed a marine geological map of these hazardous features. Shallow gas accumulations are common and occur mainly in two separate nearshore regions that cover 4613 and 3382 km^2 respectively. There are also scattered shallow gas accumulations in the offshore area, typically accompanied by paleo-channels that occur mainly in the middle of the study area. Sand ridges, erosion ditches, scarps, and irregular bedrock features are found mainly in the northeast of the study area in association with each other. In the southeastern part of the study area, the sand ridges have a linear form and trend NW–SE, representing the western part of the linear sand ridges in the East China Sea. The maximum slope gradient is 1?, which suggests that this area is prone to landslides. These hazardous marine geological features are important to marine and engineering activities in this region.

Analysis of Cu,Co,V and Zn in Coastal Waters of the East China Sea by Inductively Coupled Plasma Mass Spectrometry(ICP-MS)

In this study, a simple method for the simultaneous determination of trace metals(Cu, V, Co, Zn) in coastal seawater using the Mg(OH)2 coprecipitation inductively coupled plasma mass spectrometry(ICP-MS) was developed. This multi-element method enables the simultaneous extraction of four metals, particularly Co and V. The recoveries of Cu, Co, V and Zn after Mg(OH)2 coprecipitation were 73%, 96%, 94% and 92%, which means that our procedure was well-suited to the determination of these four trace metals. The detection limits were 3.81, 0.18, 6.09 and 1.91 nmol L-1, respectively. Then, applying this method to the simultaneous determination of these four metals in coastal water samples from the East China Sea revealed that the concentrations of Cu, Zn, Co and V were higher in bottom waters compared to water at other depths, and higher concentrations were generally observed at the Yangtze River estuary. Additionally, example vertical profiles of dissolved trace metal concentrations for the East China Sea in spring and autumn are compared. These findings indicate that Zn had the greatest seasonal variation followed by Cu, V and Co. For Zn and Co, the concentrations were higher during spring than during autumn. For Cu and V, the seasonal variation in the concentrations was opposite.

Cross-shelf transport induced by coastal trapped waves along the coast of East China Sea

Cross-shelf transport is important due to its role in the transport of nutrients, larvae, sediments, and pollutants. The role of coastal trapped waves(CTWs) and their contribution to the cross-shelf transport is presently unknown. The impact of wind-driven CTWs on the structure of the cross-shelf currents and transport is investigated in the East China Sea(ECS) starting from theory. The cross-shelf currents are divided into four terms: the geostrophic balance(GB) term, the second-order wave(SOW) term, the bottom friction(BF) term and Ekman(EK) term, as well as three modes: the Kelvin wave(KW) mode, the first shelf wave(SW1) mode and the second shelf wave(SW2) mode. Comparison among these decompositions shows that(1) for the four terms, the effect of the GB and EK terms is continual, while that of the BF term is confi ned to 60–240 km of fshore, and the contribution of the SOW term can be ignored;(2) for the three modes, the KW and SW1 modes are dominant in cross-shelf transport. The results show that the total cross-shelf transport travels onshore under idealized wind stress on the order of 10^(-1), and it increases along the cross-shelf direction and peaks about-0.73 Sv at the continental shelf margin. With the increase of linear bottom friction coeffi cient, the cross-shelf transport declines with distance with the slope becoming more uniform.

The continental shelf wave of the East China Sea and its effect on the Kuroshio

The free shelf wave theory is applied to the practical case of the continental shelf in the East China Sea to analyse the effects of the shelf wave on the Kuroshio. The results indicate that the shelf wave in lower frequency travels from north to south and its phase velocity is proportional to the Kuroshio's current velocity) the maximum current velocity of the Kuroshio lies at the continental margin. The analytical solutions obtained indicate that the hydrodynamic characters of the sea region over the shelf present band structure. The horizontal motion ( x -component) caused by the shelf wave at the margin may be one of the causes for generating wavy pattern of the Kuroshio's axis .

Transport patterns of micro nutrient elements from the continental shelf of the East China Sea to the Kuroshio area

On the basis of the in situ data of DO2, pH, SiO2. PO4-P, NO3-N and NO2-N collected in the north of the East China Sea during 1987-1988, the following points are mainly expounded.1.The inorgonic nutrients are obviously affected by continent runoff in the north of the East China Sea. Their distributions are characteristic of its distribution of terrigenous materials.2.There are three transport paths of nutrients from the shelf to the Kuroshio area. The first is mixing-diffusing-advec-tion and upwelling process, the process of biology and biochemistry belongs to the second, and the sinking process is the last one.3.The swing of the Kuroshio axis affectes both the range of the migration of substances through mixing-diffusing-advec-tion process and the upwelling degree of the subsurface Kuroshio water to the shelf.4.Most part of the substances sink as macroparticles to the deep layer before reaching the Kuroshio area.

Sedimentary Environment Analysis of Ancient Sand Ridges from Zk23 Hole in the East China Sea

Abstract： Based on the analysis of core samples from the hole of Zk23 in the East China Sea Continental Shelf and by means of sedimentary stratigraphy, biostratigraphy and chronostratigraphy, the authors consider that the fine-sand deposition in borehole was part of buried ancient estuary sand ridges of the Yangtze River. The deposition history of study area around the hole before and after the glacial period as well as postglacial period is made clear after our research： （1） the estuarine sublayer -undersea delta facies strata was deposited under the fast sea level rise about 15 kaB.P; （2） sand ridges mostly consisting of fine-sand, were formed when the sea level was the fluctuant range of 60 - 80 m of isoba during the deglacial period around 15 - 12 kaB.P; （3） first silty clay and clay silt strata above the sand ridges were deposited during the period when the sea level rose fast from 12 to 7 kaB.P, and then it keeps stable to the present.

Late Quaternary sedimentary environmental evolution offshore of the Hangzhou Bay,East China——implications for sea level change and formation of Changjiang alongshore current

This study focuses on sedimentary environmental changes offshore of Hangzhou Bay, East China, since the Late Quaternary. AMS ^14C ages from core CJK10, lithologies, distribution of foraminifera, heavy minerals, and S and C1 elements show a fluvial terrace environment during -23.2-11.0 cal ka BP; a littoral to tidal-flat environment during 11.0-10.2 cal ka BP; and a shallow marine environment with a relatively low sedimentation rate （0.1-0.22 cm/a） since 4.3 cal ka BP. High depositional rates （-1.6 cm/a） from 10.9 to 10.2 cal ka BP resulted from sufficient accommodation space created by rapid sea level rise from -44 m to -33 m, from high sediment delivery by local rivers, and effective trapping of sediments by tidal-flat vegetation. The rate of sea level rise was variable; relatively high from 10.9 to 10.6 cal ka BP （2.1 cm/a）, and lower since 10.6 cal ka BP （1.2 cm/a）. The Changjiang alongshore current crossed the Hangzhou Bay to form the mud wedge on the inner shelf of the East China Sea later than 9.4 cal ka BP. The CJK10 site was a tide-dominated shelf environment and experienced erosion from approximately 9.4-9.2 cal ka BP to 4.3 cal ka BP. The depositional hiatus was caused by the Changjiang alongshore current, which was relatively weak during 9.4-7.5 cal ka BP and increased in strength during -7.5-4 cal ka BP. From -4.3 cal ka BP, a large amount of sediment from the Changjiang River was partly deposited on the continental shelf of Hangzhou Bay with some transported southward. Therefore, this study clarifies the history of Changjiang-derived sediment dispersal and deposition, although a detailed record of the changes in the Chang3iang alongshore current since 4.3 cal ka BP is difficult to obtain because of the scarcity of evidence.

The circulation in the southern Huanghai Sea and northern East China Sea in June 1999

On the basis of hydrographic data and current measurement (the mooring system, vessel-mounted ADCP and toward ADCP) data obtained in June 1999, the circulations in the southern Huanghai Sea (HS) and northern East China Sea (ECS) are computed by using the modified inverse method. The Kuroshio flows northeastward through eastern part of the investigated region and has the main core at Section PN, a northward flow at the easternmost part of Section PN, a weaker anti-cyclonic eddy between these two northward flows, and a weak cyclonic eddy at the western part of Section PN. The above current structure is one type of the current structures at Section PN in ECS. The net northward volume transport (VT) of the Kuroshio and the offshore branch of Taiwan Warm Current (TWCOB) through Section PN is about 26.2 x 10(6) m(3)/s in June 1999. The VT of the inshore branch of Taiwan Warm Current (TWCIB) through the investigated region is about 0.4 x 10(6) m(3)/s. The Taiwan Warm Current (TWC) has much effect on the currents over the continental shelf. The Huanghai Sea Coastal Current (HSCC) flows southeastward and enters into the northwestern part of investigated region, and flows to turn cyclonically, and then it flows northeastward, due to the influences of the Taiwan Warm Current and topography. There is a cyclonic eddy south of Cheju Island where the Huanghai Sea Coastal Current flows to turn cyclonically. It has the feature of high dense and cold water. The uniform and cold water is occurred in the layer from about 30 m level to the bottom between Stations C306 and C311 at the northernmost Section C3. It is a southern part of the Huanghai Sea Cold Water Mass (HSCWM).